FR2436627A1 - Reforming and aromatising catalysts - contg. platinum-group metal, antimony and Gp=IVA metal - Google Patents

Reforming and aromatising catalysts - contg. platinum-group metal, antimony and Gp=IVA metal

Info

Publication number
FR2436627A1
FR2436627A1 FR7827324A FR7827324A FR2436627A1 FR 2436627 A1 FR2436627 A1 FR 2436627A1 FR 7827324 A FR7827324 A FR 7827324A FR 7827324 A FR7827324 A FR 7827324A FR 2436627 A1 FR2436627 A1 FR 2436627A1
Authority
FR
France
Prior art keywords
catalysts
metal
reforming
aromatising
contg
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7827324A
Other languages
French (fr)
Other versions
FR2436627B1 (en
Inventor
Francois Andreeff
Bernard Juguin
Jean Miquel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pro Catalyse SA
Original Assignee
Pro Catalyse SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pro Catalyse SA filed Critical Pro Catalyse SA
Priority to FR7827324A priority Critical patent/FR2436627A1/en
Publication of FR2436627A1 publication Critical patent/FR2436627A1/en
Application granted granted Critical
Publication of FR2436627B1 publication Critical patent/FR2436627B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/12—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6445—Antimony
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/10—Catalytic reforming with moving catalysts
    • C10G35/12—Catalytic reforming with moving catalysts according to the "moving-bed" method

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Claimed catalyst comprises an alumina support and, based on the wt. of the support, 0.05-0.6 (pref. 0.1-0.5) wt.% of a Pt-gp. metal, 0.005-5 (pref. 0.03-3) wt.% of Sb, 0.005-5 (pref. 0.05-3) wt.% of Ti, Hf or Zr, and 0.1-10 wt.% halogen. The catalyst can be used for reforming naphtha fractions to produce high octane gasoline or for atomizing pyrolysis gasoline, catalytic reformates or naphthenes to produce BTX products. When used in mobile-bed reaction systems (esp. using >=2 reactors in series), the catalysts have higher activity and esp. a longer life than prior art catalysts.
FR7827324A 1978-09-21 1978-09-21 Reforming and aromatising catalysts - contg. platinum-group metal, antimony and Gp=IVA metal Granted FR2436627A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7827324A FR2436627A1 (en) 1978-09-21 1978-09-21 Reforming and aromatising catalysts - contg. platinum-group metal, antimony and Gp=IVA metal

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7827324A FR2436627A1 (en) 1978-09-21 1978-09-21 Reforming and aromatising catalysts - contg. platinum-group metal, antimony and Gp=IVA metal

Publications (2)

Publication Number Publication Date
FR2436627A1 true FR2436627A1 (en) 1980-04-18
FR2436627B1 FR2436627B1 (en) 1981-11-13

Family

ID=9212980

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7827324A Granted FR2436627A1 (en) 1978-09-21 1978-09-21 Reforming and aromatising catalysts - contg. platinum-group metal, antimony and Gp=IVA metal

Country Status (1)

Country Link
FR (1) FR2436627A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2735489A1 (en) * 1995-06-16 1996-12-20 Inst Francais Du Petrole Conversion of 5-12C hydrocarbon(s) into aromatics to improve octane ratings of petrol distillates
US7563358B2 (en) 2006-08-24 2009-07-21 Exxonmobil Chemical Patents Inc. Process for the production of benzene, toluene, and xylenes

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2090058A1 (en) * 1970-05-15 1972-01-14 Asahi Chemical Ind
FR2201338A1 (en) * 1972-09-27 1974-04-26 Inst Francais Du Petrole

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2090058A1 (en) * 1970-05-15 1972-01-14 Asahi Chemical Ind
FR2201338A1 (en) * 1972-09-27 1974-04-26 Inst Francais Du Petrole

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2735489A1 (en) * 1995-06-16 1996-12-20 Inst Francais Du Petrole Conversion of 5-12C hydrocarbon(s) into aromatics to improve octane ratings of petrol distillates
WO1997000305A1 (en) * 1995-06-16 1997-01-03 Institut Français Du Petrole Method for converting hydrocarbons into aromatic compounds using a catalyst containing doping metals
US6007700A (en) * 1995-06-16 1999-12-28 Institut Francais Du Petrole Process for the catalyst conversion of hydrocarbons into aromatics using a catalyst containing at least one doping metal chosen from the group consisting of titanium, zirconium, hafnium, cobalt, nickel, zinc, and/or the lanthanides
US7563358B2 (en) 2006-08-24 2009-07-21 Exxonmobil Chemical Patents Inc. Process for the production of benzene, toluene, and xylenes

Also Published As

Publication number Publication date
FR2436627B1 (en) 1981-11-13

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