FR2072399A5 - Ammoxidation of alkanes to nitriles - Google Patents
Ammoxidation of alkanes to nitrilesInfo
- Publication number
- FR2072399A5 FR2072399A5 FR7042384A FR7042384A FR2072399A5 FR 2072399 A5 FR2072399 A5 FR 2072399A5 FR 7042384 A FR7042384 A FR 7042384A FR 7042384 A FR7042384 A FR 7042384A FR 2072399 A5 FR2072399 A5 FR 2072399A5
- Authority
- FR
- France
- Prior art keywords
- oxides
- ammoxidation
- chosen
- nitriles
- alkanes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of actinides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/847—Vanadium, niobium or tantalum or polonium
- B01J23/8472—Vanadium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
Ammoxidation is carried out by leading the alkane and ammonia, at 350-650 degrees C, over a solid catalyst in which the active components are: (a) the oxides of Sb and a metal chosen from Sn, Fe, U, Ce and Mo, (b) the oxides of any 3 metals chosen from Sb, Sn, Ti, V and U, except for the combination Sb/Sn/V, (c) the oxides of Sn and Mo, (d) the oxides of As and Sn or U, (e) the oxides of Sn and Ti, Zr or Hf, (f) the oxides of V and Cr, Mo or Sn, (g) the oxides of Ti and W, Mo, V, Cr or U, and (h) the oxides of Mo and Bi or Cr, or, in each ase a compound which contains the 2 or 3 chosen metals and oxygen. The partial pressure of the alkane is >0.20 atm. The preparation of acrylonitrile from propane and/or methacrylonitrile from butane is claimed.
Applications Claiming Priority (13)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5758769 | 1969-11-25 | ||
GB1407570 | 1970-03-24 | ||
GB1407970 | 1970-03-24 | ||
GB1407670 | 1970-03-24 | ||
GB1407870 | 1970-03-24 | ||
GB1407770 | 1970-03-24 | ||
GB2066270 | 1970-04-29 | ||
GB2066170 | 1970-04-29 | ||
GB2066070 | 1970-04-29 | ||
GB2255570 | 1970-05-11 | ||
GB3209670 | 1970-07-02 | ||
GB3209770 | 1970-07-02 | ||
GB3215170 | 1970-07-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2072399A5 true FR2072399A5 (en) | 1971-09-24 |
Family
ID=27584046
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7042384A Expired FR2072399A5 (en) | 1969-11-25 | 1970-11-25 | Ammoxidation of alkanes to nitriles |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2072399A5 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2104020A5 (en) * | 1970-08-08 | 1972-04-14 | Degussa | |
FR2201127A1 (en) * | 1972-09-28 | 1974-04-26 | Ugine Kuhlmann | Antimony, bismuth, tin or lead oxide catalysts - for producing phthalic anhydride by catalytic oxidation of o-xylene |
FR2383703A1 (en) * | 1977-03-18 | 1978-10-13 | Gulf Research Development Co | Uranium oxide-antimony oxide catalyst compsn. - contg. Gp. IV B metal, esp. useful for ammonoxidation of propylene to acrylonitrile |
FR2678610A1 (en) * | 1991-07-04 | 1993-01-08 | Rhone Poulenc Chimie | PROCESS FOR AMMOXYDATING SATURATED HYDROCARBONS |
FR2684989A1 (en) * | 1991-12-16 | 1993-06-18 | Rhone Poulenc Chimie | PROCESS FOR AMMOXYDATING SATURATED HYDROCARBONS |
US5332855A (en) * | 1992-02-20 | 1994-07-26 | Rhone-Poulenc Chimie | Ammoxidation of saturated hydrocarbons |
US5336804A (en) * | 1992-02-06 | 1994-08-09 | Rhone-Poulenc Chimie | Ammoxidation of saturated hydrocarbons |
-
1970
- 1970-11-25 FR FR7042384A patent/FR2072399A5/en not_active Expired
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2104020A5 (en) * | 1970-08-08 | 1972-04-14 | Degussa | |
FR2201127A1 (en) * | 1972-09-28 | 1974-04-26 | Ugine Kuhlmann | Antimony, bismuth, tin or lead oxide catalysts - for producing phthalic anhydride by catalytic oxidation of o-xylene |
FR2383703A1 (en) * | 1977-03-18 | 1978-10-13 | Gulf Research Development Co | Uranium oxide-antimony oxide catalyst compsn. - contg. Gp. IV B metal, esp. useful for ammonoxidation of propylene to acrylonitrile |
FR2678610A1 (en) * | 1991-07-04 | 1993-01-08 | Rhone Poulenc Chimie | PROCESS FOR AMMOXYDATING SATURATED HYDROCARBONS |
EP0524895A1 (en) * | 1991-07-04 | 1993-01-27 | RHONE-POULENC FIBER & RESIN INTERMEDIATES | Process for the ammoxidation of saturated hydrocarbons |
US5556984A (en) * | 1991-07-04 | 1996-09-17 | Rhone-Poulenc Chimie | Ammoxidation of saturated hydrocarbons |
FR2684989A1 (en) * | 1991-12-16 | 1993-06-18 | Rhone Poulenc Chimie | PROCESS FOR AMMOXYDATING SATURATED HYDROCARBONS |
EP0547981A1 (en) * | 1991-12-16 | 1993-06-23 | Rhone-Poulenc Chimie | Process for ammoxidation of saturated hydrocarbons |
US5334743A (en) * | 1991-12-16 | 1994-08-02 | Rhone-Poulenc Chimie | Catalytic ammoxidation of saturated hydrocarbons |
US5336804A (en) * | 1992-02-06 | 1994-08-09 | Rhone-Poulenc Chimie | Ammoxidation of saturated hydrocarbons |
US5332855A (en) * | 1992-02-20 | 1994-07-26 | Rhone-Poulenc Chimie | Ammoxidation of saturated hydrocarbons |
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