FI63242C - Herbicidiskt aktiv n-hydroxi-n-fosfonometylglycin och herbicidiskt godtagbara salter daerav - Google Patents
Herbicidiskt aktiv n-hydroxi-n-fosfonometylglycin och herbicidiskt godtagbara salter daerav Download PDFInfo
- Publication number
- FI63242C FI63242C FI780748A FI780748A FI63242C FI 63242 C FI63242 C FI 63242C FI 780748 A FI780748 A FI 780748A FI 780748 A FI780748 A FI 780748A FI 63242 C FI63242 C FI 63242C
- Authority
- FI
- Finland
- Prior art keywords
- hydroxy
- phosphonomethylglycine
- solution
- salt
- mixture
- Prior art date
Links
- OUAUXLZKLYVTSH-UHFFFAOYSA-N 2-[hydroxy(phosphonomethyl)amino]acetic acid Chemical compound OC(=O)CN(O)CP(O)(O)=O OUAUXLZKLYVTSH-UHFFFAOYSA-N 0.000 description 29
- 239000000203 mixture Substances 0.000 description 25
- 239000000243 solution Substances 0.000 description 23
- 150000003839 salts Chemical class 0.000 description 19
- 230000002363 herbicidal effect Effects 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 241000196324 Embryophyta Species 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000004480 active ingredient Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 7
- 239000004009 herbicide Substances 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- MGRVRXRGTBOSHW-UHFFFAOYSA-N (aminomethyl)phosphonic acid Chemical compound NCP(O)(O)=O MGRVRXRGTBOSHW-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- NPWGWQRXHVJJRD-UHFFFAOYSA-N N-hydroxyglycine Chemical compound ONCC(O)=O NPWGWQRXHVJJRD-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000007900 aqueous suspension Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- JKANAVGODYYCQF-UHFFFAOYSA-N prop-2-yn-1-amine Chemical class NCC#C JKANAVGODYYCQF-UHFFFAOYSA-N 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 241000287828 Gallus gallus Species 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 244000062793 Sorghum vulgare Species 0.000 description 3
- -1 alkali metal salts Chemical class 0.000 description 3
- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical class [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 description 3
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 3
- 235000019713 millet Nutrition 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- ZHWLPDIRXJCEJY-UHFFFAOYSA-N N-Hydroxyglycine Natural products NC(O)C(O)=O ZHWLPDIRXJCEJY-UHFFFAOYSA-N 0.000 description 2
- VCCDDUPPMMPOAY-UHFFFAOYSA-N OC(CN(CCP(O)(O)=O)O)=O Chemical compound OC(CN(CCP(O)(O)=O)O)=O VCCDDUPPMMPOAY-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 240000001579 Cirsium arvense Species 0.000 description 1
- 235000005918 Cirsium arvense Nutrition 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 240000008620 Fagopyrum esculentum Species 0.000 description 1
- 235000009419 Fagopyrum esculentum Nutrition 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 244000202761 Sorghum bicolor subsp verticilliflorum Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 239000005862 Whey Substances 0.000 description 1
- 102000007544 Whey Proteins Human genes 0.000 description 1
- 108010046377 Whey Proteins Proteins 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 125000005741 alkyl alkenyl group Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 210000000941 bile Anatomy 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical class CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Biochemistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77606177 | 1977-03-09 | ||
| US05/776,061 US4084953A (en) | 1977-03-09 | 1977-03-09 | N-hydroxy-N-phosphonomethylglycines and the herbicidal use thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI780748A FI780748A (fi) | 1978-09-10 |
| FI63242B FI63242B (fi) | 1983-01-31 |
| FI63242C true FI63242C (fi) | 1983-05-10 |
Family
ID=25106347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI780748A FI63242C (fi) | 1977-03-09 | 1978-03-08 | Herbicidiskt aktiv n-hydroxi-n-fosfonometylglycin och herbicidiskt godtagbara salter daerav |
Country Status (36)
| Country | Link |
|---|---|
| US (1) | US4084953A (pt) |
| JP (1) | JPS53124222A (pt) |
| AR (1) | AR218292A1 (pt) |
| AT (1) | AT358867B (pt) |
| AU (1) | AU515484B2 (pt) |
| BE (1) | BE864673A (pt) |
| BG (1) | BG35463A3 (pt) |
| BR (1) | BR7801406A (pt) |
| CA (1) | CA1099738A (pt) |
| CH (1) | CH636105A5 (pt) |
| CS (1) | CS194839B2 (pt) |
| DD (1) | DD136695A5 (pt) |
| DE (1) | DE2810080A1 (pt) |
| DK (1) | DK102778A (pt) |
| EG (1) | EG13181A (pt) |
| FI (1) | FI63242C (pt) |
| FR (1) | FR2383193A1 (pt) |
| GB (1) | GB1562074A (pt) |
| GR (1) | GR66123B (pt) |
| HU (1) | HU184657B (pt) |
| IE (1) | IE46477B1 (pt) |
| IL (1) | IL54233A (pt) |
| IT (1) | IT1094177B (pt) |
| MX (1) | MX5620E (pt) |
| MY (1) | MY8100164A (pt) |
| NL (1) | NL7802469A (pt) |
| NO (1) | NO146955C (pt) |
| NZ (1) | NZ186645A (pt) |
| PH (1) | PH12996A (pt) |
| PL (1) | PL106799B1 (pt) |
| PT (1) | PT67755A (pt) |
| SE (1) | SE430893B (pt) |
| SU (1) | SU710501A3 (pt) |
| TR (1) | TR19933A (pt) |
| YU (1) | YU54578A (pt) |
| ZA (1) | ZA781358B (pt) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4395374A (en) * | 1981-01-02 | 1983-07-26 | Monsanto Company | Alkyl N-arylsulfenyl-N-diaryloxy-phosphinylmethylglycinates |
| US5580841A (en) * | 1985-05-29 | 1996-12-03 | Zeneca Limited | Solid, phytoactive compositions and method for their preparation |
| US5468718A (en) * | 1985-10-21 | 1995-11-21 | Ici Americas Inc. | Liquid, phytoactive compositions and method for their preparation |
| US5047079A (en) * | 1986-08-18 | 1991-09-10 | Ici Americas Inc. | Method of preparation and use of solid, phytoactive compositions |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA775575A (en) * | 1961-11-13 | 1968-01-09 | R. Irani Riyad | Organic phosphorus compounds |
| US3853530A (en) * | 1971-03-10 | 1974-12-10 | Monsanto Co | Regulating plants with n-phosphonomethylglycine and derivatives thereof |
| US3888915A (en) * | 1973-09-04 | 1975-06-10 | Monsanto Co | N-nitroso-n-phosphonomethyl glycine compounds and herbicidal use thereof |
| US3933946A (en) * | 1974-11-19 | 1976-01-20 | Monsanto Company | N-hydroxy-N-phosphonomethylglycinates |
| GB1580899A (en) * | 1976-07-27 | 1980-12-10 | Fujisawa Pharmaceutical Co | Hydroxyaminohydrocarbonphosphonic acid derivatives and production and use thereof |
-
1977
- 1977-03-09 US US05/776,061 patent/US4084953A/en not_active Expired - Lifetime
-
1978
- 1978-03-07 NL NL7802469A patent/NL7802469A/xx not_active Application Discontinuation
- 1978-03-07 IT IT20958/78A patent/IT1094177B/it active
- 1978-03-07 EG EG152/78A patent/EG13181A/xx active
- 1978-03-07 SU SU782588847A patent/SU710501A3/ru active
- 1978-03-07 TR TR19933A patent/TR19933A/xx unknown
- 1978-03-08 AU AU33971/78A patent/AU515484B2/en not_active Expired
- 1978-03-08 MX MX786919U patent/MX5620E/es unknown
- 1978-03-08 FR FR7806705A patent/FR2383193A1/fr active Granted
- 1978-03-08 DD DD78204035A patent/DD136695A5/xx unknown
- 1978-03-08 BG BG7838948A patent/BG35463A3/xx unknown
- 1978-03-08 PT PT67755A patent/PT67755A/pt unknown
- 1978-03-08 CS CS781467A patent/CS194839B2/cs unknown
- 1978-03-08 FI FI780748A patent/FI63242C/fi not_active IP Right Cessation
- 1978-03-08 NO NO780794A patent/NO146955C/no unknown
- 1978-03-08 CH CH251178A patent/CH636105A5/de not_active IP Right Cessation
- 1978-03-08 ZA ZA00781358A patent/ZA781358B/xx unknown
- 1978-03-08 AR AR271356A patent/AR218292A1/es active
- 1978-03-08 SE SE7802644A patent/SE430893B/sv unknown
- 1978-03-08 PL PL1978205163A patent/PL106799B1/pl unknown
- 1978-03-08 DK DK102778A patent/DK102778A/da not_active Application Discontinuation
- 1978-03-08 AT AT167078A patent/AT358867B/de not_active IP Right Cessation
- 1978-03-08 DE DE19782810080 patent/DE2810080A1/de not_active Withdrawn
- 1978-03-08 IL IL54233A patent/IL54233A/xx unknown
- 1978-03-08 NZ NZ186645A patent/NZ186645A/xx unknown
- 1978-03-08 CA CA298,532A patent/CA1099738A/en not_active Expired
- 1978-03-08 YU YU00545/78A patent/YU54578A/xx unknown
- 1978-03-08 JP JP2552678A patent/JPS53124222A/ja active Granted
- 1978-03-08 IE IE474/78A patent/IE46477B1/en unknown
- 1978-03-08 HU HU78MO1007A patent/HU184657B/hu unknown
- 1978-03-08 GB GB9148/78A patent/GB1562074A/en not_active Expired
- 1978-03-08 BR BR7801406A patent/BR7801406A/pt unknown
- 1978-03-08 BE BE185752A patent/BE864673A/xx not_active IP Right Cessation
- 1978-03-08 PH PH20858A patent/PH12996A/en unknown
- 1978-03-08 GR GR55646A patent/GR66123B/el unknown
-
1981
- 1981-12-30 MY MY164/81A patent/MY8100164A/xx unknown
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed |
Owner name: MONSANTO COMPANY |