FR2234923A1 - Hydrocarbon-conversion (esp. reforming) catalysts - contg. platinum, ruthenium and a group IVA or IVB metal - Google Patents

Hydrocarbon-conversion (esp. reforming) catalysts - contg. platinum, ruthenium and a group IVA or IVB metal

Info

Publication number
FR2234923A1
FR2234923A1 FR7323416A FR7323416A FR2234923A1 FR 2234923 A1 FR2234923 A1 FR 2234923A1 FR 7323416 A FR7323416 A FR 7323416A FR 7323416 A FR7323416 A FR 7323416A FR 2234923 A1 FR2234923 A1 FR 2234923A1
Authority
FR
France
Prior art keywords
esp
catalysts
reforming
hydrocarbon
contg
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7323416A
Other languages
French (fr)
Other versions
FR2234923B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7323416A priority Critical patent/FR2234923A1/en
Priority to DE19742426597 priority patent/DE2426597A1/en
Priority to JP49062438A priority patent/JPS5027794A/ja
Priority to NL7407512A priority patent/NL7407512A/xx
Publication of FR2234923A1 publication Critical patent/FR2234923A1/en
Application granted granted Critical
Publication of FR2234923B1 publication Critical patent/FR2234923B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • C07C5/417—Catalytic processes with metals of the platinum group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Hydrocarbon conversion catalysts comprise (a) 100 pts. wt. of a support; (b) 0.005-1 (pref. 0.05-0.8) pt. wt. Pt; (c) 0.005-1 (pref. 0.01-1) pt. wt. Ru; and (d) 0.005-5 (pref. 0.05-3) pt. wt. of Ge, Sn, Pb, Ti, Zr or Hf; and pref. also (e) 0.1-10 (esp. 0.2-5) pt. wt. halogen. The catalysts are esp. useful for reforming, but can also be used for isomerisation, hydrocracking, dehydrogenation, etc. Component (d) increases the activity and particularly the life of the catalyst.
FR7323416A 1973-06-01 1973-06-26 Hydrocarbon-conversion (esp. reforming) catalysts - contg. platinum, ruthenium and a group IVA or IVB metal Granted FR2234923A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR7323416A FR2234923A1 (en) 1973-06-26 1973-06-26 Hydrocarbon-conversion (esp. reforming) catalysts - contg. platinum, ruthenium and a group IVA or IVB metal
DE19742426597 DE2426597A1 (en) 1973-06-01 1974-05-31 Reforming catalyst contg. platinum and ruthenium - with a third metal component for increased life and activity
JP49062438A JPS5027794A (en) 1973-06-01 1974-05-31
NL7407512A NL7407512A (en) 1973-06-01 1974-06-04

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7323416A FR2234923A1 (en) 1973-06-26 1973-06-26 Hydrocarbon-conversion (esp. reforming) catalysts - contg. platinum, ruthenium and a group IVA or IVB metal

Publications (2)

Publication Number Publication Date
FR2234923A1 true FR2234923A1 (en) 1975-01-24
FR2234923B1 FR2234923B1 (en) 1977-05-13

Family

ID=9121627

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7323416A Granted FR2234923A1 (en) 1973-06-01 1973-06-26 Hydrocarbon-conversion (esp. reforming) catalysts - contg. platinum, ruthenium and a group IVA or IVB metal

Country Status (1)

Country Link
FR (1) FR2234923A1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2091114A5 (en) * 1970-05-04 1972-01-14 Shell Int Research
FR2137837A1 (en) * 1971-05-14 1972-12-29 Shell Int Research Increasing aromatic hydrocarbon content - of fractions containing n-hexane and n-heptane by removing n-paraffins
FR2144702A1 (en) * 1971-07-02 1973-02-16 Shell Int Research

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2091114A5 (en) * 1970-05-04 1972-01-14 Shell Int Research
FR2137837A1 (en) * 1971-05-14 1972-12-29 Shell Int Research Increasing aromatic hydrocarbon content - of fractions containing n-hexane and n-heptane by removing n-paraffins
FR2144702A1 (en) * 1971-07-02 1973-02-16 Shell Int Research

Also Published As

Publication number Publication date
FR2234923B1 (en) 1977-05-13

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Legal Events

Date Code Title Description
ST Notification of lapse