FR2868068A1 - Nouveaux composes soufres : utilisation comme agent de transfert pour la polymerisation radicalaire controlee de l'acide acrylique, polymeres obtenus et leurs applications - Google Patents

Nouveaux composes soufres : utilisation comme agent de transfert pour la polymerisation radicalaire controlee de l'acide acrylique, polymeres obtenus et leurs applications

Info

Publication number
FR2868068A1
FR2868068A1 FR0403197A FR0403197A FR2868068A1 FR 2868068 A1 FR2868068 A1 FR 2868068A1 FR 0403197 A FR0403197 A FR 0403197A FR 0403197 A FR0403197 A FR 0403197A FR 2868068 A1 FR2868068 A1 FR 2868068A1
Authority
FR
France
Prior art keywords
acrylic acid
radical polymerization
sulfur compounds
polymers obtained
controlled radical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR0403197A
Other languages
English (en)
Other versions
FR2868068B1 (fr
Inventor
Jean Marc Suau
Christian Jacquemet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Coatex SAS
Original Assignee
Coatex SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Coatex SAS filed Critical Coatex SAS
Priority to FR0403197A priority Critical patent/FR2868068B1/fr
Priority to PCT/FR2005/000702 priority patent/WO2005095466A1/fr
Priority to US10/594,520 priority patent/US7956211B2/en
Priority to TW094108930A priority patent/TW200604158A/zh
Priority to ARP050101198A priority patent/AR048114A1/es
Priority to UY28824A priority patent/UY28824A1/es
Publication of FR2868068A1 publication Critical patent/FR2868068A1/fr
Application granted granted Critical
Publication of FR2868068B1 publication Critical patent/FR2868068B1/fr
Priority to US13/084,775 priority patent/US8227633B2/en
Priority to US13/526,694 priority patent/US8470750B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C329/00—Thiocarbonic acids; Halides, esters or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/16—Sulfur-containing compounds
    • C04B24/161—Macromolecular compounds comprising sulfonate or sulfate groups
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2652—Nitrogen containing polymers, e.g. polyacrylamides, polyacrylonitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/40—Surface-active agents, dispersants

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Structural Engineering (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

L'invention concerne de nouveaux composés soufrés, leur fabrication par un procédé en milieux aqueux, leur utilisation comme agents de transfert dans un procédé de polymérisation radicalaire contrôlée dans l'eau de l'acide acrylique et/ou de l'acide acrylique avec des monomères hydrosolubles. Elle concerne aussi les polymères obtenus et leurs utilisations comme agents dispersants ou d'aide au broyage et/ou d'aide au cobroyage de matières minérales en suspensions aqueuses, et comme agents dispersants incorporés directement dans des formulations aqueuses contenant des matières minérales. L'invention concerne enfin les formulations de matières minérales ainsi obtenues.
FR0403197A 2002-03-23 2004-03-29 Nouveaux composes soufres : utilisation comme agent de transfert pour la polymerisation radicalaire controlee de l'acide acrylique, polymeres obtenus et leurs applications Expired - Fee Related FR2868068B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR0403197A FR2868068B1 (fr) 2004-03-29 2004-03-29 Nouveaux composes soufres : utilisation comme agent de transfert pour la polymerisation radicalaire controlee de l'acide acrylique, polymeres obtenus et leurs applications
US10/594,520 US7956211B2 (en) 2004-03-29 2005-03-23 Trithiocarbonate derivatives and the use thereof in the form of transfer agents for acrylic acid controlled radical polymerisation
TW094108930A TW200604158A (en) 2004-03-29 2005-03-23 New sulphur compounds: use as transfer agents for controlled radical polymerisation of acrylic acid, polymers obtained and applications thereof
PCT/FR2005/000702 WO2005095466A1 (fr) 2004-03-29 2005-03-23 Derives du trithiocarbonate et leur utilisation comme agents de transfert pour la polymerisation radicalaire controlee de l’ acide acrylique
ARP050101198A AR048114A1 (es) 2004-03-29 2005-03-28 Nuevos compuestos azufrados: uso como agentes de transferencia para la polimerizacion radicalaria controlada del acido acrilico, polimeros obtenidos y sus aplicaciones.
UY28824A UY28824A1 (es) 2004-03-29 2005-03-29 Nuevos compuestos azufrados: uso como agentes de transferencia para la polimerización radicalaria controlada del ácido acrílico, polímeros obtenidos y sus aplicaciones
US13/084,775 US8227633B2 (en) 2004-03-29 2011-04-12 Trithiocarbonate derivatives and the use thereof in the form of transfer agents for acrylic acid controlled radical polymerisation
US13/526,694 US8470750B2 (en) 2002-03-23 2012-06-19 Trithiocarbonate derivatives and the use thereof in the form of transfer agents for acrylic acid controlled radical polymerisation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0403197A FR2868068B1 (fr) 2004-03-29 2004-03-29 Nouveaux composes soufres : utilisation comme agent de transfert pour la polymerisation radicalaire controlee de l'acide acrylique, polymeres obtenus et leurs applications

Publications (2)

Publication Number Publication Date
FR2868068A1 true FR2868068A1 (fr) 2005-09-30
FR2868068B1 FR2868068B1 (fr) 2006-07-14

Family

ID=34945530

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0403197A Expired - Fee Related FR2868068B1 (fr) 2002-03-23 2004-03-29 Nouveaux composes soufres : utilisation comme agent de transfert pour la polymerisation radicalaire controlee de l'acide acrylique, polymeres obtenus et leurs applications

Country Status (6)

Country Link
US (3) US7956211B2 (fr)
AR (1) AR048114A1 (fr)
FR (1) FR2868068B1 (fr)
TW (1) TW200604158A (fr)
UY (1) UY28824A1 (fr)
WO (1) WO2005095466A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2921477A3 (fr) * 2010-01-27 2015-11-25 Mitsubishi Rayon Co., Ltd. Nouvel agent de transfert de chaîne et polymérisation d'émulsion utilisant celui-ci

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0814541A2 (pt) * 2007-07-13 2015-01-27 Kemira Oyj Dispersantes minerais e métodos para preparar pastas minerais usando os mesmos
EP2178832B1 (fr) * 2007-08-09 2018-01-17 The Lubrizol Corporation Procédé de production de dérivés de trithiocarbonate substitués
EP2143688B1 (fr) 2008-07-07 2016-09-07 Omya International AG Procédé de fabrication de suspensions aqueuses de carbonate de calcium et suspensions obtenues ainsi que leurs utilisations
EP2182011A1 (fr) * 2008-10-29 2010-05-05 Basf Se Procédé de préparation de solutions aqueuses d'acide polyacrylique par polymerisation radicalaire contrôlée
FR2942477B1 (fr) * 2009-02-25 2012-03-30 Coatex Sas Procede de neutralisation d'un polymere acrylique hydrosoluble par au moins un agent monovalent et au moins un agent divalent, polymeres obtenus.
FR2972649B1 (fr) 2011-03-18 2013-03-15 Coatex Sas Procede de broyage de carbonate de calcium dans l'eau en presence d'une solution de polymere acrylique et d'un sel alcalin de carbonate fabrique in situ dans ladite solution
EP2712895B1 (fr) 2012-09-26 2016-05-18 Omya International AG Suspensions de matières minérales aqueuses rhéologiquement stables comprenant des polymères organiques présentant une teneur en composé organique volatile (cov) réduite
FR2995899B1 (fr) 2012-09-26 2014-10-03 Coatex Sas Procede de polymerisation de l'acide (meth)acrylique en solution, solutions de polymeres obtenues et leurs utilisations.
FR3012462B1 (fr) 2013-10-31 2016-01-01 Arkema France Compositions stables de poly (3,4-ethylenedioxythiophene) et de stabilisants anioniques a acidite limitee
FR3013711B1 (fr) 2013-11-26 2015-12-11 Coatex Sas Procede de polymerisation de l'acide (meth)acrylique en solution, solutions de polymeres obtenues et leurs utilisations
FR3015490B1 (fr) * 2013-12-20 2016-01-15 Coatex Sas Procede de polymerisation de l'acide (meth)acrylique en solution
FR3027905B1 (fr) 2014-10-29 2016-12-09 Coatex Sas Procede de polymerisation de l'acide (meth)acrylique en solution.
EP3018151A1 (fr) 2014-11-06 2016-05-11 Universiteit Gent Procédé de préparation de polymères raft inertes
FR3029528B1 (fr) 2014-12-03 2018-05-11 Coatex Agents d'aide a la dispersion et/ou au broyage du kaolin en suspension aqueuse, suspensions aqueuses obtenues et leurs utilisations
FR3029524B1 (fr) 2014-12-08 2018-03-02 Coatex Procede continu d'esterification et ou d'amidification, sans solvant organique, d'un homopolymere ou copolymere acide
CN104592072A (zh) * 2015-01-14 2015-05-06 中科院广州化学有限公司 一种不对称三硫代碳酸酯型raft试剂及其制法与应用
BR112017023973A2 (pt) 2015-05-08 2018-07-17 Lubrizol Corp agentes de transferência de cadeia solúveis em água
WO2018081964A1 (fr) 2016-11-02 2018-05-11 Basf Se Polymères d'acide acrylique neutralisés par des ions sodium et calcium et présentant une étroite distribution des masses moléculaires
CN106750055A (zh) * 2016-11-25 2017-05-31 合众（佛山）化工有限公司 一种raft技术合成的嵌段聚合物分散剂
FR3069548B1 (fr) * 2017-07-28 2019-08-02 Coatex Composition polymerique aqueuse et copolymere
FR3069546B1 (fr) * 2017-07-28 2020-09-25 Coatex Sas Composition polymerique aqueuse et copolymere
FR3069547B1 (fr) * 2017-07-28 2019-08-23 Coatex Composition polymerique aqueuse et copolymere
CA3129103A1 (fr) 2019-02-11 2020-08-20 Dow Global Technologies Llc Procede de polymerisation par transfert d'iode inverse et compositions en resultant
BR112021013425A2 (pt) 2019-02-11 2021-09-21 Dow Global Technologies Llc Método de produção de um polímero de ácido (met)acrílico, e, solução de polímero de ácido (met)acrílico
WO2021228928A1 (fr) 2020-05-13 2021-11-18 Basf Se Dispersions de pigment exemptes de biocide et leurs méthodes de préparation
WO2022214567A1 (fr) 2021-04-09 2022-10-13 Basf Se Utilisation de polyéthers pour dispersions de pigments
CN114790262B (zh) * 2022-04-26 2023-06-09 北京科技大学 一种碱性环境可溶树脂及其制备方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD217214A1 (de) * 1983-05-02 1985-01-09 Jenapharm Veb Verfahren zur herstellung von trithiocarbonato-verbindungen
WO2001060792A1 (fr) * 2000-02-16 2001-08-23 Noveon Ip Holdings Corp. ACIDE S,S'-BIS-(α, α'- DISUBSTITUE - α' - ACETIQUE)-TRITHIOCARBONATE ET DERIVES UTILISES COMME INITIATEUR AGENT DE TRANSFERT DE CHAINE AGENT DE TERMINAISON DE POLYMERISATIONS RADICALAIRES CONTROLEES ET LEUR PROCEDE DE PREPARATION
WO2002070571A1 (fr) * 2001-03-02 2002-09-12 Coatex S.A.S. Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres de faible polydispersite obtenus, et leurs applications
WO2003055919A1 (fr) * 2001-12-21 2003-07-10 University Of Sydney Dispersions aqueuses de particules de polymere

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Publication number Priority date Publication date Assignee Title
FR2842814B1 (fr) 2002-07-26 2004-10-22 Coatex Sas Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications.

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD217214A1 (de) * 1983-05-02 1985-01-09 Jenapharm Veb Verfahren zur herstellung von trithiocarbonato-verbindungen
WO2001060792A1 (fr) * 2000-02-16 2001-08-23 Noveon Ip Holdings Corp. ACIDE S,S'-BIS-(α, α'- DISUBSTITUE - α' - ACETIQUE)-TRITHIOCARBONATE ET DERIVES UTILISES COMME INITIATEUR AGENT DE TRANSFERT DE CHAINE AGENT DE TERMINAISON DE POLYMERISATIONS RADICALAIRES CONTROLEES ET LEUR PROCEDE DE PREPARATION
WO2002070571A1 (fr) * 2001-03-02 2002-09-12 Coatex S.A.S. Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres de faible polydispersite obtenus, et leurs applications
WO2003055919A1 (fr) * 2001-12-21 2003-07-10 University Of Sydney Dispersions aqueuses de particules de polymere

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Title
LAI, J.T. ET AL.: "Functional polymers from novel carboxyl-terminated trithiocarbonates as highly efficient RAFT agents", MACROMOLECULES, vol. 35, no. 18, 2002, pages 6754 - 6756, XP002313952 *
MAYADUNNE R T A ET AL: "Living polymers by the use of trithiocarbonates as reversible addition-fragmentation chain transfer (RAFT) agents: ABA triblock copolymers by radical polymerization in two steps", MACROMOLECULES, AMERICAN CHEMICAL SOCIETY. EASTON, US, vol. 33, 2000, pages 243 - 245, XP002244803, ISSN: 0024-9297 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2921477A3 (fr) * 2010-01-27 2015-11-25 Mitsubishi Rayon Co., Ltd. Nouvel agent de transfert de chaîne et polymérisation d'émulsion utilisant celui-ci
US9452978B2 (en) 2010-01-27 2016-09-27 Mitsubishi Rayon Co., Ltd. Chain transfer agent and emulsion polymerization using the same
US9676888B2 (en) 2010-01-27 2017-06-13 Mitsubishi Chemical Corporation Chain transfer agent and emulsion polymerization using the same

Also Published As

Publication number Publication date
US20120259083A1 (en) 2012-10-11
TW200604158A (en) 2006-02-01
WO2005095466A1 (fr) 2005-10-13
UY28824A1 (es) 2005-10-31
US8227633B2 (en) 2012-07-24
US20070179262A1 (en) 2007-08-02
US20110186773A1 (en) 2011-08-04
FR2868068B1 (fr) 2006-07-14
US8470750B2 (en) 2013-06-25
AR048114A1 (es) 2006-03-29
US7956211B2 (en) 2011-06-07

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