ES464010A1 - Procedimiento continuo de sintesis de un halogenuro organo- metalico. - Google Patents

Procedimiento continuo de sintesis de un halogenuro organo- metalico.

Info

Publication number
ES464010A1
ES464010A1 ES464010A ES464010A ES464010A1 ES 464010 A1 ES464010 A1 ES 464010A1 ES 464010 A ES464010 A ES 464010A ES 464010 A ES464010 A ES 464010A ES 464010 A1 ES464010 A1 ES 464010A1
Authority
ES
Spain
Prior art keywords
halide
organometallic
rmx
group
processes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES464010A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Orkem SA
Original Assignee
Chimique des Charbonnages SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chimique des Charbonnages SA filed Critical Chimique des Charbonnages SA
Publication of ES464010A1 publication Critical patent/ES464010A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C01F5/26—Magnesium halides
    • C01F5/30—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/02—Halides of titanium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
    • C07F3/02—Magnesium compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Glass Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Procedimiento continuo de síntesis de un halogenuro organometálico de fórmula: ***(ver fórmula) en el que a >0,45, b>0,15 y c>0,30, X es un halógeno, R es un radical hidrocarbonado tal como un radical alifático, saturado, cicloalifático, aromático, alifático insaturado, alquilarilo, arilalquilo, alcoxialquilo, alcoxiarilo y heterocíclico, M es un metal elegido entre el magnesio, el zinc el berilio y el calcio, mediante reacción bajo atmósfera de gas inerte y seco entre un monohalogenuro orgánico RX y el metal M, encontrándose dicho metal en exceso molar con relación a dicho monohalogenuro.
ES464010A 1976-11-09 1977-11-10 Procedimiento continuo de sintesis de un halogenuro organo- metalico. Expired ES464010A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7633757A FR2370054A1 (fr) 1976-11-09 1976-11-09 Reactifs de grignard, leur procede de preparation et leur application a la synthese d'halogenure de magnesium anhydre

Publications (1)

Publication Number Publication Date
ES464010A1 true ES464010A1 (es) 1978-11-16

Family

ID=9179700

Family Applications (2)

Application Number Title Priority Date Filing Date
ES473049A Expired ES473049A1 (es) 1976-11-09 1976-11-09 Procedimiento de sintesis de halogenuro de magnesio anhidro
ES464010A Expired ES464010A1 (es) 1976-11-09 1977-11-10 Procedimiento continuo de sintesis de un halogenuro organo- metalico.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES473049A Expired ES473049A1 (es) 1976-11-09 1976-11-09 Procedimiento de sintesis de halogenuro de magnesio anhidro

Country Status (16)

Country Link
US (3) US4187254A (es)
JP (1) JPS5359628A (es)
AU (1) AU521017B2 (es)
BE (1) BE860580A (es)
BR (1) BR7707472A (es)
CA (1) CA1126482A (es)
CH (2) CH629213A5 (es)
DE (1) DE2749983A1 (es)
ES (2) ES473049A1 (es)
FR (1) FR2370054A1 (es)
GB (1) GB1561730A (es)
IN (2) IN147281B (es)
IT (1) IT1091035B (es)
NL (1) NL7712360A (es)
NO (4) NO773824L (es)
TR (1) TR20857A (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2370054A1 (fr) * 1976-11-09 1978-06-02 Charbonnages Ste Chimique Reactifs de grignard, leur procede de preparation et leur application a la synthese d'halogenure de magnesium anhydre
FR2424760A1 (fr) * 1978-05-05 1979-11-30 Charbonnages Ste Chimique Catalyseurs comprenant du magnesium et un metal de transition
FR2464922A1 (fr) * 1979-09-13 1981-03-20 Charbonnages Ste Chimique Procede de reduction d'halogenures metalliques en phase vapeur par des composes organomagnesiens solides et produits reduits obtenus
DE3244972C1 (de) * 1982-12-04 1984-02-09 Condea Chemie GmbH, 2212 Brunsbüttel Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Aluminiumalkoholaten
US4764347A (en) * 1983-04-05 1988-08-16 Milligan John D Grid plate assembly for ebullated bed reactor
DE3722993A1 (de) * 1987-07-11 1989-01-19 Studiengesellschaft Kohle Mbh Loesliche magnesiumdihydride, verfahren zu ihrer herstellung und ihre verwendung
GB9126339D0 (en) * 1991-12-11 1992-02-12 Ici Plc Chemical process
US6395840B1 (en) * 1997-10-03 2002-05-28 Southwest Research Institute Precursor polymers to refractory metal carbides and metal borides
DE19757499A1 (de) * 1997-12-23 1999-06-24 Studiengesellschaft Kohle Mbh Verfahren zur Synthese von Organomagnesium-Verbindungen unter Einsatz von Katalysatoren
CN102093396B (zh) * 2010-12-27 2012-07-25 浙江新和成股份有限公司 一种格氏试剂的制备方法
US9815918B2 (en) 2012-03-19 2017-11-14 Formosa Plastics Corporation, U.S.A. Catalyst component for high activity and high stereoselectivity in olefin polymerization
WO2021056193A1 (zh) * 2019-09-24 2021-04-01 凯莱英医药集团（天津）股份有限公司 一种苄基卤化锌及其衍生物的连续制备方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1992090A (en) * 1930-12-22 1935-02-19 Pestalozza Paolo Process for mixing gases and solids
US2066198A (en) * 1932-02-26 1936-12-29 Standard Oil Dev Co Process for preparing grignard compounds
US2464685A (en) * 1946-12-02 1949-03-15 Diamond Alkali Co Continuous grignard method
DE847595C (de) * 1951-03-17 1952-08-25 Richard Dipl-Chem Bauer Verfahren zur Herstellung von Grignardverbindungen
US2852544A (en) * 1955-10-26 1958-09-16 Phillips Petroleum Co Preparation of organometallic halides
GB955806A (en) * 1959-04-29 1964-04-22 Nat Res Dev Preparation and use of organomagnesium materials
US3144473A (en) * 1959-08-17 1964-08-11 Shell Oil Co Method for preparing zinc dialkyls suitable for use in polymerization catalysts
US3140321A (en) * 1960-02-16 1964-07-07 Cincinnati Milling Machine Co Preparation of grignard reagents in predominantly hydrocarbon media
US3137714A (en) * 1960-10-27 1964-06-16 Exxon Research Engineering Co Preparation of organomercurials
US3095460A (en) * 1961-10-25 1963-06-25 Dow Chemical Co Preparation of stabilized magnesium alkyls
GB1051394A (es) * 1964-10-06
NL162921B (nl) * 1969-01-10 1980-02-15 Montedison Spa Werkwijze om een katalysator te bereiden voor de polymerisatie van alkenen-1.
US3641081A (en) * 1969-01-21 1972-02-08 Int Lead Zinc Res Process for preparing dialkylzinc compounds from alkylbromide
US3766280A (en) * 1970-10-28 1973-10-16 Lithium Corp Diorganomagnesium reagents and methods of preparing same
US3755478A (en) * 1971-08-18 1973-08-28 Lithium Corp Cyclic process for the preparation of diorganomagnesium compounds
FR2370054A1 (fr) * 1976-11-09 1978-06-02 Charbonnages Ste Chimique Reactifs de grignard, leur procede de preparation et leur application a la synthese d'halogenure de magnesium anhydre
FR2424760A1 (fr) * 1978-05-05 1979-11-30 Charbonnages Ste Chimique Catalyseurs comprenant du magnesium et un metal de transition
FR2464922A1 (fr) * 1979-09-13 1981-03-20 Charbonnages Ste Chimique Procede de reduction d'halogenures metalliques en phase vapeur par des composes organomagnesiens solides et produits reduits obtenus
SU1449139A1 (ru) * 1986-01-21 1989-01-07 Ставропольский государственный педагогический институт Акробатическа дорожка

Also Published As

Publication number Publication date
CH628903A5 (fr) 1982-03-31
FR2370054A1 (fr) 1978-06-02
US4474703A (en) 1984-10-02
CA1126482A (fr) 1982-06-29
CH629213A5 (fr) 1982-04-15
NO773824L (no) 1978-05-10
JPS5359628A (en) 1978-05-29
AU521017B2 (en) 1982-03-11
AU3027777A (en) 1979-05-10
NL7712360A (nl) 1978-05-11
US4366140A (en) 1982-12-28
BR7707472A (pt) 1978-06-20
DE2749983A1 (de) 1978-05-11
BE860580A (fr) 1978-05-08
NO823382L (no) 1978-05-10
GB1561730A (en) 1980-02-27
US4187254A (en) 1980-02-05
NO823381L (no) 1978-05-10
IN147281B (es) 1980-01-19
TR20857A (tr) 1982-11-01
NO840514L (no) 1978-05-10
FR2370054B1 (es) 1980-11-07
ES473049A1 (es) 1979-10-16
IT1091035B (it) 1985-06-26
IN149351B (es) 1981-10-31

Similar Documents

Publication Publication Date Title
ES473049A1 (es) Procedimiento de sintesis de halogenuro de magnesio anhidro
ES470502A1 (es) Un procedimiento para la polimerizacion e las alfas-olefinas
KR840002400A (ko) 7-옥사비시클로헵탄 및 7-옥사비시클로헵텐 프로스타글라딘 동족체의 제조방법
ES8601797A1 (es) Procedimiento de fabricacion de hidruros de silicio por hidrolisis acida de aleaciones ternarias de silicio
GB754869A (en) Improvements in or relating to the production of titanium
WO1987007899A1 (en) Process for producing stereoregular polyolefins
ES8600418A1 (es) Procedimiento para preparar magnesio sumamente reactivo y finamente dividido a partir de hidruro de magnesio
JPS51136625A (en) Process for preparation of titanium double compound
ZA835253B (en) Method for preparing a catalyst
ES8204403A1 (es) Un procedimiento para la oxihidrocloracion catalica de hidrocarburos en lecho fluido, para producir hidrocarburos clora-dos.
ES8303450A1 (es) "procedimiento para la preparacion de 17a-alcohil-17b-hidroxi-1a-metil-4-androsten-3-onas".
JPS5249921A (en) Equipment for poducing metallic titanium
GB813663A (en) A process for the production of metals and non-metals
ES471394A1 (es) Procedimiento para la polimerizacion y copolimerizacion de monoolefinas
DE3071567D1 (en) Catalytic component and process for its preparation
DE3168532D1 (en) Process for the production of 3-amino-4,6-diacetyl phenol or a derivative thereof
ES8304162A1 (es) "procedimiento para la polimerizacion de una 1-olefina".
DE3174614D1 (en) Pharmaceutical compositions containing androstenes
KR880000455A (ko) 주석알콕시드의 제조방법
Samuels et al. Synthesis and reactions of η5-C5H5Fe (CO) 2 (acetylene)+ BF4− complexes
US3642849A (en) Method of preparing tetramethyllead
GB755083A (en) Improvements in or relating to production of refractory metals
EP0102086A3 (en) Alpha-substituted-alpha-fluoro-alpha-cyanoacetic acid or its derivatives
JPS5545638A (en) Exo-5-halomethyl-endo-2,3-trimethylene norbornane
GB955860A (en) A method for continuously manufacturing aluminum