FR2367081A1 - Procede de production de composants de catalyseurs pour la polymerisation d'olefines - Google Patents
Procede de production de composants de catalyseurs pour la polymerisation d'olefinesInfo
- Publication number
- FR2367081A1 FR2367081A1 FR7730282A FR7730282A FR2367081A1 FR 2367081 A1 FR2367081 A1 FR 2367081A1 FR 7730282 A FR7730282 A FR 7730282A FR 7730282 A FR7730282 A FR 7730282A FR 2367081 A1 FR2367081 A1 FR 2367081A1
- Authority
- FR
- France
- Prior art keywords
- olefins
- polymerization
- production
- catalyst components
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 abstract 2
- DSPXASHHKFVPCL-UHFFFAOYSA-N 1-isocyanocyclohexene Chemical compound [C-]#[N+]C1=CCCCC1 DSPXASHHKFVPCL-UHFFFAOYSA-N 0.000 abstract 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- -1 magnesium halide Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000008247 solid mixture Substances 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
L'invention concerne un procédé de production de composants de catalyseurs pour la polymérisation d'oléfines. On prépare un composant de catalyseur, à combiner avec un composant organique de l'aluminium pour constituer un catalyseur de Ziegler pour la polymérisation d'oléfines, par traitement : 1 degrés d'une composition solide résultant d'un processus de combinaison d'un halogénure de magnésium tel que le chlorure de magnésium anhydre, d'un composé donneur d'électrons tel que le benzoate d'éthyle et d'un composé halogéné du titane tel que le tétrachlorure de titane; et 2 degrés d'un composé inter-halogéné ou d'un halogène tel que le trichlorure d'iode Le rendement en polymères et leur stéréo-spécificité sont fortement améfiorés.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12063476A JPS5345688A (en) | 1976-10-07 | 1976-10-07 | Production of olefin polymerization catalyst component |
JP9668977A JPS5431092A (en) | 1977-08-12 | 1977-08-12 | Production of olefin polymerization catalyst component |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2367081A1 true FR2367081A1 (fr) | 1978-05-05 |
Family
ID=26437864
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7730282A Withdrawn FR2367081A1 (fr) | 1976-10-07 | 1977-10-07 | Procede de production de composants de catalyseurs pour la polymerisation d'olefines |
Country Status (8)
Country | Link |
---|---|
US (1) | US4146502A (fr) |
CA (1) | CA1095018A (fr) |
CS (1) | CS204012B2 (fr) |
DE (1) | DE2744559A1 (fr) |
FR (1) | FR2367081A1 (fr) |
GB (1) | GB1586241A (fr) |
IT (1) | IT1116127B (fr) |
NL (1) | NL7710919A (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0131359A1 (fr) * | 1983-06-15 | 1985-01-16 | Imperial Chemical Industries Plc | Fabrication d'un composant de catalyseur et son utilisation |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS595202B2 (ja) * | 1978-04-12 | 1984-02-03 | 東亜燃料工業株式会社 | α−オレフィンの重合用触媒成分の製造方法 |
JPS5919564B2 (ja) * | 1978-04-12 | 1984-05-07 | 東亜燃料工業株式会社 | α−オレフインの重合用触媒成分の製造方法 |
JPS5919565B2 (ja) * | 1978-04-12 | 1984-05-07 | 東亜燃料工業株式会社 | α−オレフインの重合用触媒成分の製造法 |
DE2839136A1 (de) * | 1978-09-08 | 1980-03-20 | Bayer Ag | Katalysator auf einem festen traeger zur polymerisation von alpha -olefinen |
JPS5582103A (en) * | 1978-12-15 | 1980-06-20 | Mitsubishi Petrochem Co Ltd | Production of alpha-olefin polymer |
JPS55102606A (en) * | 1979-01-30 | 1980-08-06 | Mitsui Toatsu Chem Inc | Polymerization of alpha-olefin |
JPS55115416A (en) * | 1979-02-27 | 1980-09-05 | Nippon Oil Co Ltd | Manufacture of copolymer |
DE3064564D1 (en) * | 1979-04-30 | 1983-09-22 | Shell Int Research | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions |
CA1141093A (fr) * | 1979-05-17 | 1983-02-08 | Brian L. Goodall | Compositions catalytiques pour la polymerisation d'olefines, et methode de polymerisation d'olefines utilisant ces compositions |
JPS5665008A (en) * | 1979-10-31 | 1981-06-02 | Denki Kagaku Kogyo Kk | Catalyst component for olefin polymerization |
DE3068239D1 (en) * | 1979-11-20 | 1984-07-19 | Shell Int Research | Preparation of catalyst components and polymerization of olefins employing such catalyst components |
US4325836A (en) * | 1980-07-18 | 1982-04-20 | Stauffer Chemical Company | Novel titanium halide containing catalyst |
US4353813A (en) * | 1980-09-29 | 1982-10-12 | Standard Oil Company (Indiana) | Catalyst for polymerization of alpha-olefins |
US4347162A (en) * | 1981-03-06 | 1982-08-31 | Euteco Impianti S.P.A. | Catalyst for the polymerization of alpha-olefins |
US4384984A (en) * | 1981-09-30 | 1983-05-24 | Stauffer Chemical Company | Titanium catalyst for polymerizing olefins |
US4681924A (en) * | 1982-12-29 | 1987-07-21 | National Distillers And Chemical Corporation | Catalyst systems for polymerizations at high temperatures |
US4707530A (en) * | 1983-01-31 | 1987-11-17 | Exxon Research & Engineering Co. | Polymerization catalyst |
US4960593A (en) * | 1985-01-30 | 1990-10-02 | Hilmont Incorporated | Process for preparing thermally stable olefinic polymers |
FI102070B (fi) * | 1996-03-29 | 1998-10-15 | Borealis As | Uusi kompleksiyhdiste, sen valmistus ja käyttö |
US6306983B1 (en) | 1999-05-14 | 2001-10-23 | 3M Innovative Properties Company | Ziegler-Natta polymerization of alpha-olefins in the presence of non-polymerizing olefins |
EP1916264A1 (fr) * | 2006-10-23 | 2008-04-30 | Total Petrochemicals Research Feluy | Préparation de polypropylène ayant un faible taux de cendres. |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3206447A (en) * | 1961-03-13 | 1965-09-14 | Phillips Petroleum Co | Production of cis-1, 4-polybutadiene with a titanium halide-mgr-i catalyst |
US3223694A (en) * | 1962-03-20 | 1965-12-14 | Phillips Petroleum Co | Process and catalyst for production of rubbery polymers |
US3524840A (en) * | 1968-09-11 | 1970-08-18 | Gen Tire & Rubber Co | Catalysts for the polymerization of 1,3-butadiene,their methods of preparation and use |
US3953414A (en) * | 1972-09-13 | 1976-04-27 | Montecatini Edison S.P.A., | Catalysts for the polymerization of olefins to spherically shaped polymers |
US3859231A (en) * | 1972-10-13 | 1975-01-07 | Gulf Research Development Co | Simplified process for manufacture of catalyst component |
US3972862A (en) * | 1974-07-22 | 1976-08-03 | Tornqvist Erik G M | Stereoregulated copolymers of butadiene and piperylene |
-
1977
- 1977-10-04 DE DE19772744559 patent/DE2744559A1/de not_active Withdrawn
- 1977-10-05 NL NL7710919A patent/NL7710919A/xx not_active Application Discontinuation
- 1977-10-06 US US05/839,843 patent/US4146502A/en not_active Expired - Lifetime
- 1977-10-06 IT IT51294/77A patent/IT1116127B/it active
- 1977-10-06 CA CA288,277A patent/CA1095018A/fr not_active Expired
- 1977-10-07 FR FR7730282A patent/FR2367081A1/fr not_active Withdrawn
- 1977-10-07 CS CS776533A patent/CS204012B2/cs unknown
- 1977-10-07 GB GB41801/77A patent/GB1586241A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0131359A1 (fr) * | 1983-06-15 | 1985-01-16 | Imperial Chemical Industries Plc | Fabrication d'un composant de catalyseur et son utilisation |
Also Published As
Publication number | Publication date |
---|---|
CA1095018A (fr) | 1981-02-03 |
IT1116127B (it) | 1986-02-10 |
NL7710919A (nl) | 1978-04-11 |
US4146502A (en) | 1979-03-27 |
DE2744559A1 (de) | 1978-04-13 |
CS204012B2 (en) | 1981-03-31 |
GB1586241A (en) | 1981-03-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |