FI85507C - Process for making Perlitic cast iron varieties - Google Patents
Process for making Perlitic cast iron varieties Download PDFInfo
- Publication number
- FI85507C FI85507C FI871214A FI871214A FI85507C FI 85507 C FI85507 C FI 85507C FI 871214 A FI871214 A FI 871214A FI 871214 A FI871214 A FI 871214A FI 85507 C FI85507 C FI 85507C
- Authority
- FI
- Finland
- Prior art keywords
- stabilizing element
- added
- perlite
- cast iron
- metallic sheath
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/10—Making spheroidal graphite cast-iron
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/08—Manufacture of cast-iron
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/10—Making spheroidal graphite cast-iron
- C21C1/105—Nodularising additive agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Continuous Casting (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Chemical Vapour Deposition (AREA)
- Thin Magnetic Films (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Description
1 855071 85507
Menetelmä peri Iitti Sten valurautalaatujen valmistamiseksiThe method inherited from Iitti Sten for the production of cast iron grades
Keksintö koskee menetelmää periiittiSten valurautalaatujen, kuten GG, GGG ja GGV valmistamiseksi.The invention relates to a process for the production of cast iron grades such as GG, GGG and GGV.
Eräs tähänastinen mahdollisuus perliittisen GG:n, GGG:n ja GGV:n valmistamiseksi on, että panostetaan perii iti n stabilointiainetta, esim. kuparia, sulatusuuniin tai lisätään sitä senkassa olevaan vaiurautasulaan. Tämä tapahtuu erityisesti silloin, kun käsitelty valurauta valetaan automaattisesta valu-uunista tai tulppakauhasta suoraan valumuottiin. Tämä menetelmä aiheuttaa kuitenkin vaikeuksia silloin, kun käytetään samaa sulatusuunia sekä ferriittisell e että periiittisei 1 e valuraudalle. Esim. painekaasukäyttöisen valu-uunin puhdistaminen jäänteistä vaatii paljon aikaa, ja voi johtaa koko va-lulinjan pysähtymiseen. Siitä huolimatta liittyy jokaiseen periiittisestä ferriittiseen vaiurautalaatuun muuttamiseen riskejä, koska uunin syöttöön mahdollisesti jäävät perl iitin stabilointiaineen muodostamat epäpuhtaudet voivat vaikuttaa haitallisesti seuraavaan ferriittiseen vaiurautalaatuun.One hitherto possible possibility for the production of perlite GG, GGG and GGV is to charge a heritic stabilizer, e.g. copper, in a melting furnace or to add it to the molten iron melt in the ladle. This is especially the case when the treated cast iron is cast from an automatic casting furnace or plug bucket directly into a casting mold. However, this method causes difficulties when using the same melting furnace for both ferritic and peritite alloys. For example, cleaning a pressurized gas-fired casting furnace from debris requires a lot of time, and can result in the entire casting line stopping. Nevertheless, there are risks associated with any change from peritol to ferritic cast iron grade, as any perlite stabilizer impurities that may remain in the furnace feed may adversely affect subsequent ferritic cast iron grade.
Tämä ratkaistaan keksinnön mukaisesti patenttivaatimuksen 1 tunnusmerkkiosan avulla.This is solved according to the invention by means of the characterizing part of claim 1.
Muut keksinnön menetelmän mukaiset edulliset suoritusmuodot ilmenevät aiivaatimuksista.Other preferred embodiments of the method of the invention will be apparent from the claims.
Tämän keksinnön menetelmä perustuu siihen, että ainakin yksi perliitin stabilointiaine lisätään sulassa tilassa olevaan valurautaan valu-uunista tai -senkasta valumuotin sisään kaa-::: tamisen yhteydessä. Perliitin stabilointiaineen lisäys suori tetaan mieluiten valuvirtaan. Täten sulatus- ja vai ui aitteita ei altisteta perliitin stabilointiaineen kontaminaatiolle.The process of the present invention is based on the addition of at least one perlite stabilizer to molten iron in a casting furnace or ladle during pouring into a mold. The addition of perlite stabilizer is preferably performed in the casting stream. Thus, the melting and / or swimming devices are not exposed to contamination of the perlite stabilizer.
Kun ymppäysaineeseen lisättävä perliitin stabilointiaine ei 2 85507 saa aiheuttaa valuvirtaan liian suurta termistä kuormitusta, käytetään kuparin (Cu) asemesta tinaa (Sn) tai antimonia (Sb) oleellisesti pienemmissä määrin kuin annosteltua kuparia. Täten taataan, että lisätty ymppäysaine ja perliitin stabilointiaine sulaa valuvirrassa heti ja tasaisesti. Tässä auttavat vielä Curiin verrattuna Sn:n ja Sb:n alhaisemmat sulamisläm-pötilat ja alhaisemmat ominaislämmöt.When the perlite stabilizer 2 85507 to be added to the inoculum must not cause an excessive thermal load on the casting stream, tin (Sn) or antimony (Sb) are used instead of copper (Cu) to a substantially lesser extent than the dosed copper. This ensures that the added inoculant and perlite stabilizer melt immediately and evenly in the casting stream. This is further aided by the lower melting temperatures and lower specific temperatures of Sn and Sb compared to Cur.
Esimerkki 1:Example 1:
Pal 1ografiittivaiurautalaadun GGG 50 valmistamiseksi lejeera-taan siihen tarpeellisen periiittipitoisuuden saavuttamiseksi lisänä tavallisesti 0,3 % Cu:a. Edellyttäen, että perusraudan (romua) kuparipitoisuus on alle 0,1 % Cu:a, tarvitaan lisättävän 0,2 % Cu:n asemesta vain 0,015 % Sn:aa.In order to produce GGG 50 grade graphite wax, it is usually alloyed with 0.3% Cu in addition to obtain the required perite content. Provided that the copper content of the base iron (scrap) is less than 0.1% Cu, only 0.015% Sn is required instead of 0.2% Cu.
Esimerkki 2:Example 2:
Pal 1ografiittivaiurautalaadun GGG 60 valmistamiseksi lejee-rataan sen joukkoon tavallisesti 0,5-0,7 % Cu:a. Samoin edellytyksin kuin esimerkissä 1 tarvitaan silloin 0,4-0,6 %, keskimäärin 0,5 % Cu:a, joka korvataan, vain 0,015 % $n:aa li-säämäl1ä.To produce GGG 60 grade graphite wax, it is usually alloyed with 0.5-0.7% Cu. Under the same conditions as in Example 1, then 0.4-0.6%, on average 0.5% Cu, to be replaced, only 0.015% $ 1 of li is required.
Perliitin stabilointiaineiden, kuten esim. Sn:n ja/tai Sb:n lisäys voi tapahtua mm. jauheen, langan tai 1ankamaisessa . muodossa olevan metallisen tai epämetallisen vaipan ympäröimän jauheen muodossa. Sn tai Sb voidaan lisätä yhdistelmänä ‘ - ymppäysaineen (FeSi ym.) kanssa, esim. jauhesekoituksen muodossa (sisään puhaltamalla), 1ejeerinkinä, esim. langan muo-, dossa, jolloin pui verisekoitusta ympäröi metallinen tai epä-·' metallinen vaippa. Jauhemainen ymppäysaine voi olla ympäröitynä metallisella vaipalla, joka on sisältä tai ulkoa pää 1 -' lystetty tinalla tai antimonilla. Jos lisäys tapahtuu langan muodossa, voi jauhemaisen ymppäysaineen vaippa olla Sn:aa tai Sb:a. Lanka voi myös olla sovitettuna jauhemaisen ymppäysai-. neen sisään, jolloin vaippa voi olla metallista tai epämetallista ainetta. Sb:n lisäys on erityisen edullista, koska Sb:n 3 85507The addition of perlite stabilizers, such as Sn and / or Sb, can take place e.g. in powder, wire or 1. in the form of a powder surrounded by a metallic or non-metallic sheath in the form of. Sn or Sb may be added in combination with an inoculant (FeSi and the like), e.g. in the form of a powder mixture (by blowing in), as an alloy, e.g. in the form of a wire, the wood blood mixture being surrounded by a metallic or non-metallic sheath. The powdered inoculum may be surrounded by a metallic sheath which is internally or externally terminated with tin or antimony. If the addition takes place in the form of a wire, the shell of the powdered inoculant may be Sn or Sb. The wire may also be fitted with a powdered seed. in which case the sheath may be of metallic or non-metallic material. The addition of Sb is particularly advantageous because Sb 3 85507
OO
kiehumispiste on 1440 C, siis alempana kuin sulan lämpö ennen käsittelyä. Näin ollen voidaan käyttää kiertoraaka-ainetta periiittisistä ferriittisiin vaiurautalaatuihi n, sillä siinä mahdollisesti oleva Sb höyrystyy sulatuksen yhteydessä.the boiling point is 1440 C, i.e. lower than the heat of the melt before treatment. Thus, a circulating raw material from peritite to ferritic cast iron grades can be used, since any Sb therein evaporates during smelting.
Kuvatun menetelmän eräs erityinen etu on mahdollisuus valmistaa ferriittisiä ja perii i tti siä vaiurautalaatuja samassa sulatus- ja vaiusenkkalaitteessa ilman tuotannon keskeytystä näiden laitteiden täydellistä tyhjentämistä varten. Sen ohella välttyy tunnettuun menetelmään sisältyvä vaara, että syöttö j ärjestel mään jäävät perliitin stabilointiaineiden jäännökset haittaavat seuraavaa ferriittisen valuraudan tuotantoa. Sn:n tai Sb:n lisäys ymppäysaineen kanssa kuvatussa lankamuo-dossa on sangen edullista, koska siten saavutetaan Sn:n tai Sb:n tarkka annostelu.One particular advantage of the described method is the possibility to produce ferritic and traditional cast iron grades in the same smelting and siling machine without interrupting production for the complete emptying of these equipment. In addition, the risk inherent in the known process that residues of perlite stabilizers remaining in the feed system will interfere with the subsequent production of ferritic cast iron is avoided. The addition of Sn or Sb in the form of yarn described with the inoculant is quite advantageous, since thus accurate dosing of Sn or Sb is achieved.
Claims (10)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH113186 | 1986-03-20 | ||
CH1131/86A CH665851A5 (en) | 1986-03-20 | 1986-03-20 | METHOD FOR PRODUCING PERLITIC CAST IRON TYPES. |
Publications (4)
Publication Number | Publication Date |
---|---|
FI871214A0 FI871214A0 (en) | 1987-03-19 |
FI871214A FI871214A (en) | 1987-09-21 |
FI85507B FI85507B (en) | 1992-01-15 |
FI85507C true FI85507C (en) | 1992-04-27 |
Family
ID=4203222
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI871214A FI85507C (en) | 1986-03-20 | 1987-03-19 | Process for making Perlitic cast iron varieties |
Country Status (20)
Country | Link |
---|---|
JP (1) | JPS62230926A (en) |
KR (1) | KR910001353B1 (en) |
CN (1) | CN1005994B (en) |
AT (1) | AT398984B (en) |
AU (1) | AU594439B2 (en) |
CH (1) | CH665851A5 (en) |
DD (1) | DD259001A5 (en) |
DE (1) | DE3706901A1 (en) |
ES (1) | ES2002591A6 (en) |
FI (1) | FI85507C (en) |
FR (1) | FR2601039B1 (en) |
GB (1) | GB2187985B (en) |
IN (1) | IN168111B (en) |
IT (1) | IT1204930B (en) |
NO (1) | NO871116L (en) |
NZ (1) | NZ219725A (en) |
PL (1) | PL264592A1 (en) |
SE (1) | SE462976B (en) |
YU (1) | YU41487A (en) |
ZA (1) | ZA871685B (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6973954B2 (en) * | 2001-12-20 | 2005-12-13 | International Engine Intellectual Property Company, Llc | Method for manufacture of gray cast iron for crankcases and cylinder heads |
NO20045611D0 (en) * | 2004-12-23 | 2004-12-23 | Elkem Materials | Modifying agents for cast iron |
CN102296226A (en) * | 2011-07-28 | 2011-12-28 | 徐州胜海机械制造科技有限公司 | Post inoculant for large-scale ductile iron casting and manufacture method thereof |
CN102936679A (en) * | 2012-11-22 | 2013-02-20 | 宁夏共享集团有限责任公司 | Gray cast iron electric-furnace smelting method |
CN106676250A (en) * | 2016-12-15 | 2017-05-17 | 广西大学 | Thermal treatment method for chilled cast iron roll |
CN112962018B (en) * | 2021-01-29 | 2022-04-01 | 宁波日星铸业有限公司 | Chilling process manufacturing method of non-label QT600-7 nodular cast iron |
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GB728402A (en) * | 1951-11-16 | 1955-04-20 | Boehler & Co Ag Geb | An improved method of grain-refining during the casting of high-melting-point metals especially iron and steel in chill moulds |
GB829375A (en) * | 1956-07-06 | 1960-03-02 | Koppers Co Inc | Improvements in or relating to coke oven door closure apparatus |
US2955933A (en) * | 1958-11-17 | 1960-10-11 | Union Carbide Corp | Inoculants for cast iron |
NL299266A (en) * | 1963-10-15 | |||
DE1483619B2 (en) * | 1965-01-11 | 1974-10-31 | Paderwerk Gebr. Benteler, 4794 Schloss Neuhaus | Continuous casting of killed steel |
NL6511874A (en) * | 1965-09-10 | 1967-03-13 | ||
DE1458899A1 (en) * | 1965-11-17 | 1969-02-13 | Metallgesellschaft Ag | Method of inoculating cast iron |
LU50927A1 (en) * | 1966-04-19 | 1967-10-19 | ||
GB1127486A (en) * | 1966-03-01 | 1968-09-18 | Edgar Allen & Co Ltd | Apparatus for the introduction of particulate material into molten metals |
AU441280B2 (en) * | 1969-12-11 | 1973-10-09 | Meehanite Metal Corporation | Improved method of making nodular iron |
DE2132417A1 (en) * | 1971-06-30 | 1973-01-11 | Schwaebische Huettenwerke Gmbh | High tensile pearlitic cast iron prodn - contg aluminium as replacement for silicon |
CH584075A5 (en) * | 1973-04-11 | 1977-01-31 | Fischer Ag Georg | |
DE2318078A1 (en) * | 1973-04-11 | 1974-10-31 | Buderus Eisenwerk | Pearlitic flake graphite cast iron - having superior hardness and tensile strength, by addition of antimony |
GB1446947A (en) * | 1973-09-08 | 1976-08-18 | Pont A Mousson | Method for obtaining spheroidal graphite castings and a device for carrying out said method |
US3911993A (en) * | 1974-07-12 | 1975-10-14 | Caterpillar Tractor Co | Method and apparatus for adding treating agents to molten metal |
US3991810A (en) * | 1974-07-15 | 1976-11-16 | Caterpillar Tractor Co. | Method and apparatus for introducing additives into a casting mold |
US3991808A (en) * | 1974-07-15 | 1976-11-16 | Caterpillar Tractor Co. | Method and apparatus for the introduction of additives into a casting mold |
US4028099A (en) * | 1975-04-17 | 1977-06-07 | Ford Motor Company | Continuous stream - inclined trough treatment of ductile iron |
US4191563A (en) * | 1976-03-08 | 1980-03-04 | Ford Motor Company | Continuous stream treatment of ductile iron |
US4107393A (en) * | 1977-03-14 | 1978-08-15 | Caterpillar Tractor Co. | Inoculation article |
GB1527054A (en) * | 1977-05-11 | 1978-10-04 | British Cast Iron Res Ass | Producing nodular graphite iron |
JPS5524980A (en) * | 1978-08-14 | 1980-02-22 | Mitsubishi Heavy Ind Ltd | Cast iron and spheroidal graphite cast iron surface hardening |
JPS5575855A (en) * | 1978-11-30 | 1980-06-07 | Hitachi Metals Ltd | Adding method of inoculant |
ATE14455T1 (en) * | 1980-01-15 | 1985-08-15 | Materials & Methods Ltd | PROCESS FOR THE MANUFACTURE OF CAST IRON WITH VERMICULAR GRAPHITE AND CAST IRON MANUFACTURED BY THE PROCESS. |
GB2069898A (en) * | 1980-02-26 | 1981-09-03 | Metal Research Corp | Inoculation to a molten cast iron during pouring |
GB2073072B (en) * | 1980-04-08 | 1984-04-18 | British Steel Corp | Introducing reactants into a steel melt |
GB2078784A (en) * | 1980-06-27 | 1982-01-13 | British Aluminium Co Ltd | Alloying Additive |
GB2096032A (en) * | 1981-04-07 | 1982-10-13 | Mitsubishi Steel Mfg | Continuously casting lead-containing steel |
US4363661A (en) * | 1981-04-08 | 1982-12-14 | Ford Motor Company | Method for increasing mechanical properties in ductile iron by alloy additions |
FR2511044A1 (en) * | 1981-08-04 | 1983-02-11 | Nobel Bozel | FERRO-ALLOY FOR THE TREATMENT OF INOCULATION OF SPHEROIDAL GRAPHITE FONT |
JPS5861209A (en) * | 1981-10-08 | 1983-04-12 | Kubota Ltd | Production of spheroidal graphite cast iron |
JPS59208030A (en) * | 1983-05-12 | 1984-11-26 | Hirotoshi Taniguchi | Method and device for continuous treatment of molten metal |
-
1986
- 1986-03-20 CH CH1131/86A patent/CH665851A5/en not_active IP Right Cessation
-
1987
- 1987-03-02 GB GB8704816A patent/GB2187985B/en not_active Expired - Fee Related
- 1987-03-04 DE DE19873706901 patent/DE3706901A1/en active Granted
- 1987-03-05 AT AT0049787A patent/AT398984B/en not_active IP Right Cessation
- 1987-03-09 IN IN187/CAL/87A patent/IN168111B/en unknown
- 1987-03-09 ZA ZA871685A patent/ZA871685B/en unknown
- 1987-03-12 PL PL1987264592A patent/PL264592A1/en unknown
- 1987-03-13 YU YU00414/87A patent/YU41487A/en unknown
- 1987-03-13 KR KR1019870002274A patent/KR910001353B1/en not_active IP Right Cessation
- 1987-03-13 JP JP62058705A patent/JPS62230926A/en active Pending
- 1987-03-13 IT IT19681/87A patent/IT1204930B/en active
- 1987-03-18 DD DD87300906A patent/DD259001A5/en not_active IP Right Cessation
- 1987-03-18 NO NO871116A patent/NO871116L/en unknown
- 1987-03-18 ES ES8700760A patent/ES2002591A6/en not_active Expired
- 1987-03-19 FR FR8703842A patent/FR2601039B1/en not_active Expired - Fee Related
- 1987-03-19 FI FI871214A patent/FI85507C/en not_active IP Right Cessation
- 1987-03-19 SE SE8701146A patent/SE462976B/en not_active IP Right Cessation
- 1987-03-20 CN CN87102216.8A patent/CN1005994B/en not_active Expired
- 1987-03-20 NZ NZ219725A patent/NZ219725A/en unknown
- 1987-03-20 AU AU70424/87A patent/AU594439B2/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
JPS62230926A (en) | 1987-10-09 |
DD259001A5 (en) | 1988-08-10 |
GB8704816D0 (en) | 1987-04-08 |
AT398984B (en) | 1995-02-27 |
GB2187985A (en) | 1987-09-23 |
KR870009036A (en) | 1987-10-22 |
PL264592A1 (en) | 1988-02-04 |
FR2601039B1 (en) | 1992-12-31 |
FI871214A0 (en) | 1987-03-19 |
NO871116D0 (en) | 1987-03-18 |
CN87102216A (en) | 1987-09-30 |
AU7042487A (en) | 1987-09-24 |
KR910001353B1 (en) | 1991-03-04 |
SE8701146D0 (en) | 1987-03-19 |
FI871214A (en) | 1987-09-21 |
IT8719681A0 (en) | 1987-03-13 |
FR2601039A1 (en) | 1988-01-08 |
FI85507B (en) | 1992-01-15 |
AU594439B2 (en) | 1990-03-08 |
ES2002591A6 (en) | 1988-08-16 |
DE3706901C2 (en) | 1989-02-16 |
YU41487A (en) | 1990-02-28 |
ZA871685B (en) | 1987-08-31 |
SE8701146L (en) | 1987-09-21 |
ATA49787A (en) | 1994-07-15 |
GB2187985B (en) | 1990-12-12 |
CN1005994B (en) | 1989-12-06 |
DE3706901A1 (en) | 1987-10-01 |
NZ219725A (en) | 1990-03-27 |
IT1204930B (en) | 1989-03-10 |
NO871116L (en) | 1987-09-21 |
SE462976B (en) | 1990-09-24 |
CH665851A5 (en) | 1988-06-15 |
IN168111B (en) | 1991-02-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM | Patent lapsed |
Owner name: GEORG FISCHER AKTIENGESELLSCHAFT |