FI76326B - Herbicidiskt verkande kinoxalinyloxifenoxipropionutderivat. - Google Patents

Herbicidiskt verkande kinoxalinyloxifenoxipropionutderivat. Download PDF

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Publication number
FI76326B
FI76326B FI813773A FI813773A FI76326B FI 76326 B FI76326 B FI 76326B FI 813773 A FI813773 A FI 813773A FI 813773 A FI813773 A FI 813773A FI 76326 B FI76326 B FI 76326B
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FI
Finland
Prior art keywords
oxy
formula
compound
compounds
derivatives
Prior art date
Application number
FI813773A
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English (en)
Finnish (fi)
Other versions
FI813773L (fi
FI76326C (sv
Inventor
Georg Frater
Milos Suchy
Jean Wenger
Paul Winternitz
Original Assignee
Hoffmann La Roche
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoffmann La Roche filed Critical Hoffmann La Roche
Publication of FI813773L publication Critical patent/FI813773L/fi
Application granted granted Critical
Publication of FI76326B publication Critical patent/FI76326B/fi
Publication of FI76326C publication Critical patent/FI76326C/sv

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/63—One oxygen atom
    • C07D213/64—One oxygen atom attached in position 2 or 6
    • C07D213/643—2-Phenoxypyridines; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
    • C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D215/20—Oxygen atoms
    • C07D215/22—Oxygen atoms attached in position 2 or 4
    • C07D215/227—Oxygen atoms attached in position 2 or 4 only one oxygen atom which is attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/36—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems
    • C07D241/38—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems with only hydrogen or carbon atoms directly attached to the ring nitrogen atoms
    • C07D241/40—Benzopyrazines
    • C07D241/44—Benzopyrazines with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring

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  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (11)

1. Kinoxalinyloxifenoxipropionatderivat med den all-männa formeln I /-v N \ 0 ^OOtCH^ON^ Σ . - \ '' R '
10 CH3 3 6 7 väri R är halogen, m är 1 eller 2, och R och r' betecknar lägre alkyl och n är 1 eller 2.
2. Derivat enligt patentkravet 1, känneteck- 6 7 15. a d e därav, att R och R betecknar alkyl med 1 eller 2 kolatomer, i synnerhet metyl.
3. D-isomererna av derivaten enligt patentkravet 1 eller 2.
4 . /Tlsopropylidenamino) oxi/metyl-2-/p~-/T6-f luor-2-20 kinolyl)ox£7fenoxi/propionat.
5 CH3 3 6 7 väri R är halogen, m är 1 eller 2, och R och R beteck- nar lägre alkyl och n är 1 eller 2, känneteck- n a t därav, att en förening med formeln 10 fi , R6 Z ^,COO(CH„) ON=C · ... II V 2 n ··. 7 I R 15 väri Z är en avgäende grupp säsom klor, brom, jod, mesyl- 6 7 oxi eller tosyloxi och R , R och n har ovan angiven be-tydelse, omsätts med en förening med den allmänna formeln III N 20 <r3»mK- il /r\ N/.i-o-i/jj— 0H 111 3 väri R och m har ovan angiven betydelse, eller med ett 25 alkalimetallsalt därav, vid behov i närvaro av en bas.
5. ZUlsopropylidenamino) oxi.7metyl-2-/p-/T6-klor-2-kinoxalinyl)oxi/fenoxi/propionat.
6. D-isomererna av föreningarna enligt patentkravet 4 och 5.
7. Användning av kinoxalinyloxifenoxipropionatderi- vat med formeln I säsom herbicider ( Ύ 3 ^ 30 °\ /-°\ /COO(CH ) 0N=C \__-y γ V I CH3 3 6 i vilken formeln R är halogen, m är 1 eller 2, och R och 7 R betecknar en lägre alkyl och n är 1 eller 2. 35
8. Förfarande för framställning av kinoxalinyloxi- fenoxipropionatderivat med den allmänna formeln I 13 7 632 6 <R V:00(CH2)n0N=C:C. ? 1
9. Förfarande enligt patentkravet 8, känne-t e c k n a t därav, att säsom utgängsmaterialet med formeln II används D-isomeren eller att ur det erhällna racematet isoleras D-isomeren. 30
10. Förfarande enligt patentkravet 8 eller 9, kännetecknat därav, att säsom utgängsmate-rialet används en förening med formeln II, väri R^ och 7 R betecknar alkyl med 1 eller 2 kolatomer, i synnerhet metyl.
FI813773A 1980-11-26 1981-11-25 Herbicidiskt verkande kinoxalinyloxifenoxipropionutderivat FI76326C (sv)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CH875080 1980-11-26
CH875080 1980-11-26
CH632881 1981-10-01
CH632881 1981-10-01

Publications (3)

Publication Number Publication Date
FI813773L FI813773L (fi) 1982-05-27
FI76326B true FI76326B (fi) 1988-06-30
FI76326C FI76326C (sv) 1988-10-10

Family

ID=25699381

Family Applications (1)

Application Number Title Priority Date Filing Date
FI813773A FI76326C (sv) 1980-11-26 1981-11-25 Herbicidiskt verkande kinoxalinyloxifenoxipropionutderivat

Country Status (19)

Country Link
US (2) US4435207A (sv)
EP (1) EP0052798B1 (sv)
AR (1) AR229683A1 (sv)
AU (1) AU554852B2 (sv)
BG (1) BG60413B2 (sv)
BR (1) BR8107679A (sv)
CA (1) CA1248107A (sv)
DD (1) DD202091A5 (sv)
DE (1) DE3170423D1 (sv)
DK (1) DK156772C (sv)
ES (1) ES508009A0 (sv)
FI (1) FI76326C (sv)
GB (1) GB2087890B (sv)
HU (1) HU191820B (sv)
IE (1) IE51879B1 (sv)
IL (1) IL64318A (sv)
NL (1) NL971004I2 (sv)
NO (1) NO159589C (sv)
PL (1) PL133253B1 (sv)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0113831A3 (de) * 1982-12-17 1984-11-07 F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft Carbaminsäureester, Verfahren zu deren Herstellung und deren Verwendung
US4687849A (en) * 1985-10-04 1987-08-18 Hoffmann-La Roche Inc. [(Isopropylideneamino)oxy]-ethyl-2-[[6-chloroquinoxalinyl)oxy]phenoxy]propionate postemergent herbicide
WO1991004969A1 (de) * 1989-10-05 1991-04-18 Hoechst Aktiengesellschaft Herbizide hetrocyclisch substituierte phenoxyalkancarbonsäurederivate und verfahren zu ihrer herstellung
HU208311B (en) * 1989-11-02 1993-09-28 Alkaloida Vegyeszeti Gyar Resolving process for producing enantiomers of 2-/4-(5-trifluoromethyl-2-pyridyloxy)-phenoxy/-propanoic acid
US20040014695A1 (en) * 1992-06-19 2004-01-22 Supergen, Inc. Pharmaceutical formulation
US5434306A (en) * 1993-11-25 1995-07-18 Ciba-Geigy Corporation Process for the preparation of O-substituted oximes
EP2052607A1 (de) 2007-10-24 2009-04-29 Bayer CropScience AG Herbizid-Kombination
DE102008037622A1 (de) * 2008-08-14 2010-02-25 Bayer Cropscience Ag Herbizid-Kombination mit Dimethoxytriazinyl-substituierten Difluormethansulfonylaniliden
AR096214A1 (es) 2013-05-08 2015-12-16 Quena Plant Prot N V Mezcla herbicida de imazetapir y propaquizafop

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH372190A (fr) 1956-06-27 1963-09-30 Boots Pure Drug Co Ltd Procédé pour combattre sélectivement les mauvaises herbes et composition herbicide pour la mise en oeuvre de ce procédé
US3771995A (en) * 1968-07-22 1973-11-13 Stauffer Chemical Co Method of combating weeds with certain oxime esters
US3718653A (en) 1970-02-26 1973-02-27 Int Minerals & Chem Corp Quinoyl alkanesulfonates and toluenesulfonates
US3923810A (en) 1971-05-11 1975-12-02 Minnesota Mining & Mfg Perfluoroalkanesulfonamides N-substituted by heterocyclic groups
DE2262402A1 (de) * 1972-12-15 1974-08-01 Schering Ag Herbizide phenoxycarbonsaeureoximester
DE2623558C2 (de) 1976-05-26 1984-12-06 Hoechst Ag, 6230 Frankfurt 2-[4'-Phenoxy-phenoxy]propionsäure-Derivate, Verfahren zu ihrer Herstellung und sie enthaltende herbizide Mittel
EP0001473B1 (en) * 1977-08-12 1988-07-27 Imperial Chemical Industries Plc Herbicidal halogenomethyl--pyridyloxy-phenoxy-alkanecarboxylic acids and derivatives, and processes of controlling unwanted plants therewith
DE2961917D1 (en) * 1978-01-18 1982-03-11 Ciba Geigy Ag Herbicidal active unsaturated esters of 4- (3',5'-dihalogenpyridyl-(2')-oxy)-alpha-phenoxy propionic acids, process for their preparation, herbicidal compositions containing them and their use
DE2830141A1 (de) 1978-07-08 1980-01-17 Hoechst Ag Neue verbindungen aus der gruppe der phenoxypropionsaeuren bzw. ihrer derivate und diese verbindungen enthaltende herbizide mittel
US4309210A (en) 1978-12-01 1982-01-05 Ciba-Geigy Corporation Preemergence method of selectively controlling weeds in crops of cereals and composition therefor
JPS6033389B2 (ja) * 1979-02-22 1985-08-02 日産化学工業株式会社 複素環エ−テル系フェノシキ脂肪酸誘導体、その製造法および該誘導体を含有する除草剤
NZ194196A (en) * 1979-07-17 1983-07-15 Ici Australia Ltd -(quinoxalin-2-yl(oxy or thio) phen (oxy or ylthio)-alkanoic acid derivatives or precursors
AU541697B2 (en) * 1979-11-19 1985-01-17 Ici Australia Limited Quinoline derivatives
JPS56113744A (en) 1980-02-13 1981-09-07 Nippon Nohyaku Co Ltd Benzoate derivative, its preparation, and use of said derivative
PH17279A (en) * 1980-10-15 1984-07-06 Ciba Geigy Novel alpha-(pyridyl-2-oxy-phenoxy)-propionic acid derivatives and their use as herbicides and/or regulators of plant growth
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US4440930A (en) * 1982-10-25 1984-04-03 Ppg Industries, Inc. Herbicidally active quinoline or quinoxaline acetophenone oxime derivatives

Also Published As

Publication number Publication date
AU7790781A (en) 1982-06-03
IL64318A0 (en) 1982-02-28
FI813773L (fi) 1982-05-27
NO814019L (no) 1982-05-27
EP0052798A1 (de) 1982-06-02
BG60413B2 (bg) 1995-02-28
IL64318A (en) 1986-01-31
DK156772B (da) 1989-10-02
US4435207A (en) 1984-03-06
DD202091A5 (de) 1983-08-31
EP0052798B1 (de) 1985-05-08
HU191820B (en) 1987-04-28
FI76326C (sv) 1988-10-10
US4545807A (en) 1985-10-08
AU554852B2 (en) 1986-09-04
ES8304085A1 (es) 1983-02-16
AR229683A1 (es) 1983-10-31
ES508009A0 (es) 1983-02-16
NL971004I1 (nl) 1997-06-02
CA1248107A (en) 1989-01-03
BR8107679A (pt) 1982-08-24
NO159589B (no) 1988-10-10
NL971004I2 (nl) 1997-10-01
PL133253B1 (en) 1985-05-31
DK523581A (da) 1982-05-27
DE3170423D1 (en) 1985-06-13
GB2087890A (en) 1982-06-03
IE51879B1 (en) 1987-04-15
NO159589C (no) 1989-01-18
GB2087890B (en) 1984-10-10
IE812757L (en) 1982-05-26
PL233977A1 (en) 1983-03-14
DK156772C (da) 1990-03-19

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TC Name/ company changed in patent

Owner name: NOVARTIS AG

ND Supplementary protection certificate (spc) granted
SPCG Supplementary protection certificate granted

Spc suppl protection certif: K2

Extension date: 20031201

MA Patent expired

Owner name: SYNGENTA PARTICIPATIONS AG