FR2509282A1 - Procede de separation des actinides et des lanthanides presents a l'etat trivalent, dans une solution aqueuse acide - Google Patents

Procede de separation des actinides et des lanthanides presents a l'etat trivalent, dans une solution aqueuse acide Download PDF

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Publication number
FR2509282A1
FR2509282A1 FR8113530A FR8113530A FR2509282A1 FR 2509282 A1 FR2509282 A1 FR 2509282A1 FR 8113530 A FR8113530 A FR 8113530A FR 8113530 A FR8113530 A FR 8113530A FR 2509282 A1 FR2509282 A1 FR 2509282A1
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FR
France
Prior art keywords
extractant
organic
organic solvent
actinides
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8113530A
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English (en)
French (fr)
Other versions
FR2509282B1 (enExample
Inventor
Michele Bonnin
Claude Musikas
Pierre Vitorge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat à l'Énergie Atomique et Aux Énergies Alternatives
Original Assignee
Commissariat a lEnergie Atomique CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR8113530A priority Critical patent/FR2509282A1/fr
Priority to EP82401250A priority patent/EP0070226B1/fr
Priority to DE8282401250T priority patent/DE3263252D1/de
Priority to US06/394,491 priority patent/US4496523A/en
Priority to CA000406707A priority patent/CA1197382A/en
Priority to JP57118718A priority patent/JPS5819453A/ja
Publication of FR2509282A1 publication Critical patent/FR2509282A1/fr
Application granted granted Critical
Publication of FR2509282B1 publication Critical patent/FR2509282B1/fr
Granted legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/007—Recovery of isotopes from radioactive waste, e.g. fission products
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G56/00—Compounds of transuranic elements
    • C01G56/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/34—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing sulfur, e.g. sulfonium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/40—Mixtures
    • C22B3/406—Mixtures at least one compound thereof being a heterocyclic compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Geology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacturing & Machinery (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
FR8113530A 1981-07-09 1981-07-09 Procede de separation des actinides et des lanthanides presents a l'etat trivalent, dans une solution aqueuse acide Granted FR2509282A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR8113530A FR2509282A1 (fr) 1981-07-09 1981-07-09 Procede de separation des actinides et des lanthanides presents a l'etat trivalent, dans une solution aqueuse acide
EP82401250A EP0070226B1 (fr) 1981-07-09 1982-07-02 Procédé de séparation des actinides et des lanthanides présents à l'état trivalent, dans une solution aqueuse acide
DE8282401250T DE3263252D1 (en) 1981-07-09 1982-07-02 Process for separating trivalent actinides from trivalent lanthanides in an acidic aqueous solution
US06/394,491 US4496523A (en) 1981-07-09 1982-07-02 Process for separating the actinides and lanthanides present in the trivalent state in an acid aqueous solution
CA000406707A CA1197382A (en) 1981-07-09 1982-07-06 Process for separating the actinides and lanthanides present in the trivalent state in an acid aqueous solution
JP57118718A JPS5819453A (ja) 1981-07-09 1982-07-09 酸性水溶液中に３価の状態で存在するアクチニドとランタニドの分離方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8113530A FR2509282A1 (fr) 1981-07-09 1981-07-09 Procede de separation des actinides et des lanthanides presents a l'etat trivalent, dans une solution aqueuse acide

Publications (2)

Publication Number Publication Date
FR2509282A1 true FR2509282A1 (fr) 1983-01-14
FR2509282B1 FR2509282B1 (enExample) 1983-11-04

Family

ID=9260389

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8113530A Granted FR2509282A1 (fr) 1981-07-09 1981-07-09 Procede de separation des actinides et des lanthanides presents a l'etat trivalent, dans une solution aqueuse acide

Country Status (6)

Country Link
US (1) US4496523A (enExample)
EP (1) EP0070226B1 (enExample)
JP (1) JPS5819453A (enExample)
CA (1) CA1197382A (enExample)
DE (1) DE3263252D1 (enExample)
FR (1) FR2509282A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2845616A1 (fr) * 2002-10-15 2004-04-16 Commissariat Energie Atomique Procede cyclique de separation d'elements chimiques presents dans une solution aqueuse

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2607021B1 (fr) * 1986-11-21 1990-11-16 Commissariat Energie Atomique Procede d'extraction selective de metaux de transition a partir de solutions acides par des systemes de ligands azotes polydentes et d'echangeurs cationiques
FR2618165B1 (fr) * 1987-07-17 1991-05-10 Rhone Poulenc Chimie Procede de reduction par electrolyse et de separation de l'europium et cellule d'electrolyse pour la mise en oeuvre de ce procede.
US4867951A (en) * 1988-03-31 1989-09-19 The United States Of America As Represented By The United States Department Of Energy Separation of actinides from lanthanides
US4923630A (en) * 1988-03-31 1990-05-08 The United States Of America As Represented By The United States Department Of Energy Extractant composition
FR2680363B1 (fr) * 1991-08-14 1994-03-04 Commissariat A Energie Atomique Procede pour separer les actinides des lanthanides par extraction selective des actinides dans un solvant organique comprenant un propanediamide.
FR2684670B1 (fr) * 1991-12-05 1995-04-07 Commissariat Energie Atomique Amides a substituant heterocyclique azote, leur procede de preparation et leur utilisation pour extraire selectivement les actinides (iii) et les separer en particulier des lanthanides (iii).
JPH07104096A (ja) * 1993-10-05 1995-04-21 Japan Atom Energy Res Inst 酸性溶液中のランタニド元素と超プルトニウム元素の溶媒抽出による相互分離法
GB2296917B (en) * 1994-12-21 1998-08-26 Univ Reading Separation of actinides from lanthanides using 1,3,5-triazine derivatives
FR2748951B1 (fr) * 1996-05-24 1998-07-03 Commissariat Energie Atomique Procede de separation selective des actinides (iii) et lanthanides (iii)
JP2003242906A (ja) 2002-02-21 2003-08-29 Toshiba Corp 偏向ヨークおよびこれを備えた陰極線管装置
DE10339328A1 (de) * 2003-08-25 2005-03-24 Forschungszentrum Jülich GmbH Verfahren zur Trennung von dreiwertigem Americium von dreiwertigem Curium
FR2948371B1 (fr) * 2009-07-21 2011-08-19 Commissariat Energie Atomique Composes utiles comme ligands des actinides, leur synthese et leurs utilisations
CN102712578B (zh) 2009-07-30 2014-09-24 原子能秘书部 用于从镧系元素中分离三价锕系元素的二烷基二氮杂-四烷基辛烷二酰胺衍生物及其制备方法
EP2377861B1 (de) * 2010-04-17 2013-12-04 Karlsruher Institut für Technologie Wasserlösliche Bis-triazinyl-pyridine, -bipyridine und terpyridine, deren Synthese und Verwendung
JP7108519B2 (ja) * 2018-10-31 2022-07-28 日立Ｇｅニュークリア・エナジー株式会社 マイナーアクチノイドの分離方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3243254A (en) * 1963-08-20 1966-03-29 Iii Thomas H Siddall Method for extracting lanthanides and actinides
FR1510877A (fr) * 1966-02-28 1968-01-26 Atomic Energy Commission Procédé pour séparer les lanthanides et les actinides trivalents des solutions aqueuses de nitrates
FR1534888A (fr) * 1967-06-21 1968-08-02 Commissariat Energie Atomique Procédé de séparation des éléments des groupes actinides et lanthanides
FR1553200A (enExample) * 1967-01-13 1969-01-10
FR2068159A5 (en) * 1969-11-28 1971-08-20 Commissariat Energie Atomique Separation of actinides
US3743696A (en) * 1971-02-04 1973-07-03 Atomic Energy Commission Separation of americium and curium
US4025602A (en) * 1976-05-25 1977-05-24 The United States Of America As Represented By The United States Energy Research And Development Administration Recovery of transplutonium elements from nuclear reactor waste

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2877092A (en) * 1947-03-26 1959-03-10 William H Reas Coordination compound-solvent extraction process for uranium recovery
US3004051A (en) * 1958-08-28 1961-10-10 Phillips Petroleum Co Extraction of uranium values from aqueous solutions
GB1047232A (enExample) * 1963-07-12
US3276849A (en) * 1964-09-18 1966-10-04 Fletcher L Moore Method for separating members of actinide and lanthanide groups
US3558288A (en) * 1965-04-15 1971-01-26 Ashland Oil Inc Extraction of metal ions from acidic aqueous solution using an amine and a carboxylic acid
US3323857A (en) * 1965-12-16 1967-06-06 Donald J Bauer Selective extraction and separation of lanthanides with a quaternary ammonium compound
US3409415A (en) * 1967-05-31 1968-11-05 Atomic Energy Commission Usa Method of extracting soluble metal complexes using amine solvents
GB1282089A (en) * 1970-10-28 1972-07-19 Miles Lab Composition for the detection of uric acid
JPS5929660B2 (ja) * 1977-12-14 1984-07-21 動力炉・核燃料開発事業団 湿式法リン酸からウラニウムを抽出する方法
US4162230A (en) * 1977-12-28 1979-07-24 The United States Of America As Represented By The United States Department Of Energy Method for the recovery of actinide elements from nuclear reactor waste
FR2465687A1 (fr) * 1979-09-21 1981-03-27 Rhone Poulenc Ind Procede de recuperation globale de l'uranium, des terres rares, du thorium et de l'yttrium contenus dans une solution acide
US4255396A (en) * 1979-12-18 1981-03-10 Gte Products Corporation Process for separating molybdenum values from tungsten values

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3243254A (en) * 1963-08-20 1966-03-29 Iii Thomas H Siddall Method for extracting lanthanides and actinides
FR1510877A (fr) * 1966-02-28 1968-01-26 Atomic Energy Commission Procédé pour séparer les lanthanides et les actinides trivalents des solutions aqueuses de nitrates
FR1553200A (enExample) * 1967-01-13 1969-01-10
FR1534888A (fr) * 1967-06-21 1968-08-02 Commissariat Energie Atomique Procédé de séparation des éléments des groupes actinides et lanthanides
FR2068159A5 (en) * 1969-11-28 1971-08-20 Commissariat Energie Atomique Separation of actinides
US3743696A (en) * 1971-02-04 1973-07-03 Atomic Energy Commission Separation of americium and curium
US4025602A (en) * 1976-05-25 1977-05-24 The United States Of America As Represented By The United States Energy Research And Development Administration Recovery of transplutonium elements from nuclear reactor waste

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CA1971 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2845616A1 (fr) * 2002-10-15 2004-04-16 Commissariat Energie Atomique Procede cyclique de separation d'elements chimiques presents dans une solution aqueuse
US7157003B2 (en) 2002-10-15 2007-01-02 Commissariat A L'energie Atomique Cyclic method for separating chemical elements present in an aqueous solution

Also Published As

Publication number Publication date
JPH0470370B2 (enExample) 1992-11-10
EP0070226A1 (fr) 1983-01-19
JPS5819453A (ja) 1983-02-04
DE3263252D1 (en) 1985-05-30
FR2509282B1 (enExample) 1983-11-04
EP0070226B1 (fr) 1985-04-24
US4496523A (en) 1985-01-29
CA1197382A (en) 1985-12-03

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