ES8504209A1 - Procedimiento para preparar n-fosfonometilglicina. - Google Patents
Procedimiento para preparar n-fosfonometilglicina.Info
- Publication number
- ES8504209A1 ES8504209A1 ES523690A ES523690A ES8504209A1 ES 8504209 A1 ES8504209 A1 ES 8504209A1 ES 523690 A ES523690 A ES 523690A ES 523690 A ES523690 A ES 523690A ES 8504209 A1 ES8504209 A1 ES 8504209A1
- Authority
- ES
- Spain
- Prior art keywords
- formil
- reacted
- formamide
- phosphonomethylglycine
- diethylphosphonometyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title abstract 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 abstract 3
- MGRVRXRGTBOSHW-UHFFFAOYSA-N (aminomethyl)phosphonic acid Chemical compound NCP(O)(O)=O MGRVRXRGTBOSHW-UHFFFAOYSA-N 0.000 abstract 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 abstract 2
- MNQOPPDTVHYCEZ-UHFFFAOYSA-N n-(hydroxymethyl)formamide Chemical compound OCNC=O MNQOPPDTVHYCEZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000004471 Glycine Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- QABLOFMHHSOFRJ-UHFFFAOYSA-N methyl 2-chloroacetate Chemical compound COC(=O)CCl QABLOFMHHSOFRJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000004702 methyl esters Chemical class 0.000 abstract 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Saccharide Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Abstract
PROCEDIMIENTO PARA PREPARAR N-FOSFONOMETILGLICINA.COMPRENDE LAS SIGUIENTES ETAPAS: PRIMERA, SE HACE REACCIONAR FORMALDEHIOO CON FORMAMIDA A UN PH COMPRENDIDO ENTRE 9 Y 10, PARA FORMAR N-(HIDROXIMETIL)FORMAMIDA; SEGUNDA, LA N-(HIDROXIMETIL)FORMAMIDA SE HACE REACCIONAR CON FOSFATO DE TRIETILO PARA OBTENER DIETIL-N-(FORMIL) AMINOMETILFOSFONATO; TERCERA, EL DIETIL-N-(FORMIL)AMINOMETILFOSFONATO SE HACE REACCIONAR CON CLOROACETATO DE METILO PARA FORMAR ESTER DE METILO DE N-(DIETILFOSFONOMETIL)-N-(FORMIL)GLICINA; Y POR ULTIMO, SE HACE REACCIONAR EL ESTER DE METILO DE N-(DIETILFOSFONOMETIL)-N-(FORMIL)GLICINA, CON UN AGENTE HIDROLIZANTE, PARA OBTENER LA N-FOSFONOMETILGLICINA.DE APLICACION COMO HERBICIDA Y COMO AGENTE REGULADOR DEL CRECIMIENTO DE LAS PLANTAS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/393,574 US4422982A (en) | 1982-06-30 | 1982-06-30 | Method for preparation of N-phosphonomethylglycine |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8504209A1 true ES8504209A1 (es) | 1985-04-01 |
ES523690A0 ES523690A0 (es) | 1985-04-01 |
Family
ID=23555297
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES523690A Granted ES523690A0 (es) | 1982-06-30 | 1983-06-29 | Procedimiento para preparar n-fosfonometilglicina. |
ES538163A Granted ES538163A0 (es) | 1982-06-30 | 1984-11-30 | Procedimiento para preparar n-fosfonometilglicina |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES538163A Granted ES538163A0 (es) | 1982-06-30 | 1984-11-30 | Procedimiento para preparar n-fosfonometilglicina |
Country Status (18)
Country | Link |
---|---|
US (1) | US4422982A (es) |
EP (1) | EP0098159B1 (es) |
JP (1) | JPS5913795A (es) |
KR (1) | KR870001334B1 (es) |
AT (1) | ATE21903T1 (es) |
AU (1) | AU555801B2 (es) |
BR (1) | BR8303370A (es) |
CA (1) | CA1205487A (es) |
CS (2) | CS244939B2 (es) |
DD (1) | DD212966A5 (es) |
DE (1) | DE3365866D1 (es) |
DK (1) | DK292283A (es) |
ES (2) | ES523690A0 (es) |
HU (1) | HU194256B (es) |
IL (3) | IL69112A (es) |
PL (1) | PL140912B1 (es) |
RO (1) | RO86524B (es) |
ZA (1) | ZA834740B (es) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES534413A0 (es) * | 1983-07-27 | 1986-01-01 | Rhone Poulenc Agrochimie | Procedimiento de preparacion de sulfonamidas con grupo ansinometilfosfonico |
FR2560198B1 (fr) * | 1984-02-23 | 1987-05-07 | Rhone Poulenc Agrochimie | Esters de la famille de la n-phosphonomethylglycine et leur utilisation pour la preparation d'herbicides connus |
US4548758A (en) * | 1984-08-30 | 1985-10-22 | Stauffer Chemical Company | Preparation of phosphonomethylated amino acids |
US4548759A (en) * | 1984-08-30 | 1985-10-22 | Stauffer Chemical Company | Preparation of phosphonomethylated amino acids |
US4921991A (en) * | 1985-02-22 | 1990-05-01 | Guy Lacroix | Preparation of esters of the N-phosphonomethylglycine and the N-phosphonomethyl glycines |
FR2611204B1 (fr) * | 1987-02-19 | 1989-05-05 | Rhone Poulenc Agrochimie | Composes intermediaires utiles pour la preparation d'herbicides |
US4830788A (en) * | 1987-11-20 | 1989-05-16 | Crompton & Knowles Corporation | Process for preparation of substituted-aminomethylphosphonic acids |
IN2015DN01080A (es) | 2012-07-17 | 2015-06-26 | Straitmark Holding Ag | |
CN104812766B (zh) | 2012-07-17 | 2017-06-06 | 斯特雷特马克控股股份公司 | 用于合成氨基亚烷基膦酸的方法 |
EP2875038A1 (en) | 2012-07-17 | 2015-05-27 | Straitmark Holding AG | Method for the synthesis of n-phosphonomethyliminodiacetic acid |
US20150232493A1 (en) | 2012-07-17 | 2015-08-20 | Straitmark Holding Ag | Method for the synthesis of alpha-aminoalkylenephosphonic acid |
CN110771607A (zh) * | 2019-10-09 | 2020-02-11 | 集美大学 | 一类n-羟甲基酰胺类抗菌剂及其制备方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE764270A (fr) * | 1970-03-20 | 1971-08-02 | Benckiser Gmbh Joh A | Acide niril-tris-(methylenephosphonique) et son procede de preparation |
US3853530A (en) * | 1971-03-10 | 1974-12-10 | Monsanto Co | Regulating plants with n-phosphonomethylglycine and derivatives thereof |
US4053505A (en) * | 1976-01-05 | 1977-10-11 | Monsanto Company | Preparation of n-phosphonomethyl glycine |
CH647528A5 (fr) * | 1978-10-27 | 1985-01-31 | Bcap Biolog Chem Act Pat | Procede pour la preparation de n-phosphonomethylglycine. |
HU184601B (en) * | 1979-07-09 | 1984-09-28 | Alkaloida Vegyeszeti Gyar | Process for producing n-/phosphono-methyl/-glycine |
-
1982
- 1982-06-30 US US06/393,574 patent/US4422982A/en not_active Expired - Fee Related
-
1983
- 1983-06-23 BR BR8303370A patent/BR8303370A/pt unknown
- 1983-06-24 DK DK292283A patent/DK292283A/da not_active Application Discontinuation
- 1983-06-28 PL PL1983242729A patent/PL140912B1/pl unknown
- 1983-06-28 AU AU16316/83A patent/AU555801B2/en not_active Ceased
- 1983-06-28 RO RO111440A patent/RO86524B/ro unknown
- 1983-06-28 JP JP58115298A patent/JPS5913795A/ja active Pending
- 1983-06-28 CA CA000431323A patent/CA1205487A/en not_active Expired
- 1983-06-29 DE DE8383303749T patent/DE3365866D1/de not_active Expired
- 1983-06-29 ES ES523690A patent/ES523690A0/es active Granted
- 1983-06-29 DD DD83252532A patent/DD212966A5/de unknown
- 1983-06-29 EP EP83303749A patent/EP0098159B1/en not_active Expired
- 1983-06-29 ZA ZA834740A patent/ZA834740B/xx unknown
- 1983-06-29 IL IL69112A patent/IL69112A/xx unknown
- 1983-06-29 IL IL80523A patent/IL80523A/xx unknown
- 1983-06-29 CS CS834849A patent/CS244939B2/cs unknown
- 1983-06-29 KR KR1019830002953A patent/KR870001334B1/ko not_active IP Right Cessation
- 1983-06-29 HU HU832357A patent/HU194256B/hu unknown
- 1983-06-29 AT AT83303749T patent/ATE21903T1/de not_active IP Right Cessation
-
1984
- 1984-04-20 CS CS843017A patent/CS244948B2/cs unknown
- 1984-11-30 ES ES538163A patent/ES538163A0/es active Granted
-
1986
- 1986-11-06 IL IL80523A patent/IL80523A0/xx unknown
Also Published As
Publication number | Publication date |
---|---|
BR8303370A (pt) | 1984-02-07 |
KR840005158A (ko) | 1984-11-05 |
US4422982A (en) | 1983-12-27 |
RO86524A (ro) | 1985-03-15 |
PL242729A1 (en) | 1984-07-16 |
AU1631683A (en) | 1984-01-05 |
DK292283D0 (da) | 1983-06-24 |
IL80523A (en) | 1987-10-20 |
DE3365866D1 (en) | 1986-10-09 |
HU194256B (en) | 1988-01-28 |
EP0098159B1 (en) | 1986-09-03 |
ES8507565A1 (es) | 1985-09-01 |
ES538163A0 (es) | 1985-09-01 |
DD212966A5 (de) | 1984-08-29 |
KR870001334B1 (ko) | 1987-07-18 |
EP0098159A2 (en) | 1984-01-11 |
IL80523A0 (en) | 1987-02-27 |
ES523690A0 (es) | 1985-04-01 |
IL69112A0 (en) | 1983-10-31 |
JPS5913795A (ja) | 1984-01-24 |
ATE21903T1 (de) | 1986-09-15 |
ZA834740B (en) | 1984-04-25 |
CS244939B2 (en) | 1986-08-14 |
AU555801B2 (en) | 1986-10-09 |
CA1205487A (en) | 1986-06-03 |
RO86524B (ro) | 1985-03-30 |
CS244948B2 (en) | 1986-08-14 |
IL69112A (en) | 1987-10-20 |
DK292283A (da) | 1983-12-31 |
EP0098159A3 (en) | 1984-03-21 |
PL140912B1 (en) | 1987-06-30 |
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