FI123696B - Menetelmä polymeeripartikkelien kokojakauman hallitsemiseksi vesipitoista polymeeridispersiota valmistettaessa, vesipitoinen polymeeridispersio ja sen käyttö - Google Patents

Menetelmä polymeeripartikkelien kokojakauman hallitsemiseksi vesipitoista polymeeridispersiota valmistettaessa, vesipitoinen polymeeridispersio ja sen käyttö Download PDF

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FI123696B
FI123696B FI20125036A FI20125036A FI123696B FI 123696 B FI123696 B FI 123696B FI 20125036 A FI20125036 A FI 20125036A FI 20125036 A FI20125036 A FI 20125036A FI 123696 B FI123696 B FI 123696B
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weight
polymer dispersion
starch
aqueous polymer
viscosity
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FI20125036A (fi
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Kimmo Huhtala
Perttu Heiska
Nina Bruun
Helena Peuranen
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Kemira Oyj
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Priority to PCT/FI2013/050031 priority patent/WO2013104832A1/en
Priority to RU2014133043A priority patent/RU2627365C2/ru
Priority to BR112014016924-1A priority patent/BR112014016924B1/pt
Priority to KR1020147017594A priority patent/KR101970348B1/ko
Priority to PT137016754T priority patent/PT2802611T/pt
Priority to HUE13701675A priority patent/HUE033029T2/hu
Priority to EP13701675.4A priority patent/EP2802611B1/en
Priority to CN201380004802.3A priority patent/CN104053688B/zh
Priority to PL13701675T priority patent/PL2802611T3/pl
Priority to CA2861073A priority patent/CA2861073C/en
Priority to KR1020197010668A priority patent/KR102046572B1/ko
Priority to ES13701675.4T priority patent/ES2610569T3/es
Priority to US13/739,071 priority patent/US9079995B2/en
Publication of FI20125036A publication Critical patent/FI20125036A/fi
Application granted granted Critical
Publication of FI123696B publication Critical patent/FI123696B/fi
Priority to US14/510,200 priority patent/US9212247B2/en

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    • C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
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    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02—Starch; Degradation products thereof, e.g. dextrin
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    • C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/28—Starch
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/35—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
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    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters

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Claims (17)

1. Menetelmä muodostuvien polymeeripartikkelien kokojakauman kontrolloimiseksi vesipitoista polymeeridispersiota valmistettaessa, käsittäen 5. aikaansaadaan vesipitoinen tärkkiliuos, joka käsittää - (a) 10 - 40 painoprosenttia tärkkiä tai muuta, vapaan hydroksyyliryhmän sisältävää polysakkaridia, - polymeroidaan tärkkiliuoksessa vesiliukoisen oksastusaktiivisen redox-systeemin läsnä ollessa 10 - (b) 30 - 60 painoprosenttia ainakin yhtä mahdollisesti substituoitua styreeniä, - (c) 60 - 30 painoprosenttia ainakin yhtä C1 - C4 alkyyli (met)akrylaattia, - (d) 0 - 10 painoprosenttia muita kopolymerisoitavissa olevia eteenityydyttämättömiä monomeereja, 15 jolloin summa (a)+(b)+(c)+(d) on 100 %, tunnettu siitä, että kontrolloidaan muodostuneiden polymeeripartikkelien kokojakaumaa säätämällä tärkkiliuoksen viskositeettia ennen polymerointia tasolle < 20 mPas, mitattuna 23 Oissa käyttäen Brookfield LVDV viskometria karalla 18, 60 rpm. 20
2. Vaatimuksen 1 mukainen menetelmä, tunnettu siitä, että säädetään tärkkiliuoksen viskositeetti ennen polymerointia tasolle < 15 mPas, edullisemmin < 10 mPas, mitattuna 23 Oissa käyttäen Brookfield LV DV viskometria karalla 18, 60 CO -r- rpm. o ™ 25 CVJ
° 3. Vaatimuksen 1 tai 2 mukainen menetelmä, tunnettu siitä, että suoritetaan r». tärkkiliuoksen viskositeetin säätö säätämällä ennen polymerointia tärkkiliuoksen * pH < 2,5, edullisemmin < 2,3. CD CO O c\j 30
4. Vaatimuksen 1, 2 tai 3 mukainen menetelmä, tunnettu siitä, että suoritetaan O c\j tärkkiliuoksen viskositeetin säätö säätämällä ennen polymerointia tärkkiliuoksen kuiva-ainepitoisuus < 35 painoprosenttia, edullisesti < 30 painoprosenttia, edullisemmin < 25 painoprosenttia.
5. Jonkin edeltävän vaatimuksen 1 - 4 mukainen menetelmä, tunnettu siitä, että suoritetaan tärkkiliuoksen viskositeetin säätö valitsemalla tärkki, joka on anioninen tärkkijohdannainen, edullisesti anioninen perunatärkkijohdannainen, jonka viskositeetti on < 10 mPas, edullisesti < 8 mPas, kuiva-aineessa 15 %, mitattuna 5 80 Oissa käyttäen Brookfield LVDV viskometria kara Ma 18, 60 rpm.
6. Jonkin edeltävän vaatimuksen 1 - 5 mukainen menetelmä, tunnettu siitä, että vetyperoksidin ja rauta(ll)suolan yhdistelmää käytetään vesiliukoisena oksastusaktiivisena redox-systeeminä. 10
7. Vaatimuksen 6 mukainen menetelmä, tunnettu siitä, että rauta(ll)suolaa käytetään konsentraatiossa 3 - 200 mg Fe(ll) ionia/l, edullisesti 5 - 45 mg Fe(ll) ionia/l, edullisemmin 8 - 18 mg Fe(ll) ionia/l, koko dispersioon perustuen.
8. Vesipitoinen polymeeridispersio, joka on aikaansaatu eteenityydyttämättömien monomeerien vapaaradikaaliemulsiokopolymeroinnilla, jolloin läsnä on - (a) 10-40 painoprosenttia tärkkiä tai muuta, vapaan hydroksyyliryhmän käsittävää polysakkaridia, monomeerien käsittäessä 20 - (b) 30 - 60 painoprosenttia ainakin yhtä mahdollisesti substituoitua styreeniä, - (c) 60 - 30 painoprosenttia ainakin yhtä C1 - C4 alkyyli (met)akrylaattia (d) 0 - 10 painoprosenttia muita kopolymerisoitavissa olevia eteenityydyttämättömiä monomeereja, ja käytettäessä (e) vesiliukoista oksastusaktiivista redox-systeemiä vapaaradikaali-^ 25 initiaatorina vapaaradikaaliemulsiokopolymeroinnille, ° jolloin summa (a)+(b)+(c)+(d) on 100 %, ° tunnettu siitä, että tärkkiliuoksen viskositeetti ennen polymerointia on tasolla < 20 mPas, mitattuna 23 g ‘Cissa käyttäen Brookfield LVDV viskometria karalla 18, 60 rpm, ja että 30 polymeeridispersiossa polymeeripartikkeleiden D(99) arvo on < 160 nm. δ C\J
9. Vaatimuksen 8 mukainen vesipitoinen polymeeridispersio, tunnettu siitä, että dispersion kuiva-ainepitoisuus on > 30 painoprosenttia, tyypillisemmin > 35 painoprosenttia, koko dispersion painoon perustuen.
10. Vaatimuksen 8 tai 9 mukainen vesipitoinen polymeeridispersio, tunnettu siitä, että polymeeridispersiossa polymeeripartikkeleilla on D(50) arvo < 70 nm, edullisesti < 65 nm, edullisemmin < 60 nm, ja D(99) arvo < 160 nm, edullisesti < 150 nm, edullisemmin < 130 nm.
11. Vaatimuksen 10 mukainen vesipitoinen polymeeridispersio, tunnettu siitä, että D(50) arvo on välillä 45 - 70 nm, edullisesti 45 - 60 nm, edullisemmin 45 - 55 nm.
12. Vaatimuksen 10 tai 11 mukainen vesipitoinen polymeeridispersio, tunnettu siitä, että D(99) arvo on välillä 100 - 160 nm, edullisesti 110 - 140 nm, 15 edullisemmin 115 - 135 nm.
13. Jonkin edeltävän vaatimuksen 8 - 12 mukainen vesipitoinen polymeeridispersio, tunnettu siitä, että tärkki on anioninen tärkkijohdannainen, edullisesti anioninen perunatärkkijohdannainen, jonka viskositeetti on < 10 mPas, 20 edullisesti < 8 mPas, kuiva-aineessa 15 %, mitattuna 80 Oissa käyttäen Brookfield LVDV viskometria karalla 18, 60 rpm.
14. Jonkin edeltävän vaatimuksen 8 - 13 mukainen vesipitoinen t? polymeeridispersio, tunnettu siitä, että vesiliukoinen oksastusaktiivinen redox- ^ 25 systeemi on vetyperoksidin ja rauta(ll)suolan yhdistelmä, o i 1^
15. Vaatimuksen 14 mukainen vesipitoinen polymeeridispersio, tunnettu siitä, että * rauta(ll)suolan konsentraatio on 3 - 200 mg Fe(ll) ionia/l, edullisesti 5 - 45 mg co Fe(ll) ionia/l, edullisemmin 8 - 18 mg Fe(ll) ionia/l, koko dispersioon perustuen. LO cvj 30
° 16. Vaatimuksen 8 mukainen vesipitoinen polymeeridispersio, tunnettu siitä, että vapaan hydroksyyliryhmän käsittävä polysakkaridi on valittu ryhmästä, joka koostuu amyloosista, amylopektiinistä, karrageenista, selluloosasta, kitosaanista, kitiinistä, dekstriineistä, guarkumista ja muista galaktomannaaneista, arabikumista, hemiselluloosakomponenteista, ja pullulaanista, edullisesti amyloosista, amylopektiinistä ja galaktomannaaneista.
17. Jonkin vaatimuksen 8-16 mukaisen vesipitoisen polymeeridispersion käyttö paperin, kartongin tai vastaavan valmistuksessa käytettävän koostumuksen valmistamiseksi. CO δ c\j i CVJ o 1^ o X cc CL CD CO O m CVJ δ CVJ
FI20125036A 2012-01-12 2012-01-12 Menetelmä polymeeripartikkelien kokojakauman hallitsemiseksi vesipitoista polymeeridispersiota valmistettaessa, vesipitoinen polymeeridispersio ja sen käyttö FI123696B (fi)

Priority Applications (15)

Application Number Priority Date Filing Date Title
FI20125036A FI123696B (fi) 2012-01-12 2012-01-12 Menetelmä polymeeripartikkelien kokojakauman hallitsemiseksi vesipitoista polymeeridispersiota valmistettaessa, vesipitoinen polymeeridispersio ja sen käyttö
CA2861073A CA2861073C (en) 2012-01-12 2013-01-11 Method for controlling size distribution of polymer particles during preparation of aqueous polymer dispersion, aqueous polymer dispersion and its use
BR112014016924-1A BR112014016924B1 (pt) 2012-01-12 2013-01-11 método para controlar a distribuição de partículas de polímero durante a preparação de uma dispersão aquosa de polímero
KR1020147017594A KR101970348B1 (ko) 2012-01-12 2013-01-11 수성 중합체 분산액의 제조 동안 중합체 입자들의 크기 분포를 제어하기 위한 방법, 수성 중합체 분산액 및 이를 사용하는 방법
PT137016754T PT2802611T (pt) 2012-01-12 2013-01-11 Método para controlar a distribuição de tamanho de partículas de polímero durante a preparação de uma dispersão polimérica aquosa, dispersão polimérica aquosa e a sua utilização
HUE13701675A HUE033029T2 (hu) 2012-01-12 2013-01-11 Eljárás polimer részecskék méreteloszlásának szabályozására vizes polimer diszperzió készítése során; a vizes polimer diszperzió; és annak alkalmazása
PCT/FI2013/050031 WO2013104832A1 (en) 2012-01-12 2013-01-11 Method for controlling size distribution of polymer particles during preparation of aqueous polymer dispersion, aqueous polymer dispersion and its use
CN201380004802.3A CN104053688B (zh) 2012-01-12 2013-01-11 在制备水性聚合物分散体的过程中控制聚合物颗粒的粒径分布的方法、水性聚合物分散体及其用途
PL13701675T PL2802611T3 (pl) 2012-01-12 2013-01-11 Sposób regulacji składu granulometrycznego cząstek polimeru podczas przygotowywania wodnej dyspersji polimeru, wodna dyspersja polimeru i jej zastosowanie
RU2014133043A RU2627365C2 (ru) 2012-01-12 2013-01-11 Способ контроля распределения по размерам полимерных частиц в ходе получения водной полимерной дисперсии, водная полимерная дисперсия и ее применение
KR1020197010668A KR102046572B1 (ko) 2012-01-12 2013-01-11 수성 중합체 분산액의 제조 동안 중합체 입자들의 크기 분포를 제어하기 위한 방법, 수성 중합체 분산액 및 이를 사용하는 방법
ES13701675.4T ES2610569T3 (es) 2012-01-12 2013-01-11 Método para controlar la distribución del tamaño de partículas de un polímero durante la preparación de una dispersión acuosa del polímero, dispersión acuosa del polímero y su uso
US13/739,071 US9079995B2 (en) 2012-01-12 2013-01-11 Method for controlling size distribution of polymer particles during preparation of aqueous polymer dispersion and aqueous polymer dispersion
EP13701675.4A EP2802611B1 (en) 2012-01-12 2013-01-11 Method for controlling size distribution of polymer particles during preparation of aqueous polymer dispersion, aqueous polymer dispersion and its use
US14/510,200 US9212247B2 (en) 2012-01-12 2014-10-09 Method for controlling size distribution of polymer particles during preparation of aqueous polymer dispersion and aqueous polymer dispersion

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FI20125036A FI123696B (fi) 2012-01-12 2012-01-12 Menetelmä polymeeripartikkelien kokojakauman hallitsemiseksi vesipitoista polymeeridispersiota valmistettaessa, vesipitoinen polymeeridispersio ja sen käyttö
FI20125036 2012-01-12

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FI123696B true FI123696B (fi) 2013-09-30

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FI128576B (fi) 2015-12-21 2020-08-14 Kemira Oyj Menetelmä liima-ainekoostumuksen valmistamiseksi, liima-ainekoostumus ja sen käyttö
FI126948B (fi) * 2016-03-22 2017-08-31 Kemira Oyj Vesipitoinen polymeeridispersio, sen käyttö ja menetelmä vesipitoisen polymeeridispersion valmistamiseksi
FI20165235A (fi) * 2016-03-22 2017-09-23 Kemira Oyj Koostumus päällystyspastan reologian modifioimiseksi, sen käyttö ja päällystyspasta
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JP6760344B2 (ja) 2018-09-18 2020-09-23 栗田工業株式会社 製紙用表面サイズ剤
CN110093811B (zh) * 2019-06-17 2022-03-29 南昌市龙然实业有限公司 一种储存稳定、强附着性的表面施胶剂及其制备方法
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CA2861073A1 (en) 2013-07-18
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CA2861073C (en) 2018-10-16
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US9212247B2 (en) 2015-12-15
CN104053688B (zh) 2016-06-01
RU2014133043A (ru) 2016-02-27
US9079995B2 (en) 2015-07-14
RU2627365C2 (ru) 2017-08-07
FI20125036A (fi) 2013-07-13
WO2013104832A1 (en) 2013-07-18
BR112014016924A2 (pt) 2017-06-13
US20130184407A1 (en) 2013-07-18
CN104053688A (zh) 2014-09-17
EP2802611A1 (en) 2014-11-19
PT2802611T (pt) 2017-01-13
KR102046572B1 (ko) 2019-11-20
KR101970348B1 (ko) 2019-04-18
KR20140123478A (ko) 2014-10-22

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