FR2459683A1 - Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene - Google Patents

Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene Download PDF

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Publication number
FR2459683A1
FR2459683A1 FR7916096A FR7916096A FR2459683A1 FR 2459683 A1 FR2459683 A1 FR 2459683A1 FR 7916096 A FR7916096 A FR 7916096A FR 7916096 A FR7916096 A FR 7916096A FR 2459683 A1 FR2459683 A1 FR 2459683A1
Authority
FR
France
Prior art keywords
catalyst
cobalt
hydroformylation
reaction
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7916096A
Other languages
English (en)
French (fr)
Other versions
FR2459683B1 (xx
Inventor
Claude Demay
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Original Assignee
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Produits Chimiques Ugine Kuhlmann, Ugine Kuhlmann SA filed Critical Produits Chimiques Ugine Kuhlmann
Priority to FR7916096A priority Critical patent/FR2459683A1/fr
Priority to IN366/DEL/80A priority patent/IN154375B/en
Priority to AR281215A priority patent/AR223042A1/es
Priority to JP7565380A priority patent/JPS5628647A/ja
Priority to US06/157,501 priority patent/US4306086A/en
Priority to SE8004359A priority patent/SE8004359L/xx
Priority to BE0/201050A priority patent/BE883849A/fr
Priority to AU59460/80A priority patent/AU517508B2/en
Priority to NL8003595A priority patent/NL8003595A/nl
Priority to CA000354514A priority patent/CA1137963A/fr
Priority to BR8003845A priority patent/BR8003845A/pt
Priority to ES492668A priority patent/ES492668A0/es
Priority to IT8067974A priority patent/IT8067974A0/it
Priority to LU82535A priority patent/LU82535A1/fr
Priority to NO801864A priority patent/NO801864L/no
Priority to DE19803023025 priority patent/DE3023025A1/de
Priority to GB8020163A priority patent/GB2055053B/en
Priority to ZA00803704A priority patent/ZA803704B/xx
Publication of FR2459683A1 publication Critical patent/FR2459683A1/fr
Application granted granted Critical
Publication of FR2459683B1 publication Critical patent/FR2459683B1/fr
Granted legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0219—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
FR7916096A 1979-06-22 1979-06-22 Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene Granted FR2459683A1 (fr)

Priority Applications (18)

Application Number Priority Date Filing Date Title
FR7916096A FR2459683A1 (fr) 1979-06-22 1979-06-22 Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene
IN366/DEL/80A IN154375B (xx) 1979-06-22 1980-05-20
AR281215A AR223042A1 (es) 1979-06-22 1980-05-28 Un procedimiento de estabilizacion y regeneracion del catalizador de la hidroformilacion de propeno
JP7565380A JPS5628647A (en) 1979-06-22 1980-06-06 Method of stabilizing and regenerating hydroformylated catalyst of propene
US06/157,501 US4306086A (en) 1979-06-22 1980-06-09 Hydroformylation catalyst system and processes
SE8004359A SE8004359L (sv) 1979-06-22 1980-06-11 Forfarande for stabilisering och regenerering av en katalysator for hydroformylering av propen
BE0/201050A BE883849A (fr) 1979-06-22 1980-06-17 Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene
NO801864A NO801864L (no) 1979-06-22 1980-06-20 Fremgangsmaate for stabilisering og regenerering av en propenhydroformyleringskatalysator
AU59460/80A AU517508B2 (en) 1979-06-22 1980-06-20 Regeneration of rhodium containing hydroformylation catalyst
BR8003845A BR8003845A (pt) 1979-06-22 1980-06-20 Processo de estabilizacao e de regeneracao do catalisador de hidroformilacao de propeno
ES492668A ES492668A0 (es) 1979-06-22 1980-06-20 Procedimiento de estabilizacion y regeneracion del cataliza-dor de hidroformilacion del propeno
IT8067974A IT8067974A0 (it) 1979-06-22 1980-06-20 Procedimento di stabilizzazione e rigenerazione del catalizzatore di idroformilazione del propilene
LU82535A LU82535A1 (fr) 1979-06-22 1980-06-20 Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene
NL8003595A NL8003595A (nl) 1979-06-22 1980-06-20 Werkwijze voor het stabiliseren en regenereren van een hydroformyleringskatalysator voor propeen.
DE19803023025 DE3023025A1 (de) 1979-06-22 1980-06-20 Verfahren zur stabilisierung und regenerierung von hydroformylierungskatalysatoren
GB8020163A GB2055053B (en) 1979-06-22 1980-06-20 Process for the stabilisation and regeneration of catalysts for the hydroformylation of propene
ZA00803704A ZA803704B (en) 1979-06-22 1980-06-20 Process for the stabilisation and regeneration of the hydroformylation catalyst of propene
CA000354514A CA1137963A (fr) 1979-06-22 1980-06-20 Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7916096A FR2459683A1 (fr) 1979-06-22 1979-06-22 Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene

Publications (2)

Publication Number Publication Date
FR2459683A1 true FR2459683A1 (fr) 1981-01-16
FR2459683B1 FR2459683B1 (xx) 1983-06-03

Family

ID=9226990

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7916096A Granted FR2459683A1 (fr) 1979-06-22 1979-06-22 Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene

Country Status (18)

Country Link
US (1) US4306086A (xx)
JP (1) JPS5628647A (xx)
AR (1) AR223042A1 (xx)
AU (1) AU517508B2 (xx)
BE (1) BE883849A (xx)
BR (1) BR8003845A (xx)
CA (1) CA1137963A (xx)
DE (1) DE3023025A1 (xx)
ES (1) ES492668A0 (xx)
FR (1) FR2459683A1 (xx)
GB (1) GB2055053B (xx)
IN (1) IN154375B (xx)
IT (1) IT8067974A0 (xx)
LU (1) LU82535A1 (xx)
NL (1) NL8003595A (xx)
NO (1) NO801864L (xx)
SE (1) SE8004359L (xx)
ZA (1) ZA803704B (xx)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4388477A (en) * 1981-06-02 1983-06-14 Eastman Kodak Company Hydroformylation process employing unmodified rhodium-cobalt catalyst
US4539306A (en) * 1982-09-02 1985-09-03 Ashland Oil, Inc. Use of mixed metal catalysts in the hydroformylation of olefins to produce linear aldehydes and alcohols
US4547595A (en) * 1982-09-02 1985-10-15 Ashland Oil, Inc. Method of reactivating Group VIII anionic hydroformylation catalysts
FR2544713B1 (fr) * 1983-04-22 1986-08-22 Ugine Kuhlmann Systeme catalytique pour l'hydroformylation des olefines. procede d'hydroformylation
DE3403427A1 (de) * 1984-02-01 1985-08-01 Degussa Ag, 6000 Frankfurt Verfahren zur herstellung von 1,4-butandial
US5233093A (en) * 1992-07-20 1993-08-03 Arco Chemical Technology, L.P. Hydroformylation process and bimetallic catalyst therefor
US5756855A (en) * 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
GB0106219D0 (en) * 2001-03-14 2001-05-02 Ici Plc Improvements in and relating to the production of oxygenated organic compounds
US6831035B2 (en) * 2002-01-22 2004-12-14 Eastman Kodak Company Stabilization of fluorophosphite-containing catalysts
USD915895S1 (en) 2018-11-30 2021-04-13 Graham Packaging Company, L.P. Container
USD918045S1 (en) * 2019-03-05 2021-05-04 Graham Packaging Company, L.P. Container
USD914505S1 (en) * 2019-07-04 2021-03-30 Schuetz Gmbh & Co. Kgaa Canister

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL98500C (xx) * 1956-01-11
FR2395246A1 (fr) * 1977-06-21 1979-01-19 Johnson Matthey Co Ltd Procede d'hydroformylation catalytique

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3239566A (en) * 1960-07-22 1966-03-08 Shell Oil Co Hydroformylation of olefins
NL146830C (xx) 1960-07-22
US3576881A (en) * 1966-02-04 1971-04-27 Exxon Research Engineering Co Preparation of modified oxo catalyst and process relating thereto
US3976703A (en) * 1970-04-27 1976-08-24 Chevron Research Company Hydroformylation using aryl sulfonate stabilizer for cobalt catalyst
GB1385475A (en) 1971-05-10 1975-02-26 Ici Ltd Production of butyraldehyde
FR2351077A1 (fr) * 1976-05-13 1977-12-09 Celanese Corp Procede perfectionne d'hydroformylation des olefines avec un catalyseur complexe au rhodium
US4221743A (en) 1976-07-07 1980-09-09 Union Carbide Corporation Hydroformylation process
ZA78147B (en) 1977-01-25 1978-11-29 Union Carbide Corp Improved hydroformylation process
ZA78146B (en) 1977-01-25 1978-12-27 Union Carbide Corp Improved hydroformylation process
US4230641A (en) * 1977-11-21 1980-10-28 Air Products And Chemicals, Inc. Hydroformylation of olefins
DE2840168A1 (de) * 1978-09-15 1980-03-27 Basf Ag Verfahren zur herstellung von aldehyden

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL98500C (xx) * 1956-01-11
FR2395246A1 (fr) * 1977-06-21 1979-01-19 Johnson Matthey Co Ltd Procede d'hydroformylation catalytique

Also Published As

Publication number Publication date
JPS5628647A (en) 1981-03-20
IN154375B (xx) 1984-10-20
ZA803704B (en) 1981-06-24
NO801864L (no) 1980-12-23
BE883849A (fr) 1980-12-17
AU517508B2 (en) 1981-08-06
LU82535A1 (fr) 1982-01-20
SE8004359L (sv) 1980-12-23
NL8003595A (nl) 1980-12-24
DE3023025A1 (de) 1981-01-08
AR223042A1 (es) 1981-07-15
ES8102842A1 (es) 1981-02-16
FR2459683B1 (xx) 1983-06-03
US4306086A (en) 1981-12-15
CA1137963A (fr) 1982-12-21
AU5946080A (en) 1981-03-12
GB2055053B (en) 1983-03-16
BR8003845A (pt) 1981-01-13
GB2055053A (en) 1981-02-25
ES492668A0 (es) 1981-02-16
IT8067974A0 (it) 1980-06-20

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