FR2366058A1 - Catalyseur pour la reduction selective d'oxydes d'azote provenant de gaz de combustion contenant de l'oxygene - Google Patents

Catalyseur pour la reduction selective d'oxydes d'azote provenant de gaz de combustion contenant de l'oxygene

Info

Publication number
FR2366058A1
FR2366058A1 FR7729331A FR7729331A FR2366058A1 FR 2366058 A1 FR2366058 A1 FR 2366058A1 FR 7729331 A FR7729331 A FR 7729331A FR 7729331 A FR7729331 A FR 7729331A FR 2366058 A1 FR2366058 A1 FR 2366058A1
Authority
FR
France
Prior art keywords
catalyst
nitrogen oxides
combustion gases
containing oxygen
selective reduction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7729331A
Other languages
English (en)
Other versions
FR2366058B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP11742476A external-priority patent/JPS5343092A/ja
Priority claimed from JP1687477A external-priority patent/JPS53102288A/ja
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Publication of FR2366058A1 publication Critical patent/FR2366058A1/fr
Application granted granted Critical
Publication of FR2366058B1 publication Critical patent/FR2366058B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20723—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24149—Honeycomb-like
    • Y10T428/24165—Hexagonally shaped cavities

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)

Abstract

Préparation d'un catalyseur pour la réduction catalytique sélective d'oxydes d'azote utilisant de l'ammoniac comme réducteur, par mélange d'une matière à base d'acide silicique à une matière à base de chaux, chauffage du mélange sous pression pour former une bouillie de cristaux de silicate de calcium, transformation de la bouillie en un support, puis dépôt sur le support d'un ingrédient catalytiquement actif.
FR7729331A 1976-09-30 1977-09-29 Catalyseur pour la reduction selective d'oxydes d'azote provenant de gaz de combustion contenant de l'oxygene Granted FR2366058A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP11742476A JPS5343092A (en) 1976-09-30 1976-09-30 Exhaust gas treatment catalyst
JP1687477A JPS53102288A (en) 1977-02-18 1977-02-18 Preparation of catalyst for treatment of exhaust gas

Publications (2)

Publication Number Publication Date
FR2366058A1 true FR2366058A1 (fr) 1978-04-28
FR2366058B1 FR2366058B1 (fr) 1979-06-01

Family

ID=26353315

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7729331A Granted FR2366058A1 (fr) 1976-09-30 1977-09-29 Catalyseur pour la reduction selective d'oxydes d'azote provenant de gaz de combustion contenant de l'oxygene

Country Status (3)

Country Link
US (2) US4186109A (fr)
DE (1) DE2744688C2 (fr)
FR (1) FR2366058A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2368987A1 (fr) * 1976-11-01 1978-05-26 Mitsubishi Chem Ind Reduction catalytique des oxydes d'azote
EP0220416A1 (fr) * 1985-09-06 1987-05-06 Siemens Aktiengesellschaft Catalyseur pour la réduction d'oxydes d'azote
EP0239778A1 (fr) * 1986-03-06 1987-10-07 Siemens Aktiengesellschaft Catalyseur pour diminuer le taux d'oxydes d'azote dans les gaz de fumée
EP0266540A1 (fr) * 1986-10-08 1988-05-11 Siemens Aktiengesellschaft Matériau catalyseur pour diminuer le taux d'oxydes d'azote dans des gaz de fumée
US5225390A (en) * 1988-02-23 1993-07-06 Siemens Aktiengesellschaft Catalyst for reducing nitrogen oxides

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4285838A (en) * 1977-12-08 1981-08-25 Babcock-Hitachi Kabushiki Kaisha Method of producing plate-shaped catalyst unit for NOx reduction of exhaust gas
JPS5628640A (en) * 1979-08-18 1981-03-20 Tokuyama Soda Co Ltd Molded product for absorbing liquid
DE3430886A1 (de) * 1984-08-22 1986-02-27 Didier Engineering Gmbh, 4300 Essen Katalysator zum abscheiden von stickoxiden aus verbrennungsabgasen
DE3433093A1 (de) * 1984-09-08 1986-03-20 Bergwerksverband Gmbh, 4300 Essen Mit katalytisch aktivem material beschichtete wabenkatalysatoren zur no(pfeil abwaerts)x(pfeil abwaerts)-reduktion und verfahren zu deren herstellung
DE3513567A1 (de) * 1985-04-16 1986-10-16 Bayer Ag, 5090 Leverkusen Verfahren zur reduzierung von stickoxiden
JPH064126B2 (ja) * 1985-06-10 1994-01-19 株式会社日本触媒 排ガス浄化方法
DE3532226A1 (de) * 1985-08-13 1987-03-19 Sued Chemie Ag Katalysator zur verringerung des stickoxidgehalts von verbrennungsabgasen
DE3529060A1 (de) * 1985-08-13 1987-02-26 Sued Chemie Ag Katalysator zur verringerung des stickoxidgehalts von verbrennungsgasen
EP0219600A3 (fr) * 1985-08-27 1988-04-13 Didier-Werke Ag Catalyseur pour la séparation d'oxyde d'azote à partir de gaz de combustion
US4680040A (en) * 1986-01-17 1987-07-14 Xerox Corporation Multipurpose filtering material
DE3614347A1 (de) * 1986-04-28 1987-10-29 Didier Werke Ag Katalysatorbaustein
US4874590A (en) * 1988-04-07 1989-10-17 Uop Catalytic reduction of nitrogen oxides
US4806320A (en) * 1988-04-21 1989-02-21 Sanitech, Inc. Process for Nox control
US4871522A (en) * 1988-07-25 1989-10-03 The Babcock & Wilcox Company Combined catalytic baghouse and heat pipe air heater
US5585081A (en) * 1988-07-25 1996-12-17 The Babcock & Wilcox Company SOx, NOx and particulate removal system
DE69010984T3 (de) * 1989-05-19 1998-04-16 Babcock Hitachi Kk Katalysator zur Reduktion von Stickoxyden.
US5023063A (en) * 1990-03-26 1991-06-11 The University Of Delaware Acid rain abatement
US5362463A (en) * 1992-08-26 1994-11-08 University Of De Process for removing NOx from combustion zone gases by adsorption
US5415850A (en) * 1993-02-24 1995-05-16 The Research Foundation Of State Univeristy Of New York Pillared interlayered clay catalysts for the selective reduction of nitrogen oxides with ammonia
DE19624619C1 (de) * 1996-06-20 1997-07-10 Metallgesellschaft Ag Verfahren zur Regelung oder Steuerung des Gehaltes an NO¶x¶ in Abgasen, die beim Betrieb von Glasschmelzöfen mit mehreren Brennern, die im Wechsel betrieben werden, anfallen
DE19806266C1 (de) * 1998-02-16 1999-08-26 Siemens Ag Katalysator und Verfahren zur Abgasreinigung
US6120580A (en) * 1998-04-15 2000-09-19 Hera, Llc Method for testing systems designed for NOx reduction in the combustion of carbonaceous fuels
US6821490B2 (en) * 2001-02-26 2004-11-23 Abb Lummus Global Inc. Parallel flow gas phase reactor and method for reducing the nitrogen oxide content of a gas
CN101332424B (zh) * 2007-06-28 2011-04-06 长春融成环保科技有限公司 脱氮催化剂及其制备方法
JP6714989B2 (ja) * 2015-01-19 2020-07-01 国立大学法人秋田大学 排ガス浄化触媒用担体及び排ガス浄化触媒

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3112184A (en) * 1958-09-08 1963-11-26 Corning Glass Works Method of making ceramic articles
DE1253685B (de) * 1963-01-22 1967-11-09 Degussa Verfahren zur Entfernung von Stickstoffoxyden aus stickstoffoxydhaltigen Abgasen
US3279884A (en) * 1963-10-31 1966-10-18 Basf Ag Selective removal of oxides of nitrogen from gas mixtures containing oxygen
US3939104A (en) * 1972-10-04 1976-02-17 Imperial Chemical Industries Limited Catalytic process
JPS5523086B2 (fr) * 1973-03-26 1980-06-20
US3960510A (en) * 1973-05-21 1976-06-01 W. R. Grace & Co. Honeycomb structure for countercurrent gas flow
JPS5152363A (fr) * 1974-11-01 1976-05-08 Hitachi Ltd
US4043939A (en) * 1975-10-10 1977-08-23 Kurashiki Boseki Kabushiki Kaisha Reactivation of catalysts useful for nitrogen oxide removal

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2368987A1 (fr) * 1976-11-01 1978-05-26 Mitsubishi Chem Ind Reduction catalytique des oxydes d'azote
EP0220416A1 (fr) * 1985-09-06 1987-05-06 Siemens Aktiengesellschaft Catalyseur pour la réduction d'oxydes d'azote
EP0239778A1 (fr) * 1986-03-06 1987-10-07 Siemens Aktiengesellschaft Catalyseur pour diminuer le taux d'oxydes d'azote dans les gaz de fumée
EP0266540A1 (fr) * 1986-10-08 1988-05-11 Siemens Aktiengesellschaft Matériau catalyseur pour diminuer le taux d'oxydes d'azote dans des gaz de fumée
US5225390A (en) * 1988-02-23 1993-07-06 Siemens Aktiengesellschaft Catalyst for reducing nitrogen oxides

Also Published As

Publication number Publication date
US4282115A (en) 1981-08-04
DE2744688A1 (de) 1978-04-06
US4186109A (en) 1980-01-29
FR2366058B1 (fr) 1979-06-01
DE2744688C2 (de) 1984-12-06

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DL Decision of the director general to leave to make available licences of right
ST Notification of lapse