FI63247C - Foerfarande foer framstaellning av dispersioner genom emulsionspolymerisation av vinylestrar - Google Patents
Foerfarande foer framstaellning av dispersioner genom emulsionspolymerisation av vinylestrar Download PDFInfo
- Publication number
- FI63247C FI63247C FI773416A FI773416A FI63247C FI 63247 C FI63247 C FI 63247C FI 773416 A FI773416 A FI 773416A FI 773416 A FI773416 A FI 773416A FI 63247 C FI63247 C FI 63247C
- Authority
- FI
- Finland
- Prior art keywords
- water
- good
- acetate
- mixture
- sodium
- Prior art date
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 25
- 239000000178 monomer Substances 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 10
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 claims description 9
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 9
- -1 alkaline earth metal acetate Chemical class 0.000 claims description 7
- 229940011182 cobalt acetate Drugs 0.000 claims description 7
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 claims description 7
- 229920001567 vinyl ester resin Polymers 0.000 claims description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 5
- 239000000084 colloidal system Substances 0.000 claims description 5
- 230000001681 protective effect Effects 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 3
- 239000012986 chain transfer agent Substances 0.000 claims description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 3
- 239000012736 aqueous medium Substances 0.000 claims description 2
- 239000007853 buffer solution Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- MGJURKDLIJVDEO-UHFFFAOYSA-N formaldehyde;hydrate Chemical compound O.O=C MGJURKDLIJVDEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000002609 medium Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims 2
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 claims 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 claims 1
- 150000001242 acetic acid derivatives Chemical class 0.000 claims 1
- UTOVMEACOLCUCK-PLNGDYQASA-N butyl maleate Chemical compound CCCCOC(=O)\C=C/C(O)=O UTOVMEACOLCUCK-PLNGDYQASA-N 0.000 claims 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- 235000015497 potassium bicarbonate Nutrition 0.000 claims 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical class [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 24
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 23
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 20
- 239000002245 particle Substances 0.000 description 20
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 16
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000013049 sediment Substances 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 description 7
- 238000010790 dilution Methods 0.000 description 7
- 239000012895 dilution Substances 0.000 description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- 238000006136 alcoholysis reaction Methods 0.000 description 5
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 5
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 229920000151 polyglycol Polymers 0.000 description 4
- 239000010695 polyglycol Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- YGWLMFNSGMKGIB-HJWRWDBZSA-N 1-o-ethyl 4-o-hexyl (z)-but-2-enedioate Chemical compound CCCCCCOC(=O)\C=C/C(=O)OCC YGWLMFNSGMKGIB-HJWRWDBZSA-N 0.000 description 1
- 108700028369 Alleles Proteins 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- JOJMQRPFXIKGJG-UHFFFAOYSA-N acetic acid;carbonic acid Chemical compound CC(O)=O.OC(O)=O JOJMQRPFXIKGJG-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001299 aldehydes Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000012674 dispersion polymerization Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-M ethenesulfonate Chemical compound [O-]S(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-M 0.000 description 1
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- ISXSFOPKZQZDAO-UHFFFAOYSA-N formaldehyde;sodium Chemical compound [Na].O=C ISXSFOPKZQZDAO-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 229940106051 methylcellulose (400 cps) Drugs 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920006316 polyvinylpyrrolidine Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- IJNJLGFTSIAHEA-UHFFFAOYSA-N prop-2-ynal Chemical compound O=CC#C IJNJLGFTSIAHEA-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/02—Esters of monocarboxylic acids
- C08F18/04—Vinyl esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT29601/76A IT1064497B (it) | 1976-11-22 | 1976-11-22 | Procedimento per la produzione di dispersioni di polimeri o copolimeri da esteri vinilici e/o esteri di acidi carbossilici |
| IT2960176 | 1976-11-22 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI773416A7 FI773416A7 (fi) | 1978-05-23 |
| FI63247B FI63247B (fi) | 1983-01-31 |
| FI63247C true FI63247C (fi) | 1983-05-10 |
Family
ID=11228080
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI773416A FI63247C (fi) | 1976-11-22 | 1977-11-11 | Foerfarande foer framstaellning av dispersioner genom emulsionspolymerisation av vinylestrar |
Country Status (19)
| Country | Link |
|---|---|
| AT (1) | AT363683B (cs) |
| BE (1) | BE861061A (cs) |
| CH (1) | CH629227A5 (cs) |
| DE (1) | DE2752102C2 (cs) |
| DK (1) | DK516177A (cs) |
| EG (1) | EG12967A (cs) |
| ES (1) | ES464654A1 (cs) |
| FI (1) | FI63247C (cs) |
| FR (1) | FR2392042A1 (cs) |
| GB (1) | GB1567704A (cs) |
| GR (1) | GR64097B (cs) |
| IE (1) | IE45992B1 (cs) |
| IT (1) | IT1064497B (cs) |
| LU (1) | LU78551A1 (cs) |
| NL (1) | NL7712817A (cs) |
| NO (1) | NO150318C (cs) |
| PT (1) | PT67300B (cs) |
| SE (1) | SE432103B (cs) |
| TR (1) | TR19944A (cs) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007044788A1 (de) * | 2007-09-19 | 2009-04-02 | Wacker Chemie Ag | Herstellung von Vinylacetat-Vinylester-Mischpolymerisaten mit geringem Gehalt an hochsiedenden Vinylestern |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2998400A (en) * | 1958-05-15 | 1961-08-29 | Wyandotte Chemicals Corp | Floc-free polyvinyl acetate emulsions employing polyvinylmethyl ether copolymer as prtective colloid and process of preparation |
| FR1441940A (fr) * | 1964-07-18 | 1966-06-10 | Hoechst Ag | Procédé de préparation de dispersions aqueuses de polymères de composés oléfiniques |
-
1976
- 1976-11-22 IT IT29601/76A patent/IT1064497B/it active
-
1977
- 1977-11-02 GR GR54696A patent/GR64097B/el unknown
- 1977-11-11 FI FI773416A patent/FI63247C/fi not_active IP Right Cessation
- 1977-11-16 EG EG647/77A patent/EG12967A/xx active
- 1977-11-17 TR TR19944A patent/TR19944A/xx unknown
- 1977-11-18 CH CH1415077A patent/CH629227A5/it not_active IP Right Cessation
- 1977-11-18 NO NO773948A patent/NO150318C/no unknown
- 1977-11-21 NL NL7712817A patent/NL7712817A/xx not_active Application Discontinuation
- 1977-11-21 LU LU78551A patent/LU78551A1/xx unknown
- 1977-11-21 GB GB48444/77A patent/GB1567704A/en not_active Expired
- 1977-11-21 DK DK516177A patent/DK516177A/da not_active Application Discontinuation
- 1977-11-21 SE SE7713139A patent/SE432103B/sv unknown
- 1977-11-21 AT AT0832177A patent/AT363683B/de not_active IP Right Cessation
- 1977-11-21 FR FR7734945A patent/FR2392042A1/fr active Granted
- 1977-11-21 PT PT67300A patent/PT67300B/pt unknown
- 1977-11-22 BE BE182819A patent/BE861061A/xx not_active IP Right Cessation
- 1977-11-22 DE DE2752102A patent/DE2752102C2/de not_active Expired
- 1977-11-22 IE IE2367/77A patent/IE45992B1/en unknown
- 1977-11-22 ES ES464654A patent/ES464654A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SE432103B (sv) | 1984-03-19 |
| BE861061A (fr) | 1978-05-22 |
| DE2752102A1 (de) | 1978-05-24 |
| PT67300B (en) | 1979-04-20 |
| ES464654A1 (es) | 1978-09-01 |
| IE45992L (en) | 1978-05-22 |
| NO150318C (no) | 1984-09-26 |
| FI773416A7 (fi) | 1978-05-23 |
| FR2392042B1 (cs) | 1981-10-23 |
| IT1064497B (it) | 1985-02-18 |
| GB1567704A (en) | 1980-05-21 |
| PT67300A (en) | 1977-12-01 |
| NO150318B (no) | 1984-06-18 |
| FI63247B (fi) | 1983-01-31 |
| FR2392042A1 (fr) | 1978-12-22 |
| GR64097B (en) | 1980-01-22 |
| IE45992B1 (en) | 1983-01-26 |
| NL7712817A (nl) | 1978-05-24 |
| NO773948L (no) | 1978-05-23 |
| ATA832177A (de) | 1981-01-15 |
| DK516177A (da) | 1978-05-23 |
| LU78551A1 (cs) | 1978-04-13 |
| SE7713139L (sv) | 1978-05-23 |
| CH629227A5 (en) | 1982-04-15 |
| DE2752102C2 (de) | 1982-11-04 |
| EG12967A (en) | 1980-03-31 |
| TR19944A (tr) | 1980-05-08 |
| AT363683B (de) | 1981-08-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101910214B (zh) | 乙烯醇系聚合物及含有其的膜 | |
| JP3937449B2 (ja) | フルオロ単量体／官能化された炭化水素単量体共重合方法および共重合体生成物 | |
| WO1996006887A1 (en) | Aqueous dispersion of vinylidene fluoride copolymer, aqueous dispersion of vinylidene fluoride seed polymer, and processes for producing the dispersions | |
| JPH02289640A (ja) | 酢酸ビニル―エチレン共重合体エマルジョン及びその製造方法 | |
| TWI804482B (zh) | 塗布劑、塗布劑之製造方法及其用途 | |
| EP2876116A1 (en) | Dispersion stabilizer for suspension polymerization, and manufacturing method for vinyl resin | |
| CA1186834A (fr) | Latex de copolymeres acetate de vinyle-olefine et procede de preparation | |
| EP2679606A1 (en) | Dispersant for suspension polymerization, vinyl chloride resin and method for producing same | |
| JP2013177576A (ja) | ヒドロキシメチル基含有ビニルアルコール系重合体 | |
| EP0072735B1 (fr) | Latex de polymères d'acétate de vinyle et procédé de préparation | |
| EP0072734B1 (fr) | Procédé de préparation de latex de copolymères acétate de vinyle-oléfine | |
| FI63247C (fi) | Foerfarande foer framstaellning av dispersioner genom emulsionspolymerisation av vinylestrar | |
| CN1024802C (zh) | 呈单分散粒子胶乳态聚氯乙烯水乳液的制备方法 | |
| CH623832A5 (cs) | ||
| JP4404873B2 (ja) | カチオン性ポリビニルアセタールの製造方法及びその使用 | |
| WO2013150056A1 (fr) | Procede de synthese de polymeres a partir d'acide acrylique, d'un de ses sels ou de leur melange | |
| JP2657600B2 (ja) | 初期接着性に優れたエマルジョン接着剤及びその製造方法 | |
| EP0073702B1 (fr) | Procédé de préparation de latex de polymères d'acétate de vinyle | |
| TWI883007B (zh) | 聚乙烯醇、其製造方法及其用途 | |
| JP4615153B2 (ja) | ビニル系化合物の懸濁重合用分散安定剤 | |
| JP4405352B2 (ja) | 水性エマルジョンおよびその製造方法 | |
| JP2625812B2 (ja) | 合成樹脂エマルジョンの製造法 | |
| JP2005089540A (ja) | 酢酸ビニル樹脂系エマルジョンとその製造方法 | |
| JP2002097209A (ja) | ビニル系化合物の懸濁重合用分散安定剤 | |
| TW202506763A (zh) | 乙烯醇系聚合物、含有乙烯醇系聚合物之水溶液、塗料及水泥混合劑 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed |
Owner name: ANIC S.P.A. |