FR2726819A1 - Procede pour reduire selectivement par echange d'ions, la concentration de l'une des especes chimiques presentes dans une solution - Google Patents
Procede pour reduire selectivement par echange d'ions, la concentration de l'une des especes chimiques presentes dans une solution Download PDFInfo
- Publication number
- FR2726819A1 FR2726819A1 FR9413644A FR9413644A FR2726819A1 FR 2726819 A1 FR2726819 A1 FR 2726819A1 FR 9413644 A FR9413644 A FR 9413644A FR 9413644 A FR9413644 A FR 9413644A FR 2726819 A1 FR2726819 A1 FR 2726819A1
- Authority
- FR
- France
- Prior art keywords
- solution
- resin
- percolated
- fraction
- volume
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005342 ion exchange Methods 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims description 43
- 230000008569 process Effects 0.000 title description 16
- 239000013626 chemical specie Substances 0.000 title 1
- 239000011347 resin Substances 0.000 claims abstract description 89
- 229920005989 resin Polymers 0.000 claims abstract description 89
- 230000008929 regeneration Effects 0.000 claims abstract description 42
- 238000011069 regeneration method Methods 0.000 claims abstract description 42
- 238000005325 percolation Methods 0.000 claims description 23
- 229910001416 lithium ion Inorganic materials 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 150000001768 cations Chemical class 0.000 claims description 15
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 14
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 11
- 229910052744 lithium Inorganic materials 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 10
- 229910001415 sodium ion Inorganic materials 0.000 claims description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 claims description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000003729 cation exchange resin Substances 0.000 claims description 2
- 229940023913 cation exchange resins Drugs 0.000 claims description 2
- 235000013305 food Nutrition 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 claims description 2
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 claims 2
- 239000000203 mixture Substances 0.000 abstract description 7
- 239000000243 solution Substances 0.000 description 72
- 150000001450 anions Chemical class 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229910001414 potassium ion Inorganic materials 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 102100021935 C-C motif chemokine 26 Human genes 0.000 description 1
- 101000897493 Homo sapiens C-C motif chemokine 26 Proteins 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010669 acid-base reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- -1 for example iron Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/26—Cation exchangers for chromatographic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/20—Anion exchangers for chromatographic processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9413644A FR2726819A1 (fr) | 1994-11-15 | 1994-11-15 | Procede pour reduire selectivement par echange d'ions, la concentration de l'une des especes chimiques presentes dans une solution |
| DE1995142421 DE19542421B4 (de) | 1994-11-15 | 1995-11-14 | Verfahren zur selektiven Verringerung der Konzentration eines in einer Lösung vorhandenen Ions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9413644A FR2726819A1 (fr) | 1994-11-15 | 1994-11-15 | Procede pour reduire selectivement par echange d'ions, la concentration de l'une des especes chimiques presentes dans une solution |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2726819A1 true FR2726819A1 (fr) | 1996-05-15 |
| FR2726819B1 FR2726819B1 (enrdf_load_stackoverflow) | 1997-02-28 |
Family
ID=9468798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR9413644A Granted FR2726819A1 (fr) | 1994-11-15 | 1994-11-15 | Procede pour reduire selectivement par echange d'ions, la concentration de l'une des especes chimiques presentes dans une solution |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE19542421B4 (enrdf_load_stackoverflow) |
| FR (1) | FR2726819A1 (enrdf_load_stackoverflow) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3101246A (en) * | 1960-10-14 | 1963-08-20 | David L Hansford | Recovery and separation of lithium values from salvage solutions |
| FR1361965A (fr) * | 1962-04-03 | 1964-05-29 | Benckiser Gmbh Joh A | Procédé de récupération sélective des ions métalliques à partir des bains de filage |
| FR1460644A (fr) * | 1965-08-27 | 1966-03-04 | Metallgesellschaft Ag | Procédé pour séparer les ions de métaux lourds, tels que le zinc, le cadmium, lefer, des ions d'alcalis dans des solutions neutres ou acides |
| EP0659481A2 (en) * | 1993-12-23 | 1995-06-28 | Praxair Technology, Inc. | Adsorbent production with lithium recovery |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4859343A (en) * | 1987-12-02 | 1989-08-22 | Lithium Corporation Of America | Sodium removal from brines |
-
1994
- 1994-11-15 FR FR9413644A patent/FR2726819A1/fr active Granted
-
1995
- 1995-11-14 DE DE1995142421 patent/DE19542421B4/de not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3101246A (en) * | 1960-10-14 | 1963-08-20 | David L Hansford | Recovery and separation of lithium values from salvage solutions |
| FR1361965A (fr) * | 1962-04-03 | 1964-05-29 | Benckiser Gmbh Joh A | Procédé de récupération sélective des ions métalliques à partir des bains de filage |
| FR1460644A (fr) * | 1965-08-27 | 1966-03-04 | Metallgesellschaft Ag | Procédé pour séparer les ions de métaux lourds, tels que le zinc, le cadmium, lefer, des ions d'alcalis dans des solutions neutres ou acides |
| EP0659481A2 (en) * | 1993-12-23 | 1995-06-28 | Praxair Technology, Inc. | Adsorbent production with lithium recovery |
Also Published As
| Publication number | Publication date |
|---|---|
| DE19542421A1 (de) | 1996-05-23 |
| DE19542421B4 (de) | 2005-06-16 |
| FR2726819B1 (enrdf_load_stackoverflow) | 1997-02-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2040811B1 (fr) | Procede de separation sequence multicolonnes | |
| FR2666996A1 (fr) | Methode de purification d'un aminoacide utilisant une resine echangeuse d'ions. | |
| FR2594431A1 (fr) | Procede pour le traitement d'une eau residuaire contenant de l'uranium et du fluor | |
| EP2227303B1 (fr) | Procede de separation sequence multicolonnes d'un derive metallique ionique | |
| JP4385407B2 (ja) | テトラアルキルアンモニウムイオン含有液の処理方法 | |
| FR2976280A1 (fr) | Procede de production d'une solution de chlorure de lithium a partir d'une saumure | |
| US4036751A (en) | Method of treating water containing chromate | |
| FR2503128A1 (fr) | Procede de clarification de l'eau et de regeneration du coagulant/adsorbant utilise dans ce procede | |
| JP2001169800A (ja) | 混床式糖液精製装置の再生法 | |
| FR2726819A1 (fr) | Procede pour reduire selectivement par echange d'ions, la concentration de l'une des especes chimiques presentes dans une solution | |
| FR2573757A1 (fr) | Procede de separation de l-phenylalanine d'une solution la contenant | |
| Maranon et al. | Preconcentration and removal of trace metals from water by apple waste | |
| JP3968678B2 (ja) | テトラアルキルアンモニウムイオン含有液の処理方法 | |
| WO2011074495A1 (ja) | テトラアルキルアンモニウムイオン除去廃液の再利用方法 | |
| JP2005002414A (ja) | 溶液中の貴金属の回収方法 | |
| EP0498743B1 (fr) | Procédé d'élimination du ruthenium contenu dans des solutions uranifères | |
| GB2558552A (en) | Method for regenerating ion exchange material | |
| JP2004136231A (ja) | 再生後のイオン交換樹脂の水洗方法 | |
| JP2000109453A (ja) | ベタイン及びアミノ酸の回収方法 | |
| JP2000192162A (ja) | パラジウム含有液からのパラジウム回収方法 | |
| JPS58174297A (ja) | 排煙脱硫排水の処理方法 | |
| WO2022064154A1 (fr) | Procede de purification avec recyclage des effluents | |
| Lee et al. | The use of ion exclusion chromatography as approved to the normal ion exchange chromatography to achieve a more efficient lysine recovery from fermentation broth | |
| JP2003190948A (ja) | バナジウム含有水のイオン交換方法および装置 | |
| FR2844151A1 (fr) | Procede de decalcification d'une solution aqueuse et utilisation de ce procede pour la decalcification de lactoserum ou d'un permeat d'ultrafiltration de lactoserum |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |
Effective date: 20140731 |