FI56553C - Foerfarande foer utfaellning av ickejaernmetaller fraon en vattenhaltig sur mineralloesning - Google Patents
Foerfarande foer utfaellning av ickejaernmetaller fraon en vattenhaltig sur mineralloesning Download PDFInfo
- Publication number
- FI56553C FI56553C FI2469/72A FI246972A FI56553C FI 56553 C FI56553 C FI 56553C FI 2469/72 A FI2469/72 A FI 2469/72A FI 246972 A FI246972 A FI 246972A FI 56553 C FI56553 C FI 56553C
- Authority
- FI
- Finland
- Prior art keywords
- iron
- extraction
- solution
- nickel
- process according
- Prior art date
Links
- 239000002184 metal Substances 0.000 title claims description 19
- 229910052751 metal Inorganic materials 0.000 title claims description 19
- 150000002739 metals Chemical class 0.000 title description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 181
- 229910052742 iron Inorganic materials 0.000 claims description 86
- 239000000243 solution Substances 0.000 claims description 65
- 238000000034 method Methods 0.000 claims description 40
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 31
- 239000000463 material Substances 0.000 claims description 30
- 239000002253 acid Substances 0.000 claims description 28
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 18
- -1 ferrous metals Chemical class 0.000 claims description 17
- 238000001556 precipitation Methods 0.000 claims description 17
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 13
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 10
- 230000002378 acidificating effect Effects 0.000 claims description 10
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 7
- 239000011707 mineral Substances 0.000 claims description 7
- 150000004679 hydroxides Chemical class 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 4
- 230000007062 hydrolysis Effects 0.000 claims description 4
- 238000006460 hydrolysis reaction Methods 0.000 claims description 4
- 230000001376 precipitating effect Effects 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 claims 1
- 150000002505 iron Chemical class 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 102
- 238000000605 extraction Methods 0.000 description 96
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 49
- 229910052759 nickel Inorganic materials 0.000 description 46
- 239000002002 slurry Substances 0.000 description 24
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 19
- 238000002474 experimental method Methods 0.000 description 19
- 239000010941 cobalt Substances 0.000 description 13
- 229910017052 cobalt Inorganic materials 0.000 description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 13
- 239000002245 particle Substances 0.000 description 11
- 235000013980 iron oxide Nutrition 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000000746 purification Methods 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000004090 dissolution Methods 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 6
- 239000011133 lead Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 5
- 150000004763 sulfides Chemical class 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000005188 flotation Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 229910001037 White iron Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- YACDNKRCYHORLX-UHFFFAOYSA-N copper;iron;sulfanylidenenickel Chemical compound [Fe].[Ni].[Cu]=S YACDNKRCYHORLX-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000012106 screening analysis Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
- C22B23/0423—Halogenated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
- C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Manufacture Of Iron (AREA)
- Compounds Of Iron (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4202171 | 1971-09-09 | ||
| GB4202171A GB1387269A (en) | 1971-09-09 | 1971-09-09 | Hydrometallurgical separation of iron and nickel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FI56553B FI56553B (fi) | 1979-10-31 |
| FI56553C true FI56553C (fi) | 1980-02-11 |
Family
ID=10422473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI2469/72A FI56553C (fi) | 1971-09-09 | 1972-09-07 | Foerfarande foer utfaellning av ickejaernmetaller fraon en vattenhaltig sur mineralloesning |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5230932B2 (ja) |
| AU (1) | AU468412B2 (ja) |
| BE (1) | BE788344A (ja) |
| CA (1) | CA968566A (ja) |
| DE (2) | DE2239413C3 (ja) |
| FI (1) | FI56553C (ja) |
| FR (1) | FR2152939B1 (ja) |
| GB (1) | GB1387269A (ja) |
| NO (1) | NO137452C (ja) |
| ZA (1) | ZA725456B (ja) |
| ZM (1) | ZM12972A1 (ja) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1050278A (en) * | 1975-06-10 | 1979-03-13 | Inco Limited | Leaching limonitic ores |
| JPS571008U (ja) * | 1980-05-30 | 1982-01-06 | ||
| DE4447658C2 (de) * | 1994-05-28 | 1996-12-19 | Karlsruhe Forschzent | Chirurgisches Nähinstrument |
| WO2011120127A1 (en) * | 2010-04-01 | 2011-10-06 | Search Minerals Inc. | Low acid leaching of nickel and cobalt from lean iron-containing nickel ores |
| US8361191B2 (en) | 2010-04-01 | 2013-01-29 | Search Minerals, Inc. | Low acid leaching of nickel and cobalt from lean iron-containing nickel ores |
| CN103194768B (zh) * | 2013-04-16 | 2016-01-13 | 中南大学 | 利用高铁高磷锰矿制备电解金属锰的方法 |
| CN113023701A (zh) * | 2021-02-26 | 2021-06-25 | 广东邦普循环科技有限公司 | 从红土镍矿浸出液中分离镍铁并制备磷酸铁的方法和应用 |
-
0
- BE BE788344D patent/BE788344A/xx unknown
-
1971
- 1971-09-09 GB GB4202171A patent/GB1387269A/en not_active Expired
-
1972
- 1972-08-02 CA CA148,553A patent/CA968566A/en not_active Expired
- 1972-08-08 ZM ZM129/72*UA patent/ZM12972A1/xx unknown
- 1972-08-08 ZA ZA725456A patent/ZA725456B/xx unknown
- 1972-08-10 DE DE2239413A patent/DE2239413C3/de not_active Expired
- 1972-08-10 DE DE2264541*A patent/DE2264541C3/de not_active Expired
- 1972-08-14 AU AU45549/72A patent/AU468412B2/en not_active Expired
- 1972-09-07 FI FI2469/72A patent/FI56553C/fi active
- 1972-09-08 FR FR7232507A patent/FR2152939B1/fr not_active Expired
- 1972-09-08 JP JP47089661A patent/JPS5230932B2/ja not_active Expired
-
1975
- 1975-03-03 NO NO750701A patent/NO137452C/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE2239413B2 (de) | 1975-03-27 |
| FR2152939A1 (ja) | 1973-04-27 |
| JPS4836005A (ja) | 1973-05-28 |
| FI56553B (fi) | 1979-10-31 |
| BE788344A (fr) | 1973-03-05 |
| AU4554972A (en) | 1974-02-21 |
| NO137452B (no) | 1977-11-21 |
| AU468412B2 (en) | 1976-01-15 |
| GB1387269A (en) | 1975-03-12 |
| JPS5230932B2 (ja) | 1977-08-11 |
| NO137452C (no) | 1978-03-01 |
| CA968566A (en) | 1975-06-03 |
| DE2239413A1 (de) | 1973-03-15 |
| DE2264541C3 (de) | 1975-11-06 |
| NO750701L (ja) | 1973-03-12 |
| DE2264541B2 (de) | 1975-03-20 |
| ZA725456B (en) | 1973-05-30 |
| ZM12972A1 (en) | 1974-05-21 |
| FR2152939B1 (ja) | 1976-08-13 |
| DE2239413C3 (de) | 1975-12-04 |
| DE2264541A1 (de) | 1974-02-14 |
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