FI92405C - Uusi olefiinipolymerointikatalyytti, menetelmä sen valmistamiseksi ja sen käyttö olefiinien polymerointiin - Google Patents
Uusi olefiinipolymerointikatalyytti, menetelmä sen valmistamiseksi ja sen käyttö olefiinien polymerointiin Download PDFInfo
- Publication number
- FI92405C FI92405C FI925832A FI925832A FI92405C FI 92405 C FI92405 C FI 92405C FI 925832 A FI925832 A FI 925832A FI 925832 A FI925832 A FI 925832A FI 92405 C FI92405 C FI 92405C
- Authority
- FI
- Finland
- Prior art keywords
- process according
- ethylene
- compound
- sheep
- alkyl
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 42
- 238000006116 polymerization reaction Methods 0.000 title claims description 25
- 150000001336 alkenes Chemical class 0.000 title claims description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 3
- 238000002360 preparation method Methods 0.000 title description 12
- 239000002685 polymerization catalyst Substances 0.000 title description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 49
- 239000000203 mixture Substances 0.000 claims description 44
- 150000002681 magnesium compounds Chemical class 0.000 claims description 35
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 30
- 239000005977 Ethylene Substances 0.000 claims description 30
- 239000011777 magnesium Substances 0.000 claims description 29
- 239000010936 titanium Substances 0.000 claims description 27
- 238000005470 impregnation Methods 0.000 claims description 26
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 22
- 238000009826 distribution Methods 0.000 claims description 20
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 claims description 20
- 229910052736 halogen Inorganic materials 0.000 claims description 18
- 150000002367 halogens Chemical class 0.000 claims description 17
- 150000004703 alkoxides Chemical group 0.000 claims description 16
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 16
- 229910052749 magnesium Inorganic materials 0.000 claims description 16
- 150000003609 titanium compounds Chemical group 0.000 claims description 16
- 239000012320 chlorinating reagent Substances 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 229930195733 hydrocarbon Natural products 0.000 claims description 10
- 235000011147 magnesium chloride Nutrition 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- 239000004711 α-olefin Substances 0.000 claims description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 238000005660 chlorination reaction Methods 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 3
- 125000005234 alkyl aluminium group Chemical group 0.000 claims description 3
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 150000002894 organic compounds Chemical class 0.000 claims description 3
- 239000002516 radical scavenger Substances 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 239000007791 liquid phase Substances 0.000 claims description 2
- 239000012071 phase Substances 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- 241001494479 Pecora Species 0.000 claims 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminum chloride Substances Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 2
- 239000001569 carbon dioxide Substances 0.000 claims 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 238000010186 staining Methods 0.000 claims 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 32
- 239000000377 silicon dioxide Substances 0.000 description 23
- 239000003054 catalyst Substances 0.000 description 15
- 239000001257 hydrogen Substances 0.000 description 14
- 229910052739 hydrogen Inorganic materials 0.000 description 14
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 13
- 239000000460 chlorine Substances 0.000 description 12
- -1 magnesium halides Chemical class 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 125000003545 alkoxy group Chemical group 0.000 description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 10
- 229910052801 chlorine Inorganic materials 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 6
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 4
- WNJYXPXGUGOGBO-UHFFFAOYSA-N magnesium;propan-1-olate Chemical compound CCCO[Mg]OCCC WNJYXPXGUGOGBO-UHFFFAOYSA-N 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 230000002902 bimodal effect Effects 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 125000006528 (C2-C6) alkyl group Chemical group 0.000 description 1
- KPWDGTGXUYRARH-UHFFFAOYSA-N 2,2,2-trichloroethanol Chemical compound OCC(Cl)(Cl)Cl KPWDGTGXUYRARH-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- ZJZAHICNIPELMG-UHFFFAOYSA-N N[P]N Chemical compound N[P]N ZJZAHICNIPELMG-UHFFFAOYSA-N 0.000 description 1
- 101100023124 Schizosaccharomyces pombe (strain 972 / ATCC 24843) mfr2 gene Proteins 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- RBCRFPZQMJBCFZ-UHFFFAOYSA-M [S+]=O.[F-] Chemical compound [S+]=O.[F-] RBCRFPZQMJBCFZ-UHFFFAOYSA-M 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- FSBVERYRVPGNGG-UHFFFAOYSA-N dimagnesium dioxido-bis[[oxido(oxo)silyl]oxy]silane hydrate Chemical compound O.[Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O FSBVERYRVPGNGG-UHFFFAOYSA-N 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 235000013847 iso-butane Nutrition 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- YHNWUQFTJNJVNU-UHFFFAOYSA-N magnesium;butane;ethane Chemical compound [Mg+2].[CH2-]C.CCC[CH2-] YHNWUQFTJNJVNU-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 1
- ATVLVRVBCRICNU-UHFFFAOYSA-N trifluorosilicon Chemical compound F[Si](F)F ATVLVRVBCRICNU-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI925832A FI92405C (fi) | 1992-12-22 | 1992-12-22 | Uusi olefiinipolymerointikatalyytti, menetelmä sen valmistamiseksi ja sen käyttö olefiinien polymerointiin |
| DE69308200T DE69308200T2 (de) | 1992-12-22 | 1993-12-16 | Neuer Katalysator für Olefinpolymerisation, Verfahren zu seiner Herstellung und Verwendung zur Polymerisation von Olefinen |
| EP93120347A EP0604850B1 (en) | 1992-12-22 | 1993-12-16 | Novel olefin polymerizing catalyst, method for preparing it and use for the polymerization of olefins |
| PCT/FI1993/000550 WO1994014857A1 (en) | 1992-12-22 | 1993-12-21 | Novel olefin polymerizing catalyst, method for preparing it and use for the polymerization of olefins |
| MYPI93002788A MY109240A (en) | 1992-12-22 | 1993-12-21 | Novel olefin polymerizing catalyst, method for preparing it use for the polymerization of olefins |
| CA002152355A CA2152355A1 (en) | 1992-12-22 | 1993-12-21 | Novel olefin polymerizing catalyst, method for preparing it and use for the polymerization of olefins |
| BR9307720-3A BR9307720A (pt) | 1992-12-22 | 1993-12-21 | Processo para preparar uma composição de procatalisador para a polimerização de olefinas em etapas, composição de procatalisador para a polimerização de olefinas e processo para a homopolimerização e copolimerização de eteno |
| CN93119884A CN1051318C (zh) | 1992-12-22 | 1993-12-22 | 烯烃聚合催化剂、其制备方法及其在烯烃聚合中的应用 |
| TW083100675A TW297028B (enExample) | 1992-12-22 | 1994-01-27 | |
| NO952499A NO952499L (no) | 1992-12-22 | 1995-06-21 | Alkenpolymerisasjonskatalysator |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI925832A FI92405C (fi) | 1992-12-22 | 1992-12-22 | Uusi olefiinipolymerointikatalyytti, menetelmä sen valmistamiseksi ja sen käyttö olefiinien polymerointiin |
| FI925832 | 1992-12-22 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI925832A0 FI925832A0 (fi) | 1992-12-22 |
| FI92405B FI92405B (fi) | 1994-07-29 |
| FI92405C true FI92405C (fi) | 1994-11-10 |
Family
ID=8536443
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI925832A FI92405C (fi) | 1992-12-22 | 1992-12-22 | Uusi olefiinipolymerointikatalyytti, menetelmä sen valmistamiseksi ja sen käyttö olefiinien polymerointiin |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0604850B1 (enExample) |
| CN (1) | CN1051318C (enExample) |
| BR (1) | BR9307720A (enExample) |
| CA (1) | CA2152355A1 (enExample) |
| DE (1) | DE69308200T2 (enExample) |
| FI (1) | FI92405C (enExample) |
| MY (1) | MY109240A (enExample) |
| NO (1) | NO952499L (enExample) |
| TW (1) | TW297028B (enExample) |
| WO (1) | WO1994014857A1 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI942949A0 (fi) * | 1994-06-20 | 1994-06-20 | Borealis Polymers Oy | Prokatalysator foer producering av etenpolymerer och foerfarande foer framstaellning daerav |
| FI990140A0 (fi) * | 1999-01-26 | 1999-01-26 | Borealis Polymers Oy | Korkea-aktiivinen olefiinipolymerointikatalysaattori, sen valmistus, katalysaattorisysteemi ja käyttö |
| ATE401123T1 (de) | 2004-12-17 | 2008-08-15 | Borealis Tech Oy | Verfahren zur polymerisation von olefinen in gegenwart eines olefin polymerisationskatalysators |
| RU2009102047A (ru) * | 2006-06-23 | 2010-07-27 | Базелль Полиолефин Италия С.Р.Л. (It) | Предшественники катализитора на основе хлоралкоголята магния |
| WO2007147714A1 (en) * | 2006-06-23 | 2007-12-27 | Basell Poliolefine Italia S.R.L. | Magnesium chloroalkolate-based catalyst precursors |
| CN102040687B (zh) * | 2009-10-20 | 2013-09-25 | 中国石油化工股份有限公司 | 一种用于乙烯聚合反应的催化剂组分及其催化剂 |
| CN104395362B (zh) * | 2012-04-19 | 2018-01-12 | 英尼奥斯欧洲股份公司 | 用于烯烃聚合的催化剂、其生产方法及用途 |
| CN104245759A (zh) * | 2012-04-26 | 2014-12-24 | 沙特基础工业公司 | 用于聚合乙烯的方法 |
| CN104140481B (zh) * | 2014-07-17 | 2017-09-26 | 任丘市利和科技发展有限公司 | 一种用于乙烯聚合或共聚合的催化剂组分、制备方法及其应用 |
| WO2022111966A1 (en) | 2020-11-27 | 2022-06-02 | Borealis Ag | Catalyst feed system |
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| US4405495A (en) | 1980-06-30 | 1983-09-20 | Union Carbide Corporation | Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization |
| US4379758A (en) | 1980-12-24 | 1983-04-12 | Union Carbide Corporation | Catalyst composition for polymerizing ethylene |
| US4451574A (en) | 1981-09-30 | 1984-05-29 | Exxon Research & Engineering Co. | Polymerization catalyst |
| IL71357A (en) | 1983-03-29 | 1987-03-31 | Union Carbide Corp | Process for producing low density ethylene copolymers |
| US4565797A (en) | 1984-08-03 | 1986-01-21 | Exxon Research & Engineering Co. | Polymerization catalyst, production and use (P-1010) |
| US4565796A (en) | 1984-08-06 | 1986-01-21 | Exxon Research & Engineering Co. | Polymerization catalyst, production and use |
| US4558024A (en) | 1984-08-06 | 1985-12-10 | Exxon Research & Engineering Co. | Polymerization catalyst, production and use |
| DE3431302A1 (de) | 1984-08-25 | 1986-03-06 | Philips Patentverwaltung Gmbh, 2000 Hamburg | Selektivruf- und waehleinrichtung fuer eine bewegliche funkstation eines funkuebertragungssystems |
| FR2574878B1 (fr) | 1984-12-14 | 1987-01-23 | Richoux Raymond | Dispositif flexible tubulaire de transmission d'efforts longitudinaux |
| US4888318A (en) | 1986-01-24 | 1989-12-19 | Mobil Oil Corporation | Catalyst composition for polymerizing alpha-olefins |
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| DE3723526A1 (de) * | 1987-07-16 | 1989-01-26 | Hoechst Ag | Verfahren zur herstellung eines polyolefins mit einer breiten molmassenverteilung |
| DE3735883A1 (de) | 1987-10-23 | 1989-05-03 | Thyssen Stahl Ag | Kokille zum stranggiessen |
| US4833111A (en) | 1988-01-14 | 1989-05-23 | Mobil Oil Corporation | Catalyst composition for polymerizing alpha-olefin polymers of narrow molecular weight distribution |
| US4876229A (en) | 1988-05-31 | 1989-10-24 | Mobil Oil Corporation | Catalyst composition for polymerizing olefins of narrow molecular weight distribution and polymerization therewith |
| JP2717723B2 (ja) * | 1989-07-17 | 1998-02-25 | 日本石油株式会社 | ポリオレフィンの製造方法 |
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| FI85981C (fi) | 1989-12-28 | 1992-06-25 | Neste Oy | Foerfarande foer framstaellning av en prokatalytkomposition avsedd foer polymerisering av olefiner samt anvaendning av kompositionen. |
| IT1246265B (it) * | 1990-09-07 | 1994-11-17 | Enimont Anic Srl | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene |
| FI86867C (fi) | 1990-12-28 | 1992-10-26 | Neste Oy | Flerstegsprocess foer framstaellning av polyeten |
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-
1992
- 1992-12-22 FI FI925832A patent/FI92405C/fi not_active IP Right Cessation
-
1993
- 1993-12-16 DE DE69308200T patent/DE69308200T2/de not_active Expired - Lifetime
- 1993-12-16 EP EP93120347A patent/EP0604850B1/en not_active Expired - Lifetime
- 1993-12-21 WO PCT/FI1993/000550 patent/WO1994014857A1/en not_active Ceased
- 1993-12-21 CA CA002152355A patent/CA2152355A1/en not_active Abandoned
- 1993-12-21 BR BR9307720-3A patent/BR9307720A/pt not_active IP Right Cessation
- 1993-12-21 MY MYPI93002788A patent/MY109240A/en unknown
- 1993-12-22 CN CN93119884A patent/CN1051318C/zh not_active Expired - Lifetime
-
1994
- 1994-01-27 TW TW083100675A patent/TW297028B/zh active
-
1995
- 1995-06-21 NO NO952499A patent/NO952499L/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO952499L (no) | 1995-08-21 |
| TW297028B (enExample) | 1997-02-01 |
| FI92405B (fi) | 1994-07-29 |
| DE69308200D1 (de) | 1997-03-27 |
| MY109240A (en) | 1996-12-31 |
| FI925832A0 (fi) | 1992-12-22 |
| CN1089955A (zh) | 1994-07-27 |
| CN1051318C (zh) | 2000-04-12 |
| BR9307720A (pt) | 1999-08-31 |
| DE69308200T2 (de) | 1997-06-05 |
| EP0604850B1 (en) | 1997-02-19 |
| CA2152355A1 (en) | 1994-07-07 |
| EP0604850A2 (en) | 1994-07-06 |
| WO1994014857A1 (en) | 1994-07-07 |
| EP0604850A3 (en) | 1994-10-26 |
| NO952499D0 (no) | 1995-06-21 |
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| GB | Transfer or assigment of application |
Owner name: BOREALIS POLYMERS OY |
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Owner name: BOREALIS POLYMERS OY |
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| MM | Patent lapsed |