FI85507B - FOERFARANDE FOER FRAMSTAELLNING AV PERLITISKA GJUTJAERNSSORTER. - Google Patents

FOERFARANDE FOER FRAMSTAELLNING AV PERLITISKA GJUTJAERNSSORTER. Download PDF

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Publication number
FI85507B
FI85507B FI871214A FI871214A FI85507B FI 85507 B FI85507 B FI 85507B FI 871214 A FI871214 A FI 871214A FI 871214 A FI871214 A FI 871214A FI 85507 B FI85507 B FI 85507B
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FI
Finland
Prior art keywords
stabilizing element
added
perlite
cast iron
metallic sheath
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Application number
FI871214A
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Finnish (fi)
Swedish (sv)
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FI871214A (en
FI85507C (en
FI871214A0 (en
Inventor
Ivo Henych
Original Assignee
Fischer Ag Georg
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Publication of FI871214A publication Critical patent/FI871214A/en
Publication of FI85507B publication Critical patent/FI85507B/en
Application granted granted Critical
Publication of FI85507C publication Critical patent/FI85507C/en

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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00Refining of pig-iron; Cast iron
    • C21C1/10Making spheroidal graphite cast-iron
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00Refining of pig-iron; Cast iron
    • C21C1/08Manufacture of cast-iron
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00Refining of pig-iron; Cast iron
    • C21C1/10Making spheroidal graphite cast-iron
    • C21C1/105Nodularising additive agents

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Continuous Casting (AREA)
  • Thin Magnetic Films (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Chemical Vapour Deposition (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Description

1 855071 85507

Menetelmä peri Iitti Sten valurautalaatujen valmistamiseksiThe method inherited from Iitti Sten for the production of cast iron grades

Keksintö koskee menetelmää periiittiSten valurautalaatujen, kuten GG, GGG ja GGV valmistamiseksi.The invention relates to a process for the production of cast iron grades such as GG, GGG and GGV.

Eräs tähänastinen mahdollisuus perliittisen GG:n, GGG:n ja GGV:n valmistamiseksi on, että panostetaan perii iti n stabilointiainetta, esim. kuparia, sulatusuuniin tai lisätään sitä senkassa olevaan vaiurautasulaan. Tämä tapahtuu erityisesti silloin, kun käsitelty valurauta valetaan automaattisesta valu-uunista tai tulppakauhasta suoraan valumuottiin. Tämä menetelmä aiheuttaa kuitenkin vaikeuksia silloin, kun käytetään samaa sulatusuunia sekä ferriittisell e että periiittisei 1 e valuraudalle. Esim. painekaasukäyttöisen valu-uunin puhdistaminen jäänteistä vaatii paljon aikaa, ja voi johtaa koko va-lulinjan pysähtymiseen. Siitä huolimatta liittyy jokaiseen periiittisestä ferriittiseen vaiurautalaatuun muuttamiseen riskejä, koska uunin syöttöön mahdollisesti jäävät perl iitin stabilointiaineen muodostamat epäpuhtaudet voivat vaikuttaa haitallisesti seuraavaan ferriittiseen vaiurautalaatuun.One hitherto possible possibility for the production of perlite GG, GGG and GGV is to charge a heritic stabilizer, e.g. copper, in a melting furnace or to add it to the molten iron melt in the ladle. This is especially the case when the treated cast iron is cast from an automatic casting furnace or plug bucket directly into a casting mold. However, this method causes difficulties when using the same melting furnace for both ferritic and peritite alloys. For example, cleaning a pressurized gas-fired casting furnace from debris requires a lot of time, and can result in the entire casting line stopping. Nevertheless, there are risks associated with any change from peritol to ferritic cast iron grade, as any perlite stabilizer impurities that may remain in the furnace feed may adversely affect subsequent ferritic cast iron grade.

Tämä ratkaistaan keksinnön mukaisesti patenttivaatimuksen 1 tunnusmerkkiosan avulla.This is solved according to the invention by means of the characterizing part of claim 1.

Muut keksinnön menetelmän mukaiset edulliset suoritusmuodot ilmenevät aiivaatimuksista.Other preferred embodiments of the method of the invention will be apparent from the claims.

Tämän keksinnön menetelmä perustuu siihen, että ainakin yksi perliitin stabilointiaine lisätään sulassa tilassa olevaan valurautaan valu-uunista tai -senkasta valumuotin sisään kaa-::: tamisen yhteydessä. Perliitin stabilointiaineen lisäys suori tetaan mieluiten valuvirtaan. Täten sulatus- ja vai ui aitteita ei altisteta perliitin stabilointiaineen kontaminaatiolle.The process of the present invention is based on the addition of at least one perlite stabilizer to molten iron in a casting furnace or ladle during pouring into a mold. The addition of perlite stabilizer is preferably performed in the casting stream. Thus, the melting and / or swimming devices are not exposed to contamination of the perlite stabilizer.

Kun ymppäysaineeseen lisättävä perliitin stabilointiaine ei 2 85507 saa aiheuttaa valuvirtaan liian suurta termistä kuormitusta, käytetään kuparin (Cu) asemesta tinaa (Sn) tai antimonia (Sb) oleellisesti pienemmissä määrin kuin annosteltua kuparia. Täten taataan, että lisätty ymppäysaine ja perliitin stabilointiaine sulaa valuvirrassa heti ja tasaisesti. Tässä auttavat vielä Curiin verrattuna Sn:n ja Sb:n alhaisemmat sulamisläm-pötilat ja alhaisemmat ominaislämmöt.When the perlite stabilizer 2 85507 to be added to the inoculum must not cause an excessive thermal load on the casting stream, tin (Sn) or antimony (Sb) are used instead of copper (Cu) to a substantially lesser extent than the dosed copper. This ensures that the added inoculant and perlite stabilizer melt immediately and evenly in the casting stream. This is further aided by the lower melting temperatures and lower specific temperatures of Sn and Sb compared to Cur.

Esimerkki 1:Example 1:

Pal 1ografiittivaiurautalaadun GGG 50 valmistamiseksi lejeera-taan siihen tarpeellisen periiittipitoisuuden saavuttamiseksi lisänä tavallisesti 0,3 % Cu:a. Edellyttäen, että perusraudan (romua) kuparipitoisuus on alle 0,1 % Cu:a, tarvitaan lisättävän 0,2 % Cu:n asemesta vain 0,015 % Sn:aa.In order to produce GGG 50 grade graphite wax, it is usually alloyed with 0.3% Cu in addition to obtain the required perite content. Provided that the copper content of the base iron (scrap) is less than 0.1% Cu, only 0.015% Sn is required instead of 0.2% Cu.

Esimerkki 2:Example 2:

Pal 1ografiittivaiurautalaadun GGG 60 valmistamiseksi lejee-rataan sen joukkoon tavallisesti 0,5-0,7 % Cu:a. Samoin edellytyksin kuin esimerkissä 1 tarvitaan silloin 0,4-0,6 %, keskimäärin 0,5 % Cu:a, joka korvataan, vain 0,015 % $n:aa li-säämäl1ä.To produce GGG 60 grade graphite wax, it is usually alloyed with 0.5-0.7% Cu. Under the same conditions as in Example 1, then 0.4-0.6%, on average 0.5% Cu, to be replaced, only 0.015% $ 1 of li is required.

Perliitin stabilointiaineiden, kuten esim. Sn:n ja/tai Sb:n lisäys voi tapahtua mm. jauheen, langan tai 1ankamaisessa . muodossa olevan metallisen tai epämetallisen vaipan ympäröimän jauheen muodossa. Sn tai Sb voidaan lisätä yhdistelmänä ‘ - ymppäysaineen (FeSi ym.) kanssa, esim. jauhesekoituksen muodossa (sisään puhaltamalla), 1ejeerinkinä, esim. langan muo-, dossa, jolloin pui verisekoitusta ympäröi metallinen tai epä-·' metallinen vaippa. Jauhemainen ymppäysaine voi olla ympäröitynä metallisella vaipalla, joka on sisältä tai ulkoa pää 1 -' lystetty tinalla tai antimonilla. Jos lisäys tapahtuu langan muodossa, voi jauhemaisen ymppäysaineen vaippa olla Sn:aa tai Sb:a. Lanka voi myös olla sovitettuna jauhemaisen ymppäysai-. neen sisään, jolloin vaippa voi olla metallista tai epämetallista ainetta. Sb:n lisäys on erityisen edullista, koska Sb:n 3 85507The addition of perlite stabilizers, such as Sn and / or Sb, can take place e.g. in powder, wire or 1. in the form of a powder surrounded by a metallic or non-metallic sheath in the form of. Sn or Sb may be added in combination with an inoculant (FeSi and the like), e.g. in the form of a powder mixture (by blowing in), as an alloy, e.g. in the form of a wire, the wood blood mixture being surrounded by a metallic or non-metallic sheath. The powdered inoculum may be surrounded by a metallic sheath which is internally or externally terminated with tin or antimony. If the addition takes place in the form of a wire, the shell of the powdered inoculant may be Sn or Sb. The wire may also be fitted with a powdered seed. in which case the sheath may be of metallic or non-metallic material. The addition of Sb is particularly advantageous because Sb 3 85507

OO

kiehumispiste on 1440 C, siis alempana kuin sulan lämpö ennen käsittelyä. Näin ollen voidaan käyttää kiertoraaka-ainetta periiittisistä ferriittisiin vaiurautalaatuihi n, sillä siinä mahdollisesti oleva Sb höyrystyy sulatuksen yhteydessä.the boiling point is 1440 C, i.e. lower than the heat of the melt before treatment. Thus, a circulating raw material from peritite to ferritic cast iron grades can be used, since any Sb therein evaporates during smelting.

Kuvatun menetelmän eräs erityinen etu on mahdollisuus valmistaa ferriittisiä ja perii i tti siä vaiurautalaatuja samassa sulatus- ja vaiusenkkalaitteessa ilman tuotannon keskeytystä näiden laitteiden täydellistä tyhjentämistä varten. Sen ohella välttyy tunnettuun menetelmään sisältyvä vaara, että syöttö j ärjestel mään jäävät perliitin stabilointiaineiden jäännökset haittaavat seuraavaa ferriittisen valuraudan tuotantoa. Sn:n tai Sb:n lisäys ymppäysaineen kanssa kuvatussa lankamuo-dossa on sangen edullista, koska siten saavutetaan Sn:n tai Sb:n tarkka annostelu.One particular advantage of the described method is the possibility to produce ferritic and traditional cast iron grades in the same smelting and siling machine without interrupting production for the complete emptying of these equipment. In addition, the risk inherent in the known process that residues of perlite stabilizers remaining in the feed system will interfere with the subsequent production of ferritic cast iron is avoided. The addition of Sn or Sb in the form of yarn described with the inoculant is quite advantageous, since thus accurate dosing of Sn or Sb is achieved.

Claims (10)

1. Förfarande för framställning av ferritiska och perli-tiska gjutjärnssorter de senare i formen av GG, GGG eller GGV genom att använda samma gjutugn resp. gjutpanna, ur vilken gjutjärnsmältan gjutes genom ett utlopp tili en gjutform, varvid under tillverkning av ett perlitiskt gjut-järn tili gjutjärnsmältan tillsättes minst ett perlitstabi-liserande element, kännetecknat av att det perlitstabili-serande elementet tillsättes möjligen med ett ympmedel tili gjutjärnssmältan, som fortfarande förefinnes i smält till-ständ mellan utloppet och det inre av gjutformen.1. A process for the production of ferritic and perlite cast iron varieties the latter in the form of GG, GGG or GGV using the same casting furnace, respectively. casting furnace from which the cast iron melt is poured through an outlet into a mold, wherein during the manufacture of a perlitic cast iron to the cast iron melt, at least one perlite stabilizing element is characterized, the perlite stabilizing element possibly being added with a grafting iron to is found in the molten state between the outlet and the interior of the mold. 2. Förfarande enligt patentkravet 1, kännetecknat av att det perlitstabiliserande elementet tillsättes tili gjutsträ-len.Method according to claim 1, characterized in that the pearlite stabilizing element is added to the casting beam. 3. Förfarande enligt patentkravet 1 eller 2, kännetecknat av att tenn (Sn) eller antimon (Sb) tillsättes säsom perlitstabiliserande element.Method according to claim 1 or 2, characterized in that tin (Sn) or antimony (Sb) is added as perlite stabilizing element. : 4. Förfarande enligt nägot av patentkraven 1-3, känneteck- .···. nat av att det perlitstabiliserande elementet tillsättes med ett ympdel säsom en legering. 6 Ö 5 507Method according to any of claims 1-3, characterized in. ···. by adding the perlite stabilizing element with a graft portion such as an alloy. 6 Ö 5 507 5. Förfarande enligt nägot av patentkraven 1-3, känneteck-nat av att det perlitstabiliserande elementet tillsättes säsom träd eller säsom pulver.Process according to any one of claims 1-3, characterized in that the pearlite stabilizing element is added as a tree or as a powder. 6. Förfarande enligt patentkravet 5, kännetecknat av att det perlitstabiliserande elementet tillsättes i trädform säsom pulver ommantlat med en icke-metallisk ommantling.6. A process according to claim 5, characterized in that the pearl stabilizing element is added in tree form such as powder sheathed with a non-metallic sheath. 7. Förfarande enligt patentkravet 6, kännetecknat av att det perlitstabiliserande elementet och ympmedlet tillsättes i trädform säsom pulver ommantlat med en icke-metallisk ommantling.Process according to claim 6, characterized in that the pearl stabilizing element and the inoculant are added in tree form such as powder sheathed with a non-metallic sheath. 8. Förfarande enligt nägot av patentkraven 1-3, kännetecknat av att det perlitstabiliserande elementet tillsättes i form av en ommantling av ett pulverformigt ympmedel.Method according to any one of claims 1-3, characterized in that the perlite stabilizing element is added in the form of a sheath of a powdered grafting agent. 9. Förfarande enligt nägot av patentkraven 1-3, kännetecknat av att det perlitstabiliserande elementet tillsättes säsom ett skikt päfört pä den yttre eller inre ytan av en metallisk ommantling av ett pulverformigt ympmedel.Method according to any of claims 1-3, characterized in that the perlite stabilizing element is added as a layer applied to the outer or inner surface of a metallic sheath of a powdered grafting agent. 10. Förfarande enligt nägot av patentkraven 1-3, 5 och 6, kännetecknat av att det perlitstabiliserande elementet tillsättes säsom träd inbäddad i pulverformigt, med en icke-metallisk ommantling ommantlat ympmedel.Method according to any one of claims 1-3, 5 and 6, characterized in that the pearl stabilizing element is added as a tree embedded in powdered, with a non-metallic sheath wrapped grafting agent.
FI871214A 1986-03-20 1987-03-19 Process for making Perlitic cast iron varieties FI85507C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH1131/86A CH665851A5 (en) 1986-03-20 1986-03-20 METHOD FOR PRODUCING PERLITIC CAST IRON TYPES.
CH113186 1986-03-20

Publications (4)

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FI871214A0 FI871214A0 (en) 1987-03-19
FI871214A FI871214A (en) 1987-09-21
FI85507B true FI85507B (en) 1992-01-15
FI85507C FI85507C (en) 1992-04-27

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FI871214A FI85507C (en) 1986-03-20 1987-03-19 Process for making Perlitic cast iron varieties

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JP (1) JPS62230926A (en)
KR (1) KR910001353B1 (en)
CN (1) CN1005994B (en)
AT (1) AT398984B (en)
AU (1) AU594439B2 (en)
CH (1) CH665851A5 (en)
DD (1) DD259001A5 (en)
DE (1) DE3706901A1 (en)
ES (1) ES2002591A6 (en)
FI (1) FI85507C (en)
FR (1) FR2601039B1 (en)
GB (1) GB2187985B (en)
IN (1) IN168111B (en)
IT (1) IT1204930B (en)
NO (1) NO871116L (en)
NZ (1) NZ219725A (en)
PL (1) PL264592A1 (en)
SE (1) SE462976B (en)
YU (1) YU41487A (en)
ZA (1) ZA871685B (en)

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US6973954B2 (en) * 2001-12-20 2005-12-13 International Engine Intellectual Property Company, Llc Method for manufacture of gray cast iron for crankcases and cylinder heads
NO20045611D0 (en) * 2004-12-23 2004-12-23 Elkem Materials Modifying agents for cast iron
CN102296226A (en) * 2011-07-28 2011-12-28 徐州胜海机械制造科技有限公司 Post inoculant for large-scale ductile iron casting and manufacture method thereof
CN102936679A (en) * 2012-11-22 2013-02-20 宁夏共享集团有限责任公司 Gray cast iron electric-furnace smelting method
CN106676250A (en) * 2016-12-15 2017-05-17 广西大学 Thermal treatment method for chilled cast iron roll
CN112962018B (en) * 2021-01-29 2022-04-01 宁波日星铸业有限公司 Chilling process manufacturing method of non-label QT600-7 nodular cast iron

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Also Published As

Publication number Publication date
SE8701146L (en) 1987-09-21
DD259001A5 (en) 1988-08-10
GB8704816D0 (en) 1987-04-08
FR2601039B1 (en) 1992-12-31
IT8719681A0 (en) 1987-03-13
DE3706901C2 (en) 1989-02-16
GB2187985A (en) 1987-09-23
NO871116D0 (en) 1987-03-18
IN168111B (en) 1991-02-09
KR870009036A (en) 1987-10-22
KR910001353B1 (en) 1991-03-04
ATA49787A (en) 1994-07-15
FR2601039A1 (en) 1988-01-08
AU594439B2 (en) 1990-03-08
YU41487A (en) 1990-02-28
PL264592A1 (en) 1988-02-04
AT398984B (en) 1995-02-27
ES2002591A6 (en) 1988-08-16
CN87102216A (en) 1987-09-30
AU7042487A (en) 1987-09-24
CN1005994B (en) 1989-12-06
IT1204930B (en) 1989-03-10
FI871214A (en) 1987-09-21
SE462976B (en) 1990-09-24
NO871116L (en) 1987-09-21
FI85507C (en) 1992-04-27
CH665851A5 (en) 1988-06-15
FI871214A0 (en) 1987-03-19
GB2187985B (en) 1990-12-12
JPS62230926A (en) 1987-10-09
ZA871685B (en) 1987-08-31
NZ219725A (en) 1990-03-27
DE3706901A1 (en) 1987-10-01
SE8701146D0 (en) 1987-03-19

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Owner name: GEORG FISCHER AKTIENGESELLSCHAFT