ES8704356A1 - Un metodo para eliminar compuestos de yoduro a partir de un medio organico no acuoso. - Google Patents
Un metodo para eliminar compuestos de yoduro a partir de un medio organico no acuoso.Info
- Publication number
- ES8704356A1 ES8704356A1 ES552717A ES552717A ES8704356A1 ES 8704356 A1 ES8704356 A1 ES 8704356A1 ES 552717 A ES552717 A ES 552717A ES 552717 A ES552717 A ES 552717A ES 8704356 A1 ES8704356 A1 ES 8704356A1
- Authority
- ES
- Spain
- Prior art keywords
- aqueous organic
- removal
- iodide compounds
- organic media
- medium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/47—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/04—Processes using organic exchangers
- B01J39/05—Processes using organic exchangers in the strongly acidic form
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/79—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Abstract
3METODO PARA LA ELIMINACION DE COMPUESTOS DE YODURO DE MEDIOS ORGANICOS NO ACUOSOS. CONSISTE EN PASAR EL MEDIO QUE CONTIENE LOS COMPUESTOS DE YODURO A TRAVES DE UNA RESINA DE INTERCAMBIO CATIONICO DE ACIDO FUERTE MACRORRETICULADA, ESTABLE EN EL MEDIO ORGANICO Y CUYOS CENTROS ACTIVOS SE HALLAN CONVERTIDOS EN FORMA DE PLATA O MERCURIO, AL MENOS EN UN 1%. EL MEDIO ORGANICO SE PASA A TRAVES DE LA RESINA, A UN CAUDAL DE 0,2 A 50 VOLUMENES DE LECHO POR HORA, A UNA TEMPERATURA COMPRENDIDA ENTRE 17JC Y 100JC. TIENE APLICACIONES PARA ELIMINAR YODURO DE METILO Y HEXILO DE ACIDO ACETICO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06708992 US4615806B1 (en) | 1985-03-07 | 1985-03-07 | Removal of iodide compounds from non-aqueous organic media |
Publications (2)
Publication Number | Publication Date |
---|---|
ES552717A0 ES552717A0 (es) | 1987-04-01 |
ES8704356A1 true ES8704356A1 (es) | 1987-04-01 |
Family
ID=24848035
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES552717A Expired ES8704356A1 (es) | 1985-03-07 | 1986-03-06 | Un metodo para eliminar compuestos de yoduro a partir de un medio organico no acuoso. |
Country Status (14)
Country | Link |
---|---|
US (1) | US4615806B1 (es) |
EP (1) | EP0196173B1 (es) |
JP (1) | JPS61209053A (es) |
KR (1) | KR900006072B1 (es) |
CN (1) | CN86101411B (es) |
AU (1) | AU572444B2 (es) |
BR (1) | BR8601008A (es) |
CA (1) | CA1240450A (es) |
DE (1) | DE3660379D1 (es) |
ES (1) | ES8704356A1 (es) |
HK (1) | HK67692A (es) |
NO (1) | NO162844C (es) |
NZ (1) | NZ215388A (es) |
ZA (1) | ZA861720B (es) |
Families Citing this family (87)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4515906A (en) * | 1983-02-28 | 1985-05-07 | Bend Research, Inc. | Anisotropic microporous supports impregnated with polymeric ion-exchange materials |
JPH0714488B2 (ja) * | 1987-06-24 | 1995-02-22 | ユニオン・カーバイド・コーポレーション | カルボン酸からのハライドの除去 |
US5139981A (en) * | 1987-06-24 | 1992-08-18 | Union Carbide Chemicals & Plastics Technology Corporation | Process for preparing silver(I)-exchanged resins |
JP2611774B2 (ja) * | 1987-07-01 | 1997-05-21 | 和光純薬工業 株式会社 | 酢酸の精製方法 |
US5155265A (en) * | 1987-12-23 | 1992-10-13 | Hoechst Celanese Corporation | Purification of acetic acid with ozone followed by treatment with activated carbon and/or an ion-exchange resin |
US5202481A (en) * | 1987-12-23 | 1993-04-13 | Hoechst Celanese Corporation | Purification of acetic acid produced by the low water carbonylation of methanol by treatment with ozone |
DE3823645C1 (es) † | 1988-07-13 | 1989-11-30 | Hoechst Ag | |
GB8822661D0 (en) * | 1988-09-27 | 1988-11-02 | Bp Chem Int Ltd | Removal of iodine/iodide impurities |
GB9022787D0 (en) * | 1990-10-19 | 1990-12-05 | British Petroleum Co Plc | Process |
GB9023634D0 (en) * | 1990-10-31 | 1990-12-12 | British Petroleum Co Plc | Process for purifying acetic acid and/or acetic anhydride |
US5220058A (en) * | 1991-09-30 | 1993-06-15 | Union Carbide Chemicals & Plastics Technology Corporation | Iodide removal process |
GB9122168D0 (en) * | 1991-10-18 | 1991-11-27 | Bp Chem Int Ltd | Process |
US5300685A (en) * | 1991-11-25 | 1994-04-05 | Hoechst Celanese Corporation | Removal of halide impurities from organic liquids |
GB9211671D0 (en) * | 1992-06-02 | 1992-07-15 | Bp Chem Int Ltd | Process |
DE4238915A1 (de) * | 1992-11-19 | 1994-05-26 | Solvay Fluor & Derivate | Verfahren zur Wiedergewinnung von Jod |
KR950013467B1 (ko) * | 1993-03-31 | 1995-11-08 | 포항종합제철주식회사 | 초산중의 요오드 화합물의 제거방법 |
CN1070167C (zh) * | 1994-05-13 | 2001-08-29 | 派蒂斯艾西提克公司 | 用基于铱和碘化物的可溶性催化剂制备羧酸或相应酯的方法 |
FR2725983B1 (fr) * | 1994-10-21 | 1996-12-20 | Rhone Poulenc Chimie | Procede de preparation d'acides carboxyliques en presence d'un catalyseur a base d'iridium et d'iodures sous forme soluble |
SG44317A1 (en) * | 1994-06-15 | 1997-12-19 | Daicel Chem | Process for producing high purity acetic acid |
US5672266A (en) * | 1995-10-13 | 1997-09-30 | The Lubrizol Corporation | Treatment of organic compounds to reduce chlorine level |
US5674819A (en) * | 1995-11-09 | 1997-10-07 | The Lubrizol Corporation | Carboxylic compositions, derivatives,lubricants, fuels and concentrates |
US5624567A (en) * | 1996-02-12 | 1997-04-29 | Umpqua Research Company | Process for removing iodine/iodide from aqueous solutions |
JP3281258B2 (ja) * | 1996-04-26 | 2002-05-13 | ダイセル化学工業株式会社 | 有機媒質中に含まれるヨウ素化合物を除去する際の運転方法 |
GB9715489D0 (en) | 1997-07-23 | 1997-10-01 | Bp Chem Int Ltd | Composition |
US6506935B1 (en) | 1998-03-06 | 2003-01-14 | Uop Llc | Combination pretreatment/adsorption for treating a liquid stream contaminated with an iodine-containing compound |
US5962735A (en) | 1998-03-06 | 1999-10-05 | Uop Llc | Method for treating an organic liquid contaminated with an iodide compound |
AU1597500A (en) * | 1998-11-06 | 2000-05-29 | Celanese International Corporation | Process for removing halide impurities by resin treatment |
US6007724A (en) * | 1998-12-21 | 1999-12-28 | Uop Llc | Method for treating a liquid stream contaminated with an iodine-containing compound using a solid absorbent comprising a metal phthalocyanine |
US6342462B1 (en) | 1999-03-22 | 2002-01-29 | Uop Llc | Process for regenerating an adsorbent |
US6211408B1 (en) * | 1999-03-24 | 2001-04-03 | Celanese International Corporation | Method of removing iodides from non-aqueous organic media utilizing silver or mercury exchanged macroporous organofunctional polysiloxane resins |
US6190562B1 (en) | 1999-03-24 | 2001-02-20 | Uop Llc | Method for treating a liquid stream contaminated with an iodine-containing compound using a cation-exchanged crystalline manganese phosphate |
US6225498B1 (en) * | 2000-03-24 | 2001-05-01 | Celanese International Corporation | Method of removing organic iodides from organic media |
US6627770B1 (en) | 2000-08-24 | 2003-09-30 | Celanese International Corporation | Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process |
US6657078B2 (en) * | 2001-02-07 | 2003-12-02 | Celanese International Corporation | Low energy carbonylation process |
US6642168B1 (en) | 2001-04-27 | 2003-11-04 | Uop Llc | Method for metal loading of a multi-bed adsorbent system |
JP4995522B2 (ja) | 2006-09-25 | 2012-08-08 | 千代田化工建設株式会社 | 有機酸からのヨウ素化合物除去方法 |
KR100781566B1 (ko) * | 2006-11-08 | 2007-12-03 | (주)비룡 | 요오드화칼륨 폐용액의 재생처리 장치 및 방법 |
US20080116417A1 (en) * | 2006-11-14 | 2008-05-22 | Samuels George J | Iodine and iodide removal method |
JP4889621B2 (ja) * | 2006-12-15 | 2012-03-07 | 日揮株式会社 | 水銀吸着剤、水銀吸着剤の製造方法及び水銀吸着除去方法 |
CN100581646C (zh) * | 2006-12-28 | 2010-01-20 | 中国科学院化学研究所 | 一种载银高分子衍生碳除碘吸附剂及制法和应用 |
CN101712613B (zh) * | 2008-10-06 | 2013-03-27 | 兖矿国泰化工有限公司 | 一种醋酸脱碘精制方法 |
US7588690B1 (en) * | 2009-02-10 | 2009-09-15 | The Purolite Company | Method of iodide removal |
US8704010B2 (en) | 2010-05-07 | 2014-04-22 | Celanese International Corporation | Alcohol production process with impurity removal |
JP5781279B2 (ja) * | 2010-06-15 | 2015-09-16 | 三菱重工業株式会社 | 放射性ヨウ素の吸着材及び放射性ヨウ素の除去装置 |
US20110313193A1 (en) * | 2010-06-17 | 2011-12-22 | Hallinan Noel C | Purification of acetic acid |
US8394987B2 (en) * | 2010-06-17 | 2013-03-12 | Lyondell Chemical Technology, L.P. | Methyl iodide removal from acetic acid waste stream |
US8378141B2 (en) | 2010-08-16 | 2013-02-19 | Celanese International Corporation | Process and system for supplying vapor from drying column to light ends column |
US8461379B2 (en) | 2010-10-12 | 2013-06-11 | Celanese International Corporation | Production of acetic acid comprising feeding at least one reactant to a recycle stream |
EP2627624B1 (en) | 2010-10-13 | 2019-02-13 | Celanese International Corporation | Process for recovering halogen promoters and removing permanganate reducing compounds |
US8637698B2 (en) | 2010-11-19 | 2014-01-28 | Celanese International Corporation | Production of acetic acid with an increased production rate |
MX2013007647A (es) | 2010-12-30 | 2013-08-01 | Celanese Int Corp | Purificacion de torrentes de productos de acido acetico. |
US8686199B2 (en) | 2011-04-26 | 2014-04-01 | Celanese International Corporation | Process for reducing the concentration of acetic acid in a crude alcohol product |
WO2012149199A2 (en) | 2011-04-26 | 2012-11-01 | Celanese International Corporation | Process for producing ethanol and reducing acetic acid concentration |
US8933278B2 (en) | 2011-04-26 | 2015-01-13 | Celanese International Corporation | Process for producing ethanol and reducing acetic acid concentration |
WO2012149135A2 (en) | 2011-04-26 | 2012-11-01 | Celanese International Corporation | Using a dilute acid stream as an extractive agent |
TW201245127A (en) | 2011-04-26 | 2012-11-16 | Celanese Int Corp | Process to reduce ethanol recycled to hydrogenation reactor |
US8884081B2 (en) | 2011-04-26 | 2014-11-11 | Celanese International Corporation | Integrated process for producing acetic acid and alcohol |
TW201247301A (en) | 2011-04-26 | 2012-12-01 | Celanese Int Corp | Extractive distillation of crude alcohol product |
WO2013070216A1 (en) | 2011-11-09 | 2013-05-16 | Celanese International Corporation | Integrated ethanol production from methanol via carbonylation and hydrogenation by extracting halides from acetic acid |
CN103121934B (zh) * | 2011-11-18 | 2014-07-23 | 中国石油化工股份有限公司 | 降低醋酸中碘化物杂质含量的方法 |
CN103122044B (zh) * | 2011-11-18 | 2015-05-13 | 中国石油化工股份有限公司 | 磺酸型大孔离子交换树脂及其制备方法 |
CN103122043B (zh) * | 2011-11-18 | 2015-04-08 | 中国石油化工股份有限公司 | 脱碘剂的制备方法 |
US8859810B2 (en) | 2012-08-21 | 2014-10-14 | Celanese International Corporation | Process for recovering permanganate reducing compounds from an acetic acid production process |
JP2014113586A (ja) * | 2012-11-19 | 2014-06-26 | Toshiba Corp | ハロゲン吸着剤、水処理用タンク、及び水処理システム |
CN106715379B (zh) | 2014-10-02 | 2020-05-19 | 国际人造丝公司 | 用于生产乙酸的方法 |
US9260369B1 (en) | 2014-11-14 | 2016-02-16 | Celanese International Corporation | Processes for producing acetic acid product having low butyl acetate content |
US9302975B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for flashing a reaction medium |
US9487464B2 (en) | 2015-01-30 | 2016-11-08 | Celanese International Corporation | Processes for producing acetic acid |
US9561994B2 (en) | 2015-01-30 | 2017-02-07 | Celanese International Corporation | Processes for producing acetic acid |
CN107207391B (zh) | 2015-01-30 | 2020-11-06 | 国际人造丝公司 | 生产乙酸的方法 |
MY181742A (en) | 2015-01-30 | 2021-01-06 | Celanese Int Corp | Processes for producing acetic acid |
US10413840B2 (en) | 2015-02-04 | 2019-09-17 | Celanese International Coporation | Process to control HI concentration in residuum stream |
US9505696B2 (en) | 2015-02-04 | 2016-11-29 | Celanese International Corporation | Process to control HI concentration in residuum stream |
US9512056B2 (en) | 2015-02-04 | 2016-12-06 | Celanese International Corporation | Process to control HI concentration in residuum stream |
US9822055B2 (en) * | 2015-06-23 | 2017-11-21 | Lyondellbasell Acetyls, Llc | Silver loaded halide removal resins for treating halide containing solutions |
US9302974B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for producing acetic acid |
US9382183B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for flashing a reaction medium |
CN106552596A (zh) * | 2015-09-24 | 2017-04-05 | 中国石油化工股份有限公司 | 一种脱碘树脂吸附剂及其制备方法和应用 |
MY181882A (en) | 2015-10-02 | 2021-01-12 | Celanese Int Corp | Process to produce acetic acid with recycle of water |
US9908835B2 (en) | 2015-11-13 | 2018-03-06 | Celanese International Corporation | Processes for purifying acetic and hydrating anhydride |
US9957216B2 (en) | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
US10435309B2 (en) | 2016-04-22 | 2019-10-08 | Korea Atomic Energy Research Institute | Process and device for removing iodine using gold particles |
US10807935B2 (en) | 2018-11-02 | 2020-10-20 | Celanese International Corporation | Process for continuous acetic acid production |
US20220355287A1 (en) * | 2019-10-02 | 2022-11-10 | Enerkem Inc. | Liquid phase removal of trace of iodide from an organic media using tertiary amine ion exchange adsorbent |
JP2021155353A (ja) * | 2020-03-26 | 2021-10-07 | 株式会社ダイセル | 精製酢酸の製造方法 |
US20230127564A1 (en) | 2020-04-01 | 2023-04-27 | Celanese International Corporation | Processes for removing and/or reducing permanganate reducing compounds and alkyl iodides |
WO2021247854A1 (en) | 2020-06-03 | 2021-12-09 | Celanese International Corporation | Production and purification of acetic acid |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1843354A (en) * | 1929-10-30 | 1932-02-02 | Behrman Abraham Sidney | Halogen recovery |
US2945746A (en) * | 1959-05-28 | 1960-07-19 | Dow Chemical Co | Process for recovering iodides from aqueous solutions by ion exchange and conversion of the iodides to iodine |
DE1598589B2 (de) * | 1967-05-18 | 1972-05-31 | Hitachi, Ltd., Tokio | Verfahren zum chromatographischen trennen einer mischung von verbindungen mit koordinativen gruppen |
US3658467A (en) * | 1969-07-28 | 1972-04-25 | Atomic Energy Commission | System for total iodine retention |
DE2109146C3 (de) * | 1971-02-26 | 1980-03-20 | Bayer Ag, 5090 Leverkusen | Verfahren zur Entfernung von Jod und Jodverbindungen aus Gasen und Dämpfen und silbernitratimprägnierte Sorptionsmittel zur Durchführung des Verfahrens |
JPS4837762A (es) * | 1971-09-20 | 1973-06-04 | ||
US3943229A (en) * | 1973-11-30 | 1976-03-09 | Rohm And Haas Company | Method of removing iodine and compounds thereof from gaseous effluents |
US4008131A (en) * | 1975-12-11 | 1977-02-15 | Monsanto Company | Purification of acetic acid |
US4204980A (en) * | 1976-01-08 | 1980-05-27 | American Air Filter Company, Inc. | Method and composition for removing iodine from gases |
US4088737A (en) * | 1976-11-02 | 1978-05-09 | The United States Of America As Represented By The United States Department Of Energy | Dry method for recycling iodine-loaded silver zeolite |
JPS54133495A (en) * | 1978-04-10 | 1979-10-17 | Asahi Chem Ind Co Ltd | Recovering method for liquid phase oxidation catalyst |
US4305882A (en) * | 1980-03-21 | 1981-12-15 | The United States Of America As Represented By The Secretary Of Agriculture | Partial argentation resin chromatography for separation of polyunsaturated fatty esters |
NL8204901A (nl) * | 1981-12-30 | 1983-07-18 | Halcon Sd Group Inc | Zuivering van carbonyleringsprodukten. |
GB2122394A (en) * | 1982-06-22 | 1984-01-11 | Dennis W Ruediger | Channel marker |
US4451375A (en) * | 1983-08-25 | 1984-05-29 | The Dow Chemical Company | Iodine adsorption via picolylamine ion exchange resins |
-
1985
- 1985-03-07 US US06708992 patent/US4615806B1/en not_active Expired - Lifetime
-
1986
- 1986-02-17 CA CA000501988A patent/CA1240450A/en not_active Expired
- 1986-02-28 AU AU54241/86A patent/AU572444B2/en not_active Expired
- 1986-03-05 JP JP61046465A patent/JPS61209053A/ja active Granted
- 1986-03-06 CN CN86101411A patent/CN86101411B/zh not_active Expired
- 1986-03-06 ES ES552717A patent/ES8704356A1/es not_active Expired
- 1986-03-06 KR KR1019860001581A patent/KR900006072B1/ko not_active IP Right Cessation
- 1986-03-06 NZ NZ215388A patent/NZ215388A/en unknown
- 1986-03-06 EP EP86301585A patent/EP0196173B1/en not_active Expired
- 1986-03-06 DE DE8686301585T patent/DE3660379D1/de not_active Expired
- 1986-03-06 NO NO860841A patent/NO162844C/no unknown
- 1986-03-07 ZA ZA861720A patent/ZA861720B/xx unknown
- 1986-03-07 BR BR8601008A patent/BR8601008A/pt not_active IP Right Cessation
-
1992
- 1992-09-10 HK HK676/92A patent/HK67692A/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
KR900006072B1 (ko) | 1990-08-22 |
ES552717A0 (es) | 1987-04-01 |
BR8601008A (pt) | 1986-11-18 |
NZ215388A (en) | 1988-08-30 |
NO162844C (no) | 1990-02-28 |
JPS61209053A (ja) | 1986-09-17 |
NO860841L (no) | 1986-09-08 |
HK67692A (en) | 1992-09-18 |
US4615806A (en) | 1986-10-07 |
JPH0521031B2 (es) | 1993-03-23 |
US4615806B1 (en) | 1994-05-03 |
CA1240450A (en) | 1988-08-09 |
CN86101411B (zh) | 1988-07-20 |
EP0196173A1 (en) | 1986-10-01 |
AU5424186A (en) | 1986-09-11 |
AU572444B2 (en) | 1988-05-05 |
CN86101411A (zh) | 1986-10-29 |
EP0196173B1 (en) | 1988-07-13 |
DE3660379D1 (en) | 1988-08-18 |
ZA861720B (en) | 1986-11-26 |
KR860007005A (ko) | 1986-10-06 |
NO162844B (no) | 1989-11-20 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 20070205 |