FR1425320A - Process for the purification of nitro derivatives of aromatic hydrocarbons - Google Patents
Process for the purification of nitro derivatives of aromatic hydrocarbonsInfo
- Publication number
- FR1425320A FR1425320A FR992414A FR992414A FR1425320A FR 1425320 A FR1425320 A FR 1425320A FR 992414 A FR992414 A FR 992414A FR 992414 A FR992414 A FR 992414A FR 1425320 A FR1425320 A FR 1425320A
- Authority
- FR
- France
- Prior art keywords
- nitrophenols
- resin
- basic anion
- nitro compounds
- purification
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
- C07C201/16—Separation; Purification; Stabilisation; Use of additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
- B01J41/05—Processes using organic exchangers in the strongly basic form
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/06—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/07—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms
- C07C205/11—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms having nitro groups bound to carbon atoms of six-membered aromatic rings
- C07C205/12—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms having nitro groups bound to carbon atoms of six-membered aromatic rings the six-membered aromatic ring or a condensed ring system containing that ring being substituted by halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/13—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups
- C07C205/20—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C07C205/21—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings having nitro groups and hydroxy groups bound to carbon atoms of the same non-condensed six-membered aromatic ring
- C07C205/22—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings having nitro groups and hydroxy groups bound to carbon atoms of the same non-condensed six-membered aromatic ring having one nitro groups bound to the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Mixtures containing aromatic nitro compounds and nitrophenols are separated by washing the mixture with water and passing it over a basic anion-exchange resin preferably in the presence of dilute aqueous sodium hydroxide solution, which retains the nitrophenols, while purified nitro compounds pass from the resin, separating the nitrophenols with simultaneous regeneration of the resin by treating the resins with a dilute mineral acid, preferably sulphuric acid, and an organic solvent preferably acetone, for nitrophenols. The resin may be a macroporous strongly basic anion exchanger based on a styrene/divinyl benzene copolymer containing quaternary ammonium groups.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF41132A DE1222904B (en) | 1963-10-29 | 1963-10-29 | Process for the purification of crude aromatic nitro compounds containing nitrophenol |
Publications (1)
Publication Number | Publication Date |
---|---|
FR1425320A true FR1425320A (en) | 1966-01-24 |
Family
ID=7098536
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR992414A Expired FR1425320A (en) | 1963-10-29 | 1964-10-23 | Process for the purification of nitro derivatives of aromatic hydrocarbons |
Country Status (6)
Country | Link |
---|---|
BE (1) | BE654746A (en) |
CH (1) | CH443247A (en) |
DE (1) | DE1222904B (en) |
FR (1) | FR1425320A (en) |
GB (1) | GB1031450A (en) |
NL (1) | NL6412608A (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4482769A (en) * | 1983-09-16 | 1984-11-13 | Air Products And Chemicals, Inc. | Reducing 2,4-dinitroortho-cresol in effluent stream from dinitrotoluene process |
US4597875A (en) * | 1985-05-07 | 1986-07-01 | Air Products And Chemicals, Inc. | Precipitative removal of nitrocresols from dinitrotoluene waste streams |
US4604214A (en) * | 1985-08-16 | 1986-08-05 | Air Products And Chemicals, Inc. | Removal of nitrocresols from dinitrotoluene waste streams using fentons reagent |
HUE026178T2 (en) * | 2011-01-31 | 2016-05-30 | Basf Se | Prevention of precipitation from nitrated aromatic crude products |
US8637712B2 (en) * | 2011-01-31 | 2014-01-28 | Basf Se | Prevention of precipitation from nitrated aromatic crude products |
UA108437C2 (en) * | 2011-05-19 | 2015-04-27 | METHOD AND DEVICES FOR CLEANING OF NUTRITION PRODUCTS | |
US9249083B2 (en) | 2012-04-25 | 2016-02-02 | Basf Se | Process for scrubbing dinitrotoluene |
WO2013160367A1 (en) | 2012-04-25 | 2013-10-31 | Basf Se | Method for dinitrotoluene washes |
RU2712699C1 (en) * | 2019-02-20 | 2020-01-30 | Федеральное Казенное Предприятие "Бийский Олеумный Завод" | Method of producing a mixture of dinitrotoluene and trinitrotoluene (versions) |
-
1963
- 1963-10-29 DE DEF41132A patent/DE1222904B/en active Pending
-
1964
- 1964-09-25 CH CH1246064A patent/CH443247A/en unknown
- 1964-10-14 GB GB41934/64A patent/GB1031450A/en not_active Expired
- 1964-10-23 FR FR992414A patent/FR1425320A/en not_active Expired
- 1964-10-23 BE BE654746D patent/BE654746A/xx unknown
- 1964-10-29 NL NL6412608A patent/NL6412608A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
CH443247A (en) | 1967-09-15 |
BE654746A (en) | 1965-02-15 |
GB1031450A (en) | 1966-06-02 |
NL6412608A (en) | 1965-05-03 |
DE1222904B (en) | 1966-08-18 |
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