FR2427377A2 - IMPROVED PROCESS FOR TREATMENT OF A CORROSIVE PETROLEUM DISTILLATE - Google Patents

IMPROVED PROCESS FOR TREATMENT OF A CORROSIVE PETROLEUM DISTILLATE

Info

Publication number
FR2427377A2
FR2427377A2 FR7914144A FR7914144A FR2427377A2 FR 2427377 A2 FR2427377 A2 FR 2427377A2 FR 7914144 A FR7914144 A FR 7914144A FR 7914144 A FR7914144 A FR 7914144A FR 2427377 A2 FR2427377 A2 FR 2427377A2
Authority
FR
France
Prior art keywords
treatment
petroleum distillate
improved process
corrosive petroleum
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7914144A
Other languages
French (fr)
Other versions
FR2427377B2 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/911,604 external-priority patent/US4142964A/en
Application filed by UOP LLC filed Critical UOP LLC
Publication of FR2427377A2 publication Critical patent/FR2427377A2/en
Application granted granted Critical
Publication of FR2427377B2 publication Critical patent/FR2427377B2/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/30—Non-coordinating groups comprising sulfur
    • B01J2540/32—Sulfonic acid groups or their salts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

L'invention a pour objet un procédé de traitement d'un distillat de pétrole corrosif qui constitue un perfectionnement du procédé décrit dans le brevet principal. On met en contact le distillat avec une phtalocyanine métallique déposée sur un support, utilisée comme catalyseur, en présence d'un réactif alcalin et dans des conditions oxydantes, le catalyseur ayant été préparé par imprégnation d'un support adsorbant solide à partir d'une solution aqueuse d'imprégnation de la phtalocyanine métallique contenant de 5 à 50 ppm en poids de morpholine. Traitement des kérosènes et autres distillats pour les débarrasser des mercaptans.The subject of the invention is a process for treating a corrosive petroleum distillate which constitutes an improvement of the process described in the main patent. The distillate is contacted with a metallic phthalocyanine deposited on a support, used as a catalyst, in the presence of an alkaline reagent and under oxidizing conditions, the catalyst having been prepared by impregnation of a solid adsorbent support from a solid adsorbent support. aqueous solution for impregnating the metal phthalocyanine containing from 5 to 50 ppm by weight of morpholine. Treatment of kerosene and other distillates to rid them of mercaptans.

FR7914144A 1978-06-01 1979-06-01 IMPROVED PROCESS FOR TREATMENT OF A CORROSIVE PETROLEUM DISTILLATE Granted FR2427377A2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/911,604 US4142964A (en) 1977-08-01 1978-06-01 Process for treating a sour petroleum distillate

Publications (2)

Publication Number Publication Date
FR2427377A2 true FR2427377A2 (en) 1979-12-28
FR2427377B2 FR2427377B2 (en) 1983-12-23

Family

ID=25430550

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7914144A Granted FR2427377A2 (en) 1978-06-01 1979-06-01 IMPROVED PROCESS FOR TREATMENT OF A CORROSIVE PETROLEUM DISTILLATE

Country Status (7)

Country Link
JP (1) JPS5811471B2 (en)
CA (1) CA1123359A (en)
DE (1) DE2908417C2 (en)
ES (1) ES478531A2 (en)
FR (1) FR2427377A2 (en)
GB (1) GB2027049B (en)
IT (1) IT1165010B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987007904A1 (en) * 1986-06-17 1987-12-30 Merichem Company Treatment of mercaptan-containing streams utilizing nitrogen based promoters

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6296388U (en) * 1985-12-06 1987-06-19
JPS63175581U (en) * 1987-05-06 1988-11-15
FR2619822B1 (en) * 1987-08-24 1990-01-12 Inst Francais Du Petrole PROCESS OF CONTINUOUS SOFTENING OF OIL CUTS IN LIQUID PHASE
GB0908986D0 (en) * 2009-05-26 2009-07-01 Univ Belfast Process for removing organic acids from crude oil and crude oil distillates
GB2484301B8 (en) 2010-10-05 2017-11-22 The Queen's Univ Of Belfast Process for removing metals from hydrocarbons
CN109266402A (en) * 2018-10-23 2019-01-25 唐钢美锦（唐山）煤化工有限公司 A kind of do not stop production reduces the device and method of desulfurization pressure tower

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3408287A (en) * 1966-04-20 1968-10-29 Universal Oil Prod Co Oxidation of mercaptans
US4070307A (en) * 1976-08-12 1978-01-24 Uop Inc. Method of catalyst manufacture
FR2399476A1 (en) * 1977-08-01 1979-03-02 Uop Inc PROCESS FOR TREATING A CORROSIVE PETROLEUM DISTILLATE

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3408287A (en) * 1966-04-20 1968-10-29 Universal Oil Prod Co Oxidation of mercaptans
US4070307A (en) * 1976-08-12 1978-01-24 Uop Inc. Method of catalyst manufacture
FR2399476A1 (en) * 1977-08-01 1979-03-02 Uop Inc PROCESS FOR TREATING A CORROSIVE PETROLEUM DISTILLATE

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987007904A1 (en) * 1986-06-17 1987-12-30 Merichem Company Treatment of mercaptan-containing streams utilizing nitrogen based promoters

Also Published As

Publication number Publication date
CA1123359A (en) 1982-05-11
JPS54157104A (en) 1979-12-11
FR2427377B2 (en) 1983-12-23
DE2908417C2 (en) 1982-03-25
GB2027049B (en) 1982-11-24
DE2908417A1 (en) 1979-12-06
JPS5811471B2 (en) 1983-03-03
GB2027049A (en) 1980-02-13
IT7921259A0 (en) 1979-03-23
ES478531A2 (en) 1979-06-16
IT1165010B (en) 1987-04-22

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