ES8500959A1 - Procedimiento para preparar n-fosfonometilglicina - Google Patents

Procedimiento para preparar n-fosfonometilglicina

Info

Publication number
ES8500959A1
ES8500959A1 ES523938A ES523938A ES8500959A1 ES 8500959 A1 ES8500959 A1 ES 8500959A1 ES 523938 A ES523938 A ES 523938A ES 523938 A ES523938 A ES 523938A ES 8500959 A1 ES8500959 A1 ES 8500959A1
Authority
ES
Spain
Prior art keywords
phosphonomethylglycine
compound
diketopiperazine
phosphonomethyl
reacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES523938A
Other languages
English (en)
Other versions
ES523938A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stauffer Chemical Co
Original Assignee
Stauffer Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stauffer Chemical Co filed Critical Stauffer Chemical Co
Publication of ES523938A0 publication Critical patent/ES523938A0/es
Publication of ES8500959A1 publication Critical patent/ES8500959A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/44—Amides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
    • C07F9/6509—Six-membered rings
    • C07F9/650952—Six-membered rings having the nitrogen atoms in the positions 1 and 4

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PROCEDIMIENTO PARA PREPARAR N-FOSFONOMETILGLICINA.COMPRENDE LAS ETAPAS SIGUIENTES: A) REACCIONAR 2,5-DICETOPIPERAZINA CON P-FORMALDEHIDO, AN/ADIR ENTONCES UN COMPUESTO DE FOSFORO SUSTITUIDO DE FORMULA PXYZ, EN DONDE X ES UN HALOGENO E Y Y Z SE ELIGEN INDEPENDIENTEMENTE ENTRE LOS HALOGENOS, EN PRESENCIA DE UN ACIDO CARBOXILICO DE BAJO PESO MOLECULAR COMO DISOLVENTE, PARA FORMAR EL COMPUESTO INTERMEDIO BIS-FOSFONOMETIL-2,5-DICETOPIPERAZINA; B) AISLAR DICHO COMPUESTO INTERMEDIO BIS-FOSFONOMETIL-2,5-DICETOPIPERAZINA; C) REACCIONAR EL COMPUESTO INTERMEDIO BIS-FOSFONOMETIL-2,5-DICETOPIPERAZINA CON UN AGENTE HIDROLIZANTE ELEGIDO ENTRE BASES ALCALINAS Y ALCALINOTERREAS PARA FORMAR UNA SAL DE N-FOSFONOMETILGLICINA; Y D) ACIDIFICAR DICHA SAL CON UN ACIDO MINERAL ADECUADO PARA CAUSAR LA FORMACION DEL PRODUCTO FINAL, N-FOSFONOMETILGLICINA.TIENE APLICACION COMO HERBICIDA Y COMO REGULADOR DEL CRECIMIENTO DE LAS PLANTAS.
ES523938A 1982-07-29 1983-07-07 Procedimiento para preparar n-fosfonometilglicina Expired ES8500959A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/403,239 US4400330A (en) 1982-07-29 1982-07-29 Method for preparation of N-phosphonomethylglycine

Publications (2)

Publication Number Publication Date
ES523938A0 ES523938A0 (es) 1984-11-01
ES8500959A1 true ES8500959A1 (es) 1984-11-01

Family

ID=23595035

Family Applications (1)

Application Number Title Priority Date Filing Date
ES523938A Expired ES8500959A1 (es) 1982-07-29 1983-07-07 Procedimiento para preparar n-fosfonometilglicina

Country Status (18)

Country Link
US (1) US4400330A (es)
EP (1) EP0102694B1 (es)
JP (1) JPS5929698A (es)
KR (1) KR840005460A (es)
AR (1) AR231451A1 (es)
AT (1) ATE29500T1 (es)
AU (1) AU552195B2 (es)
BR (1) BR8303922A (es)
CA (1) CA1205486A (es)
CS (1) CS235046B2 (es)
DD (1) DD213220A5 (es)
DE (1) DE3373479D1 (es)
DK (1) DK299483A (es)
ES (1) ES8500959A1 (es)
IL (1) IL69096A0 (es)
PL (1) PL140398B1 (es)
RO (1) RO87040B (es)
ZA (1) ZA834683B (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4578224A (en) * 1982-10-18 1986-03-25 Stauffer Chemical Company Method for preparation of salts of N-phosphonomethylglycine
DK467083A (da) * 1982-10-18 1984-04-19 Stauffer Chemical Co Fremgangsmaade til fremstilling af n-phosphonomethylglycin
CA1248531A (en) * 1984-04-17 1989-01-10 Jeffrey C. Watkins 4-substituted piperazine-2-carboxylic acids
US4694082A (en) * 1985-09-23 1987-09-15 Monsanto Company Compound 1,4-diisopropyl-2,5-diketopiperazine
US4694081A (en) * 1985-09-23 1987-09-15 Monsanto Company Process to prepare 2,5-diketopiperazines
US4804499A (en) * 1985-09-23 1989-02-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
US5352461A (en) * 1992-03-11 1994-10-04 Pharmaceutical Discovery Corporation Self assembling diketopiperazine drug delivery system
CN1239473A (zh) * 1997-02-13 1999-12-22 孟山都公司 制备氨基羧酸的方法
EP1104428A1 (en) * 1998-08-12 2001-06-06 Monsanto Company Continuous process for the preparation of n-(phosphonomethyl) iminodiacetic acid
WO2014012991A1 (en) 2012-07-17 2014-01-23 Straitmark Holding Ag Method for the synthesis of n-(phosphonomethyl)glycine
RU2015103314A (ru) * 2012-07-17 2016-09-10 Страйтмарк Холдинг Аг Способ синтеза N-фосфонометилиминодиуксусной кислоты
BR112015000990B1 (pt) 2012-07-17 2020-04-28 Monsanto Technology Llc Método para a síntese de um ácido aminoalquilenofosfônico ouseus ésteres fosfatos
RU2674022C9 (ru) 2012-07-17 2019-01-24 МОНСАНТО ТЕКНОЛОДЖИ ЭлЭлСи Способ синтеза альфа-аминоалкиленфосфоновой кислоты

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2959590A (en) * 1960-11-08 Chz-chz
CA775575A (en) * 1961-11-13 1968-01-09 R. Irani Riyad Organic phosphorus compounds
US3954761A (en) * 1968-10-17 1976-05-04 Petrolite Corporation Piperazine phosphonic acids
RO65811A (fr) * 1974-06-26 1979-07-15 Budapesti Vegyimuevek Procede pour obtenir du n-phosphonombethyl-glycine
DE2434312A1 (de) * 1974-07-17 1976-01-29 Bayer Ag Heterocyclische phosphonsaeureester
ES444490A1 (es) * 1975-01-16 1977-09-16 Chinoin Gyogyszer Es Vegyeszet Procedimiento para la fabricacion de n-fosfono-metilglicina y sus intermedios.
US4053505A (en) * 1976-01-05 1977-10-11 Monsanto Company Preparation of n-phosphonomethyl glycine

Also Published As

Publication number Publication date
AU552195B2 (en) 1986-05-22
CA1205486A (en) 1986-06-03
ZA834683B (en) 1985-02-27
RO87040A (ro) 1985-06-29
DK299483A (da) 1984-01-30
CS235046B2 (en) 1985-04-16
DK299483D0 (da) 1983-06-29
EP0102694A1 (en) 1984-03-14
EP0102694B1 (en) 1987-09-09
DD213220A5 (de) 1984-09-05
US4400330A (en) 1983-08-23
ES523938A0 (es) 1984-11-01
AU1627783A (en) 1984-02-02
AR231451A1 (es) 1984-11-30
ATE29500T1 (de) 1987-09-15
PL243175A1 (en) 1984-07-30
KR840005460A (ko) 1984-11-12
IL69096A0 (en) 1983-10-31
PL140398B1 (en) 1987-04-30
BR8303922A (pt) 1984-04-24
JPS5929698A (ja) 1984-02-16
DE3373479D1 (en) 1987-10-15
RO87040B (ro) 1985-06-30

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