ES478531A2 - Process for Treating a Sour- Petroleum Distillate - Google Patents
Process for Treating a Sour- Petroleum DistillateInfo
- Publication number
- ES478531A2 ES478531A2 ES478531A ES478531A ES478531A2 ES 478531 A2 ES478531 A2 ES 478531A2 ES 478531 A ES478531 A ES 478531A ES 478531 A ES478531 A ES 478531A ES 478531 A2 ES478531 A2 ES 478531A2
- Authority
- ES
- Spain
- Prior art keywords
- petroleum distillate
- phthalocyanine
- sour
- treating
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003209 petroleum derivative Substances 0.000 title abstract 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 abstract 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 230000000274 adsorptive effect Effects 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000003610 charcoal Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0204—Ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
- B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
- B01J2531/56—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
- B01J2540/30—Non-coordinating groups comprising sulfur
- B01J2540/32—Sulfonic acid groups or their salts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
The sweetening of a mercaptan- containing sour petroleum distillate by contacting with a supported metal phthalocyanine catalyst in the presence of an alkaline reagent at oxidation conditions is carried out using a catalyst which has been prepared by impregnating a solid adsorptive support (such as charcoal) with the phthalocyanine from an aqueous solution and/or dispersion of the phthalocyanine also containing from 5 to 50 wt. ppm morpholine.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/911,604 US4142964A (en) | 1977-08-01 | 1978-06-01 | Process for treating a sour petroleum distillate |
Publications (1)
Publication Number | Publication Date |
---|---|
ES478531A2 true ES478531A2 (en) | 1979-06-16 |
Family
ID=25430550
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES478531A Expired ES478531A2 (en) | 1978-06-01 | 1979-03-12 | Process for Treating a Sour- Petroleum Distillate |
Country Status (7)
Country | Link |
---|---|
JP (1) | JPS5811471B2 (en) |
CA (1) | CA1123359A (en) |
DE (1) | DE2908417C2 (en) |
ES (1) | ES478531A2 (en) |
FR (1) | FR2427377A2 (en) |
GB (1) | GB2027049B (en) |
IT (1) | IT1165010B (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6296388U (en) * | 1985-12-06 | 1987-06-19 | ||
US4753722A (en) * | 1986-06-17 | 1988-06-28 | Merichem Company | Treatment of mercaptan-containing streams utilizing nitrogen based promoters |
JPS63175581U (en) * | 1987-05-06 | 1988-11-15 | ||
FR2619822B1 (en) * | 1987-08-24 | 1990-01-12 | Inst Francais Du Petrole | PROCESS OF CONTINUOUS SOFTENING OF OIL CUTS IN LIQUID PHASE |
GB0908986D0 (en) | 2009-05-26 | 2009-07-01 | Univ Belfast | Process for removing organic acids from crude oil and crude oil distillates |
GB2484301B8 (en) * | 2010-10-05 | 2017-11-22 | The Queen's Univ Of Belfast | Process for removing metals from hydrocarbons |
CN109266402A (en) * | 2018-10-23 | 2019-01-25 | 唐钢美锦(唐山)煤化工有限公司 | A kind of do not stop production reduces the device and method of desulfurization pressure tower |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3408287A (en) * | 1966-04-20 | 1968-10-29 | Universal Oil Prod Co | Oxidation of mercaptans |
US4070307A (en) * | 1976-08-12 | 1978-01-24 | Uop Inc. | Method of catalyst manufacture |
US4100057A (en) * | 1977-08-01 | 1978-07-11 | Uop Inc. | Method of treating a sour petroleum distillate |
-
1979
- 1979-02-22 CA CA322,100A patent/CA1123359A/en not_active Expired
- 1979-03-02 GB GB7907432A patent/GB2027049B/en not_active Expired
- 1979-03-03 DE DE2908417A patent/DE2908417C2/en not_active Expired
- 1979-03-06 JP JP54026058A patent/JPS5811471B2/en not_active Expired
- 1979-03-12 ES ES478531A patent/ES478531A2/en not_active Expired
- 1979-03-23 IT IT21259/79A patent/IT1165010B/en active
- 1979-06-01 FR FR7914144A patent/FR2427377A2/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5811471B2 (en) | 1983-03-03 |
GB2027049B (en) | 1982-11-24 |
FR2427377B2 (en) | 1983-12-23 |
CA1123359A (en) | 1982-05-11 |
GB2027049A (en) | 1980-02-13 |
IT7921259A0 (en) | 1979-03-23 |
FR2427377A2 (en) | 1979-12-28 |
DE2908417A1 (en) | 1979-12-06 |
IT1165010B (en) | 1987-04-22 |
DE2908417C2 (en) | 1982-03-25 |
JPS54157104A (en) | 1979-12-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4124493A (en) | Catalytic oxidation of mercaptan in petroleum distillate including alkaline reagent and substituted ammonium halide | |
US2853432A (en) | Regeneration of used alkaline reagents by oxidizing the same in the presence of a phthalocyanine catalyst | |
US4159964A (en) | Metal chelate catalyst and alkanolamine hydroxide on adsorptive support | |
US4070307A (en) | Method of catalyst manufacture | |
US4127474A (en) | Treating a petroleum distillate with an alkanolamine hydroxide and a supported oxidation catalyst impregnated with polynuclear aromatic sulfonic acid | |
ES478531A2 (en) | Process for Treating a Sour- Petroleum Distillate | |
SU784792A3 (en) | Method of purifying oil distillates from sulfuric compounds and catalyst poisons | |
US4028269A (en) | Process for the preparation of a solid bed catalyst system | |
SU1382404A3 (en) | Method and catalytic agent for purifying mercaptan-containing hydrocarbon fractions | |
US4248694A (en) | Process for treating a sour petroleum distillate | |
US4100057A (en) | Method of treating a sour petroleum distillate | |
US4260479A (en) | Catalytic oxidation of mercaptan in sour petroleum distillate | |
IE43118L (en) | Treatment of mercaptan-containing petroleum distillates | |
ES471694A1 (en) | Process for the recovery of gallium from very basic solutions by liquid/liquid extraction. | |
US4121997A (en) | Treating a petroleum distillate with a supported metal phthalocyanine and an alkaline reagent containing alkanolamine halide | |
ES8308916A1 (en) | A method of refining sour hydrocarbon distillates. | |
US4168245A (en) | Preparation of a supported metal phthalocyanine catalyst | |
GB996500A (en) | Process and catalyst for the preparation of hydrocarbon oils completely or substantially completely freed from mercaptans | |
KR820002013B1 (en) | Method for treating sour petroleum distillates | |
KR820000539B1 (en) | Catalytic composite particularly useful for oxiclation of mercaptans contained in sour petroleum distillate | |
JO1044B1 (en) | Process for treating sour petroleum distillates | |
KR920006485A (en) | Softening acidic petroleum distillate using a fixed bed at a temperature between about 125 ° C. and about 350 ° C. | |
GB944054A (en) | Process for the preparation of hydrocarbon oils, entirely or substantially entirely freed from mercaptans | |
ES456480A1 (en) | Process for sweetening sour hydrocarbon distillates | |
GB1068544A (en) | Process for treating sour hydrocarbon distillates |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD2A | Announcement of lapse in spain |
Effective date: 20170707 |