ES468080A1 - Un procedimiento para eliminar sustancialmente la acumula- cion de polimeros - Google Patents
Un procedimiento para eliminar sustancialmente la acumula- cion de polimerosInfo
- Publication number
- ES468080A1 ES468080A1 ES468080A ES468080A ES468080A1 ES 468080 A1 ES468080 A1 ES 468080A1 ES 468080 A ES468080 A ES 468080A ES 468080 A ES468080 A ES 468080A ES 468080 A1 ES468080 A1 ES 468080A1
- Authority
- ES
- Spain
- Prior art keywords
- reaction vessel
- condensation product
- coating
- internally coated
- polyhydric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
- C08F2/004—Scale prevention in a polymerisation reactor or its auxiliary parts by a prior coating on the reactor walls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/31—Monomer units or repeat units incorporating structural elements in the main chain incorporating aromatic structural elements in the main chain
- C08G2261/312—Non-condensed aromatic systems, e.g. benzene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Materials For Medical Uses (AREA)
Abstract
Esta invención se refiere a una vasija de reacción de polimerización con un recubrimiento sobre sus superficies internas, resultante de la aplicación de una composición de recubrimiento que contiene, como ingrediente fundamental, (1) el producto de autocondensación de un fenol polihídrico, (2) el producto de condensación de dcs o más fenoles polihídricos o (3) el producto de autocondensación de un naftol polihídrico, disuelto en una solución acuosa de un hidróxido de metal alcalino. En la polimerización de monómeros olefínicos, como haluros de vinilo, haluros de vinilideno y monómeros vinilidénicos que contienen por lo menos un grupo CH2=Cmayor que terminal, y mezclas de los mismos, en presencia de dicho recubrimiento, se elimina sustancialmente la acumulación de polímeros sobre las superficies internas de la vasija de reacción. Además, pueden realizarse múltiples cargas o lotes de polímero en dicha vasija de reacción recubierta internamente, sin abrir la misma entre cargas, evitando así que escape a la atmósfera circundante el monómero que no ha reaccionado.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/807,959 US4080173A (en) | 1977-06-20 | 1977-06-20 | Internally coated reaction vessel for use in olefinic polymerization |
Publications (1)
Publication Number | Publication Date |
---|---|
ES468080A1 true ES468080A1 (es) | 1979-09-01 |
Family
ID=25197525
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES468080A Expired ES468080A1 (es) | 1977-06-20 | 1978-03-20 | Un procedimiento para eliminar sustancialmente la acumula- cion de polimeros |
Country Status (26)
Country | Link |
---|---|
US (1) | US4080173A (es) |
JP (1) | JPS547487A (es) |
AT (1) | AT363684B (es) |
AU (1) | AU516968B2 (es) |
BE (1) | BE865096A (es) |
BR (1) | BR7801707A (es) |
CA (1) | CA1109342A (es) |
CH (1) | CH628524A5 (es) |
DE (1) | DE2826681A1 (es) |
DK (1) | DK151887C (es) |
ES (1) | ES468080A1 (es) |
FR (1) | FR2395280B1 (es) |
GB (1) | GB1576198A (es) |
GR (1) | GR64568B (es) |
IN (1) | IN147318B (es) |
IT (1) | IT1111456B (es) |
MX (1) | MX148167A (es) |
NL (1) | NL176858C (es) |
NO (1) | NO155492C (es) |
NZ (1) | NZ186709A (es) |
PH (1) | PH13108A (es) |
PT (1) | PT67795A (es) |
SE (1) | SE444516B (es) |
TR (1) | TR20103A (es) |
YU (1) | YU40032B (es) |
ZA (1) | ZA782062B (es) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1589404A (en) * | 1976-12-23 | 1981-05-13 | Ici Australia Ltd | Halogenated a-olefin polymerisation process and reactor therefor |
US4182808A (en) * | 1978-08-25 | 1980-01-08 | The B. F. Goodrich Company | Inversion polymerization process for producing vinyl resins using a dual layer coating |
AU526104B2 (en) * | 1978-09-08 | 1982-12-16 | Geon Company, The | Polymerization of vinyl chloride |
US4200712A (en) * | 1978-10-23 | 1980-04-29 | The B. F. Goodrich Company | Coating polymerization reactors with oligomer coatings derived from reaction products of substituted phenols |
US4228130A (en) * | 1978-10-23 | 1980-10-14 | The B. F. Goodrich Company | Coating polymerization reactors with oligomers derived from polyhydric phenols plus a bleach |
US4297320A (en) * | 1979-04-30 | 1981-10-27 | The B. F. Goodrich Company | Coating polymerization reactors with the reaction products of thiodiphenols and a bleach |
CA1147098A (en) * | 1979-04-30 | 1983-05-24 | Louis Cohen | Coating polymerization reactors with the reaction products of thiodiphenols and a bleach |
US4267291A (en) * | 1979-09-14 | 1981-05-12 | The B. F. Goodrich Company | Process for coating reactors using organic compound vapor application |
US4263421A (en) * | 1979-09-14 | 1981-04-21 | The B. F. Goodrich Company | Process for coating reactors using organic compound vapor application |
JPS578207A (en) * | 1980-06-17 | 1982-01-16 | Tokuyama Sekisui Kogyo Kk | Suspension polymerization of vinyl chloride |
WO1982000645A1 (en) * | 1980-08-25 | 1982-03-04 | Co B F Goodrich | Internally coated reaction vessel for use in emulsion polymerization of olefinic monomers |
DE3175656D1 (en) * | 1980-10-31 | 1987-01-15 | Ici Plc | Vinyl chloride polymerisation process |
EP0070296B1 (en) * | 1981-01-16 | 1987-03-25 | The B.F. GOODRICH Company | Internally coated reaction vessel for use in olefinic polymerization |
WO1982002555A1 (en) * | 1981-01-16 | 1982-08-05 | Co B F Goodrich | Internally coated reaction vessel for use in olefinic polymerization |
GB2101498B (en) * | 1981-05-22 | 1984-09-19 | Kanegafuchi Chemical Ind | A process for polymerizing vinyl chloride |
GR77680B (es) * | 1981-07-27 | 1984-09-25 | Goodrich Co B F | |
US4432840A (en) * | 1982-04-26 | 1984-02-21 | Formosa Plastics Corporation | Prevention of polymer buildup in polymerization reactors using thin organic coatings by electrolysis of phenol |
FR2527102A1 (fr) * | 1982-05-19 | 1983-11-25 | Chloe Chemie | Procede de traitement d'un reacteur de polymerisation |
US4659791A (en) * | 1984-09-11 | 1987-04-21 | The B.F. Goodrich Company | Internally coated reaction vessel for use in olefinic polymerization |
US4719089A (en) * | 1984-09-11 | 1988-01-12 | The B. F. Goodrich Company | Internally coated reaction vessel for use in olefinic polymerization |
US4588613A (en) * | 1984-10-10 | 1986-05-13 | Formosa Plastics Corporation | Process for reducing polymer buildup |
US4680349A (en) * | 1985-01-14 | 1987-07-14 | Toyo Soda Manufacturing Co., Ltd. | Method of polymerizing vinyl monomers with coated reactor |
JPH0739445B2 (ja) * | 1988-12-07 | 1995-05-01 | 信越化学工業株式会社 | 重合体スケールの付着防止方法 |
JP2831412B2 (ja) * | 1989-12-28 | 1998-12-02 | 三井化学株式会社 | 塩化ビニルの重合方法 |
US5194301A (en) * | 1990-08-09 | 1993-03-16 | Investigacion Y Desarrollo, C.A. | Process for reducing scale formation in vinyl polymerization reactors |
US5139823A (en) * | 1990-08-09 | 1992-08-18 | Investigacion Y Desarrollo C.A. | Process for reducing scale formation in vinyl polymerization reactors |
DE69408215T2 (de) * | 1993-06-15 | 1998-06-10 | Shinetsu Chemical Co | Polymerablagerungsinhibitor |
CA2138182C (en) * | 1993-12-27 | 1996-11-12 | Seiichi Masuko | Polymerization process of vinyl chloride |
DE69501137T2 (de) | 1994-09-14 | 1998-04-09 | Shinetsu Chemical Co | Verfahren zur Herstellung von einem Vinyl-Chlorid-Typ Polymer |
US5780104A (en) * | 1995-12-28 | 1998-07-14 | Mitsui Chemicals, Inc. | Method for preventing the inner wall surfaces of the polymerization apparatus from being fouled with scale during the polymerizatioin of vinyl chloride |
KR100779640B1 (ko) | 2001-12-12 | 2007-11-27 | 가부시끼가이샤 도꾸야마 | 스케일 부착 방지제, 그 제조 방법 및 그것을 내벽면에도포한 중합 반응기 및 이 중합 반응기를 사용한 비닐계중합체의 제조 방법 |
JP4554602B2 (ja) * | 2004-03-11 | 2010-09-29 | 株式会社クラレ | スケール付着防止剤 |
CN109369831A (zh) * | 2018-09-12 | 2019-02-22 | 蓝凤祥 | 一种不需清釜的防冻型多元酚黄色防粘釜剂及其制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3340160A (en) * | 1964-06-23 | 1967-09-05 | Phillips Petroleum Co | Composition and method for inhibiting the formation of polymers during fractional distillation |
US3825434A (en) * | 1972-10-27 | 1974-07-23 | Goodrich Co B F | Internally coated reaction vessel and process for coating the same |
US3849179A (en) * | 1973-08-27 | 1974-11-19 | Goodrich Co B F | Internally coated reaction vessel and process for coating the same |
US4007320A (en) * | 1974-05-21 | 1977-02-08 | Kemanord Aktiebolag | Process for reducing polymer build-up |
US4024330A (en) * | 1975-04-08 | 1977-05-17 | The B. F. Goodrich Company | Internally coated reaction vessel and process for coating the same |
CA1077197A (en) * | 1975-03-24 | 1980-05-06 | Kazuhiko Kurimoto | Method for bulk polymerization of vinyl chloride |
US4024301A (en) * | 1975-05-02 | 1977-05-17 | The B. F. Goodrich Company | Internally coated reaction vessel for use in olefinic polymerization |
GB1589404A (en) * | 1976-12-23 | 1981-05-13 | Ici Australia Ltd | Halogenated a-olefin polymerisation process and reactor therefor |
-
1977
- 1977-06-20 US US05/807,959 patent/US4080173A/en not_active Expired - Lifetime
-
1978
- 1978-03-16 NZ NZ186709A patent/NZ186709A/xx unknown
- 1978-03-17 CA CA299,215A patent/CA1109342A/en not_active Expired
- 1978-03-17 IN IN285/CAL/78A patent/IN147318B/en unknown
- 1978-03-17 GR GR55730A patent/GR64568B/el unknown
- 1978-03-20 DK DK124978A patent/DK151887C/da active
- 1978-03-20 ES ES468080A patent/ES468080A1/es not_active Expired
- 1978-03-20 PT PT67795A patent/PT67795A/pt unknown
- 1978-03-20 BE BE186100A patent/BE865096A/xx not_active IP Right Cessation
- 1978-03-20 AU AU34324/78A patent/AU516968B2/en not_active Expired
- 1978-03-20 MX MX172844A patent/MX148167A/es unknown
- 1978-03-20 BR BR7801707A patent/BR7801707A/pt unknown
- 1978-03-20 GB GB10865/78A patent/GB1576198A/en not_active Expired
- 1978-03-20 JP JP3117478A patent/JPS547487A/ja active Granted
- 1978-03-20 NL NLAANVRAGE7802989,A patent/NL176858C/xx not_active IP Right Cessation
- 1978-03-20 YU YU667/78A patent/YU40032B/xx unknown
- 1978-03-20 NO NO780996A patent/NO155492C/no unknown
- 1978-03-21 CH CH305078A patent/CH628524A5/fr not_active IP Right Cessation
- 1978-03-23 IT IT67649/78A patent/IT1111456B/it active
- 1978-04-11 ZA ZA00782062A patent/ZA782062B/xx unknown
- 1978-04-17 FR FR7811269A patent/FR2395280B1/fr not_active Expired
- 1978-04-25 TR TR20103A patent/TR20103A/xx unknown
- 1978-05-04 PH PH21101A patent/PH13108A/en unknown
- 1978-06-08 SE SE7806683A patent/SE444516B/sv not_active IP Right Cessation
- 1978-06-19 DE DE19782826681 patent/DE2826681A1/de active Granted
- 1978-06-19 AT AT0445378A patent/AT363684B/de not_active IP Right Cessation
Also Published As
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