FR2366247A1 - Procede d'hydrogenation selective des groupements cetoniques dans les cetones olefiniques non conjuguees - Google Patents

Procede d'hydrogenation selective des groupements cetoniques dans les cetones olefiniques non conjuguees

Info

Publication number
FR2366247A1
FR2366247A1 FR7729903A FR7729903A FR2366247A1 FR 2366247 A1 FR2366247 A1 FR 2366247A1 FR 7729903 A FR7729903 A FR 7729903A FR 7729903 A FR7729903 A FR 7729903A FR 2366247 A1 FR2366247 A1 FR 2366247A1
Authority
FR
France
Prior art keywords
selective hydrogenation
conjugate
ketones
ketonic groups
olefinic ketones
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7729903A
Other languages
English (en)
Other versions
FR2366247B1 (fr
Inventor
Peter S Gradeff
Giuseppe Formic
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc Industries SA
Original Assignee
Rhone Poulenc Industries SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Industries SA filed Critical Rhone Poulenc Industries SA
Publication of FR2366247A1 publication Critical patent/FR2366247A1/fr
Application granted granted Critical
Publication of FR2366247B1 publication Critical patent/FR2366247B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/02—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains containing only carbon and hydrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/08—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Procédé d'hydrogénation sélective de cétones éthyléniques du groupe de la méthylhepténone et de ses homologues en alcools éthylénique en présence d'un catalyseur au nickel contenant du chrome, de méthanol ou d'éthanol et d'une base alcaline.
FR7729903A 1976-09-30 1977-09-29 Procede d'hydrogenation selective des groupements cetoniques dans les cetones olefiniques non conjuguees Granted FR2366247A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/728,346 US4041083A (en) 1976-09-30 1976-09-30 Process for the selective hydrogenation of the keto group in nonconjugated olefinic ketones

Publications (2)

Publication Number Publication Date
FR2366247A1 true FR2366247A1 (fr) 1978-04-28
FR2366247B1 FR2366247B1 (fr) 1980-04-25

Family

ID=24926471

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7729903A Granted FR2366247A1 (fr) 1976-09-30 1977-09-29 Procede d'hydrogenation selective des groupements cetoniques dans les cetones olefiniques non conjuguees

Country Status (11)

Country Link
US (1) US4041083A (fr)
JP (1) JPS5344506A (fr)
BE (1) BE859220A (fr)
CA (1) CA1086332A (fr)
CH (1) CH624372A5 (fr)
DE (1) DE2744134A1 (fr)
ES (1) ES462810A1 (fr)
FR (1) FR2366247A1 (fr)
GB (1) GB1569334A (fr)
IT (1) IT1084796B (fr)
NL (1) NL7710677A (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2934251A1 (de) * 1979-08-24 1981-03-26 Basf Ag, 67063 Ludwigshafen Verfahren zur herstellung von ungesaettigten alkoholen.
IT1129758B (it) * 1980-01-23 1986-06-11 Montedison Spa Processo per la riduzione catalitica di chetoni insaturi
CH648281A5 (fr) * 1981-04-21 1985-03-15 Firmenich & Cie Composes macrocycliques et leur utilisation.
DE3130805A1 (de) * 1981-08-04 1983-02-24 Basf Ag, 6700 Ludwigshafen Neue ruthenium/kohle-hydrierkatalysatoren, deren herstellung und verwendung zur selektiven hydrierung von ungesaettigten carbonylverbindungen
GB2215330A (en) * 1988-03-04 1989-09-20 Shell Int Research Hydrogenation of esters into alcohols
DE3824625A1 (de) * 1988-07-20 1990-01-25 Bayer Ag Verfahren zur hydrierung von (alpha),(beta)-ungesaettigten ketonen
DE3824518A1 (de) * 1988-07-20 1990-01-25 Bayer Ag Verfahren zur herstellung von 4,4-dimethyl-1-(p-chlor-phenyl)-pentan-3-on
JPH0753680B2 (ja) * 1989-07-17 1995-06-07 高砂香料工業株式会社 光学活性ケトンの製造法
DE19505938A1 (de) * 1995-02-21 1996-08-22 Bayer Ag Verfahren zur Herstellung von 1-(4-Chlorphenyl)-4,4-dimethyl-pentan-3-on
CN102603473A (zh) * 2012-01-13 2012-07-25 河北科技大学 一种羰基化合物选择性加氢制备相应醇的方法
CN117986090A (zh) * 2018-07-23 2024-05-07 西姆莱斯股份公司 具有玫瑰气味的新型香味剂

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2983734A (en) * 1961-05-09 Catalytic hydrogenation
US2009948A (en) * 1931-08-27 1935-07-30 Ig Farbenindustrie Ag Production of unsaturated alcohols
US2448047A (en) * 1947-02-15 1948-08-31 Burton T Bush Inc Preparation of unsaturated alcohols
US2767221A (en) * 1953-06-11 1956-10-16 Shell Dev Production of unsaturated alcohols
US3102150A (en) * 1960-02-19 1963-08-27 Exxon Research Engineering Co Process for hydrogenating carbonyl compounds
US3109865A (en) * 1961-10-24 1963-11-05 Standard Oil Co Manufacture of allyl alcohol
US3471575A (en) * 1962-04-28 1969-10-07 Shiro Kudo Catalytic hydrogenation of alpha,beta-unsaturated carbonyl compounds,unsaturated fatty acids,and unsaturated fatty acid esters
US3268589A (en) * 1963-05-29 1966-08-23 Reynolds Tobacco Co R Process for preparing 4-(2-butenylidene)-3, 5, 5-trimethyl-2-cyclohexene-1-one
US3284517A (en) * 1963-09-11 1966-11-08 Engelhard Ind Inc Hydrogenation of alpiia, beta-unsaturated aldehydes to alpha, beta-unsaturated alcohols
US3463818A (en) * 1966-01-25 1969-08-26 Int Flavors & Fragrances Inc Unsaturated aldehydes and alcohols
US3991127A (en) * 1967-03-18 1976-11-09 Basf Aktiengesellschaft Production of saturated aliphatic alcohols
NL6712077A (fr) * 1967-09-01 1969-03-04
US3655777A (en) * 1968-11-12 1972-04-11 Engelhard Min & Chem Hydrogenation of unsaturated aldehydes to unsaturated alcohols
GB1383246A (en) * 1971-01-13 1975-02-05 Yeda Res & Dev Production of alcohols from aldehydes and ketones
CH566113A5 (fr) * 1973-02-09 1975-09-15 Firmenich & Cie
CH576926A5 (fr) * 1973-03-21 1976-06-30 Hoffmann La Roche

Also Published As

Publication number Publication date
JPS5344506A (en) 1978-04-21
NL7710677A (nl) 1978-04-03
GB1569334A (en) 1980-06-11
FR2366247B1 (fr) 1980-04-25
ES462810A1 (es) 1978-05-16
US4041083A (en) 1977-08-09
IT1084796B (it) 1985-05-28
CH624372A5 (fr) 1981-07-31
BE859220A (fr) 1978-03-29
DE2744134A1 (de) 1978-04-06
CA1086332A (fr) 1980-09-23

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