FR2895284B1 - Catalyseur supporte de forme irreguliere, non spherique et procede d'hydroconversion de fractions petrolieres lourdes en lit bouillonnant - Google Patents

Catalyseur supporte de forme irreguliere, non spherique et procede d'hydroconversion de fractions petrolieres lourdes en lit bouillonnant

Info

Publication number
FR2895284B1
FR2895284B1 FR0513166A FR0513166A FR2895284B1 FR 2895284 B1 FR2895284 B1 FR 2895284B1 FR 0513166 A FR0513166 A FR 0513166A FR 0513166 A FR0513166 A FR 0513166A FR 2895284 B1 FR2895284 B1 FR 2895284B1
Authority
FR
France
Prior art keywords
hydroconversioning
beds
irregular
supported catalyst
petroleum fractions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0513166A
Other languages
English (en)
Other versions
FR2895284A1 (fr
Inventor
Auberger Magalie Roy
Denis Guillaume
Stephane Kressmann
Loarer Jean Luc Le
Jean Francois Chapat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0513166A priority Critical patent/FR2895284B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to CA2634564A priority patent/CA2634564C/fr
Priority to UAA200809520A priority patent/UA88742C2/uk
Priority to PCT/FR2006/002765 priority patent/WO2007080288A1/fr
Priority to RU2008130097/04A priority patent/RU2414297C2/ru
Priority to EP06841968A priority patent/EP1986776B1/fr
Priority to US12/158,594 priority patent/US20090166260A1/en
Priority to CN200680053312.2A priority patent/CN101384364B/zh
Priority to PL06841968T priority patent/PL1986776T3/pl
Priority to AT06841968T priority patent/ATE460224T1/de
Priority to BRPI0620252A priority patent/BRPI0620252B1/pt
Priority to DE602006012882T priority patent/DE602006012882D1/de
Priority to JP2008546509A priority patent/JP5559969B2/ja
Priority to DK06841968.8T priority patent/DK1986776T3/da
Priority to SA6270479A priority patent/SA06270479B1/ar
Publication of FR2895284A1 publication Critical patent/FR2895284A1/fr
Application granted granted Critical
Publication of FR2895284B1 publication Critical patent/FR2895284B1/fr
Priority to US13/463,255 priority patent/US8618017B2/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0063—Granulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/10—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 with moving solid particles
    • C10G49/12—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 with moving solid particles suspended in the oil, e.g. slurries
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
FR0513166A 2005-12-22 2005-12-22 Catalyseur supporte de forme irreguliere, non spherique et procede d'hydroconversion de fractions petrolieres lourdes en lit bouillonnant Expired - Fee Related FR2895284B1 (fr)

Priority Applications (16)

Application Number Priority Date Filing Date Title
FR0513166A FR2895284B1 (fr) 2005-12-22 2005-12-22 Catalyseur supporte de forme irreguliere, non spherique et procede d'hydroconversion de fractions petrolieres lourdes en lit bouillonnant
BRPI0620252A BRPI0620252B1 (pt) 2005-12-22 2006-12-14 catalisador suportado de forma irregular, não esférica e processo de hidroconversão de frações petrolíferas pesadas
PCT/FR2006/002765 WO2007080288A1 (fr) 2005-12-22 2006-12-14 Catalyseur supporté de forme irreguliere , non spherique et procede d’ηydroconversion de fractions pétrolières lourdes
RU2008130097/04A RU2414297C2 (ru) 2005-12-22 2006-12-14 Катализатор на носителе нерегулярной, несферической формы и способ гидроконверсии тяжелых нефтяных фракций
EP06841968A EP1986776B1 (fr) 2005-12-22 2006-12-14 Catalyseur supporté de forme irreguliere , non spherique et procede d'hydroconversion de fractions pétrolières lourdes
US12/158,594 US20090166260A1 (en) 2005-12-22 2006-12-14 Irregularly shaped non-spherical supported catalyst, and a process for hydroconverting heavy oil fractions
CN200680053312.2A CN101384364B (zh) 2005-12-22 2006-12-14 不规则形状的非球形负载催化剂和重油馏分的加氢转化方法
PL06841968T PL1986776T3 (pl) 2005-12-22 2006-12-14 Katalizator na nośniku o postaci nieregularnej, niekulistej i sposób hydrokonwersji ciężkich frakcji ropy naftowej
CA2634564A CA2634564C (fr) 2005-12-22 2006-12-14 Catalyseur supporte de forme irreguliere, non spherique et procede d'hydroconversion de fractions petrolieres lourdes
UAA200809520A UA88742C2 (uk) 2005-12-22 2006-12-14 Каталізатор на носії нерегулярної, несферичної форми та спосіб гідрообробки і/або гідроконверсії вихідних важких вуглеводнів
DE602006012882T DE602006012882D1 (de) 2005-12-22 2006-12-14 Unregelmässig geformter, nicht kugelförmiger trägerkatalysator und verfahren zur hydrierenden konversion von schweren erdölfraktionen
JP2008546509A JP5559969B2 (ja) 2005-12-22 2006-12-14 不規則な形状の非球形の担持触媒および重質オイル留分の水素化変換方法
DK06841968.8T DK1986776T3 (da) 2005-12-22 2006-12-14 Katalysator på underlag, der er uregelmæssigt, ikke sfærisk formet, samt fremgangsmåde til hydrokonvertering af tunge oliefraktioner
AT06841968T ATE460224T1 (de) 2005-12-22 2006-12-14 Unregelmässig geformter, nicht kugelförmiger trägerkatalysator und verfahren zur hydrierenden konversion von schweren erdölfraktionen
SA6270479A SA06270479B1 (ar) 2005-12-22 2006-12-23 حفاز مدعم غير كروي وغير منتظم، وعملية للتحول المائي للأجزاء الزيتية الثقيلة
US13/463,255 US8618017B2 (en) 2005-12-22 2012-05-03 Irregularly shaped non-spherical supported catalyst, and a process for hydroconversion heavy oil fractions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0513166A FR2895284B1 (fr) 2005-12-22 2005-12-22 Catalyseur supporte de forme irreguliere, non spherique et procede d'hydroconversion de fractions petrolieres lourdes en lit bouillonnant

Publications (2)

Publication Number Publication Date
FR2895284A1 FR2895284A1 (fr) 2007-06-29
FR2895284B1 true FR2895284B1 (fr) 2009-06-05

Family

ID=36645764

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0513166A Expired - Fee Related FR2895284B1 (fr) 2005-12-22 2005-12-22 Catalyseur supporte de forme irreguliere, non spherique et procede d'hydroconversion de fractions petrolieres lourdes en lit bouillonnant

Country Status (4)

Country Link
US (1) US8618017B2 (fr)
CN (1) CN101384364B (fr)
FR (1) FR2895284B1 (fr)
UA (1) UA88742C2 (fr)

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Publication number Priority date Publication date Assignee Title
FR2913691B1 (fr) 2007-03-16 2010-10-22 Inst Francais Du Petrole Procede d'hydroconversion de charges hydrocarbonees lourdes en reacteur slurry en presence d'un catalyseur a base d'heteropolyanion
CN102041084B (zh) * 2009-10-21 2013-11-06 中国石油化工股份有限公司 一种重烃加氢组合工艺方法
RU2472583C1 (ru) * 2011-06-09 2013-01-20 Общество с ограниченной ответственностью Научно Производственная фирма "ОЛКАТ" Шариковый катализатор для гидроочистки нефтяных фракций и способ его приготовления
WO2015136390A1 (fr) * 2014-03-14 2015-09-17 Reliance Industries Limited Supports d'oxydes inorganiques stabilisés et adsorbants dérivés de ceux-ci pour la capture du dioxyde de carbone
FR3084267B1 (fr) * 2018-07-25 2021-10-08 Axens Alumine a acidite et structure de porosite optimales
CN111100679A (zh) * 2018-10-26 2020-05-05 中国石油化工股份有限公司 一种渣油加氢处理方法
CN113663699B (zh) * 2020-05-15 2024-05-07 中国石油化工股份有限公司 一种氧化铝载体及其制备方法
CN114471507B (zh) * 2020-10-27 2023-07-28 中国石油化工股份有限公司 一种催化载体材料及其制法与催化材料和应用
CN112701304B (zh) * 2021-01-07 2021-12-14 淮北德昇科技有限公司 一种海胆状P掺杂ZrMo2O8纳米催化剂的制备方法

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FR2496631B1 (fr) * 1980-12-23 1989-06-30 Rhone Poulenc Ind Procede de preparation d'agglomeres d'alumine
FR2528721B1 (fr) * 1982-06-17 1986-02-28 Pro Catalyse Ste Fse Prod Cata Catalyseur supporte presentant une resistance accrue aux poisons et son utilisation en particulier pour l'hydrotraitement de fractions petrolieres contenant des metaux
FR2534828B1 (fr) * 1982-10-21 1986-12-26 Pro Catalyse Catalyseurs a base d'alumine, de silice ou de silice-alumine, leur preparation et leur utilisation dans le domaine de l'hydrotraitement des huiles d'hydrocarbures
FR2538814B1 (fr) * 1982-12-30 1986-06-27 Inst Francais Du Petrole Procede de traitement d'une huile lourde ou d'une fraction d'huile lourde pour les convertir en fractions plus legeres
FR2538813A1 (fr) * 1982-12-31 1984-07-06 Inst Francais Du Petrole Procede d'hydrotraitement convertissant en au moins deux etapes une fraction lourde d'hydrocarbures contenant des impuretes soufrees et des impuretes metalliques
JP3674227B2 (ja) * 1997-03-14 2005-07-20 株式会社日立製作所 可搬メディアを収納する記憶装置
FR2764213B1 (fr) 1997-06-10 1999-07-16 Inst Francais Du Petrole Catalyseur d'hydrotraitement de charges hydrocarbonees dans un reacteur a lit fixe
FR2764298B1 (fr) * 1997-06-10 1999-07-16 Inst Francais Du Petrole Hydrotraitement de charges hydrocarbonees dans un reacteur en lit bouillonnant
FR2787040B1 (fr) 1998-12-10 2001-01-19 Inst Francais Du Petrole Hydrotraitement de charges hydrocarbonees dans un reacteur en lit bouillonnant
FR2867988B1 (fr) * 2004-03-23 2007-06-22 Inst Francais Du Petrole Catalyseur supporte dope de forme spherique et procede d'hydrotraitement et d'hydroconversion de fractions petrolieres contenant des metaux

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FR2895284A1 (fr) 2007-06-29
US20120245023A1 (en) 2012-09-27
CN101384364A (zh) 2009-03-11
US8618017B2 (en) 2013-12-31
UA88742C2 (uk) 2009-11-10
CN101384364B (zh) 2012-03-21

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