GB1007929A - Improvements in or relating to the production of unsaturated aliphatic nitriles - Google Patents

Improvements in or relating to the production of unsaturated aliphatic nitriles

Info

Publication number
GB1007929A
GB1007929A GB43241/63A GB4324163A GB1007929A GB 1007929 A GB1007929 A GB 1007929A GB 43241/63 A GB43241/63 A GB 43241/63A GB 4324163 A GB4324163 A GB 4324163A GB 1007929 A GB1007929 A GB 1007929A
Authority
GB
United Kingdom
Prior art keywords
polyvalent metal
oxygen
relating
production
unsaturated aliphatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB43241/63A
Inventor
William John Ball
John Lynn Barclay
John Bohemen
Edward James Gasson
Barrie Wood
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Distillers Co Yeast Ltd
Distillers Co Ltd
Original Assignee
Distillers Co Yeast Ltd
Distillers Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA756121A priority Critical patent/CA756121A/en
Priority to IT740770D priority patent/IT740770A/it
Application filed by Distillers Co Yeast Ltd, Distillers Co Ltd filed Critical Distillers Co Yeast Ltd
Priority to GB43241/63A priority patent/GB1007929A/en
Priority to NL646411912A priority patent/NL141863B/en
Priority to FR993151A priority patent/FR1415967A/en
Priority to DE19641443750 priority patent/DE1443750C/en
Priority to BE655056D priority patent/BE655056A/xx
Publication of GB1007929A publication Critical patent/GB1007929A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/843—Arsenic, antimony or bismuth
    • B01J23/8435—Antimony
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Acrylonitrile is prepared by reacting at an elevated temperature in the vapour phase propylene, molecular oxygen, and ammonia over an oxide composition comprising antimony, uranium, oxygen and a polyvalent metal of atomic number 22 to 41, 44 to 49, 73, 77 to 83, or 90 as catalyst. The polyvalent metal is preferably Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ge, Zr, In, Ta, Tl or Pb. Examples are given in which the polyvalent metal is (a) copper, (b) iron, and (c) titanium. Acrolein is obtained as a by-product.ALSO:Catalysts for the reaction of propylene with ammonia and molecular oxygen (see Division C2) are oxide compositions comprising antimony, uranium, oxygen, and a polyvalent metal of atomic number 22-41, 44-49, 73, 77-83, or 90, many such metals being specified. Examples describe the preparation of catalysts in which the polyvalent metal is (1) copper, (2) iron, and (3) titanium.
GB43241/63A 1963-11-01 1963-11-01 Improvements in or relating to the production of unsaturated aliphatic nitriles Expired GB1007929A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CA756121A CA756121A (en) 1963-11-01 Production of unsaturated aliphatic nitriles
IT740770D IT740770A (en) 1963-11-01
GB43241/63A GB1007929A (en) 1963-11-01 1963-11-01 Improvements in or relating to the production of unsaturated aliphatic nitriles
NL646411912A NL141863B (en) 1963-11-01 1964-10-14 PROCESS FOR THE PREPARATION OF ACRYLONITRILE.
FR993151A FR1415967A (en) 1963-11-01 1964-10-20 Improvements in the production of unsaturated aliphatic nitriles
DE19641443750 DE1443750C (en) 1963-11-01 1964-10-28 Process for the production of acrylonitrile from propylene
BE655056D BE655056A (en) 1963-11-01 1964-10-30

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB4324263 1963-11-01
GB43241/63A GB1007929A (en) 1963-11-01 1963-11-01 Improvements in or relating to the production of unsaturated aliphatic nitriles

Publications (1)

Publication Number Publication Date
GB1007929A true GB1007929A (en) 1965-10-22

Family

ID=26265089

Family Applications (1)

Application Number Title Priority Date Filing Date
GB43241/63A Expired GB1007929A (en) 1963-11-01 1963-11-01 Improvements in or relating to the production of unsaturated aliphatic nitriles

Country Status (6)

Country Link
BE (1) BE655056A (en)
CA (1) CA756121A (en)
FR (1) FR1415967A (en)
GB (1) GB1007929A (en)
IT (1) IT740770A (en)
NL (1) NL141863B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3960925A (en) * 1973-09-07 1976-06-01 Bp Chemicals International Limited Production of acrylonitrile by ammoxidation of propylene
US3962310A (en) * 1973-01-02 1976-06-08 Monsanto Company Ammoxidation process
FR2383703A1 (en) * 1977-03-18 1978-10-13 Gulf Research Development Co Uranium oxide-antimony oxide catalyst compsn. - contg. Gp. IV B metal, esp. useful for ammonoxidation of propylene to acrylonitrile

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3962310A (en) * 1973-01-02 1976-06-08 Monsanto Company Ammoxidation process
US3960925A (en) * 1973-09-07 1976-06-01 Bp Chemicals International Limited Production of acrylonitrile by ammoxidation of propylene
FR2383703A1 (en) * 1977-03-18 1978-10-13 Gulf Research Development Co Uranium oxide-antimony oxide catalyst compsn. - contg. Gp. IV B metal, esp. useful for ammonoxidation of propylene to acrylonitrile

Also Published As

Publication number Publication date
NL6411912A (en) 1965-05-03
BE655056A (en) 1965-04-30
DE1443750B2 (en) 1973-01-04
CA756121A (en) 1967-04-04
NL141863B (en) 1974-04-16
DE1443750A1 (en) 1971-12-16
FR1415967A (en) 1965-10-29
IT740770A (en)

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