FR2365601A1 - Melange thermoplastique elastomere a base d'un caoutchouc polyolefinique et d'un copolymere sequence propylene-ethylene - Google Patents

Melange thermoplastique elastomere a base d'un caoutchouc polyolefinique et d'un copolymere sequence propylene-ethylene

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Publication number
FR2365601A1
FR2365601A1 FR7728725A FR7728725A FR2365601A1 FR 2365601 A1 FR2365601 A1 FR 2365601A1 FR 7728725 A FR7728725 A FR 7728725A FR 7728725 A FR7728725 A FR 7728725A FR 2365601 A1 FR2365601 A1 FR 2365601A1
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FR
France
Prior art keywords
ethylene
weight
propylene
copolymer
rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7728725A
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English (en)
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FR2365601B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stamicarbon BV
Original Assignee
Stamicarbon BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from NL7610674A external-priority patent/NL7610674A/xx
Priority claimed from NLAANVRAGE7610672,A external-priority patent/NL184425C/xx
Application filed by Stamicarbon BV filed Critical Stamicarbon BV
Publication of FR2365601A1 publication Critical patent/FR2365601A1/fr
Application granted granted Critical
Publication of FR2365601B1 publication Critical patent/FR2365601B1/fr
Granted legal-status Critical Current

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/48Biological material, e.g. blood, urine; Haemocytometers
    • G01N33/50Chemical analysis of biological material, e.g. blood, urine; Testing involving biospecific ligand binding methods; Immunological testing
    • G01N33/53Immunoassay; Biospecific binding assay; Materials therefor
    • G01N33/543Immunoassay; Biospecific binding assay; Materials therefor with an insoluble carrier for immobilising immunochemicals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013Fillers, pigments or reinforcing additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/24Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Immunology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Hematology (AREA)
  • Molecular Biology (AREA)
  • Urology & Nephrology (AREA)
  • Biomedical Technology (AREA)
  • Food Science & Technology (AREA)
  • Microbiology (AREA)
  • Cell Biology (AREA)
  • Biotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Pathology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

Procédé pour la préparation d'un mélange thermoplastique élastomère à base d'un caoutchouc polyoléfinique et d'une polyoléfine thermoplastique. Le mélange contient : 1. 25 à 85 %-poids d'un copolymère essentiellement amorphe d'éthylène et d' alpha -oléfine avec une cristallinité inférieure à 4 %-poids et une résistance à la traction d'au moins 10 kg/cm**2, et 2. 15 à 75 %-poids d'un copolymère séquencé essentiellement cristallin de propylène et d'éthylène avec une teneur en éthylène de 1 à 25 %-poids et une cristallinité supérieure à 25 %-poids. Les mélanges à base de ces copolymères séquencés de propylène ont un travail plus facile et une résistance à la traction plus élevée que ceux à base des homopolymères de propylène. On peut incorporer dans les mélanges 20 à 200 parties d'huile par 100 parties de copolymère amorphe d'éthylène et d' alpha -oléfine pour obtenir une amélioration ultérieure de la traitabilité et de l'allongement à la rupture. Les mélanges peuvent être préparés selon les procédés connus pour le caoutchouc et les matières plastiques au moyen de l'appareillage usuel à des températures de 170 à 200 degrés C. Les mélanges de l'invention, en s'étendant de produits souples et caoutchouteux à des produits rigides et résistants au choc, se prêtent à d'innombrables applications, spécialement à la fabrication de gaines pour câbles et pare-chocs d'automobiles.
FR7728725A 1976-09-25 1977-09-23 Melange thermoplastique elastomere a base d'un caoutchouc polyolefinique et d'un copolymere sequence propylene-ethylene Granted FR2365601A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL7610674A NL7610674A (en) 1976-09-25 1976-09-25 Thermoplastic elastomer compsn. contg. ethylene! copolymer rubber - with block copolymer of propylene! and ethylene! giving easy processing
NLAANVRAGE7610672,A NL184425C (nl) 1976-09-25 1976-09-25 Werkwijze voor het bereiden van een thermoplastisch, elastomeer mengsel en voorwerpen daaruit vervaardigd.

Publications (2)

Publication Number Publication Date
FR2365601A1 true FR2365601A1 (fr) 1978-04-21
FR2365601B1 FR2365601B1 (fr) 1984-06-29

Family

ID=26645245

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7728725A Granted FR2365601A1 (fr) 1976-09-25 1977-09-23 Melange thermoplastique elastomere a base d'un caoutchouc polyolefinique et d'un copolymere sequence propylene-ethylene

Country Status (9)

Country Link
US (1) US4272431A (fr)
JP (1) JPS5340045A (fr)
AT (1) ATA674777A (fr)
DE (1) DE2742910A1 (fr)
ES (1) ES462615A1 (fr)
FR (1) FR2365601A1 (fr)
GB (1) GB1589067A (fr)
IT (1) IT1089898B (fr)
SE (1) SE424875B (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0052469A1 (fr) * 1980-11-10 1982-05-26 Uniroyal, Inc. Elastomère thermoplastique et prises et connecteurs électriques fabriqués au moyen de cet élastomère
EP0132968A2 (fr) * 1983-07-04 1985-02-13 Mitsui Petrochemical Industries, Ltd. Composition à base d'un polymère d'éthylène
EP0216193A1 (fr) * 1985-09-11 1987-04-01 Bayer Ag Elastomères thermoplastiques
EP0486700A1 (fr) * 1990-06-12 1992-05-27 Advanced Elastomer Systems, L.P. Composition elastomere thermoplastique

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7705367A (nl) * 1977-05-16 1978-11-20 Stamicarbon Werkwijze voor het bereiden van een thermo- plastisch elastomeer polymeer.
JPS54103451A (en) * 1978-02-01 1979-08-14 Kohkoku Chem Ind Synthetic resin sheet for books and stationery
JPS55151045A (en) * 1979-05-14 1980-11-25 Idemitsu Petrochem Co Ltd Propylene copolymer resin composition
DE3012804C2 (de) * 1980-04-02 1982-05-27 Dynamit Nobel Ag, 5210 Troisdorf Ternäre thermoplastische Formmasse enthaltend Polypropylen-Copolymere
JPS5763350A (en) * 1980-10-03 1982-04-16 Showa Denko Kk Propylene copolymeric composition
JPS5817140A (ja) * 1981-07-23 1983-02-01 Sumitomo Chem Co Ltd 新規ポリプロピレン樹脂組成物
JPS58157839A (ja) * 1982-03-16 1983-09-20 Nippon Oil Co Ltd 耐衝撃性ポリオレフイン樹脂組成物
DE4214170A1 (de) * 1992-04-30 1993-11-04 Alkor Gmbh Verwendung eines zusatzes von vernetzten pp-epdm-mischungen zur kraftfahrzeugfolienherstellung
DE19821718A1 (de) * 1997-05-15 1998-11-19 Sumitomo Chemical Co Harzmasse auf Polypropylenbasis und spritzgeformter Gegenstand daraus
TW577908B (en) * 2001-03-14 2004-03-01 Mitsui Chemicals Inc Olefinic thermoplastic elastomer composition
CN106317663A (zh) * 2016-08-30 2017-01-11 广州市丰源塑料模具有限公司 一种内金属外塑料的万向接头

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354239A (en) * 1962-03-28 1967-11-21 Shell Oil Co Polyolefin blend
US3478128A (en) * 1965-12-27 1969-11-11 Eastman Kodak Co Blend of crystalline block copolymer and ethylene-propylene rubber
JPS5145200B2 (fr) * 1971-12-08 1976-12-02
JPS5425063B2 (fr) * 1972-01-19 1979-08-25
US3767613A (en) * 1972-01-28 1973-10-23 Phillips Petroleum Co Carbon black pigmented flame retardant thermoplastic polymer compositions stabilized against degradationat polymer melt temperatures

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0052469A1 (fr) * 1980-11-10 1982-05-26 Uniroyal, Inc. Elastomère thermoplastique et prises et connecteurs électriques fabriqués au moyen de cet élastomère
EP0132968A2 (fr) * 1983-07-04 1985-02-13 Mitsui Petrochemical Industries, Ltd. Composition à base d'un polymère d'éthylène
EP0132968A3 (en) * 1983-07-04 1985-04-03 Mitsui Petrochemical Industries, Ltd. Propylene resin composition
EP0216193A1 (fr) * 1985-09-11 1987-04-01 Bayer Ag Elastomères thermoplastiques
US4745149A (en) * 1985-09-11 1988-05-17 Bayer Aktiengesellschaft Thermoplastic elastomers
EP0486700A1 (fr) * 1990-06-12 1992-05-27 Advanced Elastomer Systems, L.P. Composition elastomere thermoplastique
EP0486700A4 (en) * 1990-06-12 1992-07-22 Monsanto Japan Limited Thermoplastic elastomer composition
US5349005A (en) * 1990-06-12 1994-09-20 Advanced Elastomer Systems, L.P. Thermoplastic elastomer composition

Also Published As

Publication number Publication date
JPS5340045A (en) 1978-04-12
DE2742910A1 (de) 1978-03-30
IT1089898B (it) 1985-06-18
ES462615A1 (es) 1978-12-01
DE2742910C2 (fr) 1991-05-16
ATA674777A (de) 1980-11-15
GB1589067A (en) 1981-05-07
SE7710694L (sv) 1978-03-26
SE424875B (sv) 1982-08-16
FR2365601B1 (fr) 1984-06-29
US4272431A (en) 1981-06-09

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