ES8504209A1 - Procedimiento para preparar n-fosfonometilglicina. - Google Patents

Procedimiento para preparar n-fosfonometilglicina.

Info

Publication number
ES8504209A1
ES8504209A1 ES523690A ES523690A ES8504209A1 ES 8504209 A1 ES8504209 A1 ES 8504209A1 ES 523690 A ES523690 A ES 523690A ES 523690 A ES523690 A ES 523690A ES 8504209 A1 ES8504209 A1 ES 8504209A1
Authority
ES
Spain
Prior art keywords
formil
reacted
formamide
phosphonomethylglycine
diethylphosphonometyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES523690A
Other languages
English (en)
Other versions
ES523690A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stauffer Chemical Co
Original Assignee
Stauffer Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stauffer Chemical Co filed Critical Stauffer Chemical Co
Publication of ES523690A0 publication Critical patent/ES523690A0/es
Publication of ES8504209A1 publication Critical patent/ES8504209A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Saccharide Compounds (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

PROCEDIMIENTO PARA PREPARAR N-FOSFONOMETILGLICINA.COMPRENDE LAS SIGUIENTES ETAPAS: PRIMERA, SE HACE REACCIONAR FORMALDEHIOO CON FORMAMIDA A UN PH COMPRENDIDO ENTRE 9 Y 10, PARA FORMAR N-(HIDROXIMETIL)FORMAMIDA; SEGUNDA, LA N-(HIDROXIMETIL)FORMAMIDA SE HACE REACCIONAR CON FOSFATO DE TRIETILO PARA OBTENER DIETIL-N-(FORMIL) AMINOMETILFOSFONATO; TERCERA, EL DIETIL-N-(FORMIL)AMINOMETILFOSFONATO SE HACE REACCIONAR CON CLOROACETATO DE METILO PARA FORMAR ESTER DE METILO DE N-(DIETILFOSFONOMETIL)-N-(FORMIL)GLICINA; Y POR ULTIMO, SE HACE REACCIONAR EL ESTER DE METILO DE N-(DIETILFOSFONOMETIL)-N-(FORMIL)GLICINA, CON UN AGENTE HIDROLIZANTE, PARA OBTENER LA N-FOSFONOMETILGLICINA.DE APLICACION COMO HERBICIDA Y COMO AGENTE REGULADOR DEL CRECIMIENTO DE LAS PLANTAS.
ES523690A 1982-06-30 1983-06-29 Procedimiento para preparar n-fosfonometilglicina. Expired ES8504209A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/393,574 US4422982A (en) 1982-06-30 1982-06-30 Method for preparation of N-phosphonomethylglycine

Publications (2)

Publication Number Publication Date
ES523690A0 ES523690A0 (es) 1985-04-01
ES8504209A1 true ES8504209A1 (es) 1985-04-01

Family

ID=23555297

Family Applications (2)

Application Number Title Priority Date Filing Date
ES523690A Expired ES8504209A1 (es) 1982-06-30 1983-06-29 Procedimiento para preparar n-fosfonometilglicina.
ES538163A Granted ES538163A0 (es) 1982-06-30 1984-11-30 Procedimiento para preparar n-fosfonometilglicina

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES538163A Granted ES538163A0 (es) 1982-06-30 1984-11-30 Procedimiento para preparar n-fosfonometilglicina

Country Status (18)

Country Link
US (1) US4422982A (es)
EP (1) EP0098159B1 (es)
JP (1) JPS5913795A (es)
KR (1) KR870001334B1 (es)
AT (1) ATE21903T1 (es)
AU (1) AU555801B2 (es)
BR (1) BR8303370A (es)
CA (1) CA1205487A (es)
CS (2) CS244939B2 (es)
DD (1) DD212966A5 (es)
DE (1) DE3365866D1 (es)
DK (1) DK292283A (es)
ES (2) ES8504209A1 (es)
HU (1) HU194256B (es)
IL (3) IL69112A (es)
PL (1) PL140912B1 (es)
RO (1) RO86524B (es)
ZA (1) ZA834740B (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES8603901A1 (es) * 1983-07-27 1986-01-01 Rhone Poulenc Agrochimie Procedimiento de preparacion de sulfonamidas con grupo ansinometilfosfonico
FR2560198B1 (fr) * 1984-02-23 1987-05-07 Rhone Poulenc Agrochimie Esters de la famille de la n-phosphonomethylglycine et leur utilisation pour la preparation d'herbicides connus
US4548758A (en) * 1984-08-30 1985-10-22 Stauffer Chemical Company Preparation of phosphonomethylated amino acids
US4548759A (en) * 1984-08-30 1985-10-22 Stauffer Chemical Company Preparation of phosphonomethylated amino acids
US4921991A (en) * 1985-02-22 1990-05-01 Guy Lacroix Preparation of esters of the N-phosphonomethylglycine and the N-phosphonomethyl glycines
FR2611204B1 (fr) * 1987-02-19 1989-05-05 Rhone Poulenc Agrochimie Composes intermediaires utiles pour la preparation d'herbicides
US4830788A (en) * 1987-11-20 1989-05-16 Crompton & Knowles Corporation Process for preparation of substituted-aminomethylphosphonic acids
US10364262B2 (en) 2012-07-17 2019-07-30 Monsanto Technology Llc Method for the synthesis of N-phosphonomethyliminodiacetic acid
BR112015000995B1 (pt) 2012-07-17 2020-04-28 Monsanto Technology Llc método para a síntese de n-(fosfonometil)glicina ou um de seus derivados selecionados a partir do grupo que consiste em seus sais, seus ésteres de fosfonato e seus sais de éster de fosfonato
CN104812765B (zh) 2012-07-17 2017-06-06 斯特雷特马克控股股份公司 用于合成α‑氨基亚烷基膦酸的方法
US10280189B2 (en) 2012-07-17 2019-05-07 Monsanto Technology Llc Method for the synthesis of aminoalkylenephosphonic acid
CN110771607A (zh) * 2019-10-09 2020-02-11 集美大学 一类n-羟甲基酰胺类抗菌剂及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE764270A (fr) * 1970-03-20 1971-08-02 Benckiser Gmbh Joh A Acide niril-tris-(methylenephosphonique) et son procede de preparation
US3853530A (en) * 1971-03-10 1974-12-10 Monsanto Co Regulating plants with n-phosphonomethylglycine and derivatives thereof
US4053505A (en) * 1976-01-05 1977-10-11 Monsanto Company Preparation of n-phosphonomethyl glycine
CH647528A5 (fr) * 1978-10-27 1985-01-31 Bcap Biolog Chem Act Pat Procede pour la preparation de n-phosphonomethylglycine.
HU184601B (en) * 1979-07-09 1984-09-28 Alkaloida Vegyeszeti Gyar Process for producing n-/phosphono-methyl/-glycine

Also Published As

Publication number Publication date
BR8303370A (pt) 1984-02-07
DE3365866D1 (en) 1986-10-09
CA1205487A (en) 1986-06-03
DK292283D0 (da) 1983-06-24
CS244948B2 (en) 1986-08-14
RO86524B (ro) 1985-03-30
IL69112A (en) 1987-10-20
IL69112A0 (en) 1983-10-31
EP0098159A2 (en) 1984-01-11
ES523690A0 (es) 1985-04-01
ES8507565A1 (es) 1985-09-01
PL140912B1 (en) 1987-06-30
DD212966A5 (de) 1984-08-29
IL80523A0 (en) 1987-02-27
ATE21903T1 (de) 1986-09-15
AU555801B2 (en) 1986-10-09
AU1631683A (en) 1984-01-05
ZA834740B (en) 1984-04-25
KR870001334B1 (ko) 1987-07-18
CS244939B2 (en) 1986-08-14
HU194256B (en) 1988-01-28
ES538163A0 (es) 1985-09-01
IL80523A (en) 1987-10-20
PL242729A1 (en) 1984-07-16
KR840005158A (ko) 1984-11-05
DK292283A (da) 1983-12-31
EP0098159A3 (en) 1984-03-21
JPS5913795A (ja) 1984-01-24
US4422982A (en) 1983-12-27
RO86524A (ro) 1985-03-15
EP0098159B1 (en) 1986-09-03

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