GB1031450A - Process for the separation of nitro derivatives of aromatic hydrocarbons from nitrophenols - Google Patents

Process for the separation of nitro derivatives of aromatic hydrocarbons from nitrophenols

Info

Publication number
GB1031450A
GB1031450A GB41934/64A GB4193464A GB1031450A GB 1031450 A GB1031450 A GB 1031450A GB 41934/64 A GB41934/64 A GB 41934/64A GB 4193464 A GB4193464 A GB 4193464A GB 1031450 A GB1031450 A GB 1031450A
Authority
GB
United Kingdom
Prior art keywords
nitrophenols
resin
basic anion
nitro compounds
separation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB41934/64A
Inventor
Josef Heinen
Herbert Grunewald
Adolf Hamers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB1031450A publication Critical patent/GB1031450A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/16—Separation; Purification; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/04—Processes using organic exchangers
    • B01J41/05—Processes using organic exchangers in the strongly basic form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/06—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/07—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms
    • C07C205/11—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms having nitro groups bound to carbon atoms of six-membered aromatic rings
    • C07C205/12—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms having nitro groups bound to carbon atoms of six-membered aromatic rings the six-membered aromatic ring or a condensed ring system containing that ring being substituted by halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/13—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups
    • C07C205/20—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C07C205/21—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings having nitro groups and hydroxy groups bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C07C205/22—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings having nitro groups and hydroxy groups bound to carbon atoms of the same non-condensed six-membered aromatic ring having one nitro groups bound to the ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Mixtures containing aromatic nitro compounds and nitrophenols are separated by washing the mixture with water and passing it over a basic anion-exchange resin preferably in the presence of dilute aqueous sodium hydroxide solution, which retains the nitrophenols, while purified nitro compounds pass from the resin, separating the nitrophenols with simultaneous regeneration of the resin by treating the resins with a dilute mineral acid, preferably sulphuric acid, and an organic solvent preferably acetone, for nitrophenols. The resin may be a macroporous strongly basic anion exchanger based on a styrene/divinyl benzene copolymer containing quaternary ammonium groups.
GB41934/64A 1963-10-29 1964-10-14 Process for the separation of nitro derivatives of aromatic hydrocarbons from nitrophenols Expired GB1031450A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF41132A DE1222904B (en) 1963-10-29 1963-10-29 Process for the purification of crude aromatic nitro compounds containing nitrophenol

Publications (1)

Publication Number Publication Date
GB1031450A true GB1031450A (en) 1966-06-02

Family

ID=7098536

Family Applications (1)

Application Number Title Priority Date Filing Date
GB41934/64A Expired GB1031450A (en) 1963-10-29 1964-10-14 Process for the separation of nitro derivatives of aromatic hydrocarbons from nitrophenols

Country Status (6)

Country Link
BE (1) BE654746A (en)
CH (1) CH443247A (en)
DE (1) DE1222904B (en)
FR (1) FR1425320A (en)
GB (1) GB1031450A (en)
NL (1) NL6412608A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4482769A (en) * 1983-09-16 1984-11-13 Air Products And Chemicals, Inc. Reducing 2,4-dinitroortho-cresol in effluent stream from dinitrotoluene process
US4597875A (en) * 1985-05-07 1986-07-01 Air Products And Chemicals, Inc. Precipitative removal of nitrocresols from dinitrotoluene waste streams
US4604214A (en) * 1985-08-16 1986-08-05 Air Products And Chemicals, Inc. Removal of nitrocresols from dinitrotoluene waste streams using fentons reagent
US20120197047A1 (en) * 2011-01-31 2012-08-02 Basf Se Prevention of precipitation from nitrated aromatic crude products
WO2012104254A1 (en) * 2011-01-31 2012-08-09 Basf Se Prevention of precipitation from nitrated aromatic crude products
CN103562174A (en) * 2011-05-19 2014-02-05 约瑟夫·迈斯纳两合公司 Method and apparatus for purifying nitration products

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9249083B2 (en) 2012-04-25 2016-02-02 Basf Se Process for scrubbing dinitrotoluene
JP6193358B2 (en) 2012-04-25 2017-09-06 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ How to wash dinitrotoluene
RU2712699C1 (en) * 2019-02-20 2020-01-30 Федеральное Казенное Предприятие "Бийский Олеумный Завод" Method of producing a mixture of dinitrotoluene and trinitrotoluene (versions)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4482769A (en) * 1983-09-16 1984-11-13 Air Products And Chemicals, Inc. Reducing 2,4-dinitroortho-cresol in effluent stream from dinitrotoluene process
US4597875A (en) * 1985-05-07 1986-07-01 Air Products And Chemicals, Inc. Precipitative removal of nitrocresols from dinitrotoluene waste streams
US4604214A (en) * 1985-08-16 1986-08-05 Air Products And Chemicals, Inc. Removal of nitrocresols from dinitrotoluene waste streams using fentons reagent
US20120197047A1 (en) * 2011-01-31 2012-08-02 Basf Se Prevention of precipitation from nitrated aromatic crude products
WO2012104254A1 (en) * 2011-01-31 2012-08-09 Basf Se Prevention of precipitation from nitrated aromatic crude products
CN103339097A (en) * 2011-01-31 2013-10-02 巴斯夫欧洲公司 Prevention of precipitation from nitrated aromatic crude products
US8637712B2 (en) 2011-01-31 2014-01-28 Basf Se Prevention of precipitation from nitrated aromatic crude products
CN103339097B (en) * 2011-01-31 2015-03-18 巴斯夫欧洲公司 Prevention of precipitation from nitrated aromatic crude products
CN103562174A (en) * 2011-05-19 2014-02-05 约瑟夫·迈斯纳两合公司 Method and apparatus for purifying nitration products
CN103562174B (en) * 2011-05-19 2015-05-20 约瑟夫·迈斯纳两合公司 Method and apparatus for purifying nitration products

Also Published As

Publication number Publication date
BE654746A (en) 1965-02-15
FR1425320A (en) 1966-01-24
DE1222904B (en) 1966-08-18
CH443247A (en) 1967-09-15
NL6412608A (en) 1965-05-03

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