FR1365398A - Hydrotropic compositions of phosphorylated surfactants - Google Patents
Hydrotropic compositions of phosphorylated surfactantsInfo
- Publication number
- FR1365398A FR1365398A FR935275A FR935275A FR1365398A FR 1365398 A FR1365398 A FR 1365398A FR 935275 A FR935275 A FR 935275A FR 935275 A FR935275 A FR 935275A FR 1365398 A FR1365398 A FR 1365398A
- Authority
- FR
- France
- Prior art keywords
- weight
- blend
- phenoxy
- specified
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 10
- 239000004094 surface-active agent Substances 0.000 title abstract 2
- 230000003165 hydrotropic effect Effects 0.000 title 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 abstract 4
- 229910019142 PO4 Inorganic materials 0.000 abstract 3
- 239000003752 hydrotrope Substances 0.000 abstract 3
- 235000021317 phosphate Nutrition 0.000 abstract 3
- 229920000388 Polyphosphate Polymers 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 239000002736 nonionic surfactant Substances 0.000 abstract 2
- -1 octyl-phenoxy Chemical group 0.000 abstract 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract 2
- 239000001205 polyphosphate Substances 0.000 abstract 2
- 235000011176 polyphosphates Nutrition 0.000 abstract 2
- KTPPAWOZTRABDA-UHFFFAOYSA-N 2-nonyl-2-phenoxyoxirane Chemical class C=1C=CC=CC=1OC1(CCCCCCCCC)CO1 KTPPAWOZTRABDA-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 150000003839 salts Chemical group 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/091—Esters of phosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/645—Mixtures of compounds all of which are cationic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/362—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
- C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
- Polyethers (AREA)
Abstract
The invention comprises compositions containing (A) an alkaline builder, and (B) a blend of 10 to 80% by weight of the blend of a nonionic surfactant of the formula R(CH2CH2O)xH, where R is alkoxy, alkyl substituted amino or alkyl substituted phenoxy group, x is an average number of 1 to 30, and 90 to 20% by weight of the blend of a hydrotrope of the formula R1(CH2CH2O)yR2 where R1 is phenoxy substituted with a C6-C10 alkyl group or R1 is a C10-C18 alkoxy group, y is an average number of 1 to 20, R2 is a terminal group at least 90% of such groups being primary phosphate groups in acid or salt form, the remainder, if any, being hydrogen. Preferred alkaline builders are hydroxides, carbonates, silicates, phosphates or polyphosphates of sodium or potassium. Preferably, the compositions contain 75 to 99-5% by weight of alkaline builder and 25 to 0.5% by weight of the blend. Aqueous concentrates of the above compositions are specified, comprising 4 to 40% by weight of an alkaline builder, 0.5 to 40% of the blend, the solids content not exceeding 40% by weight. R2 may also be a secondary, tertiary or complex polyphosphate group. Specified hydrotropes include octyl-phenoxy polyethoxy phosphates and nonyl-phenoxy polyethoxy phosphates and specified non-ionic surfactants include octylphenoxy and nonyl-phenoxy ethylene oxide adducts, C13H27O(CH2CH2O)12H, t-C12- 15H25- 31 NHCH2CH2OH and t-C12- 15H25- 31NH(CH2CH2 O)10H. Many other examples of hydrotropes and non-ionic surface-active agents are given and examples of both aqueous and non-aqueous compositions are specified.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US19596762A | 1962-05-18 | 1962-05-18 | |
| US26683463A | 1963-03-21 | 1963-03-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR1365398A true FR1365398A (en) | 1964-07-03 |
Family
ID=26891530
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR935275A Expired FR1365398A (en) | 1962-05-18 | 1963-05-17 | Hydrotropic compositions of phosphorylated surfactants |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3294693A (en) |
| AU (1) | AU288953B2 (en) |
| BE (1) | BE632444A (en) |
| DE (1) | DE1243313B (en) |
| FR (1) | FR1365398A (en) |
| GB (1) | GB1016081A (en) |
| IT (1) | IT700621A (en) |
| NL (1) | NL292944A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2386604A1 (en) * | 1977-04-04 | 1978-11-03 | Gaf Corp | DETERGENT COMPOSITION CONSISTING OF A HYDROTROPIC SYNERGIC MIXTURE OF TWO CLASSES OF ORGANIC PHOSPHATES |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NO121968C (en) * | 1966-06-23 | 1977-06-13 | Mo Och Domsjoe Ab | |
| FR2193871B1 (en) * | 1972-07-25 | 1977-07-22 | Colgate Palmolive Co | |
| FR2223438A1 (en) * | 1973-03-28 | 1974-10-25 | Air Ind | PAINT DENATURATION COMPOSITIONS, ESPECIALLY FOR THE CLEANING OF PAINT CABINS |
| US3920856A (en) * | 1973-09-13 | 1975-11-18 | Basf Wyandotte Corp | Chemical peeling of edible plant products |
| DE2354223A1 (en) * | 1973-10-30 | 1975-05-28 | Hoechst Ag | LIQUID DETERGENT CONCENTRATES |
| JPS52136204A (en) * | 1976-05-11 | 1977-11-14 | Kao Corp | Detergent compositions |
| DE2754359C2 (en) * | 1977-12-07 | 1986-11-20 | Basf Ag, 6700 Ludwigshafen | Process for the preparation of strongly alkaline, aqueous and solubilizer-containing solutions of non-ionic surfactants |
| US4284532A (en) * | 1979-10-11 | 1981-08-18 | The Procter & Gamble Company | Stable liquid detergent compositions |
| US4539134A (en) * | 1982-12-02 | 1985-09-03 | Halliburton Company | Methods and cleaning compositions for removing organic materials from metallic surfaces |
| US4689168A (en) * | 1984-06-08 | 1987-08-25 | The Drackett Company | Hard surface cleaning composition |
| US4854969A (en) * | 1986-07-02 | 1989-08-08 | Sun Chemical Corporation | Lithographic fountain solutions |
| US5037474A (en) * | 1989-11-27 | 1991-08-06 | Morton International, Inc. | Bitumen antistripping agent |
| DE69734427T2 (en) | 1996-02-14 | 2006-07-20 | Stepan Co., Northfield | HYDROTROP CONTAINING CLEANERS FOR HARD SURFACES WITH REDUCED RESIDUE CONSTRUCTION |
| DE19959311A1 (en) * | 1999-12-09 | 2001-08-23 | Henkel Ecolab Gmbh & Co Ohg | Defoamer preparation and its use |
| EP1765968B1 (en) | 2004-07-15 | 2008-12-10 | Akzo Nobel N.V. | Phosphated alcanol, its use as a hydrotrope and cleaning composition containing the compound |
| CA2654596A1 (en) * | 2006-07-14 | 2008-01-17 | Ecolab Inc. | Alkaline floor cleaning composition and method of cleaning a floor |
| KR102524860B1 (en) | 2016-07-12 | 2023-04-24 | 프레스톤 프로닥츠 코포레이션 | How to Prevent Corrosion in Heat Transfer Fluids and Heat Transfer Systems |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1970578A (en) * | 1930-11-29 | 1934-08-21 | Ig Farbenindustrie Ag | Assistants for the textile and related industries |
| US2213477A (en) * | 1935-12-12 | 1940-09-03 | Gen Aniline & Film Corp | Glycol and polyglycol ethers of isocyclic hydroxyl compounds |
| US2730503A (en) * | 1952-12-29 | 1956-01-10 | Pressner Samuel | Detergent and brightening composition |
| US2855367A (en) * | 1954-09-07 | 1958-10-07 | Colgate Palmolive Co | Detergent composition |
| BE558448A (en) * | 1956-07-02 | |||
| US3033889A (en) * | 1958-10-21 | 1962-05-08 | Gen Aniline & Film Corp | Phosphate esters of branched chain alcohols |
| US3079348A (en) * | 1958-12-01 | 1963-02-26 | Rohm & Haas | Surfactants |
| BE596967A (en) * | 1959-11-12 | |||
| US3168478A (en) * | 1960-07-28 | 1965-02-02 | Gen Aniline & Film Corp | Highly alkaline surface active compositions |
| US3122508A (en) * | 1960-07-28 | 1964-02-25 | Gen Aniline & Film Corp | Heavy duty detergent compositions |
-
0
- NL NL292944D patent/NL292944A/xx unknown
- IT IT700621D patent/IT700621A/it unknown
- BE BE632444D patent/BE632444A/xx unknown
-
1963
- 1963-05-15 DE DER35185A patent/DE1243313B/en active Pending
- 1963-05-16 GB GB19512/63A patent/GB1016081A/en not_active Expired
- 1963-05-17 AU AU30827/63A patent/AU288953B2/en not_active Expired
- 1963-05-17 FR FR935275A patent/FR1365398A/en not_active Expired
-
1965
- 1965-03-12 US US439472A patent/US3294693A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2386604A1 (en) * | 1977-04-04 | 1978-11-03 | Gaf Corp | DETERGENT COMPOSITION CONSISTING OF A HYDROTROPIC SYNERGIC MIXTURE OF TWO CLASSES OF ORGANIC PHOSPHATES |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1243313B (en) | 1967-06-29 |
| IT700621A (en) | |
| AU288953B2 (en) | 1969-02-19 |
| BE632444A (en) | |
| GB1016081A (en) | 1966-01-05 |
| US3294693A (en) | 1966-12-27 |
| NL292944A (en) | |
| AU3082763A (en) | 1964-11-19 |
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