ES8308223A1 - Procedimiento para la desulfuracion catalitica de un gas acido que contiene h2s. - Google Patents
Procedimiento para la desulfuracion catalitica de un gas acido que contiene h2s.Info
- Publication number
- ES8308223A1 ES8308223A1 ES518282A ES518282A ES8308223A1 ES 8308223 A1 ES8308223 A1 ES 8308223A1 ES 518282 A ES518282 A ES 518282A ES 518282 A ES518282 A ES 518282A ES 8308223 A1 ES8308223 A1 ES 8308223A1
- Authority
- ES
- Spain
- Prior art keywords
- desulphuration
- acid gas
- catalytic
- gas containing
- volume
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0456—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8612—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/053—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/046—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide
Abstract
PROCEDIMIENTO PARA LA DESULFURACION CATALITICA DE UN GAS ACIDO QUE CONTIENE H<2S, Y EVENTUALMENTE, UNA CANTIDAD GLOBAL DE COMO MAXIMO 3% EN VOLUMEN DE CS<2 Y/O COS, CON RECUPERACION DE ESTOS COMPUESTOS DE AZUFRE EN FORMA DE AZUFRE Y, EVENTUALMENTE, DE SO<2. SE PONE EL GAS ACIDO EN CONTACTO CON UNA CANTIDAD CONTROLADA DE OTRO GAS QUE CONTIENE OXIGENO LIBRE, PREFERENTEMENTE EN FORMA DE UNA MEZCLA, CON UN CATALIZADOR A BASE DE OXIDO DE TITANIO, A TEMPERATURAS COMPRENDIDAS ENTRE 100 C Y 600 C. EL CATALIZADOR ADEMAS DEL OXIDO DE TITANIO COMPRENDE UN SULFATO DE UN METAL ALCALINO-TERREO ELEGIDO DEL GRUPO FORMADO POR EL CALCIO, EL ESTRONCIO, EL BARIO Y EL MAGNESIO. TAMBIEN CONTIENE SILICE, ALUMINA, ARCILLAS, SILICATOS, SULFATO DE TITANIO O FIBRAS CERAMICAS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8123611A FR2518424B1 (fr) | 1981-12-17 | 1981-12-17 | Procede de desulfuration catalytique d'un gaz acide renfermant h2s, et eventuellement une quantite globale d'au plus 3 % en volume de cs2 et/ou cos |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8308223A1 true ES8308223A1 (es) | 1983-09-01 |
ES518282A0 ES518282A0 (es) | 1983-09-01 |
Family
ID=9265132
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES518282A Granted ES518282A0 (es) | 1981-12-17 | 1982-12-16 | Procedimiento para la desulfuracion catalitica de un gas acido que contiene h2s. |
Country Status (15)
Country | Link |
---|---|
US (1) | US4544534A (es) |
JP (1) | JPS58502089A (es) |
AT (1) | AT385431B (es) |
BE (1) | BE895359A (es) |
CA (1) | CA1200676A (es) |
DE (1) | DE3249259C3 (es) |
ES (1) | ES518282A0 (es) |
FR (1) | FR2518424B1 (es) |
GB (1) | GB2122597B (es) |
IT (1) | IT1155430B (es) |
NL (1) | NL194033C (es) |
NO (1) | NO160491C (es) |
SE (1) | SE439118B (es) |
SU (1) | SU1400494A3 (es) |
WO (1) | WO1983002068A1 (es) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2538716B1 (fr) * | 1983-01-03 | 1985-07-05 | Elf Aquitaine | Procede de desulfuration catalytique d'un gaz acide renfermant h2s, et eventuellement une quantite globale d'au plus 3 % en volume de cs2 et/ou cos |
FR2574309B1 (fr) * | 1984-12-12 | 1989-10-06 | Elf Aquitaine | Procede d'elimination des composes cos et cs2 contenus dans un gaz industriel |
FR2589082B1 (fr) * | 1985-10-25 | 1989-12-01 | Elf Aquitaine | Procede d'elimination des composes soufres contenus dans un gaz residuaire, notamment issu d'une usine a soufre claus, avec recuperation desdits composes sous la forme de soufre |
NL8901893A (nl) * | 1989-07-21 | 1991-02-18 | Veg Gasinstituut Nv | Katalysator voor de selectieve oxidatie van zwavelverbindingen tot elementaire zwavel, werkwijze voor de bereiding van een dergelijke katalysator en werkwijze voor de selectieve oxidatie van zwavelverbindingen tot elementaire zwavel. |
DE4109891A1 (de) * | 1991-03-26 | 1992-10-01 | Metallgesellschaft Ag | Verfahren zum erzeugen von elementarschwefel aus einem h(pfeil abwaerts)2(pfeil abwaerts)s enthaltenden gas |
DE4206913A1 (de) * | 1992-03-05 | 1993-09-09 | Kronos Titan Gmbh | Katalysator fuer die carbonylsulfid-hydrolyse |
US5242880A (en) * | 1992-05-27 | 1993-09-07 | Eastman Kodak Company | Photoactive catalyst of barium phosphate or calcium phosphate supported on anatase titanium dioxide |
FR2727101B1 (fr) * | 1994-11-17 | 1996-12-20 | Elf Aquitaine | Procede pour oxyder directement en soufre par voie catalytique l'h2s contenu en faible concentration dans un gaz et catalyseur pour la mise en oeuvre de ce procede |
US5603913A (en) * | 1995-05-17 | 1997-02-18 | Azerbaidzhanskaya Gosudarstvennaya Neftianaya Academiya | Catalysts and process for selective oxidation of hydrogen sulfide to elemental sulfur |
US5891415A (en) * | 1995-05-17 | 1999-04-06 | Azerbaidzhanskaya Gosudarstvennaya Neftianaya Academiya | Process for selective oxidation of hydrogen sulfide to elemental sulfur |
FR2757084B1 (fr) * | 1996-12-13 | 1999-01-29 | Rhodia Chimie Sa | Utilisation pour l'oxydation directe des composes soufres en soufre et/ou sulfates a basse temperature d'un catalyseur a base de molybdene |
FR2783818B1 (fr) | 1998-09-24 | 2000-11-10 | Elf Exploration Prod | Procede pour oxyder directement en soufre, par voie catalytique et en phase vapeur, l'h2s contenu a faible teneur dans un gaz |
FR2830466B1 (fr) * | 2001-10-09 | 2004-02-06 | Axens | Utilisation d'une composition a base de ti02 comme catalyseur pour realiser l'hydrolyse des cos et/ou d'hcn dans un melange gazeux |
US20100150805A1 (en) * | 2008-12-17 | 2010-06-17 | Uop Llc | Highly stable and refractory materials used as catalyst supports |
US20100135883A1 (en) * | 2008-12-17 | 2010-06-03 | Uop Llc | Catalyst supports |
US8691167B2 (en) | 2012-07-19 | 2014-04-08 | Tronox Llc | Process for controlling carbonyl sulfide produced during chlorination of ores |
DE102015005610A1 (de) * | 2015-04-30 | 2016-11-03 | CCP Technology GmbH | Vorrichtung und Verfahren zur Erzeugung eines Synthesegases |
CN106833783B (zh) * | 2017-01-06 | 2019-09-20 | 浙江海洋大学 | 一种天然气深度脱硫系统及其脱硫方法 |
CN108686489B (zh) | 2017-04-12 | 2021-01-01 | 北京华石联合能源科技发展有限公司 | 一种悬浮床湿法脱硫工艺 |
CN108686487B (zh) * | 2017-04-12 | 2021-01-01 | 北京华石联合能源科技发展有限公司 | 一种悬浮床与固定床的组合脱硫工艺 |
CN108686485B (zh) | 2017-04-12 | 2020-11-10 | 北京华石联合能源科技发展有限公司 | 一种可再生的高效悬浮床脱硫工艺 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1900751A (en) * | 1928-02-27 | 1933-03-07 | Ig Farbenindustrie Ag | Purification of gases |
GB622324A (en) * | 1947-03-01 | 1949-04-29 | Gas Light & Coke Co | Improvements in or relating to the catalytic oxidation of hydrogen sulphide in gaseous mixtures |
GB769996A (en) * | 1951-04-12 | 1957-03-13 | Gas Council | Improvements in or relating to the oxidation of hydrogen sulphide to sulphur dioxide |
DE2614307A1 (de) * | 1976-04-02 | 1977-10-13 | Union Oil Co | Verfahren zur beseitigung von schwefelwasserstoff aus gasstroemen |
FR2456543A1 (fr) * | 1979-05-15 | 1980-12-12 | Inst Francais Du Petrole | Procede d'epuration d'un gaz contenant du sulfure d'hydrogene |
US4269735A (en) * | 1980-01-21 | 1981-05-26 | Conoco, Inc. | Magnesium oxide catalyst |
FR2481145A1 (fr) * | 1980-04-23 | 1981-10-30 | Rhone Poulenc Ind | Procede de fabrication de catalyseurs ou de supports de catalyseurs faconnes a base d'oxyde de titane et leurs applications a la catalyse claus |
FR2481254A1 (fr) * | 1980-04-23 | 1981-10-30 | Elf Aquitaine | Procede pour l'incineration catalytique de gaz residuaires renfermant en faible concentration au moins un compose du soufre choisi parmi cos, cs2, et les mercaptans et eventuellement au moins un membre du groupe forme par h2s, so2, soufre vapeur et/ou vesiculaire |
FR2501662A1 (fr) * | 1981-03-13 | 1982-09-17 | Rhone Poulenc Spec Chim | Catalyseurs et procede d'oxydation de l'hydrogene sulfure et/ou des composes organiques du soufre en anhydride sulfureux |
FR2501532B1 (fr) * | 1981-03-13 | 1985-12-13 | Rhone Poulenc Spec Chim | Catalyseur et procede pour le traitement des gaz residuaires industriels contenant des composes du soufre |
-
1981
- 1981-12-17 FR FR8123611A patent/FR2518424B1/fr not_active Expired
-
1982
- 1982-12-10 JP JP83500021A patent/JPS58502089A/ja active Pending
- 1982-12-10 AT AT0906482A patent/AT385431B/de not_active IP Right Cessation
- 1982-12-10 NL NL8220457A patent/NL194033C/nl not_active IP Right Cessation
- 1982-12-10 US US06/537,385 patent/US4544534A/en not_active Expired - Lifetime
- 1982-12-10 WO PCT/FR1982/000208 patent/WO1983002068A1/en active Application Filing
- 1982-12-10 GB GB08321577A patent/GB2122597B/en not_active Expired
- 1982-12-10 DE DE3249259T patent/DE3249259C3/de not_active Expired - Lifetime
- 1982-12-15 BE BE0/209737A patent/BE895359A/fr not_active IP Right Cessation
- 1982-12-16 CA CA000417924A patent/CA1200676A/fr not_active Expired
- 1982-12-16 ES ES518282A patent/ES518282A0/es active Granted
- 1982-12-17 IT IT24820/82A patent/IT1155430B/it active
-
1983
- 1983-07-20 SE SE8304069A patent/SE439118B/sv not_active IP Right Cessation
- 1983-08-16 SU SU833632600A patent/SU1400494A3/ru active
- 1983-08-16 NO NO83832946A patent/NO160491C/no unknown
Also Published As
Publication number | Publication date |
---|---|
US4544534A (en) | 1985-10-01 |
WO1983002068A1 (en) | 1983-06-23 |
DE3249259C2 (de) | 1993-09-30 |
GB8321577D0 (en) | 1983-09-14 |
FR2518424B1 (fr) | 1988-03-11 |
NL194033B (nl) | 2001-01-02 |
FR2518424A1 (fr) | 1983-06-24 |
DE3249259T1 (de) | 1983-12-29 |
NO832946L (no) | 1983-08-16 |
GB2122597A (en) | 1984-01-18 |
NO160491B (no) | 1989-01-16 |
SE8304069L (sv) | 1983-07-20 |
IT8224820A1 (it) | 1984-06-17 |
CA1200676A (fr) | 1986-02-18 |
IT1155430B (it) | 1987-01-28 |
IT8224820A0 (it) | 1982-12-17 |
JPS58502089A (ja) | 1983-12-08 |
NL8220457A (nl) | 1983-11-01 |
SE8304069D0 (sv) | 1983-07-20 |
NO160491C (no) | 1989-04-26 |
ES518282A0 (es) | 1983-09-01 |
NL194033C (nl) | 2001-05-03 |
BE895359A (fr) | 1983-03-31 |
AT385431B (de) | 1988-03-25 |
DE3249259C3 (de) | 2000-04-20 |
SU1400494A3 (ru) | 1988-05-30 |
GB2122597B (en) | 1985-08-07 |
ATA906482A (de) | 1987-09-15 |
SE439118B (sv) | 1985-06-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 20020506 |