FR2819584B1 - Procede integre de separation d'air et de generation d'energie et installation pour la mise en oeuvre d'un tel procede - Google Patents

Procede integre de separation d'air et de generation d'energie et installation pour la mise en oeuvre d'un tel procede

Info

Publication number
FR2819584B1
FR2819584B1 FR0100403A FR0100403A FR2819584B1 FR 2819584 B1 FR2819584 B1 FR 2819584B1 FR 0100403 A FR0100403 A FR 0100403A FR 0100403 A FR0100403 A FR 0100403A FR 2819584 B1 FR2819584 B1 FR 2819584B1
Authority
FR
France
Prior art keywords
separator
air
installation
carrying
turbine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0100403A
Other languages
English (en)
Other versions
FR2819584A1 (fr
Inventor
Alain Guillard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8858754&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=FR2819584(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to FR0100403A priority Critical patent/FR2819584B1/fr
Priority to AT03300172T priority patent/ATE334365T1/de
Priority to ES01403286T priority patent/ES2246301T5/es
Priority to ES03300172T priority patent/ES2269951T3/es
Priority to DE60121830T priority patent/DE60121830T2/de
Priority to DE60112396T priority patent/DE60112396T3/de
Priority to AT01403286T priority patent/ATE301272T1/de
Priority to EP03300172A priority patent/EP1406052B1/fr
Priority to EP01403286.6A priority patent/EP1223395B2/fr
Priority to US10/041,628 priority patent/US6550234B2/en
Priority to JP2002004966A priority patent/JP2002243361A/ja
Publication of FR2819584A1 publication Critical patent/FR2819584A1/fr
Publication of FR2819584B1 publication Critical patent/FR2819584B1/fr
Application granted granted Critical
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04769Operation, control and regulation of the process; Instrumentation within the process
    • F25J3/04812Different modes, i.e. "runs" of operation
    • F25J3/04818Start-up of the process
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04151Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04163Hot end purification of the feed air
    • F25J3/04169Hot end purification of the feed air by adsorption of the impurities
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04527Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general
    • F25J3/04539Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the H2/CO synthesis by partial oxidation or oxygen consuming reforming processes of fuels
    • F25J3/04545Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the H2/CO synthesis by partial oxidation or oxygen consuming reforming processes of fuels for the gasification of solid or heavy liquid fuels, e.g. integrated gasification combined cycle [IGCC]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04563Integration with a nitrogen consuming unit, e.g. for purging, inerting, cooling or heating
    • F25J3/04575Integration with a nitrogen consuming unit, e.g. for purging, inerting, cooling or heating for a gas expansion plant, e.g. dilution of the combustion gas in a gas turbine
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04593The air gas consuming unit is also fed by an air stream
    • F25J3/04606Partially integrated air feed compression, i.e. independent MAC for the air fractionation unit plus additional air feed from the air gas consuming unit
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04866Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/04951Arrangements of multiple air fractionation units or multiple equipments fulfilling the same process step, e.g. multiple trains in a network
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04866Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/04951Arrangements of multiple air fractionation units or multiple equipments fulfilling the same process step, e.g. multiple trains in a network
    • F25J3/04957Arrangements of multiple air fractionation units or multiple equipments fulfilling the same process step, e.g. multiple trains in a network and inter-connecting equipments upstream of the fractionation unit (s), i.e. at the "front-end"
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00Processes or apparatus involving steps for expanding of process streams
    • F25J2240/80Hot exhaust gas turbine combustion engine

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Power Engineering (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
FR0100403A 2001-01-12 2001-01-12 Procede integre de separation d'air et de generation d'energie et installation pour la mise en oeuvre d'un tel procede Expired - Fee Related FR2819584B1 (fr)

Priority Applications (11)

Application Number Priority Date Filing Date Title
FR0100403A FR2819584B1 (fr) 2001-01-12 2001-01-12 Procede integre de separation d'air et de generation d'energie et installation pour la mise en oeuvre d'un tel procede
AT01403286T ATE301272T1 (de) 2001-01-12 2001-12-18 Integriertes verfahren zur luftzerlegung und energieerzeugung und anlage zur ausführung des verfahrens
EP01403286.6A EP1223395B2 (fr) 2001-01-12 2001-12-18 Procédé intégré de séparation d'air et de génération d'énergie
ES03300172T ES2269951T3 (es) 2001-01-12 2001-12-18 Procedimiento integrado de separacion de aire de instalacion para la puesta en practica de tal procedimiento.
DE60121830T DE60121830T2 (de) 2001-01-12 2001-12-18 Integriertes Verfahren zur Luftzerlegung und Energieerzeugung und Anlage zur Ausführung des Verfahrens
DE60112396T DE60112396T3 (de) 2001-01-12 2001-12-18 Integriertes Verfahren zur Luftzerlegung und Energieerzeugung
AT03300172T ATE334365T1 (de) 2001-01-12 2001-12-18 Integriertes verfahren zur luftzerlegung und energieerzeugung und anlage zur ausführung des verfahrens
EP03300172A EP1406052B1 (fr) 2001-01-12 2001-12-18 Procédé intégré de séparation d'air et installation pour la mise en oeuvre d'un tel procédé
ES01403286T ES2246301T5 (es) 2001-01-12 2001-12-18 Procedimiento integrado de separación de aire y de generación de energía
US10/041,628 US6550234B2 (en) 2001-01-12 2002-01-10 Integrated air-separation/energy-generation process and plant for implementing such a process
JP2002004966A JP2002243361A (ja) 2001-01-12 2002-01-11 インテグレートされた空気分離/エネルギ生産プロセス及びそのようなプロセスを実現するためのプラント

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0100403A FR2819584B1 (fr) 2001-01-12 2001-01-12 Procede integre de separation d'air et de generation d'energie et installation pour la mise en oeuvre d'un tel procede

Publications (2)

Publication Number Publication Date
FR2819584A1 FR2819584A1 (fr) 2002-07-19
FR2819584B1 true FR2819584B1 (fr) 2003-03-07

Family

ID=8858754

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0100403A Expired - Fee Related FR2819584B1 (fr) 2001-01-12 2001-01-12 Procede integre de separation d'air et de generation d'energie et installation pour la mise en oeuvre d'un tel procede

Country Status (7)

Country Link
US (1) US6550234B2 (fr)
EP (2) EP1223395B2 (fr)
JP (1) JP2002243361A (fr)
AT (2) ATE334365T1 (fr)
DE (2) DE60112396T3 (fr)
ES (2) ES2269951T3 (fr)
FR (1) FR2819584B1 (fr)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
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US7284362B2 (en) * 2002-02-11 2007-10-23 L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Étude et l'Exploitation des Procedes Georges Claude Integrated air separation and oxygen fired power generation system
US7739874B2 (en) * 2003-09-30 2010-06-22 Bhp Billiton Innovation Pty. Ltd. Power generation
FR2862128B1 (fr) * 2003-11-10 2006-01-06 Air Liquide Procede et installation de fourniture d'oxygene a haute purete par distillation cryogenique d'air
EP1544559A1 (fr) * 2003-12-20 2005-06-22 Linde AG Procédé et dispositif pour la séparation cryogénique d'air
US7197894B2 (en) * 2004-02-13 2007-04-03 L'air Liquide, Societe Anonyme A' Directorie Et Conseil De Survelliance Pour L'etude Et, L'exploltation Des Procedes Georges, Claude Integrated process and air separation process
US20060123844A1 (en) * 2004-12-09 2006-06-15 Patrick Le Bot Integrated process for the separation of air and an integrated installation for the separation of air
US20070101989A1 (en) * 2005-11-08 2007-05-10 Mev Technology, Inc. Apparatus and method for the conversion of thermal energy sources including solar energy
US7617687B2 (en) * 2006-02-28 2009-11-17 General Electric Company Methods and systems of variable extraction for gas turbine control
US7784288B2 (en) * 2006-03-06 2010-08-31 General Electric Company Methods and systems of variable extraction for compressor protection
FR2898645B1 (fr) * 2006-03-14 2008-08-22 L'air Liquide Compresseur a plusieurs etages, appareil de separation d'air comprenant un tel compresseur et installation
US8596075B2 (en) 2009-02-26 2013-12-03 Palmer Labs, Llc System and method for high efficiency power generation using a carbon dioxide circulating working fluid
EA024852B1 (ru) 2009-02-26 2016-10-31 Палмер Лэбз, Ллк Способ и устройство для сжигания топлива при высокой температуре и высоком давлении и соответствующие система и средства
US10018115B2 (en) 2009-02-26 2018-07-10 8 Rivers Capital, Llc System and method for high efficiency power generation using a carbon dioxide circulating working fluid
US20120067054A1 (en) 2010-09-21 2012-03-22 Palmer Labs, Llc High efficiency power production methods, assemblies, and systems
US8869889B2 (en) 2010-09-21 2014-10-28 Palmer Labs, Llc Method of using carbon dioxide in recovery of formation deposits
US8752391B2 (en) * 2010-11-08 2014-06-17 General Electric Company Integrated turbomachine oxygen plant
PL2776692T3 (pl) 2011-11-02 2016-11-30 Układ wytwarzania energii i odpowiedni sposób
CN107090317B (zh) 2012-02-11 2019-10-25 八河流资产有限责任公司 具有封闭的循环骤冷的部分氧化反应
JP6250332B2 (ja) 2013-08-27 2017-12-20 8 リバーズ キャピタル,エルエルシー ガスタービン設備
TWI691644B (zh) 2014-07-08 2020-04-21 美商八河資本有限公司 具改良效率之功率生產方法及系統
EP3438049B1 (fr) 2014-09-09 2021-11-03 8 Rivers Capital, LLC Procédé de production de dioxyde de carbone liquide à basse pression à partir d'un système de production d'énergie
US11231224B2 (en) 2014-09-09 2022-01-25 8 Rivers Capital, Llc Production of low pressure liquid carbon dioxide from a power production system and method
US10961920B2 (en) 2018-10-02 2021-03-30 8 Rivers Capital, Llc Control systems and methods suitable for use with power production systems and methods
MA40950A (fr) 2014-11-12 2017-09-19 8 Rivers Capital Llc Systèmes et procédés de commande appropriés pour une utilisation avec des systèmes et des procédés de production d'énergie
US11686258B2 (en) 2014-11-12 2023-06-27 8 Rivers Capital, Llc Control systems and methods suitable for use with power production systems and methods
KR102602774B1 (ko) 2015-06-15 2023-11-15 8 리버스 캐피탈, 엘엘씨 동력 생산 플랜트의 기동을 위한 시스템 및 방법
KR102204443B1 (ko) 2016-02-18 2021-01-18 8 리버스 캐피탈, 엘엘씨 메탄화를 포함하는 동력 생산을 위한 시스템 및 방법
PL3420209T3 (pl) 2016-02-26 2024-02-05 8 Rivers Capital, Llc Systemy i sposoby sterowania elektrownią
AU2017329061B2 (en) 2016-09-13 2023-06-01 8 Rivers Capital, Llc System and method for power production using partial oxidation
MX2020002368A (es) 2017-08-28 2020-09-14 8 Rivers Capital Llc Optimizacion de calor de bajo grado de ciclos de energia de co2 supercriticos recuperativos.
ES2970038T3 (es) 2018-03-02 2024-05-24 8 Rivers Capital Llc Sistemas y métodos para la producción de energía usando un fluido de trabajo de dióxido de carbono
EP4121638A4 (fr) * 2020-03-19 2024-04-03 Kellogg Brown & Root LLC Augmentation de puissance pour turbine à gaz

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JPH11343863A (ja) * 1998-06-02 1999-12-14 Hitachi Ltd ガス化複合発電プラント
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Also Published As

Publication number Publication date
DE60112396D1 (de) 2005-09-08
DE60112396T2 (de) 2006-06-01
US20020092306A1 (en) 2002-07-18
ATE334365T1 (de) 2006-08-15
FR2819584A1 (fr) 2002-07-19
JP2002243361A (ja) 2002-08-28
EP1406052B1 (fr) 2006-07-26
DE60121830D1 (de) 2006-09-07
US6550234B2 (en) 2003-04-22
EP1406052A2 (fr) 2004-04-07
ES2246301T5 (es) 2013-10-08
ES2246301T3 (es) 2006-02-16
EP1223395A1 (fr) 2002-07-17
ATE301272T1 (de) 2005-08-15
DE60121830T2 (de) 2007-03-29
DE60112396T3 (de) 2013-10-10
EP1223395B1 (fr) 2005-08-03
EP1406052A3 (fr) 2005-01-05
EP1223395B2 (fr) 2013-05-15
ES2269951T3 (es) 2007-04-01

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