FR2397074A1 - Nouvelle pile lithium-iode a l'etat solide - Google Patents

Nouvelle pile lithium-iode a l'etat solide

Info

Publication number
FR2397074A1
FR2397074A1 FR7820227A FR7820227A FR2397074A1 FR 2397074 A1 FR2397074 A1 FR 2397074A1 FR 7820227 A FR7820227 A FR 7820227A FR 7820227 A FR7820227 A FR 7820227A FR 2397074 A1 FR2397074 A1 FR 2397074A1
Authority
FR
France
Prior art keywords
iodine
solid state
complex
lithium
iodide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7820227A
Other languages
English (en)
Other versions
FR2397074B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP8183877A external-priority patent/JPS5416624A/ja
Priority claimed from JP13540077A external-priority patent/JPS5468933A/ja
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Publication of FR2397074A1 publication Critical patent/FR2397074A1/fr
Application granted granted Critical
Publication of FR2397074B1 publication Critical patent/FR2397074B1/fr
Granted legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/182—Cells with non-aqueous electrolyte with solid electrolyte with halogenide as solid electrolyte
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49108—Electric battery cell making

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Primary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Conductive Materials (AREA)

Abstract

L'invention a trait au domaine des circuits électroniques. Elle concerne une pile à l'état solide comprenant une anode de lithium, une cathode d'iode renfermant un complexe de transfert de charge et un électrolyte solide formé d'iodure de lithium dopé avec un iodure de 1-n-alkylpyridinium. La surface de l'anode peut être revêtue d'hydroxyde ou de nitrure de lithium. La cathode d'iode est formée d'un complexe d'iode et d'iodure de 1-n-alkylpyridinium et contient de préférence du bioxyde de titane en poudre, du gel d'alumine en poudre ou du gel de silice en poudre, en mélange avec le complexe. La pile de l'invention, dont le mélange cathodique a une conductivité électronique relativement grande, est peu susceptible d'une auto-décharge interne.
FR7820227A 1977-07-07 1978-07-06 Nouvelle pile lithium-iode a l'etat solide Granted FR2397074A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP8183877A JPS5416624A (en) 1977-07-07 1977-07-07 Lithiummiodine base cell
JP13540077A JPS5468933A (en) 1977-11-10 1977-11-10 Lithiummiodine complex body battery

Publications (2)

Publication Number Publication Date
FR2397074A1 true FR2397074A1 (fr) 1979-02-02
FR2397074B1 FR2397074B1 (fr) 1983-09-09

Family

ID=26422836

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7820227A Granted FR2397074A1 (fr) 1977-07-07 1978-07-06 Nouvelle pile lithium-iode a l'etat solide

Country Status (6)

Country Link
US (2) US4148976A (fr)
CA (1) CA1108230A (fr)
CH (1) CH638343A5 (fr)
DE (1) DE2829031C3 (fr)
FR (1) FR2397074A1 (fr)
GB (1) GB2000898B (fr)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2925383A1 (de) * 1978-06-29 1980-01-03 Ebauches Sa Elektrochemische energiequelle
US4212930A (en) * 1979-03-15 1980-07-15 Medtronic, Inc. Lithium-halogen batteries
US4315975A (en) * 1979-08-15 1982-02-16 Matsushita Electric Industrial Co., Ltd. Solid-state lithium-iodine primary battery
US4276362A (en) * 1979-09-07 1981-06-30 Catalyst Research Corporation Depolarizers for lithium halide batteries
DE3039900C2 (de) * 1979-10-29 1983-11-03 Hitachi, Ltd., Tokyo Trockenelektrolyt
US4442187A (en) * 1980-03-11 1984-04-10 University Patents, Inc. Batteries having conjugated polymer electrodes
US4393125A (en) * 1980-04-21 1983-07-12 Medtronic, Inc. Battery cathodes
US4333996A (en) * 1980-09-29 1982-06-08 Union Carbide Corporation Solid state cell in which an inert nonconductive material is dispersed in the cathode
US4314010A (en) * 1980-09-29 1982-02-02 Union Carbide Corporation Solid state cell employing an electron donor-embedded anode
JPH0624122B2 (ja) * 1980-11-24 1994-03-30 メドトロニツク・インコ−ポレ−テツド 電気化学セル
DE3136578A1 (de) * 1981-09-15 1983-03-31 Varta Batterie Ag, 3000 Hannover Galvanisches element mit integriertem getter
JPS5861573A (ja) * 1981-10-08 1983-04-12 Matsushita Electric Ind Co Ltd 固体電解質電池およびその製造法
US4917974A (en) * 1989-04-14 1990-04-17 The United States Of America As Represented By The Department Of Energy Lithium/organosulfur redox cell having protective solid electrolyte barrier formed on anode and method of making same
US5114810A (en) * 1990-02-05 1992-05-19 Wilson Greatbatch Ltd. Cathode current collector material for solid cathode cell
JP2816886B2 (ja) * 1990-03-05 1998-10-27 興和株式会社 生体通電装置
US5318600A (en) * 1993-07-23 1994-06-07 Battery Engineering, Inc. Method for making a lithium anode for an electrochemical cell
ES2185479B1 (es) * 2001-02-28 2003-11-01 Vileta Jesus Anadon Pila alcalina de zinc / dioxido de manganeso con un inhibidor de corrosion
EP1552572A2 (fr) * 2002-10-15 2005-07-13 Polyplus Battery Company Composites conducteurs d'ions servant a proteger des anodes metalliques actives
FR2861218B1 (fr) * 2003-10-16 2007-04-20 Commissariat Energie Atomique Couche et procede de protection de microbatteries par une bicouche ceramique-metal
US8940443B2 (en) 2008-08-13 2015-01-27 Greatbatch Ltd. Polyvinylpyridine additives for nonaqueous electrolytes activating lithium rechargeable electrochemical cells
JP5691781B2 (ja) * 2011-03-03 2015-04-01 株式会社豊田中央研究所 非水電解質ハロゲン電池
DE102013017594A1 (de) * 2013-09-27 2015-04-02 Forschungszentrum Jülich GmbH Herstellungsverfahren für elektrochemische Zellen einer Festkörperbatterie

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1581648A (fr) * 1967-07-06 1969-09-19
US3937635A (en) * 1975-01-09 1976-02-10 Wilson Greatbatch Lithium-iodine battery
FR2306538A1 (fr) * 1975-04-03 1976-10-29 Catalyst Research Corp Pile a iode-lithium et son procede de fabrication
JPS5249490A (en) * 1975-10-17 1977-04-20 Matsushita Electric Ind Co Ltd Production method of lithium ion conductive solid state electrolyte
DE2645106A1 (de) * 1976-07-09 1978-01-12 Matsushita Electric Ind Co Ltd Primaerbatterie

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3352720A (en) * 1964-03-09 1967-11-14 Glenn R Wilson Polymeric depolarizers
US3660163A (en) * 1970-06-01 1972-05-02 Catalyst Research Corp Solid state lithium-iodine primary battery
US3709734A (en) * 1971-02-09 1973-01-09 Mallory & Co Inc P R Cathodes for solid electrolyte cells
US3837920A (en) * 1971-07-09 1974-09-24 Mallory & Co Inc P R A battery containing a solid electrolyte having cationic defects
US3957533A (en) * 1974-11-19 1976-05-18 Wilson Greatbatch Ltd. Lithium-iodine battery having coated anode
US4182797A (en) 1975-09-17 1980-01-08 Matsushita Electric Industrial Co., Ltd. Primary battery utilizing iodine charge transfer complex having a quaternary ammonium group

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1581648A (fr) * 1967-07-06 1969-09-19
US3937635A (en) * 1975-01-09 1976-02-10 Wilson Greatbatch Lithium-iodine battery
FR2306538A1 (fr) * 1975-04-03 1976-10-29 Catalyst Research Corp Pile a iode-lithium et son procede de fabrication
JPS5249490A (en) * 1975-10-17 1977-04-20 Matsushita Electric Ind Co Ltd Production method of lithium ion conductive solid state electrolyte
DE2645106A1 (de) * 1976-07-09 1978-01-12 Matsushita Electric Ind Co Ltd Primaerbatterie

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CA1977 *
EXBK/77 *

Also Published As

Publication number Publication date
US4148976A (en) 1979-04-10
DE2829031B2 (de) 1981-09-10
FR2397074B1 (fr) 1983-09-09
CH638343A5 (de) 1983-09-15
USRE31489E (en) 1984-01-10
DE2829031A1 (de) 1979-01-18
CA1108230A (fr) 1981-09-01
DE2829031C3 (de) 1982-05-19
GB2000898A (en) 1979-01-17
GB2000898B (en) 1982-07-28

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Legal Events

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ST Notification of lapse