FR2407021A1 - Catalyst for ammoxidation of alkane with nitric oxide to form nitrile - contains metallic oxide dehydrogenating agent such as chromium tri:oxide, ferric oxide or vanadium pent:oxide - Google Patents

Catalyst for ammoxidation of alkane with nitric oxide to form nitrile - contains metallic oxide dehydrogenating agent such as chromium tri:oxide, ferric oxide or vanadium pent:oxide

Info

Publication number
FR2407021A1
FR2407021A1 FR7732301A FR7732301A FR2407021A1 FR 2407021 A1 FR2407021 A1 FR 2407021A1 FR 7732301 A FR7732301 A FR 7732301A FR 7732301 A FR7732301 A FR 7732301A FR 2407021 A1 FR2407021 A1 FR 2407021A1
Authority
FR
France
Prior art keywords
oxide
derivs
partic
pref
ammoxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7732301A
Other languages
French (fr)
Inventor
Gerard Pajonk
Stanislas Jean Teichner
Farouk Zidan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bpifrance Financement SA
Original Assignee
Agence National de Valorisation de la Recherche ANVAR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agence National de Valorisation de la Recherche ANVAR filed Critical Agence National de Valorisation de la Recherche ANVAR
Priority to FR7732301A priority Critical patent/FR2407021A1/en
Publication of FR2407021A1 publication Critical patent/FR2407021A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/866—Nickel and chromium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

A new metallic deriv. comprises >=1 Ni deriv. (A), partic. an oxide, and >=1 dehydrogenation agent (B), partic. a metallic oxide. It also pref. includes >=1 refractory metal deriv. (C), partic. an oxide. (B) is pref. Cr2O3, Fe2O3 or V2O5. (C) is pref. alumina, partic. amorphous alumina. The derivs. can be prepd. by treating aq. solns. contg. the required metallic cations in the form of salts with a current of NH3 to form a complex. NH3 is then removed to give a ppte contg. the derivs. sought for. The derivs. are used as catalysts in the prepn. of nitriles (which can be subsequently polymerised) by ammoxidation of alkanes using NO, at 450-490, pref. around 480 degrees C with a contact time between the catalyst and the reactive gases >0.2 second. The derivs. posses catalytic properties which are stable over a long period. Satd. and unsatd. nitriles can be obtd. from alkanes in a single step. Premature polymerization and explosion risks are avoided.
FR7732301A 1977-10-26 1977-10-26 Catalyst for ammoxidation of alkane with nitric oxide to form nitrile - contains metallic oxide dehydrogenating agent such as chromium tri:oxide, ferric oxide or vanadium pent:oxide Withdrawn FR2407021A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7732301A FR2407021A1 (en) 1977-10-26 1977-10-26 Catalyst for ammoxidation of alkane with nitric oxide to form nitrile - contains metallic oxide dehydrogenating agent such as chromium tri:oxide, ferric oxide or vanadium pent:oxide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7732301A FR2407021A1 (en) 1977-10-26 1977-10-26 Catalyst for ammoxidation of alkane with nitric oxide to form nitrile - contains metallic oxide dehydrogenating agent such as chromium tri:oxide, ferric oxide or vanadium pent:oxide

Publications (1)

Publication Number Publication Date
FR2407021A1 true FR2407021A1 (en) 1979-05-25

Family

ID=9196974

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7732301A Withdrawn FR2407021A1 (en) 1977-10-26 1977-10-26 Catalyst for ammoxidation of alkane with nitric oxide to form nitrile - contains metallic oxide dehydrogenating agent such as chromium tri:oxide, ferric oxide or vanadium pent:oxide

Country Status (1)

Country Link
FR (1) FR2407021A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2684567A1 (en) * 1991-12-09 1993-06-11 Atochem MASSIC CATALYSTS BASED ON CHROMIUM AND NICKEL OXIDES AND THEIR APPLICATION TO FLUORINATION OF HALOGENATED HYDROCARBONS.
US5616820A (en) * 1993-01-27 1997-04-01 Elf Atochem S.A. Process for the manufacture of 1,1,1,2-tetrafluoro-2-chloroethane and of pentafluoroethane
US5932776A (en) * 1993-01-27 1999-08-03 Cheminal; Bernard Process for fluorination of perchloroethylene or of pentachloroethane

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2684567A1 (en) * 1991-12-09 1993-06-11 Atochem MASSIC CATALYSTS BASED ON CHROMIUM AND NICKEL OXIDES AND THEIR APPLICATION TO FLUORINATION OF HALOGENATED HYDROCARBONS.
EP0546883A1 (en) * 1991-12-09 1993-06-16 Elf Atochem S.A. Chromium and nickel oxydes-based solid catalysts and the use thereof for the fluorination of halogenated hydrocarbons
US5523500A (en) * 1991-12-09 1996-06-04 D'elf Atochem S.A. Mass catalysts based on chromium and nickel oxides and their application to the fluorination of halogenated hydrocarbons
US5616820A (en) * 1993-01-27 1997-04-01 Elf Atochem S.A. Process for the manufacture of 1,1,1,2-tetrafluoro-2-chloroethane and of pentafluoroethane
US5932776A (en) * 1993-01-27 1999-08-03 Cheminal; Bernard Process for fluorination of perchloroethylene or of pentachloroethane

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Legal Events

Date Code Title Description
ST Notification of lapse
AR Application made for restoration
TP Transmission of property
BR Restoration of rights
TP Transmission of property
ST Notification of lapse