ES8303283A2 - Procedimiento para preparar esteres de m-fenoxibencilo de a-cido 2-haloalquil (oxi-,tio-,sulfinil-o sulfonil) fenilalcanoicos. - Google Patents

Procedimiento para preparar esteres de m-fenoxibencilo de a-cido 2-haloalquil (oxi-,tio-,sulfinil-o sulfonil) fenilalcanoicos.

Info

Publication number
ES8303283A2
ES8303283A2 ES478785A ES47878579A ES8303283A2 ES 8303283 A2 ES8303283 A2 ES 8303283A2 ES 478785 A ES478785 A ES 478785A ES 47878579 A ES47878579 A ES 47878579A ES 8303283 A2 ES8303283 A2 ES 8303283A2
Authority
ES
Spain
Prior art keywords
novel
acaracidal
insecticidal
agent
alpha
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES478785A
Other languages
English (en)
Other versions
ES478785A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/890,568 external-priority patent/US4199595A/en
Priority claimed from US05/890,721 external-priority patent/US4178460A/en
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of ES8303283A2 publication Critical patent/ES8303283A2/es
Publication of ES478785A0 publication Critical patent/ES478785A0/es
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34Nitriles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10Sulfones; Sulfoxides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00Antiparasitic agents
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/01Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/32Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/38Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by esterified hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00Compounds having —CHO groups
    • C07C47/52Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/575Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing ether groups, groups, groups, or groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/08Preparation of carboxylic acids or their salts, halides or anhydrides from nitriles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/363Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/367Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in singly bound form
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/58Preparation of carboxylic acid halides
    • C07C51/60Preparation of carboxylic acid halides by conversion of carboxylic acids or their anhydrides or esters, lactones, salts into halides with the same carboxylic acid part
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/612Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/612Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
    • C07C69/614Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety of phenylacetic acid

Abstract

PROCEDIMIENTO PARA LA OBTENCION DE ESTERES DE M-FENOXIBENCILO DE ACIDO 2-HALOALQUIL (OXI-, TIO-, SULFINIL- O SULFONIL) FENILALCANOICOS Y DE SUS ISOMEROS OPTICOS, DE FORMULA (I), EN LA QUE RCH X, Z E Y, PUEDEN SER VARIOS RADICALES, ESTAN EN POSICION META O PARA; Y R , R Y R PUEDEN SER VARIOS TIPOS DE RADICALES (CERTIFICADO DE ADICION DE LA PATENTE N 462.835). CONSISTE EN LA REACCION DE UN COMPUESTO DE FORMULA (II) CON UN COMPUESTO DE FORMULA (III), EN LAS QUE TODOS LOS SIMBOLOS TIENEN EL MISMO SIGNIFICADO QUE EN LA FORMULA (I). LA REACCION SE LLEVA A CABO EN UN DISOLVENTE ORGANICO INERTE, EN PRESENCIA DE UNA AMINA TERCIARIA, A UNA TEMPERATURA ENTRE 10 C Y 30 C. ESTOS COMPUESTOS TIENEN APLICACIONES EN AGRICULTURA COMO AGENTES PLAGUICIDAS.
ES1979478785A 1978-03-20 1979-03-20 Procedimiento para preparar esteres de m-fenoxibencilo de a-cido 2-haloalquil (oxi-,tio-,sulfinil-o sulfonil) fenilalcanoicos. Granted ES478785A0 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/890,568 US4199595A (en) 1976-10-01 1978-03-20 M-phenoxybenzyl and α-cyano-M-phenoxybenzyl esters of 2-haloalkyl (oxy-, thio-, sulfinyl-, or sulfonyl)phenylalkanoic acids
US05/890,721 US4178460A (en) 1976-10-01 1978-03-20 2-Haloalkyl(oxy-, thio-, sulfinyl-, or sulfonyl)-phenylalkanoic acids

Publications (2)

Publication Number Publication Date
ES8303283A2 true ES8303283A2 (es) 1983-02-01
ES478785A0 ES478785A0 (es) 1983-02-01

Family

ID=27128953

Family Applications (2)

Application Number Title Priority Date Filing Date
ES1979478785A Granted ES478785A0 (es) 1978-03-20 1979-03-20 Procedimiento para preparar esteres de m-fenoxibencilo de a-cido 2-haloalquil (oxi-,tio-,sulfinil-o sulfonil) fenilalcanoicos.
ES478787A Expired ES8105253A1 (es) 1978-03-20 1979-03-20 Procedimiento para preparar acidos fenilalcanoicos.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES478787A Expired ES8105253A1 (es) 1978-03-20 1979-03-20 Procedimiento para preparar acidos fenilalcanoicos.

Country Status (17)

Country Link
JP (1) JPS54135742A (es)
AR (1) AR228014A1 (es)
AT (1) AT367965B (es)
AU (2) AU525146B2 (es)
BR (1) BR7901697A (es)
CH (2) CH641638A5 (es)
DD (5) DD150455A6 (es)
DK (1) DK112679A (es)
ES (2) ES478785A0 (es)
GB (1) GB2017688B (es)
GR (1) GR74446B (es)
HU (1) HU182016B (es)
NL (1) NL7902153A (es)
NZ (1) NZ189915A (es)
PL (1) PL123011B1 (es)
RO (1) RO79551A (es)
SE (1) SE444313B (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2837524A1 (de) * 1978-08-28 1980-03-20 Bayer Ag Substituierte alpha-phenyl-carbonsaeure- (4-fluoro-3-phenoxy-benzyl)-ester, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide
IL61348A (en) * 1979-11-28 1984-05-31 American Cyanamid Co (-)-alpha-cyano-m-phenoxybenzyl(+)alpha-isopropyl-4-difluoromethoxy-phenylacetate,its preparation and its use as an insecticide
JPS56133253A (en) * 1980-03-24 1981-10-19 Sumitomo Chem Co Ltd Optical isomer of cyanohydrin ester, its production and insecticide and acaricide containing the same as effective ingredient
JPS56139445A (en) * 1980-04-02 1981-10-30 Sumitomo Chem Co Ltd Stereoisomer of cyanohydrin ester, its production and insecticide, acaricide containing the same as active principle
JPS5793948A (en) * 1980-12-02 1982-06-11 Sumitomo Chem Co Ltd Preparation of stereoisomer mixture of higher active phenylacetic ester derivative
DE3103325A1 (de) * 1981-01-31 1982-08-26 Bayer Ag, 5090 Leverkusen 4-fluor-3-halophenoxy-benzylester, verfahren zu deren herstellung und deren verwendung in schaedlingsbekaempfungsmitteln sowie neue zwischenprodukte und verfahren zu deren herstellung
FR2512815B1 (fr) * 1981-04-16 1989-04-14 Roussel Uclaf Nouveaux derives de l'acide cyclopropane carboxylique, leur procede de preparation, leur application a la lutte contre les parasites
IL69304A0 (en) * 1982-08-23 1983-11-30 American Cyanamid Co Method for the preparation of difluoromethoxyaromatic compounds

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5133612B2 (es) * 1973-04-19 1976-09-21 Sumitomo Chemical Co
IL52973A (en) * 1976-10-01 1983-10-31 American Cyanamid Co Alpha-(haloalkoxy and haloalkyl-thiophenyl)alkanoic acid ester derivatives,their preparation and insecticidal and acaricidal compositions containing them

Also Published As

Publication number Publication date
GB2017688A (en) 1979-10-10
BR7901697A (pt) 1979-10-16
CH640513A5 (de) 1984-01-13
AU528525B2 (en) 1983-05-05
DD154535A5 (de) 1982-03-31
JPS6362507B2 (es) 1988-12-02
GR74446B (es) 1984-06-28
DD152539A5 (de) 1981-12-02
JPS54135742A (en) 1979-10-22
SE444313B (sv) 1986-04-07
PL214234A3 (es) 1980-08-25
PL123011B1 (en) 1982-09-30
ES478787A0 (es) 1981-05-16
NZ189915A (en) 1981-04-24
DD150455A6 (de) 1981-09-02
AU525146B2 (en) 1982-10-21
RO79551A (ro) 1982-08-17
DD143601A5 (de) 1980-09-03
ES478785A0 (es) 1983-02-01
DD149601A6 (de) 1981-07-22
AR228014A1 (es) 1983-01-14
SE7902467L (es) 1979-11-19
AU4525179A (en) 1979-09-27
CH641638A5 (de) 1984-03-15
ATA204979A (de) 1982-01-15
AU4524279A (en) 1979-09-27
NL7902153A (nl) 1979-09-24
AT367965B (de) 1982-08-25
DK112679A (da) 1979-09-21
HU182016B (en) 1983-12-28
ES8105253A1 (es) 1981-05-16
GB2017688B (en) 1982-08-18

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