FR2285176A1 - Catalyseur contenant du phosphore, son mode de preparation et son emploi - Google Patents

Catalyseur contenant du phosphore, son mode de preparation et son emploi

Info

Publication number
FR2285176A1
FR2285176A1 FR7528734A FR7528734A FR2285176A1 FR 2285176 A1 FR2285176 A1 FR 2285176A1 FR 7528734 A FR7528734 A FR 7528734A FR 7528734 A FR7528734 A FR 7528734A FR 2285176 A1 FR2285176 A1 FR 2285176A1
Authority
FR
France
Prior art keywords
preparation
catalyst containing
containing phosphorus
phosphorus
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7528734A
Other languages
English (en)
French (fr)
Other versions
FR2285176B1 (nl
Inventor
Stephen Allan Butter
Warren William Kaeding
Lewis Brewster Young
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/508,308 external-priority patent/US3972832A/en
Priority claimed from US508306A external-priority patent/US3906054A/en
Priority claimed from US508307A external-priority patent/US3911041A/en
Priority claimed from US05/538,666 external-priority patent/US3965208A/en
Priority claimed from US05/563,286 external-priority patent/US3962364A/en
Priority claimed from US05/605,968 external-priority patent/US4002698A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of FR2285176A1 publication Critical patent/FR2285176A1/fr
Application granted granted Critical
Publication of FR2285176B1 publication Critical patent/FR2285176B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/861—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/865—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an ether
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/868—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains sulfur as hetero-atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
FR7528734A 1974-09-23 1975-09-19 Catalyseur contenant du phosphore, son mode de preparation et son emploi Granted FR2285176A1 (fr)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US05/508,308 US3972832A (en) 1974-09-23 1974-09-23 Phosphorus-containing zeolite catalyst
US508306A US3906054A (en) 1974-09-23 1974-09-23 Alkylation of olefins
US508307A US3911041A (en) 1974-09-23 1974-09-23 Conversion of methanol and dimethyl ether
US05/538,666 US3965208A (en) 1975-01-06 1975-01-06 Methylation of toluene
US05/563,286 US3962364A (en) 1975-03-28 1975-03-28 Alkylation in presence of phosphorus-modified crystalline luminosilicate catalyst
US05/605,968 US4002698A (en) 1975-08-19 1975-08-19 Methylation of toluene in the presence of a phosphorus-modified activated crystalline aluminosilicate catalyst

Publications (2)

Publication Number Publication Date
FR2285176A1 true FR2285176A1 (fr) 1976-04-16
FR2285176B1 FR2285176B1 (nl) 1982-10-01

Family

ID=27560081

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7528734A Granted FR2285176A1 (fr) 1974-09-23 1975-09-19 Catalyseur contenant du phosphore, son mode de preparation et son emploi

Country Status (8)

Country Link
JP (1) JPS5815443B2 (nl)
DD (1) DD123446A5 (nl)
DE (4) DE2560441C2 (nl)
FR (1) FR2285176A1 (nl)
GB (1) GB1496181A (nl)
IT (1) IT1042752B (nl)
NL (1) NL7511167A (nl)
NZ (1) NZ178543A (nl)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2454328A1 (fr) * 1979-04-20 1980-11-14 Du Pont Silice cristalline et procede de preparation de para-xylene a partir de toluene l'utilisant comme catalyseur
EP0134849A1 (en) * 1983-08-15 1985-03-27 Mobil Oil Corporation Treatment of zeolites
US4576805A (en) * 1982-08-27 1986-03-18 Mobil Oil Corporation Increasing lattice metal content of porous inorganic crystalline compositions
EP0205300A2 (en) * 1985-06-12 1986-12-17 Mobil Oil Corporation Aromatization reactions with zeolites
EP0236612A1 (en) * 1983-11-21 1987-09-16 The Dow Chemical Company Phosphorus modified magnesium silicate
EP0508835A2 (en) * 1991-04-12 1992-10-14 Nippon Oil Co. Ltd. Method of preparing alkylbiphenyls
EP0521554A2 (en) * 1991-07-01 1993-01-07 Ministero Dell' Universita' E Della Ricerca Scientifica E Tecnologica Process for alkylation of aromatic compounds using a catalyst
WO1994021378A1 (es) * 1993-03-17 1994-09-29 Consejo Superior Investigaciones Cientificas Procedimiento de preparacion de catalizadores a base de zeolitas tratadas con acido fosforico, utiles para su aplicacion en unidades de craqueo catalitico
WO1998029189A1 (en) * 1996-12-31 1998-07-09 Exxon Chemical Patents Inc. Phosphorus modified small pore molecular sieve catalysts, and their use in the production of light olefins
WO2001021561A1 (en) * 1999-09-23 2001-03-29 Mobil Oil Corporation Process for converting methanol or dimethyl ether to olefins
EP3433223A4 (en) * 2016-03-25 2019-12-25 ExxonMobil Chemical Patents Inc. CATALYST AND PROCESS FOR PRODUCING PARAXYLENE

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4060568A (en) * 1976-03-31 1977-11-29 Mobil Oil Corporation Silica-modified zeolite catalyst and conversion therewith
NZ183608A (en) * 1976-03-31 1978-12-18 Mobil Oil Corp Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes
JPS5643123U (nl) * 1979-09-12 1981-04-20
US4274982A (en) * 1979-10-12 1981-06-23 Mobil Oil Corporation Method for maintaining para-selectivity of modified zeolite catalyst
EP0040015B1 (en) * 1980-05-13 1986-06-11 Imperial Chemical Industries Plc Process for making olefins
US4310440A (en) * 1980-07-07 1982-01-12 Union Carbide Corporation Crystalline metallophosphate compositions
US4417088A (en) * 1981-09-25 1983-11-22 Chevron Research Company Oligomerization of liquid olefins
US4423269A (en) * 1981-09-25 1983-12-27 Chevron Research Company Oligomerization of gaseous olefins
US4511746A (en) * 1981-09-25 1985-04-16 Chevron Research Company Low activity catalyst oligomerization process
US4431527A (en) * 1981-11-13 1984-02-14 Standard Oil Company (Indiana) Process for hydrogen treating high nitrogen content hydrocarbon feeds
US4454241A (en) * 1982-05-24 1984-06-12 Exxon Research And Engineering Co. Phosphorus-containing catalyst
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
JPS60103020A (ja) * 1983-11-08 1985-06-07 Agency Of Ind Science & Technol 結晶性アルミノホスホシリケ−トおよびそれを触媒として用いる炭化水素の製造方法
JPS60114042A (ja) * 1983-11-25 1985-06-20 Matsushita Electric Works Ltd 電力線搬送システム
DE3570689D1 (en) * 1984-09-25 1989-07-06 Catalysts & Chem Ind Co Catalytic cracking, process for heavy oil
JPS61126041A (ja) * 1984-11-22 1986-06-13 Res Assoc Util Of Light Oil ベンゼンのエチル化法
US4960504A (en) * 1984-12-18 1990-10-02 Uop Dewaxing catalysts and processes employing silicoaluminophosphate molecular sieves
JPS61221137A (ja) * 1985-03-28 1986-10-01 Teijin Yuka Kk Ｐ−キシレンの製造法
AU5645686A (en) * 1985-06-05 1986-12-18 Mobil Oil Corp. Cracking with molecular sieves containing aluminium, phosphorous and silicon
IN167718B (nl) * 1985-06-28 1990-12-08 Chevron Res
JPS6263528A (ja) * 1985-09-17 1987-03-20 Teijin Yuka Kk Ｐ−キシレンの製造法
JPS6450827A (en) * 1987-08-20 1989-02-27 Agency Ind Science Techn Production of lower olefin
US7038100B2 (en) * 2001-04-30 2006-05-02 Exxonmobil Chemical Patents, Inc. Aromatics alkylation
CN1257769C (zh) * 2003-10-31 2006-05-31 中国石油化工股份有限公司 一种含磷和金属组分的mfi结构分子筛及其应用
CA2618039C (en) * 2005-10-07 2014-04-08 Sk Energy Co., Ltd. Hydrothermally stable microporous molecular sieve catalyst and preparation method thereof
JP4823655B2 (ja) * 2005-11-21 2011-11-24 出光興産株式会社 キシレン類の製造方法
JP5094506B2 (ja) * 2008-03-28 2012-12-12 出光興産株式会社 軽質オレフィンの製造方法
US8115041B2 (en) * 2008-04-02 2012-02-14 Saudi Basic Industries Corporation Pretreatment of a phosphorus-modified zeolite catalyst for an aromatic alkylation process
US8252967B2 (en) * 2009-04-14 2012-08-28 Exxonmobil Chemical Patents Inc. Process for the purification of paraxylene
FI124814B (fi) 2010-10-18 2015-01-30 Lappeenrannan Teknillinen Yliopisto Sähkökoneen staattori ja sähkökone
JP5798821B2 (ja) 2011-07-15 2015-10-21 三菱重工業株式会社 メタノールからガソリンを製造するともに発電する方法およびシステム
JP5812781B2 (ja) 2011-09-21 2015-11-17 三菱重工業株式会社 メタノールからガソリンと水素を製造する方法および装置
WO2013059176A1 (en) * 2011-10-17 2013-04-25 Exxonmobil Research And Engineering Company Process for producing phosphorus modified zeolite catalysts
CN116477638A (zh) * 2023-03-23 2023-07-25 延长中科（大连）能源科技股份有限公司 一种高稳定性丝光沸石分子筛的制备方法及其应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3647682A (en) * 1968-10-23 1972-03-07 Union Carbide Corp Olefin production by the catalytic treatment of hydrocarbons
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3709979A (en) * 1970-04-23 1973-01-09 Mobil Oil Corp Crystalline zeolite zsm-11
GB1403329A (en) 1972-04-28 1975-08-28 Mobil Oil Corp Vapour-phase alkylation in presence of crystalline alumino silicate catalyst
US3751504A (en) 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
CS191916B2 (en) * 1973-08-09 1979-07-31 Mobil Oil Corp Method of producing aromatic hydrocarbons

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2454328A1 (fr) * 1979-04-20 1980-11-14 Du Pont Silice cristalline et procede de preparation de para-xylene a partir de toluene l'utilisant comme catalyseur
US4576805A (en) * 1982-08-27 1986-03-18 Mobil Oil Corporation Increasing lattice metal content of porous inorganic crystalline compositions
EP0134849A1 (en) * 1983-08-15 1985-03-27 Mobil Oil Corporation Treatment of zeolites
EP0236612A1 (en) * 1983-11-21 1987-09-16 The Dow Chemical Company Phosphorus modified magnesium silicate
EP0205300A2 (en) * 1985-06-12 1986-12-17 Mobil Oil Corporation Aromatization reactions with zeolites
EP0205300A3 (en) * 1985-06-12 1987-08-19 Mobil Oil Corporation Aromatization reactions with zeolites
EP0508835A2 (en) * 1991-04-12 1992-10-14 Nippon Oil Co. Ltd. Method of preparing alkylbiphenyls
EP0508835A3 (en) * 1991-04-12 1994-05-25 Nippon Oil Co Ltd Method of preparing alkylbiphenyls
EP0521554A3 (en) * 1991-07-01 1993-03-10 Ministero Dell' Universita' E Della Ricerca Scientifica E Tecnologica Catalyst for the alkylation of aromatic compounds and process which makes use of said catalyst
EP0521554A2 (en) * 1991-07-01 1993-01-07 Ministero Dell' Universita' E Della Ricerca Scientifica E Tecnologica Process for alkylation of aromatic compounds using a catalyst
WO1994021378A1 (es) * 1993-03-17 1994-09-29 Consejo Superior Investigaciones Cientificas Procedimiento de preparacion de catalizadores a base de zeolitas tratadas con acido fosforico, utiles para su aplicacion en unidades de craqueo catalitico
ES2076068A1 (es) * 1993-03-17 1995-10-16 Consejo Superior Investigacion Procedimiento de preparacion de catalizadores a base de zeolotas tratadas con acido fosforico, utiles para su aplicacion en unidades de craqueo catalitico.
WO1998029189A1 (en) * 1996-12-31 1998-07-09 Exxon Chemical Patents Inc. Phosphorus modified small pore molecular sieve catalysts, and their use in the production of light olefins
US5925586A (en) * 1996-12-31 1999-07-20 Exxon Chemical Patents, Inc. Phosphorus modified small pore molecular sieve catalysts, and their use in the production of light olefins
WO2001021561A1 (en) * 1999-09-23 2001-03-29 Mobil Oil Corporation Process for converting methanol or dimethyl ether to olefins
US6613951B1 (en) 1999-09-23 2003-09-02 Mobil Oil Corporation Process for converting methanol to olefins
EP3433223A4 (en) * 2016-03-25 2019-12-25 ExxonMobil Chemical Patents Inc. CATALYST AND PROCESS FOR PRODUCING PARAXYLENE
US10647633B2 (en) 2016-03-25 2020-05-12 Exxonmobil Chemical Patents Inc. Catalyst and process for the production of para-xylene

Also Published As

Publication number Publication date
FR2285176B1 (nl) 1982-10-01
DD123446A5 (nl) 1976-12-20
DE2560441A1 (nl) 1982-08-26
DE2560440C2 (de) 1986-11-13
DE2560442C2 (de) 1986-10-16
NZ178543A (en) 1978-04-03
DE2560441C2 (de) 1986-05-22
DE2542230A1 (de) 1976-04-01
NL7511167A (nl) 1976-03-25
JPS5157688A (en) 1976-05-20
IT1042752B (it) 1980-01-30
JPS5815443B2 (ja) 1983-03-25
DE2542230C2 (de) 1985-01-31
GB1496181A (en) 1977-12-30

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