FR2416881A1 - Procede de preparation d'acides carboxyliques aliphatiques insatures ou de leurs esters a partir de dienes conjugues aliphatiques - Google Patents
Procede de preparation d'acides carboxyliques aliphatiques insatures ou de leurs esters a partir de dienes conjugues aliphatiquesInfo
- Publication number
- FR2416881A1 FR2416881A1 FR7903464A FR7903464A FR2416881A1 FR 2416881 A1 FR2416881 A1 FR 2416881A1 FR 7903464 A FR7903464 A FR 7903464A FR 7903464 A FR7903464 A FR 7903464A FR 2416881 A1 FR2416881 A1 FR 2416881A1
- Authority
- FR
- France
- Prior art keywords
- esters
- carboxylic acids
- conjugated
- aliphatic
- dienes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
La présente invention a pour objet un procédé de préparation d'acides carboxyliques aliphatiques insaturés ou de leurs esters à partir de diènes conjugués aliphatiques. Selon ce procédé, on produit simultanément des acides ou leurs esters carboxyliques insaturés monomères et dimères, en faisant réagir un diène aliphatique conjugué en C4 à C8 à une température de 30 à 150 degrés C avec du monoxyde de carbone et un coréactif hydroxylé (eau ou alcool), en présence d'un système catalytique à trois composants constitués par un sel de palladium, un ligand donneur contenant du phosphore tertiaire et une base hétérocyclique contenant de l'azote. Les produits obtenus sont utilisables comme lubrifiants synthétiques ou comme additifs pour lubrifiants.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/877,439 US4172087A (en) | 1978-02-13 | 1978-02-13 | Process for preparing unsaturated aliphatic esters from aliphatic dienes |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2416881A1 true FR2416881A1 (fr) | 1979-09-07 |
FR2416881B1 FR2416881B1 (fr) | 1983-11-25 |
Family
ID=25369963
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7903464A Granted FR2416881A1 (fr) | 1978-02-13 | 1979-02-12 | Procede de preparation d'acides carboxyliques aliphatiques insatures ou de leurs esters a partir de dienes conjugues aliphatiques |
Country Status (7)
Country | Link |
---|---|
US (1) | US4172087A (fr) |
JP (1) | JPS54115316A (fr) |
BE (1) | BE874103A (fr) |
DE (1) | DE2905209A1 (fr) |
FR (1) | FR2416881A1 (fr) |
GB (1) | GB2014136B (fr) |
IT (1) | IT1113019B (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2475537A1 (fr) * | 1980-02-08 | 1981-08-14 | Celanese Corp | Procede de production et de recuperation d'un monadienoate d'alcoyle |
FR2498594A1 (fr) * | 1981-01-23 | 1982-07-30 | Rhone Poulenc Ind | Procede de preparation de monoesters d'acides carboxyliques b,g-insatures |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4246183A (en) * | 1979-06-08 | 1981-01-20 | Texaco Development Corp. | Process for preparing unsaturated aliphatic esters from aliphatic dienes |
DE3175174D1 (en) * | 1981-01-06 | 1986-09-25 | Shell Int Research | Process for the carbonylation of olefins |
US4536340A (en) * | 1981-04-27 | 1985-08-20 | National Distillers And Chemical Corporation | Process for the preparation of alkyl nonadienoate esters |
US4582817A (en) * | 1981-04-27 | 1986-04-15 | National Distillers And Chemical Corporation | Process for the preparation of alkyl nonadienoate esters |
EP0063818A1 (fr) * | 1981-04-27 | 1982-11-03 | National Distillers And Chemical Corporation | Procédé de préparation d'esters alkyliques de l'acide nonadiénoique |
US4491546A (en) * | 1981-04-27 | 1985-01-01 | National Distillers And Chemical Corporation | Palladium-ligand complex for use in catalyzing the reaction of a mixture of 1,3-butadiene, carbon monoxide and monoalkanol to provide alkyl nonadienoate ester |
FR2512812A1 (fr) * | 1981-09-16 | 1983-03-18 | Rhone Poulenc Chim Base | Procede de separation du palladium des produits issus de la carbonylation des dienes conjugues en presence de paladium |
FR2512813A1 (fr) * | 1981-09-16 | 1983-03-18 | Rhone Poulenc Chim Base | Procede de carbonylation des dienes conjugues en presence d'un catalyseur au palladium avec recyclage dudit catalyseur |
US4416823A (en) * | 1981-11-09 | 1983-11-22 | Celanese Corporation | Dimeric carbonylation of 1,3-alkadiene |
US4622423A (en) * | 1984-11-09 | 1986-11-11 | E. I. Du Pont De Nemours And Company | Hydrocarboxylation of butadiene to 3-pentenoic acid |
US4788333A (en) * | 1985-01-07 | 1988-11-29 | E. I. Du Pont De Nemours And Company | Hydrocarboxylation of unsaturated carboxylic acids to linear dicarboxylic acids |
US4622416A (en) * | 1985-04-19 | 1986-11-11 | National Distillers And Chemical Corporation | Carbonylation of allylic ethers to esters |
US4767574A (en) * | 1985-10-03 | 1988-08-30 | National Distillers And Chemical Corporation | Carbonylation of allylic ethers to esters |
US5004568A (en) * | 1985-10-03 | 1991-04-02 | National Distillers And Chemical Corporation | Carbonylation of allylic ethers to esters |
KR880007427A (ko) * | 1986-12-05 | 1988-08-27 | 오노 알버어스 | 공역 디엔의 카르보닐화 방법 및 이를 위한 촉매 시스템 |
KR880007418A (ko) * | 1986-12-10 | 1988-08-27 | 오노 알버어스 | 공역 디엔의 선택적 카르보닐화 방법 및 이를 위한 유기 질소-함유 열기를 갖지 않는 촉매 시스템 |
JPH07100679B2 (ja) * | 1987-03-12 | 1995-11-01 | 日本石油化学株式会社 | α−(3−ベンゾイルフエニル)プロピオン酸またはそのエステルの製造方法 |
US5026901A (en) * | 1990-03-29 | 1991-06-25 | E. I. Du Pont De Nemours And Company | Palladium catalyzed carboalkoxylation of butadiene |
US5350876A (en) * | 1992-06-29 | 1994-09-27 | Shell Oil Company | Carbonylation of conjugated dienes |
US5436356A (en) * | 1993-02-09 | 1995-07-25 | Shell Oil Company | Carbonylation process |
KR960031420A (ko) * | 1995-02-22 | 1996-09-17 | 미키엘 크램윈켈. | 부티디엔 또는 부타디엔 유도체의 카르보닐화 방법 |
MY127097A (en) * | 2000-09-27 | 2006-11-30 | Dsm Ip Assets Bv | Process for the carbonylation of a conjugated diene |
AU2021329906A1 (en) | 2020-08-18 | 2023-04-27 | Enviro Metals, LLC | Metal refinement |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1051627A (fr) * | 1961-12-29 | |||
DE1261509B (de) * | 1964-12-19 | 1968-02-22 | Basf Ag | Verfahren zur Carbonylierung von olefinisch oder acetylenisch ungesaettigten Verbindungen |
US3530155A (en) * | 1968-02-06 | 1970-09-22 | Union Oil Co | Hydrocarboxylation of olefins |
US3670029A (en) * | 1969-03-19 | 1972-06-13 | Exxon Research Engineering Co | Preparation of unsaturated ethers |
US4124617A (en) * | 1977-06-28 | 1978-11-07 | Texaco Development Corporation | Process for preparing unsaturated aliphatic esters from aliphatic dienes |
-
1978
- 1978-02-13 US US05/877,439 patent/US4172087A/en not_active Expired - Lifetime
-
1979
- 1979-01-29 GB GB7903080A patent/GB2014136B/en not_active Expired
- 1979-02-08 JP JP1284579A patent/JPS54115316A/ja active Pending
- 1979-02-12 DE DE19792905209 patent/DE2905209A1/de not_active Withdrawn
- 1979-02-12 BE BE0/193409A patent/BE874103A/fr not_active IP Right Cessation
- 1979-02-12 IT IT20119/79A patent/IT1113019B/it active
- 1979-02-12 FR FR7903464A patent/FR2416881A1/fr active Granted
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2475537A1 (fr) * | 1980-02-08 | 1981-08-14 | Celanese Corp | Procede de production et de recuperation d'un monadienoate d'alcoyle |
FR2498594A1 (fr) * | 1981-01-23 | 1982-07-30 | Rhone Poulenc Ind | Procede de preparation de monoesters d'acides carboxyliques b,g-insatures |
EP0060734A1 (fr) * | 1981-01-23 | 1982-09-22 | Rhone-Poulenc Chimie De Base | Procédé de préparation d'esters d'acides carboxyliques bêta-gamma insaturés |
Also Published As
Publication number | Publication date |
---|---|
FR2416881B1 (fr) | 1983-11-25 |
US4172087A (en) | 1979-10-23 |
GB2014136B (en) | 1982-09-02 |
GB2014136A (en) | 1979-08-22 |
IT7920119A0 (it) | 1979-02-12 |
BE874103A (fr) | 1979-08-13 |
JPS54115316A (en) | 1979-09-07 |
DE2905209A1 (de) | 1979-10-25 |
IT1113019B (it) | 1986-01-20 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |