ES483613A1 - Procedimiento para la obtencion de esteres de acido fosforo-so - Google Patents
Procedimiento para la obtencion de esteres de acido fosforo-soInfo
- Publication number
- ES483613A1 ES483613A1 ES483613A ES483613A ES483613A1 ES 483613 A1 ES483613 A1 ES 483613A1 ES 483613 A ES483613 A ES 483613A ES 483613 A ES483613 A ES 483613A ES 483613 A1 ES483613 A1 ES 483613A1
- Authority
- ES
- Spain
- Prior art keywords
- polyamides
- stabilisers
- esters
- phosphorous acids
- phosphorous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004952 Polyamide Substances 0.000 title abstract 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 title abstract 2
- 229920002647 polyamide Polymers 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 title 1
- 239000003381 stabilizer Substances 0.000 title 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 abstract 1
- 229930185605 Bisphenol Natural products 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
- 230000000087 stabilizing effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6578—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and sulfur atoms with or without oxygen atoms, as ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/527—Cyclic esters
Abstract
Procedimiento para la obtención de ésteres de ácido fósforos, que preferentemente se emplean para la estabilización de poliaminas, caracterizado porque bisfenoles se hacen reaccionar con derivados del ácido fosforoso de fórmula PW3 donde W significa halógeno u OR7, donde R7 significa H, C1-C15 - alquilo C5-C6-cicloalquilo, C7-C15- aralquilo y C6-C10-arilo, donde R7 = H solo se puede presentar en cada caso una vez en POR7, y en caso dado compuestos mono- ó polihidroxílicos a temperaturas entre 50 y 300ºC y, en caso dado, los ésteres de ácido fosforoso obtenidos se incorporan antes, durante o después de la obtención de las poliamidas en una cantidad de un 0,02 hasta 5% en peso por co-extrusión, amasamiento, mezcla o agitación.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19782837027 DE2837027A1 (de) | 1978-08-24 | 1978-08-24 | Neue phosphorigsaeureester und ihre verwendung zur stabilisierung von polyamiden |
Publications (1)
Publication Number | Publication Date |
---|---|
ES483613A1 true ES483613A1 (es) | 1980-04-16 |
Family
ID=6047847
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES483613A Expired ES483613A1 (es) | 1978-08-24 | 1979-08-24 | Procedimiento para la obtencion de esteres de acido fosforo-so |
Country Status (6)
Country | Link |
---|---|
US (2) | US4252750A (es) |
EP (1) | EP0009115B1 (es) |
JP (2) | JPS5531091A (es) |
DE (2) | DE2837027A1 (es) |
DK (1) | DK352379A (es) |
ES (1) | ES483613A1 (es) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4351759A (en) * | 1978-01-03 | 1982-09-28 | Ciba-Geigy Corporation | Alkylated 2,2'-biphenylene phosphites and stabilized compositions |
DE2929229A1 (de) * | 1979-07-19 | 1981-02-12 | Bayer Ag | Stabilisierte thermoplastische formmassen |
JPS5699246A (en) * | 1980-01-10 | 1981-08-10 | Adeka Argus Chem Co Ltd | Stabilized synthetic resin composition |
GB2087399B (en) * | 1980-11-17 | 1983-11-02 | Ciba Geigy Ag | Polyol esters of alkylidine-2,2' -bisphenyl cyclic phosphites |
US4318845A (en) * | 1980-11-24 | 1982-03-09 | Ciba-Geigy Corporation | Alkanolamine esters of 1,1'-biphenyl-2,2'-diyl-and alkylidene-1,1'-biphenyl-2,2'-diyl-cyclic phosphites |
US4374219A (en) * | 1980-11-24 | 1983-02-15 | Ciba-Geigy Corporation | Alkanolamine ester of 1,1-biphenyl-2,2-diyl-and alkylidene-1,1-biphenyl-2,2-diyl-cyclic phosphites |
DE3204334A1 (de) * | 1982-02-09 | 1983-08-11 | Bayer Ag, 5090 Leverkusen | Witterungsstabile polyamide |
EP0110820B1 (de) * | 1982-11-01 | 1987-09-09 | Ciba-Geigy Ag | Aminosubstituierte Dibenzodioxaphosphepine und Dioxaphosphocine |
US4524166A (en) * | 1982-11-01 | 1985-06-18 | Ciba-Geigy Corporation | Primary or secondary amino substituted dibenzo dioxaphosphepins and dioxaphosphocins |
US4481317A (en) * | 1983-06-07 | 1984-11-06 | Adeka Argus Chemical Co., Ltd. | Hindered bisphenol diphosphonites and stabilized synthetic resin compositions containing the same |
US4670492A (en) * | 1983-12-01 | 1987-06-02 | Adeka Argus Chemical Co., Ltd. | Cyclic bis and tris phosphites and stabilized synthetic resin compositions |
US4599206A (en) * | 1984-02-17 | 1986-07-08 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
US4737588A (en) * | 1984-12-28 | 1988-04-12 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
US4748261A (en) * | 1985-09-05 | 1988-05-31 | Union Carbide Corporation | Bis-phosphite compounds |
US4668651A (en) * | 1985-09-05 | 1987-05-26 | Union Carbide Corporation | Transition metal complex catalyzed processes |
US4885401A (en) * | 1985-09-05 | 1989-12-05 | Union Carbide Corporation | Bis-phosphite compounds |
US4835299A (en) * | 1987-03-31 | 1989-05-30 | Union Carbide Corporation | Process for purifying tertiary organophosphites |
EP0292786B1 (de) * | 1987-05-23 | 1992-08-26 | Bayer Ag | Stabilisiertes Neopentylglykol-Polycarbonat |
JP2660419B2 (ja) * | 1988-04-02 | 1997-10-08 | 旭電化工業株式会社 | 安定化された合成樹脂組成物 |
US4929654A (en) * | 1988-10-04 | 1990-05-29 | Eastman Kodak Company | Cyclic phosphites and stabilized polymeric compositions |
JP2762101B2 (ja) * | 1989-03-07 | 1998-06-04 | 旭電化工業株式会社 | 安定化された合成樹脂組成物 |
JP2763569B2 (ja) * | 1989-03-13 | 1998-06-11 | 旭電化工業株式会社 | 安定化された合成樹脂組成物 |
US4956406A (en) * | 1989-08-03 | 1990-09-11 | Eastman Kodak Company | Bis-cyclic phosphite compounds and polymeric materials stabilized therewith |
KR0156247B1 (ko) * | 1989-08-09 | 1998-12-01 | 베르너 발데크 | 방염성 인 화합물 및 이를 함유하는 조성물과 그의 용도 |
US5380774A (en) * | 1989-11-28 | 1995-01-10 | Hoechst Celanese Corporation | Nylon molding compositions exhibiting improved protection against UV-light degradation |
US5310889A (en) * | 1992-07-22 | 1994-05-10 | Ciba-Geigy Corporation | Carbohydrate substituted dibenzo(d,f)(1,3,2)dioxaphosphepin stabilizers |
US5310890A (en) * | 1992-07-22 | 1994-05-10 | Ciba-Geigy Corporation | Carbohydrate substituted dibenzoi(d,g)(1,3,2)dioxaphosphocin stabilizers |
DE4309141A1 (de) * | 1993-03-22 | 1994-09-29 | Bayer Ag | Neue zyklische Phosphorigsäureester, ein Verfahren zu deren Herstellung sowie deren Verwendung |
JPH0841245A (ja) * | 1994-05-25 | 1996-02-13 | Sumitomo Chem Co Ltd | 安定化有機材料組成物 |
DE4431528A1 (de) * | 1994-09-03 | 1996-03-07 | Basf Ag | Verfahren zur Herstellung von n-Butyraldehyd und/oder n-Butanol |
EP0705874A1 (en) * | 1994-10-06 | 1996-04-10 | Ciba-Geigy Ag | Hydroxyaryl phosphite stabilized compositions |
US5475042A (en) * | 1995-03-21 | 1995-12-12 | Ciba-Geigy Corporation | Cyclic pyrophosphites and compositions stabilized therewith |
JP3766990B2 (ja) * | 1995-10-02 | 2006-04-19 | 住友化学株式会社 | 亜リン酸エステル類、その製造方法及びその用途 |
EP0816354A1 (de) * | 1996-06-25 | 1998-01-07 | Bayer Ag | Verfahren zur Herstellung und Stabilisierung von aliphatischen Sechsringcarbonaten |
TW482765B (en) * | 1996-08-05 | 2002-04-11 | Sumitomo Chemical Co | Phosphites, process for producing the same and their use |
US5969015A (en) * | 1996-09-25 | 1999-10-19 | Witco Vinyl Additives Gmbh | Monomeric and oligomeric bisphosphites as stabilisers for polyvinyl chloride |
TW200726805A (en) * | 2005-11-16 | 2007-07-16 | Sumitomo Chemical Co | Antioxidant composition excellent in anti-blocking property |
US7872156B2 (en) * | 2007-12-26 | 2011-01-18 | Eastman Chemical Company | Fluorophosphite containing catalysts for hydroformylation processes |
US7872157B2 (en) * | 2007-12-26 | 2011-01-18 | Eastman Chemical Company | Phosphonite containing catalysts for hydroformylation processes |
US7928267B1 (en) * | 2009-06-22 | 2011-04-19 | Eastman Chemical Company | Phosphite containing catalysts for hydroformylation processes |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3231531A (en) * | 1960-07-13 | 1966-01-25 | Ferro Corp | Polyvinyl chloride resins stabilized with a combination of a calcium salt, zinc salt, a phosphorus compound, and a sulphate or saccharin |
US3662032A (en) * | 1961-12-18 | 1972-05-09 | Argus Chem | Hydroxy containing aromatic phosphites |
FR1324451A (fr) * | 1962-04-04 | 1963-04-19 | Exxon Research Engineering Co | Stabilisant pour les polyoléfines |
US3297631A (en) * | 1965-10-24 | 1967-01-10 | Exxon Research Engineering Co | Novel phenolic phosphorus stabilizers for polyolefins |
DE1259094B (de) * | 1966-03-10 | 1968-01-18 | Bayer Ag | Stabilisierung von Polyamiden |
US3558554A (en) * | 1966-06-09 | 1971-01-26 | Yoshitomi Pharmaceutical | Oxidatively stable polyolefin composition |
DE1668883A1 (de) * | 1968-01-25 | 1971-02-11 | Dynamit Nobel Ag | Verfahren zur Herstellung von halogenierten Estern der Phosphorsaeuren |
DE1927271A1 (de) * | 1969-05-29 | 1970-12-03 | Badische Anilin & Soda Fabrk A | Verfahren zum kontinuierlichen Einarbeiten von Glasfasern in thermoplastische Kunststoffe in engem Schmelzbereich |
US3907939A (en) * | 1969-06-16 | 1975-09-23 | Ashland Oil Inc | Phosphite esters of hindered phenols |
SU378389A1 (ru) | 1971-02-08 | 1973-04-18 | Способ получения сополимеров стирола иакрилонитрила | |
GB1589611A (en) * | 1976-06-11 | 1981-05-13 | Exxon Research Engineering Co | Phosphorothionate derivatives and their use in lubricants |
SU582257A1 (ru) * | 1976-07-05 | 1977-11-30 | Казанский Химико-Технологический Институт Им.С.М.Кирова | Способ получени циклических арилфосфористых кислот |
US4196117A (en) * | 1978-01-03 | 1980-04-01 | Ciba-Geigy Corporation | Alkylated 1,1'-biphenyl-2,2'-diyl phosphites and stabilized compositions |
US4233208A (en) * | 1978-07-12 | 1980-11-11 | Ciba-Geigy Corporation | Polymer compositions stabilized with hindered phenyl secondary phosphites |
-
1978
- 1978-08-24 DE DE19782837027 patent/DE2837027A1/de not_active Withdrawn
-
1979
- 1979-08-13 EP EP79102928A patent/EP0009115B1/de not_active Expired
- 1979-08-13 DE DE7979102928T patent/DE2962815D1/de not_active Expired
- 1979-08-20 US US06/068,210 patent/US4252750A/en not_active Expired - Lifetime
- 1979-08-22 JP JP10613179A patent/JPS5531091A/ja active Granted
- 1979-08-23 DK DK362379A patent/DK352379A/da unknown
- 1979-08-24 ES ES483613A patent/ES483613A1/es not_active Expired
-
1980
- 1980-09-22 US US06/189,719 patent/US4348495A/en not_active Expired - Lifetime
-
1988
- 1988-09-14 JP JP63228889A patent/JPH01125391A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPH0259157B2 (es) | 1990-12-11 |
US4348495A (en) | 1982-09-07 |
JPH01125391A (ja) | 1989-05-17 |
DK352379A (da) | 1980-02-25 |
EP0009115A1 (de) | 1980-04-02 |
DE2962815D1 (en) | 1982-07-01 |
US4252750A (en) | 1981-02-24 |
JPS5531091A (en) | 1980-03-05 |
JPH0369914B2 (es) | 1991-11-05 |
DE2837027A1 (de) | 1980-03-06 |
EP0009115B1 (de) | 1982-05-12 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 20000201 |