FR2357634A1 - Procede pour demetalliser des huiles d'hydrocarbures - Google Patents

Procede pour demetalliser des huiles d'hydrocarbures

Info

Publication number
FR2357634A1
FR2357634A1 FR7720825A FR7720825A FR2357634A1 FR 2357634 A1 FR2357634 A1 FR 2357634A1 FR 7720825 A FR7720825 A FR 7720825A FR 7720825 A FR7720825 A FR 7720825A FR 2357634 A1 FR2357634 A1 FR 2357634A1
Authority
FR
France
Prior art keywords
hydrogen
stream
hydrogen sulfide
demetallization
unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7720825A
Other languages
English (en)
Other versions
FR2357634B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of FR2357634A1 publication Critical patent/FR2357634A1/fr
Application granted granted Critical
Publication of FR2357634B1 publication Critical patent/FR2357634B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/007Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/6472-50 nm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/65150-500 nm

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

On utilise des catalyseurs ayant une surface spécifique d'au maximum 100 m**2/g et d'un porosité et une grosseur de particules telles qu'une relation donnée entre ces paramètres et la pression partielle d'hydrogène utilisée soit satisfaite. La figure montre une installation qui comprend une unité d'hydrodémétallisation 1. Une huile résiduelle d'hydrocarbures 6 contenant des métaux et du soufre est soumise à une hydro-démétallisation en même temps que deux courants de gaz 7 et 8 contenant de l'hydrogène et de l'hydrogène sulfuré et, si on le désire, un courant d'hydrogène sulfuré 9 provenant d'une source extérieure Le produit ainsi obtenu 10 est séparé en un courant liquide Il d'une basse teneur en métaux et un courant gazeux 7 contenant de l'hydrogène et de l'hydrogène sulfuré, ce dernier courant étant recyclé à l'unité de démétallisation. Application aux huiles ayant une teneur totale en vanadium et en nickel supérieure à 250 ppm en poids.
FR7720825A 1976-07-08 1977-07-06 Procede pour demetalliser des huiles d'hydrocarbures Granted FR2357634A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7607551A NL7607551A (nl) 1976-07-08 1976-07-08 Werkwijze voor het ontmetalliseren van koolwater- stofolien.

Publications (2)

Publication Number Publication Date
FR2357634A1 true FR2357634A1 (fr) 1978-02-03
FR2357634B1 FR2357634B1 (fr) 1982-07-09

Family

ID=19826555

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7720825A Granted FR2357634A1 (fr) 1976-07-08 1977-07-06 Procede pour demetalliser des huiles d'hydrocarbures

Country Status (14)

Country Link
JP (1) JPS537705A (fr)
AU (1) AU506785B2 (fr)
BE (1) BE856236A (fr)
CA (1) CA1108085A (fr)
DE (1) DE2730564A1 (fr)
DK (1) DK304277A (fr)
FI (1) FI64634C (fr)
FR (1) FR2357634A1 (fr)
GB (1) GB1560590A (fr)
IT (1) IT1081515B (fr)
NL (1) NL7607551A (fr)
NO (1) NO151505C (fr)
SE (1) SE421803B (fr)
ZA (1) ZA774070B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2475931A1 (fr) * 1980-02-19 1981-08-21 Chiyoda Chem Eng Construct Co Catalyseur pour l'hydrotraitement d'huiles hydrocarbonees lourdes contenant des asphaltenes, procede de preparation et application a l'hydrotraitement d'huiles hydrocarbonees

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1174629A (fr) * 1980-05-29 1984-09-18 Huno Van Der Eijk Methode de demetallisation du petrole
EP0683218B1 (fr) 1994-05-19 2001-04-11 Shell Internationale Researchmaatschappij B.V. Procédé de conversion d'une huile résiduelle hydrocarbonée
WO2010084112A1 (fr) 2009-01-20 2010-07-29 Shell Internationale Research Maatschappij B.V. Procédé d'hydrodémétallisation de charges d'hydrocarbure

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1407610A (en) * 1972-10-13 1975-09-24 Shell Int Research Hydrocarbon conversion process
NL184479C (nl) * 1974-03-29 1989-08-01 Shell Int Research Werkwijze voor het katalytisch hydrogenerend ontzwavelen van vooraf ontmetalliseerde koolwaterstoffen.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2475931A1 (fr) * 1980-02-19 1981-08-21 Chiyoda Chem Eng Construct Co Catalyseur pour l'hydrotraitement d'huiles hydrocarbonees lourdes contenant des asphaltenes, procede de preparation et application a l'hydrotraitement d'huiles hydrocarbonees

Also Published As

Publication number Publication date
FI64634C (fi) 1983-12-12
DE2730564C2 (fr) 1987-11-05
CA1108085A (fr) 1981-09-01
FR2357634B1 (fr) 1982-07-09
FI64634B (fi) 1983-08-31
NO772400L (no) 1978-01-10
ZA774070B (en) 1978-05-30
GB1560590A (en) 1980-02-06
AU2679777A (en) 1979-01-11
AU506785B2 (en) 1980-01-24
NO151505B (no) 1985-01-07
FI772120A (fr) 1978-01-09
NO151505C (no) 1985-04-24
JPS537705A (en) 1978-01-24
DK304277A (da) 1978-01-09
SE421803B (sv) 1982-02-01
DE2730564A1 (de) 1978-01-12
SE7707884L (sv) 1978-01-09
NL7607551A (nl) 1978-01-10
BE856236A (nl) 1977-12-29
JPH0122320B2 (fr) 1989-04-26
IT1081515B (it) 1985-05-21

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Legal Events

Date Code Title Description
ST Notification of lapse