ES8609397A1 - Un procedimiento de preparar un copolimero de bloques de nilon - Google Patents
Un procedimiento de preparar un copolimero de bloques de nilonInfo
- Publication number
- ES8609397A1 ES8609397A1 ES538443A ES538443A ES8609397A1 ES 8609397 A1 ES8609397 A1 ES 8609397A1 ES 538443 A ES538443 A ES 538443A ES 538443 A ES538443 A ES 538443A ES 8609397 A1 ES8609397 A1 ES 8609397A1
- Authority
- ES
- Spain
- Prior art keywords
- composition
- same
- block copolymers
- nylon block
- preparing nylon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001400 block copolymer Polymers 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000004677 Nylon Substances 0.000 title 1
- 229920001778 nylon Polymers 0.000 title 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 229910001629 magnesium chloride Inorganic materials 0.000 abstract 2
- 229920002292 Nylon 6 Polymers 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
- C08G69/18—Anionic polymerisation
- C08G69/20—Anionic polymerisation characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/24—Pyrrolidones or piperidones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/40—Polyamides containing oxygen in the form of ether groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/42—Polyamides containing atoms other than carbon, hydrogen, oxygen, and nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/44—Polyester-amides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Abstract
PROCEDIMIENTO PARA PREPARAR COPOLIMEROS DE BLOQUES DE NYLON. COMPRENDE: A) TRATAR DE 0,2 A 2 EQUIVALENTES DE UN MATERIAL QUE TIENE LA FUNCION HALURO DE ACIDO DE FORMULA Z(O-A0(X)B)N CON UN MOL DE UNA MAGNESIO-DILACTAMA EN E-CAPROLACTAMA, PARA FORMAR UNA PRIMERA SOLUCION QUE TIENE ACIL-LACTAMA Y UN HALURO DE MAGNESIO; Y B) MEZCLAR REACTIVAMENTE A LA PRIMERA SOLUCION CON UNA SEGUNDA SOLUCION DE MAGNESIO -DILACTAMA EN E-CAPROLACTAMA, PARA FORMAR UN HALO-MAGNESIO -LACTAMA Y POLIMERIZAR EL MONOMERO DE E-CAPROLACTAMA. LAS REACCIONES A Y B SE REALIZAN ENTRE 100 Y 160JC. SIENDO: A - CFO-R-(CFO)B-, -CFO Y OTROS; R UN GRUPO HIDROCARBURO O POLIETER DE PESO MOLECULAR DE 300; X HALOGENO; Z UN POLIETER POLI(OXIDO DE ETILENO), UN HIDROCARBURO (POLIBUTADIENO), UN POLISILOXANO Y OTROS; B, 1, 2 O 3 (ENTEROS) Y N 0 A 1.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US56064483A | 1983-12-12 | 1983-12-12 | |
US06/658,958 US4587305A (en) | 1983-12-12 | 1984-10-09 | Composition for use in preparing nylon block copolymer |
Publications (2)
Publication Number | Publication Date |
---|---|
ES538443A0 ES538443A0 (es) | 1986-09-01 |
ES8609397A1 true ES8609397A1 (es) | 1986-09-01 |
Family
ID=27072425
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES538443A Expired ES8609397A1 (es) | 1983-12-12 | 1984-12-10 | Un procedimiento de preparar un copolimero de bloques de nilon |
Country Status (10)
Country | Link |
---|---|
US (1) | US4587305A (es) |
EP (1) | EP0151911B1 (es) |
KR (1) | KR860001172B1 (es) |
AU (1) | AU566697B2 (es) |
BR (1) | BR8406338A (es) |
CA (1) | CA1246765A (es) |
DE (1) | DE3475079D1 (es) |
DK (1) | DK593284A (es) |
ES (1) | ES8609397A1 (es) |
PT (1) | PT79655B (es) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4596865A (en) * | 1984-12-17 | 1986-06-24 | Monsanto Company | Promotion of ε-caprolactam block copolymerization |
US5051469A (en) * | 1985-12-13 | 1991-09-24 | Monsanto Company | Rubber modified reaction molded nylon-6 block copolymers |
EP0232695A3 (en) * | 1985-12-13 | 1989-04-05 | Monsanto Company | Rubber modified reaction molded nylon-6 block copolymers |
CA1318420C (en) * | 1985-12-13 | 1993-05-25 | Kishore Udipi | Rubber modified reaction moldable nylon-6 compositions |
US4672085A (en) * | 1986-03-26 | 1987-06-09 | Dsm Rim Nylon Vof | Stabilized lactam polymerization solutions |
KR910003646B1 (ko) * | 1986-04-10 | 1991-06-08 | 몬산토 캄파니 | 폴리아실락탐 |
EP0752306A1 (en) | 1995-07-05 | 1997-01-08 | Monsanto Europe S.A./N.V. | Manufacture of pultruded articles |
DE10341811B4 (de) * | 2003-09-10 | 2006-09-28 | Ems-Chemie Ag | Katalysatorlösung zur Durchführung der anionischen Lactampolymerisation, Verfahren zu deren Herstellung und Polyamidformmasse |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US30371A (en) * | 1860-10-09 | Extension- washbejtch | ||
GB1067153A (en) * | 1963-05-17 | 1967-05-03 | Ici Ltd | Grafted polyamides |
US3451963A (en) * | 1965-11-15 | 1969-06-24 | Monsanto Co | Polymerization of lactams |
US3498956A (en) * | 1965-11-17 | 1970-03-03 | Huels Chemische Werke Ag | Stable solid polymerizable lactam-catalyst-cocatalyst mixtures and methods of preparing the same |
US4031164A (en) * | 1974-06-06 | 1977-06-21 | Monsanto Company | Lactam-polyol-polyacyl lactam terpolymers |
USRE30371E (en) | 1974-07-22 | 1980-08-12 | Monsanto Company | Catalytic process for imide-alcohol condensation |
US4098774A (en) * | 1976-05-19 | 1978-07-04 | Chevron Research Company | Quaternary ammonium catalyst system for the polymerization of 2-pyrrolidone |
US4346200A (en) * | 1980-12-29 | 1982-08-24 | Monsanto Company | Thermoplastic polyamide compositions |
DE3273791D1 (en) * | 1981-06-16 | 1986-11-20 | Monsanto Co | Acid halide and acyllactam functional materials and process for the preparation of nylon block polymers therewith |
EP0161549B1 (en) * | 1981-06-16 | 1988-11-17 | Dsm Rim Nylon V.O.F | Acid halide functional materials |
DE3273792D1 (en) * | 1981-06-16 | 1986-11-20 | Monsanto Co | Process for the preparaton of nylon block polymers |
-
1984
- 1984-10-09 US US06/658,958 patent/US4587305A/en not_active Expired - Fee Related
- 1984-12-07 CA CA000469617A patent/CA1246765A/en not_active Expired
- 1984-12-10 ES ES538443A patent/ES8609397A1/es not_active Expired
- 1984-12-11 AU AU36500/84A patent/AU566697B2/en not_active Ceased
- 1984-12-11 EP EP84870172A patent/EP0151911B1/en not_active Expired
- 1984-12-11 DK DK593284A patent/DK593284A/da not_active Application Discontinuation
- 1984-12-11 PT PT79655A patent/PT79655B/pt unknown
- 1984-12-11 DE DE8484870172T patent/DE3475079D1/de not_active Expired
- 1984-12-11 KR KR1019840007838A patent/KR860001172B1/ko not_active IP Right Cessation
- 1984-12-11 BR BR8406338A patent/BR8406338A/pt unknown
Also Published As
Publication number | Publication date |
---|---|
AU3650084A (en) | 1985-06-20 |
ES538443A0 (es) | 1986-09-01 |
EP0151911A2 (en) | 1985-08-21 |
DE3475079D1 (en) | 1988-12-15 |
DK593284D0 (da) | 1984-12-11 |
BR8406338A (pt) | 1985-10-08 |
AU566697B2 (en) | 1987-10-29 |
EP0151911B1 (en) | 1988-11-09 |
EP0151911A3 (en) | 1985-09-18 |
CA1246765A (en) | 1988-12-13 |
KR860004942A (ko) | 1986-07-16 |
PT79655A (en) | 1985-01-01 |
US4587305A (en) | 1986-05-06 |
KR860001172B1 (ko) | 1986-08-20 |
DK593284A (da) | 1985-06-13 |
PT79655B (en) | 1986-10-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Patent lapsed |
Effective date: 19960506 |