FR2373325A1 - - Google Patents

Info

Publication number
FR2373325A1
FR2373325A1 FR7736497A FR7736497A FR2373325A1 FR 2373325 A1 FR2373325 A1 FR 2373325A1 FR 7736497 A FR7736497 A FR 7736497A FR 7736497 A FR7736497 A FR 7736497A FR 2373325 A1 FR2373325 A1 FR 2373325A1
Authority
FR
France
Prior art keywords
hydrogen sulfide
hydrogen
sulfur compounds
passed
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7736497A
Other languages
English (en)
Other versions
FR2373325B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of FR2373325A1 publication Critical patent/FR2373325A1/fr
Application granted granted Critical
Publication of FR2373325B1 publication Critical patent/FR2373325B1/fr
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/02Preparation of sulfur; Purification
    • C01B17/04Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0456Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Treating Waste Gases (AREA)
  • Industrial Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

Procédé pour traiter des gaz contenant de l'hydrogène sulfuré. Le gaz résiduel de réaction de l'unité de récupération du soufre 7 est passé en même temps qu'un gaz contenant de l'hydrogène sulfuré et d'autres composes du soufre, en présence d'un gaz contenant de l'hydrogène libre et/ou de l'oxyde de carbone libre sur un catalyseur pour la transformation en 13 des composés du soufre autres que l'hydrogène sulfuré en hydrogène sulfuré. Le mélange de gaz réduit est refroidi et passé dans une zone d'absorption 16 dans des conditions définies. La partie non absorbée est déchargée et l'absorbant enrichi en hydrogène sulfuré est régénéré. L'absorbant régénéré est réutilisé pour une nouvelle absorption et le mélange de gaz riche en hydrogène sulfuré est passé à l'unité. Application : réduction de la pollution par les composés du soufre.
FR7736497A 1976-12-07 1977-12-05 Expired FR2373325B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB50996/76A GB1563251A (en) 1976-12-07 1976-12-07 Process for working hydrogen suphidecontaining gases

Publications (2)

Publication Number Publication Date
FR2373325A1 true FR2373325A1 (fr) 1978-07-07
FR2373325B1 FR2373325B1 (fr) 1982-04-23

Family

ID=10458241

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7736497A Expired FR2373325B1 (fr) 1976-12-07 1977-12-05

Country Status (12)

Country Link
US (1) US4153674A (fr)
JP (1) JPS5372007A (fr)
AU (1) AU512247B2 (fr)
BE (1) BE861478A (fr)
BR (1) BR7708102A (fr)
CA (1) CA1098285A (fr)
DE (1) DE2754118C2 (fr)
FR (1) FR2373325B1 (fr)
GB (1) GB1563251A (fr)
NL (1) NL188508C (fr)
PL (1) PL202656A1 (fr)
RO (1) RO76302A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2501663A1 (fr) * 1981-03-13 1982-09-17 Technip Cie Procede et installation de traitement des gaz acides pour la recuperation et la production de soufre et de gaz carbonique

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FR2425886A1 (fr) * 1978-05-16 1979-12-14 Elf Aquitaine Procede de purification de gaz residuaires industriels renfermant en faibles concentrations des composes soufres
NL186377C (nl) * 1978-05-23 1990-11-16 Shell Int Research Werkwijze voor het opwerken van zwavelwaterstof bevattende gassen.
US4528277A (en) * 1979-04-04 1985-07-09 Union Oil Company Of California Catalyst for oxidizing hydrogen sulfide
US4444908A (en) * 1979-04-04 1984-04-24 Union Oil Company Of California Catalyst and process for oxidizing hydrogen sulfide
US4576814A (en) * 1979-04-04 1986-03-18 Union Oil Company Of California Catalyst and process for oxidizing hydrogen sulfide
US4444742A (en) * 1979-04-04 1984-04-24 Union Oil Company Of California Catalyst and process for oxidizing hydrogen sulfide
JPS5613022A (en) * 1979-07-14 1981-02-07 Toyo Eng Corp Gas desulfurizing method
NL8001886A (nl) * 1980-03-31 1981-11-02 Shell Int Research Werkwijze voor het verwijderen van zure gassen uit een in hoofdzaak uit methaan bestaand gasmengsel.
US4298584A (en) * 1980-06-05 1981-11-03 Eic Corporation Removing carbon oxysulfide from gas streams
US4356161A (en) * 1981-08-24 1982-10-26 Shell Oil Company Process for reducing the total sulfur content of a high CO2 -content feed gas
CA1221223A (fr) * 1983-10-07 1987-05-05 George W. Taggart Traitement des gaz d'echappement
US4533529A (en) * 1983-10-21 1985-08-06 Standard Oil Company Sulfur recovery process
US4552747A (en) * 1984-06-20 1985-11-12 Gaa Engineered Systems, Inc. Temperature moderation of an oxygen enriched Claus sulfur plant
US4888162A (en) * 1984-07-03 1989-12-19 Air Products And Chemicals, Inc. Temperature moderation with water of an oxygen enriched claus sulfur plant
US4632818A (en) * 1984-10-03 1986-12-30 Air Products And Chemicals, Inc. Production of sulfur from an oxygen enriched claus system
US4826670A (en) * 1985-03-20 1989-05-02 Air Products And Chemicals, Inc. Oxygen enriched claus system with sulfuric acid injection
US4618481A (en) * 1985-08-30 1986-10-21 Exxon Research And Engineering Co. Absorbent composition containing a severely hindered amino compound and an amine salt and process for the absorption of H2 S using the same
US4919912A (en) * 1985-10-18 1990-04-24 Ford, Bacon & Davis Incorporated Process for the treatment of sulfur containing gases
US4798716A (en) * 1986-04-29 1989-01-17 Amoco Corporation Sulfur recovery plant and process using oxygen
US4892674A (en) * 1987-10-13 1990-01-09 Exxon Research And Engineering Company Addition of severely-hindered amine salts and/or aminoacids to non-hindered amine solutions for the absorption of H2 S
US4894178A (en) * 1987-10-13 1990-01-16 Exxon Research And Engineering Company Absorbent composition containing severely-hindered amine mixture for the absorption of H2 S
US4894179A (en) * 1987-10-13 1990-01-16 Exxon Research And Engineering Company Absorbent composition containing a tertiary amino azabicyclic alcohol and an amine salt
US4895670A (en) * 1987-10-13 1990-01-23 Exxon Research And Engineering Company Addition of severely-hindered aminoacids to severely-hindered amines for the absorption of H2 S
US4849203A (en) * 1987-12-07 1989-07-18 Amoco Corporation Sulfur recovery plant and process using oxygen
US5139765A (en) * 1988-01-21 1992-08-18 Union Carbide Industrial Gases Technology Corporation Dual combustion zone sulfur recovery process
US5139764A (en) * 1988-01-21 1992-08-18 Union Carbide Industrial Gases Technology Corporation Sulfur recovery process for ammonia-containing feed gas
US5021232A (en) * 1989-09-29 1991-06-04 Cng Research Company Sulfur recovery process
US5556606A (en) * 1994-10-07 1996-09-17 Khanmamedov; Tofik K. Method and apparatus for controlling the hydrogen sulfide concentration in the acid gas feedstock of a sulfur recovery unit
US6506349B1 (en) 1994-11-03 2003-01-14 Tofik K. Khanmamedov Process for removal of contaminants from a gas stream
AU4134796A (en) * 1994-11-03 1996-05-31 Khanmamedov, Tufik K. Method and apparatus for removal of contaminates from refinery gas
US6508998B1 (en) 1996-10-28 2003-01-21 Gaa Engineered Systems, Inc. Temperature moderation of an oxygen enriched claus sulfur plant using an ejector
DE10219900B4 (de) * 2002-05-03 2004-08-26 Lurgi Ag Verfahren zur Reinigung von kohlenwasserstoffhaltigem Gas
JP4467872B2 (ja) * 2002-08-09 2010-05-26 三菱重工業株式会社 ガス化ガス用のcos処理装置とcos処理方法
US7214358B2 (en) * 2003-08-13 2007-05-08 Cansolv Technologies Inc. Low energy regenerable SO2 scrubbing process
EA010173B1 (ru) * 2004-04-22 2008-06-30 Флуор Текнолоджиз Корпорейшн Установки и способы для переработки cos по реакции клауса
KR20070053727A (ko) 2004-08-02 2007-05-25 쉘 인터내셔날 리써취 마트샤피지 비.브이. 천연 기체 또는 불활성 기체를 포함하는 기체스트림으로부터의 메르캅탄의 제거 방법
DE102004060321A1 (de) 2004-12-15 2006-06-22 Basf Ag Verwendung von H2S-haltigen Abgasströmen zur Herstellung von schwefelhaltigen Produkten
US7597871B2 (en) 2005-01-13 2009-10-06 Goar, Allison & Associates, Inc. Steam modified Claus process
US7172746B1 (en) 2005-12-30 2007-02-06 Gaa Engineered Systems, Inc. Temperature moderated claus process
AR066680A1 (es) * 2007-05-25 2009-09-02 Shell Int Research Un proceso para remover azufre de una corriente de gas combustible, que tambien contiene dioxido de carbono y olefinas livianas
AR066682A1 (es) * 2007-05-25 2009-09-02 Shell Int Research Un proceso para remover azufre a partir de sendas corrientes de gas de combustible, menos reactivas y mas reactivas que contienen azufre organico y olefinas livianas
AU2008292143B2 (en) * 2007-08-30 2011-12-08 Shell Internationale Research Maatschappij B.V. Process for removal of hydrogen sulphide and carbon dioxide from an acid gas stream
DE102008050088A1 (de) * 2008-10-06 2010-04-22 Uhde Gmbh Verfahren zur Entschwefelung
FR2937880B1 (fr) * 2008-11-06 2011-03-18 Inst Francais Du Petrole Procede de conversion des composes soufres presents dans un gaz acide en soufre elementaire.
US8444943B2 (en) 2010-04-30 2013-05-21 Black & Veatch Corporation Methods and apparatus for sulfur recovery from acid gases
CN102631827A (zh) * 2012-04-11 2012-08-15 山东三维石化工程股份有限公司 与低温甲醇洗酸性气处理相结合的零排放硫回收工艺
DK2969131T3 (da) * 2013-03-14 2020-03-23 Stamicarbon B V Acting Under The Name Of Mt Innovation Center Cos- og cs2-reduktionsfremgangsmåde
CN103611391B (zh) 2013-12-12 2016-01-20 北京博源恒升高科技有限公司 乙二醇类复合溶液脱除气体中SOx的方法
CN116020466A (zh) * 2021-10-26 2023-04-28 中国石油化工股份有限公司 Cos转化催化剂及制备方法与回收天然气中硫的方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
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US3752877A (en) * 1969-08-27 1973-08-14 Parsons Co Ralph M Recovery of sulfur compounds from tail gases
CA918384A (en) * 1970-01-12 1973-01-09 The Ralph M. Parsons Company Sulfur production process
NL171144B (nl) * 1970-07-17 1982-09-16 Shell Int Research Werkwijze voor het verlagen van het totale zwavelgehalte van clausafgassen.
NL7013902A (fr) * 1970-09-21 1972-03-23
NL177190C (nl) * 1973-02-19 1985-08-16 Shell Int Research Verbeterde werkwijze voor het verlagen van het totale zwavelgehalte van claus-afgassen.
IT1048269B (it) * 1973-03-01 1980-11-20 Shell Int Research Processo per ridurre il contenuto totale di zolfo di gas di scarico del processo claus
NL7310929A (fr) * 1973-08-08 1974-01-25
US3985861A (en) * 1974-09-16 1976-10-12 Shell Oil Company Process for removing sulfur compounds from claus off-gases
US3965244A (en) * 1974-11-27 1976-06-22 Shell Oil Company Selective removal of sulfur compounds from acid gas mixtures containing significant quantities of carbonyl sulfide
US3989811A (en) * 1975-01-30 1976-11-02 Shell Oil Company Process for recovering sulfur from fuel gases containing hydrogen sulfide, carbon dioxide, and carbonyl sulfide

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2501663A1 (fr) * 1981-03-13 1982-09-17 Technip Cie Procede et installation de traitement des gaz acides pour la recuperation et la production de soufre et de gaz carbonique

Also Published As

Publication number Publication date
DE2754118A1 (de) 1978-06-08
GB1563251A (en) 1980-03-26
FR2373325B1 (fr) 1982-04-23
JPS627960B2 (fr) 1987-02-19
BE861478A (nl) 1978-06-05
NL188508B (nl) 1992-02-17
DE2754118C2 (de) 1986-10-23
RO76302A (fr) 1981-11-24
NL7713418A (nl) 1978-06-09
US4153674A (en) 1979-05-08
NL188508C (nl) 1992-07-16
CA1098285A (fr) 1981-03-31
AU3122777A (en) 1979-06-14
JPS5372007A (en) 1978-06-27
AU512247B2 (en) 1980-10-02
BR7708102A (pt) 1978-09-26
PL202656A1 (pl) 1978-06-19

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