FR2478136A2 - Fibres a base de polymeres acryliques et de cellulose et leur procede d'obtention - Google Patents
Fibres a base de polymeres acryliques et de cellulose et leur procede d'obtention Download PDFInfo
- Publication number
- FR2478136A2 FR2478136A2 FR8005963A FR8005963A FR2478136A2 FR 2478136 A2 FR2478136 A2 FR 2478136A2 FR 8005963 A FR8005963 A FR 8005963A FR 8005963 A FR8005963 A FR 8005963A FR 2478136 A2 FR2478136 A2 FR 2478136A2
- Authority
- FR
- France
- Prior art keywords
- cellulose
- polymer
- acrylonitrile
- acrylic polymer
- filaments
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002678 cellulose Polymers 0.000 title claims abstract description 67
- 239000001913 cellulose Substances 0.000 title claims abstract description 67
- 229920000642 polymer Polymers 0.000 title claims abstract description 14
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 title abstract description 35
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title abstract description 10
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 title description 2
- 238000009987 spinning Methods 0.000 title 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002521 macromolecule Polymers 0.000 claims abstract description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 31
- 239000000835 fiber Substances 0.000 claims description 24
- 239000013078 crystal Substances 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 2
- 102100031680 Beta-catenin-interacting protein 1 Human genes 0.000 claims 1
- 101000993469 Homo sapiens Beta-catenin-interacting protein 1 Proteins 0.000 claims 1
- -1 filaments Substances 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 abstract description 19
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 10
- 229920001577 copolymer Polymers 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 229920002239 polyacrylonitrile Polymers 0.000 abstract 1
- 235000010980 cellulose Nutrition 0.000 description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 238000004090 dissolution Methods 0.000 description 12
- 230000001112 coagulating effect Effects 0.000 description 11
- 229930040373 Paraformaldehyde Natural products 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 229920002866 paraformaldehyde Polymers 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 238000004513 sizing Methods 0.000 description 4
- SZHIIIPPJJXYRY-UHFFFAOYSA-M sodium;2-methylprop-2-ene-1-sulfonate Chemical compound [Na+].CC(=C)CS([O-])(=O)=O SZHIIIPPJJXYRY-UHFFFAOYSA-M 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical class OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Natural products CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/54—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8005963A FR2478136A2 (fr) | 1980-03-13 | 1980-03-13 | Fibres a base de polymeres acryliques et de cellulose et leur procede d'obtention |
| MX182198A MX153616A (es) | 1979-05-14 | 1980-05-06 | Composicion conformable a hilos,fibras y peliculas |
| US06/147,221 US4377648A (en) | 1979-05-14 | 1980-05-06 | Cellulose-polyacrylonitrile-DMSO-formaldehyde solutions, articles, and methods of making same |
| FI801475A FI73233C (fi) | 1979-05-14 | 1980-05-07 | Formbara loesningar av cellulosa och en polymer pao basis av akrylnitril, foerfarande foer framstaellning av dessa loesningar och fibrer, filament och traodar framstaellda av dessa loesningar samt foerfarande foer framstaellning av dessa fibrer och traodar. |
| BR8002939A BR8002939A (pt) | 1979-05-14 | 1980-05-09 | Solucoes conformaveis,processo para a obtencao destas solucoes;fios,filamentos e fibras a base de celulose e polimero acrilico,e processo para a obtencao destes fios,filamentos e fibras |
| DE8080420058T DE3060334D1 (en) | 1979-05-14 | 1980-05-12 | Shapable solutions, shaped articles obtained therefrom and process for producing them |
| AT80420058T ATE929T1 (de) | 1979-05-14 | 1980-05-12 | Formbare loesungen, hieraus erhaltene geformte gegenstaende sowie deren herstellungsverfahren. |
| PT7122380A PT71223A (fr) | 1979-05-14 | 1980-05-12 | Solutions conformables articles en forme obtenus a partir de ces solutions ainsi que leur procede d'obtention |
| EP19800420058 EP0019566B1 (fr) | 1979-05-14 | 1980-05-12 | Solutions conformables, articles en forme obtenus à partir de ces solutions ainsi que leur procédé d'obtention |
| ES491423A ES8205273A1 (es) | 1979-05-14 | 1980-05-13 | Procedimiento para la obtencion de soluciones conformables |
| NO801422A NO801422L (no) | 1979-05-14 | 1980-05-13 | Omformbare opploesninger, derav formede gjenstander, samt fremstilling derav |
| AR28103380A AR219250A1 (es) | 1979-05-14 | 1980-05-14 | Soluciones conformables para la produccion de hilos,fibras,peliculas,membranas,etc.y procedimiento para prepararlas |
| ES498277A ES8205274A1 (es) | 1979-05-14 | 1980-12-31 | Procedimiento para la obtencion de fibras, filamentos e hi- los a base de celulosa y de polimero acrilico |
| US06/418,184 US4409289A (en) | 1979-05-14 | 1982-09-14 | Cellulose-acrylonitrile polymer solutions, articles, and methods of making same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8005963A FR2478136A2 (fr) | 1980-03-13 | 1980-03-13 | Fibres a base de polymeres acryliques et de cellulose et leur procede d'obtention |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2478136A2 true FR2478136A2 (fr) | 1981-09-18 |
| FR2478136B2 FR2478136B2 (https=) | 1985-02-22 |
Family
ID=9239761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8005963A Granted FR2478136A2 (fr) | 1979-05-14 | 1980-03-13 | Fibres a base de polymeres acryliques et de cellulose et leur procede d'obtention |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2478136A2 (https=) |
-
1980
- 1980-03-13 FR FR8005963A patent/FR2478136A2/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| FR2478136B2 (https=) | 1985-02-22 |
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