FI68602B - Maongsidigt foerfarande foer att utveckla klordioxid - Google Patents

Maongsidigt foerfarande foer att utveckla klordioxid Download PDF

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Publication number
FI68602B
FI68602B FI793838A FI793838A FI68602B FI 68602 B FI68602 B FI 68602B FI 793838 A FI793838 A FI 793838A FI 793838 A FI793838 A FI 793838A FI 68602 B FI68602 B FI 68602B
Authority
FI
Finland
Prior art keywords
alkali metal
acid
reaction
chlorine dioxide
chlorine
Prior art date
Application number
FI793838A
Other languages
English (en)
Finnish (fi)
Other versions
FI793838A (fi
FI68602C (fi
Inventor
Harold Devere Partridge
Peter Lai
Original Assignee
Kema Nord Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kema Nord Ab filed Critical Kema Nord Ab
Publication of FI793838A publication Critical patent/FI793838A/fi
Publication of FI68602B publication Critical patent/FI68602B/fi
Application granted granted Critical
Publication of FI68602C publication Critical patent/FI68602C/fi

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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B11/00Oxides or oxyacids of halogens; Salts thereof
    • C01B11/02Oxides of chlorine
    • C01B11/022Chlorine dioxide (ClO2)
    • C01B11/023Preparation from chlorites or chlorates
    • C01B11/025Preparation from chlorites or chlorates from chlorates without any other reaction reducing agent than chloride ions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Removal Of Specific Substances (AREA)

Claims (6)

1. Förfarande för framställning av klordioxid, klor och alkalimetallsalt under växelvis användning av saltsyra och svavelsyra, eller blandningar därav, sora stark mineralsyra i samma reaktor, kännetecknat därav, att svavelsyra införes i en reaktor innehällande en vattenhaltig reak-tionslösning omfattande ett alkalimetallklorat, en alkalime-tallklorid och ett alkalimetallsulfat, varvid reaktionen ge-nomföres vid en syranormalitet inom intervallet cirka 2 tili 11 n i en reaktionslösning som kontinuerligt mättas med al-kalimetallkloriden och alkalimetallsulfatet, att svavelsyra-tillförseln tili reaktorn fortsättes för framställning av klordioxid, klor och ett alkalimetallsalt, att syratillför-seln växlas frän svavelsyra tili saltsyra och att saltsyra-tillförseln tili reaktorn fortsättes utan väsentlig ändring av reaktionsbetingelserna för framställning av klordioxid, klor och alkalimetallsalt.
2. Modifikation av förfarandet enligt krav 1, känne-t e c k n a d därav, att saltsyra först användes som reak-tant och att denna utbytes mot svavelsyra.
3. Förfarande enligt krav 1,kännetecknat därav, att tili lösningen, i vilken reaktionen äger rum, tillföres en katalytisk mängd av minst en katalysator vald bland vana-dinpentoxid, silverjon, manganjon, dikromatjon, palladiumjon och arsenikjon.
4. Förfarande enligt krav 1,kännetecknat därav, att reaktionen genomföres i ett enda kärl, som samtidigt utgör reaktionskärl, indunstare och kristallisationskärl.
5. Förfarande enligt krav 1, kännetecknat därav, att reaktionstemperaturen hälles mellan cirka 25-90°C och
FI793838A 1978-12-18 1979-12-10 Maongsidigt foerfarande foer att utveckla klordioxid FI68602C (fi)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/970,823 US4206193A (en) 1978-12-18 1978-12-18 Versatile process for generating chlorine dioxide
US97082378 1978-12-18

Publications (3)

Publication Number Publication Date
FI793838A FI793838A (fi) 1980-06-19
FI68602B true FI68602B (fi) 1985-06-28
FI68602C FI68602C (fi) 1985-10-10

Family

ID=25517559

Family Applications (1)

Application Number Title Priority Date Filing Date
FI793838A FI68602C (fi) 1978-12-18 1979-12-10 Maongsidigt foerfarande foer att utveckla klordioxid

Country Status (12)

Country Link
US (1) US4206193A (sv)
JP (1) JPS5585406A (sv)
AR (1) AR221630A1 (sv)
AU (1) AU528312B2 (sv)
BR (1) BR7908000A (sv)
ES (1) ES8101514A1 (sv)
FI (1) FI68602C (sv)
FR (1) FR2444643B1 (sv)
NO (1) NO153215C (sv)
NZ (1) NZ192122A (sv)
PT (1) PT70606A (sv)
SE (1) SE438145B (sv)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE452756B (sv) * 1985-03-04 1987-12-14 Eka Nobel Ab Forfarande for framstellning av klordioxid
CA2023452C (en) * 1990-03-05 1994-05-24 Birgitta Sundblad Process for production of chlorine dioxide
US5366714A (en) * 1992-06-09 1994-11-22 Sterling Canada Inc. Hydrogen peroxide-based chlorine dioxide process
US6790427B2 (en) * 2001-06-25 2004-09-14 Eka Chemicals, Inc. Process for producing chlorine dioxide
KR100860779B1 (ko) 2007-11-14 2008-09-30 목포대학교산학협력단 이산화염소 발생 장치 및 이를 이용한 이산화염소 발생방법
CA2734867C (en) * 2008-09-24 2012-01-24 Fpinnovations Process for producing chlorine dioxide using waste glycerol from a biodiesel plant

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2936219A (en) * 1957-02-18 1960-05-10 Hooker Chemical Corp Production of chlorine dioxide
US3446584A (en) * 1965-03-12 1969-05-27 Hooker Chemical Corp Method of production of chlorine dioxide and sodium sulfate
US3933987A (en) * 1966-10-24 1976-01-20 Hooker Chemicals & Plastics Corporation Simultaneous production of chlorine dioxide and a salt of a strong acid
US3754081A (en) * 1970-09-17 1973-08-21 Hooker Chemical Corp Process for the production of chlorine dioxide,chlorine and a mixtureof an alkali metal sulfate and bisulfate
US3733395A (en) * 1971-04-07 1973-05-15 Hooker Chemical Corp Process for producing chlorine dioxide,chlorine and a neutral sulfate salt in the sulfate or kraft process of preparing wood pulp
FR2293521A1 (fr) * 1974-12-06 1976-07-02 Erco Ind Ltd Procede pour l'obtention de bioxyde de chlore utilisable dans une installation de fabrication de pate a papier
US4045542A (en) * 1974-12-13 1977-08-30 Hooker Chemicals & Plastics Corporation Production of chlorine dioxide
US3975505A (en) * 1974-12-13 1976-08-17 Hooker Chemicals & Plastics Corporation Production of chlorine dioxide
FR2352746A2 (fr) * 1975-03-07 1977-12-23 Hooker Chemicals Plastics Corp Procede de production de bioxyde de chlore
US4049784A (en) * 1975-03-07 1977-09-20 Hooker Chemicals & Plastics Corporation Production of chlorine dioxide with product slurry metathesis
CA1090091A (en) * 1976-03-19 1980-11-25 Richard Swindells Production of chlorine dioxide from buffered reaction media
MX145159A (es) * 1976-05-24 1982-01-12 Hooker Chemicals Plastics Corp Metodo mejorado para la produccion de dioxido de cloro

Also Published As

Publication number Publication date
NZ192122A (en) 1982-03-16
FI793838A (fi) 1980-06-19
NO153215B (no) 1985-10-28
AU5385679A (en) 1980-06-26
FI68602C (fi) 1985-10-10
ES487039A0 (es) 1980-12-16
ES8101514A1 (es) 1980-12-16
JPS5585406A (en) 1980-06-27
US4206193A (en) 1980-06-03
NO153215C (no) 1986-02-05
SE7910369L (sv) 1980-06-19
FR2444643B1 (fr) 1985-09-06
AU528312B2 (en) 1983-04-21
BR7908000A (pt) 1980-07-22
SE438145B (sv) 1985-04-01
PT70606A (en) 1980-01-01
NO794090L (no) 1980-06-19
FR2444643A1 (fr) 1980-07-18
AR221630A1 (es) 1981-02-27

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Legal Events

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MM Patent lapsed

Owner name: KEMANORD AB