FI111558B - Bakskikt hos matta erhållet ur blockkopolymerkompositioner - Google Patents

Bakskikt hos matta erhållet ur blockkopolymerkompositioner Download PDF

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Publication number
FI111558B
FI111558B FI960273A FI960273A FI111558B FI 111558 B FI111558 B FI 111558B FI 960273 A FI960273 A FI 960273A FI 960273 A FI960273 A FI 960273A FI 111558 B FI111558 B FI 111558B
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FI
Finland
Prior art keywords
block copolymer
poly
weight
recyclable
resin
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FI960273A
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English (en)
Finnish (fi)
Other versions
FI960273A0 (sv
FI960273A (sv
Inventor
Olaf Kurt Breuer
Teunis Graafland
Peter Migschels
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Shell Int Research
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Publication of FI960273A publication Critical patent/FI960273A/sv
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Publication of FI111558B publication Critical patent/FI111558B/sv

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0063—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
    • D06N7/0071—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing
    • D06N7/0076—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing the back coating or pre-coat being a thermoplastic material applied by, e.g. extrusion coating, powder coating or laminating a thermoplastic film
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0063—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
    • D06N7/0071—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing
    • D06N7/0078—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing the back coating or pre-coat being applied as a hot melt
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D06N2201/0254—Polyolefin fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D06N2201/0263—Polyamide fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/042—Polyolefin (co)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/045—Vinyl (co)polymers
    • D06N2203/047—Arromatic vinyl (co)polymers, e.g. styrene
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/06—Melt
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1685—Wear resistance

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Textile Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Carpets (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Laminated Bodies (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Artificial Filaments (AREA)

Claims (21)

1. Lätt och helt äteranvändbara mattor innehällan-de en termoplastisk mattväv av polypropen-, polyester- el- 5 ler polyamidgarn och ett segmentpolymer pälagt pä mattvä-vens baksida, kännetecknade av att segmentpolymeret minst innehäller: a) ett segmentpolymer med minst tva terminala po-lyvinylaromatblock och minst ett inre, polykonjugerat di- 10 enblock, b) en icke-aromatisk mjukgörande olja i en mängd frän 30 till 250 viktdelar pä 100 viktdelar segmentpolymer, c) ett polyvinylaromatiskt blockkompatibelt harts, 15 valt frän kumaron-indenharts, polyfenyleneterharts, poly- styrenhartser, polyalfametylstyrenharts, vinyltoluen-alfa-metylstyrensampolymerharts, polyindenharts, och polymety-lindenharts i en mängd frän 30 till 200 viktdelar pä 100 viktdelar segmentpolymer, 20 och med en smältviskositet < 500 Pa vid behand- lingstemperaturer frän 150 till 200 °C.
2. Äteranvändbara mattor enligt krav 1, kännetecknade av att den ursprungliga, eteniska omättningen i de polykonjugerade dienblocken har hydrerats selektivt. * -*' 25
3. Äteranvändbara mattor enligt krav 1, känne tecknade av att en blocksampolymerkomposition har pä-lagts pä mattans baksida i en mängd frän 100 till 1 600 g/m2.
4. Äteranvändbara mattor enligt krav 3, kanne - 30 tecknade av att blocksampolymerkompositionen pälägges pä mattans baksida i en mängd frän 200 till 1000 g/m2.
5. Äteranvändbara mattor enligt krav 1-4, kännetecknade av att som blocksampolymerbeständsdel (a) användes linjära treblocksampolymerer eller multiarmerade 35 radiella eller stjärnformiga blocksampolymerer, vilkas 111558 block huvudsakligen härletts frän ren styren och ren buta-dien och/eller isopren respektive.
6. Äteranvändbara mattor enligt krav 1-5, kän-netecknade av att blocksampolymerbeständsdel (a) inne- 5 halier selektivt hydrerade blocksampolymerer som kan er-hallas genom ympning av omättade karboxylsyror eller est-rar eller anhydrider därav pä de polykonjuerade dienblock-en.
7. Äteranvändbara mattor enligt krav 1 - 6, kän- 10 netecknade av att en paraffinolja användes i blocksam- polymerkompositionen.
8. Äteranvändbara mattor enligt krav 1 - 6, kän-netecknade av att olefinoligomerer eller lägmolekylära olefinpolymerer användes i blocksampolymerkompositionen. 15
9. Äteranvändbara mattor enligt krav 1-8, kän- netecknade av att som komponent (c) användes ett poly-alfa-metylstyrenharts.
10. Äteranvändbara mattor enligt krav 1-9, kännetecknade av att viktförhällandet mellan kompo- 2. nenterna a) , b) och c) i blocksampolymerkompositionen är frän 30 till 180 viktdelar av komponent b) pa 100 viktde-lar blocksampolymer och frän 50 till 160 viktdelar komponent c) pä 100 viktdelar blocksampolymer.
11. Äteranvändbara mattor enligt krav 1-10, * 25 kännetecknade av att de har härletts frän smältkom- positioner med en smältviskositet pä frän 0,5 till 100 Pa vid behandlingstemperaturer frän 150 tili 200 °C.
12. Äteranvändbara mattor enligt krav 1-11, kännetecknade av att de har härletts frän en block- 30 sampolymerkomposition i form av ett fint pulver som efter * päläggning sintras tili ett kontinuerligt lager genom vär- mebehandling.
13. Äteranvändbara mattor enligt krav 1-12, kännetecknade av att kalciumkarbonat ingär som fyll- 35 medel i den pälagda blocksampolymerkompositionen. 111558
14. Äteranvändbara mattor enligt krav 1-13, kännetecknade av att skiktet pä baksidan har en tjocklek frän 0,5 tili 5 mm och en härdhet fran 40 till 60 shore A. 5
15. Äteranvändbara mattor enligt krav 1-14, kännetecknade av att de har rivits sönder.
16. Blocksampolymerkomposition för användning som beläggning pä lätt och helt äteranvändbara mattor, kän -netecknad av att den innehäller: 10 a) 100 viktdelar av en blocksampolymer innehällan- de minst tvä terminala polyvinylaromatblock och minst ett inre, polykonjugerat dienblock, b) 30 tili 80 viktdelar av en icke-aromatisk mjuk-görande oija, 15 c) 50 tili 160 viktdelar av ett polyvinylaromat- blockkompatibelt harts, valt frän kumaron-indenharts, po-lyfenyleneterharts, polystyrenharts, poly-alfa-metylsty-renharts, vinyltoluen-alfa-metylstyrensampolymerharts, po-lyindenharts och polymetylindenharts.
17. Blocksampolymerkomposition enligt krav 16, kännetecknad av att den ursprungliga, eteniska omätt-ningen i de polykonjugerade dienblocken har hydrerats se-lektivt.
18. Blocksampolymerkompositioner enligt krav 16 “ 25 och 17, kännetecknade av att de innehäller modifie- rade blocksampolymerer som kan erhällas genom ympning med omättade karboxy1syror, eller estrar eller anhydrider där-av, pä de polykonjugerade dienblocken.
19. Blocksampolymerkompositioner enligt krav 16 - 30 18, kännetecknade av att de polyvinylaromatiska • t » blocken i blocksampolymererna har härletts frän ren styren och har molekylvikter frän 5 000 tili 20 000, och att de inre polykonjugerade dienblocken har härletts frän ren bu-tadien eller isopren och har molekylvikter frän 30 000 35 tili 100 000. 111558
20. Blocksampolymerkompositioner enligt krav 16 - 19, kännetecknade av att de polykonj ugerade dien-blocken innehäller frän 5 till 50 % vinylgrupper i förhäl-lande till de konjugerade dienmolekylerna.
21. Blocksampolymerkompositioner enligt krav 16 - 20, kännetecknade av att de fullständiga blocksampo-lymererna innehäller bunden vinylaromatisk förening i en mängd frän 20 till 60 viktprocent. 1 « • ·
FI960273A 1993-07-23 1996-01-19 Bakskikt hos matta erhållet ur blockkopolymerkompositioner FI111558B (sv)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
EP93202191 1993-07-23
EP93202191 1993-07-23
EP94200850 1994-03-29
EP94200850 1994-03-29
PCT/EP1994/002397 WO1995003447A1 (en) 1993-07-23 1994-07-19 Carpet backing derived from block copolymer compositions
EP9402397 1994-07-19

Publications (3)

Publication Number Publication Date
FI960273A0 FI960273A0 (sv) 1996-01-19
FI960273A FI960273A (sv) 1996-01-19
FI111558B true FI111558B (sv) 2003-08-15

Family

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Application Number Title Priority Date Filing Date
FI960273A FI111558B (sv) 1993-07-23 1996-01-19 Bakskikt hos matta erhållet ur blockkopolymerkompositioner

Country Status (14)

Country Link
JP (1) JP3644962B2 (sv)
KR (1) KR100339458B1 (sv)
CN (1) CN1068395C (sv)
AT (1) ATE165634T1 (sv)
AU (1) AU686655B2 (sv)
BR (1) BR9407081A (sv)
CA (1) CA2167686A1 (sv)
DE (1) DE69409956T2 (sv)
DK (1) DK0710305T3 (sv)
ES (1) ES2115250T3 (sv)
FI (1) FI111558B (sv)
NO (1) NO309010B1 (sv)
RU (1) RU2138398C1 (sv)
WO (1) WO1995003447A1 (sv)

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Publication number Priority date Publication date Assignee Title
ATE180816T1 (de) * 1994-03-25 1999-06-15 Shell Int Research Förderbänder abgeleitet von zusammensetzungen auf basis von blockcopolymeren aus vinylaromatischem monomer-konjugiertem dien
EP0673970B1 (en) * 1994-03-25 1999-06-02 Shell Internationale Researchmaatschappij B.V. Conveyor belts derived from compositions comprising vinyl aromatic-conjugated diene block copolymers
PT821748E (pt) * 1995-03-17 2002-03-28 Bp Corp North America Inc Construcao melhorada de tapetes e costas para alguns tapetes
US7338698B1 (en) 1997-02-28 2008-03-04 Columbia Insurance Company Homogeneously branched ethylene polymer carpet, carpet backing and method for making same
US20030211280A1 (en) 1997-02-28 2003-11-13 Shaw Industries, Inc. Carpet, carpet backings and methods
AU7371200A (en) 1999-09-17 2001-04-17 Procter & Gamble Company, The Low stress relaxation elastomeric materials
US20030181584A1 (en) 2002-02-07 2003-09-25 Kraton Polymers U.S. Llc Elastomeric articles prepared from controlled distribution block copolymers
EP1384768A1 (en) * 2002-07-26 2004-01-28 KRATON Polymers Research B.V. Solvent-free hot melt adhesive, its use in bonding a polar leather layer to a non-polar substrate, and leather articles so produced
US6814826B1 (en) * 2003-03-03 2004-11-09 Mohawk Brands, Inc. Use of waste carpet as backing filler for floor coverings
US7592390B2 (en) * 2006-03-24 2009-09-22 Kraton Polymers U.S. Llc Hydrogenated block copolymer compositions
WO2009076920A1 (de) * 2007-12-18 2009-06-25 Fleissner Gmbh Verfahren und vorrichtung zur verfestigung von textilem material
ES2467340T3 (es) * 2009-05-18 2014-06-12 Autoneum Management Ag Moquetas de pelo insertado para aplicaciones en automoción
CA2759376C (en) 2010-01-29 2015-03-03 Kraton Polymers U.S. Llc Thermofusible composition for slush moulding
CN103534310B (zh) 2011-02-14 2016-09-07 可乐丽美国股份有限公司 适用于薄膜和片材的弹性体配方
ES2431539T3 (es) * 2011-06-07 2013-11-26 Gessner Ag Sustrato textil a partir de una pluralidad de diferentes materiales desechables y/o reciclables, utilización de un sustrato textil de este tipo y procedimiento para procesar un sustrato textil de este tipo
JP6058908B2 (ja) * 2012-04-11 2017-01-11 株式会社大和 フロアマット
JP6606641B2 (ja) * 2013-06-10 2019-11-20 ディーエスエム アイピー アセッツ ビー．ブイ． テキスタイル製品の製造方法、それから取得可能な製品、および製品の再生方法
NL2013521B1 (en) * 2014-09-24 2016-09-29 Desso B V Method for producing a floor covering (including carpet and carpet tile) with positive defined recycled content.
EP3307509B1 (en) 2015-06-12 2020-08-05 Kraton Polymers U.S. LLC A composition for soft skins and uses thereof
CN108329872A (zh) * 2018-01-31 2018-07-27 广东金源科技股份有限公司 一种环保防滑地毯背胶tpe材料及其制备方法
CN110089907A (zh) * 2019-05-05 2019-08-06 上海康贡新材料科技有限公司 Pvc立体编织地毯

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Also Published As

Publication number Publication date
RU2138398C1 (ru) 1999-09-27
AU686655B2 (en) 1998-02-12
JP3644962B2 (ja) 2005-05-11
FI960273A0 (sv) 1996-01-19
FI960273A (sv) 1996-01-19
WO1995003447A1 (en) 1995-02-02
NO960238L (no) 1996-03-19
DK0710305T3 (da) 1998-10-07
DE69409956T2 (de) 1998-09-03
JPH09500692A (ja) 1997-01-21
CN1129022A (zh) 1996-08-14
ES2115250T3 (es) 1998-06-16
ATE165634T1 (de) 1998-05-15
NO309010B1 (no) 2000-11-27
DE69409956D1 (de) 1998-06-04
CN1068395C (zh) 2001-07-11
AU7495094A (en) 1995-02-20
BR9407081A (pt) 1996-08-13
KR100339458B1 (ko) 2002-12-05
NO960238D0 (no) 1996-01-19
CA2167686A1 (en) 1995-02-02

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