ES456177A1 - Procedimiento para la obtencion de materiales espumados en poliisocianurato termoconformables. - Google Patents

Procedimiento para la obtencion de materiales espumados en poliisocianurato termoconformables.

Info

Publication number
ES456177A1
ES456177A1 ES456177A ES456177A ES456177A1 ES 456177 A1 ES456177 A1 ES 456177A1 ES 456177 A ES456177 A ES 456177A ES 456177 A ES456177 A ES 456177A ES 456177 A1 ES456177 A1 ES 456177A1
Authority
ES
Spain
Prior art keywords
thermoformable
polyisocyanurate foams
production
polyethers
reacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES456177A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of ES456177A1 publication Critical patent/ES456177A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
    • C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
    • C08G18/8012—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with diols
    • C08G18/8019—Masked aromatic polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/902—Cellular polymer containing an isocyanurate structure
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31547—Of polyisocyanurate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

Procedimiento para la obtención de materiales espumados de poliisocianurato termo-conformables por reacción de compuestos que llevan grupos hidroxilo con un exceso de poliisocianatos en presencia de catalizadores de trimerización de isocianato, agentes de propulsión y, en caso dado, ulteriores agentes auxiliares para la espumación, caracterizado porque como poliisocianato se emplea un polimetilenpolifenilpoliisocianato, que contiene como mínimo un 80% en peso de diisocianatodifenilmetano y porque como compuestos que llevan grupos hidroxilo se emplean: a) poliéteres, que llevan como mínimo un grupo hidroxilo, del índice OH 26 - 112, cuya proporción en óxido alquilénico se compone en como mínimo un 20% en peso, preferentemente un 30 a 50% en peso de restos de óxido etilénico y b) dialcoholes con un peso molecular de 62 hasta 200, empleándose el poliéter, que contiene como mínimo un grupo hidroxilo, en una cantidad de 0,015 hasta 0,04 equivalentes de OH y los dialcoholes en una cantidad de 0,2hasta 0,4 equivalentes de OH por equivalente de NCO.
ES456177A 1976-02-24 1977-02-23 Procedimiento para la obtencion de materiales espumados en poliisocianurato termoconformables. Expired ES456177A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2607380A DE2607380C3 (de) 1976-02-24 1976-02-24 Verfahren zur Herstellung von warmformbaren Polyisocyanuratschaumstoffen

Publications (1)

Publication Number Publication Date
ES456177A1 true ES456177A1 (es) 1978-01-16

Family

ID=5970687

Family Applications (1)

Application Number Title Priority Date Filing Date
ES456177A Expired ES456177A1 (es) 1976-02-24 1977-02-23 Procedimiento para la obtencion de materiales espumados en poliisocianurato termoconformables.

Country Status (10)

Country Link
US (1) US4129697A (es)
JP (1) JPS52103495A (es)
BE (1) BE851698A (es)
BR (1) BR7700994A (es)
DE (1) DE2607380C3 (es)
ES (1) ES456177A1 (es)
GB (1) GB1517673A (es)
IT (1) IT1083472B (es)
NL (1) NL7701943A (es)
SE (1) SE434161B (es)

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4169921A (en) * 1973-01-11 1979-10-02 The Celotex Corporation Polyisocyanurate
US4125505A (en) * 1976-07-06 1978-11-14 Union Carbide Corporation Polymer/polyols from high ethylene oxide content polyols
DE2722400C2 (de) * 1977-05-17 1985-05-30 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von wärmebeständigen, blasenfreien Isocyanuratgruppen aufweisenden Kunststoffen
US4212917A (en) * 1978-06-01 1980-07-15 The Celotex Corporation Polyisocyanurate foam laminate
US4311801A (en) * 1978-06-01 1982-01-19 The Celotex Corporation Polyisocyanurate foam and process therefor
JPS5552313A (en) * 1978-10-09 1980-04-16 Takeda Chem Ind Ltd Manufacture of urethane-modified rigid isocyanurate foam
JPS5565214A (en) * 1978-11-10 1980-05-16 Bridgestone Corp Preparation of flame-resistant polyisocyanurate foam
DE2856456A1 (de) * 1978-12-28 1980-07-17 Basf Ag Verfahren zur herstellung von polyurethan-hartschaumstoffen
DE2915474C2 (de) * 1979-04-17 1986-05-15 Hans-Georg Ring Biegesteifer Verbundschichtstoff, Verfahren zu seiner Herstellung, sowie Verwendung als Fertighimmel für Automobile
US4272618A (en) * 1979-04-30 1981-06-09 Texaco Development Corp. Heat stable reaction injection molded elastomers
US4299924A (en) * 1979-08-10 1981-11-10 Toyota Jidosha Kogyo Kabushiki Kaisha Polyisocyanurate resin and process for making the same
US4362678A (en) * 1980-01-18 1982-12-07 The Celotex Corporation Method of making polyisocyanurate foam laminate
DE3139395C2 (de) * 1981-10-03 1984-09-13 Bayer Ag, 5090 Leverkusen Verfahren zum Verfestigen von geologischen Gesteins-, Erd- und Kohleformationen
DE3276117D1 (en) * 1982-06-01 1987-05-27 Dow Chemical Co Polyurethane and urethane-modified isocyanurate foams and a method for their preparation
US4401769A (en) * 1982-06-23 1983-08-30 Sealed Air Corporation Foam, composition and method useful for retrofit insulation
US4430840A (en) * 1982-06-23 1984-02-14 Sealed Air Corporation Foam, composition and method useful for retrofit insulation
US4425446A (en) 1982-06-23 1984-01-10 Sealed Air Corporation Urea-modified isocyanurate foam, composition and method
US4444913A (en) * 1982-11-18 1984-04-24 Thermocell Development, Ltd. Modified polyisocyanurate foam and method of preparation
DE3309127A1 (de) * 1983-03-15 1984-09-20 Basf Ag, 6700 Ludwigshafen Zellige polyurethan-formkoerper, verfahren zu deren herstellung durch thermoplastische verformung von polyester-polyurethan-schaumstoffen sowie deren verwendung
US4607064A (en) * 1983-05-16 1986-08-19 The Dow Chemical Company Polyurethane and urethane-modified isocyanurate foams and a polyol composition useful in their preparation
US4520042A (en) * 1983-06-20 1985-05-28 Thermocell Development, Ltd. High-modulus, flexible urethane coating and method of preparation
US4661529A (en) * 1984-08-09 1987-04-28 The Dow Chemical Company Polyurethane and urethane-modified isocyanurate foams and a polyol composition useful in their preparation
JPH0621147B2 (ja) * 1985-09-27 1994-03-23 三井東圧化学株式会社 硬質ポリウレタンフオ−ムの製造法
US4623673A (en) * 1985-10-24 1986-11-18 The Dow Chemical Company Urethane-modified polyisocyanurate rigid foam
DE3610961A1 (de) * 1986-04-02 1987-10-08 Bayer Ag Thermisch verformbare pur-hartschaumstoffe, ein verfahren zu ihrer herstellung und ihre verwendung zur herstellung von automobilinnenverkleidung
DE3737524C2 (de) * 1987-11-05 1994-12-22 Bayer Ag Verfahren zur Herstellung von Skikernen
DE3942468A1 (de) * 1989-12-22 1991-06-27 Bayer Ag Verfahren zur herstellung von formkoerpern oder folien aus vernetzten polyisocyanat-polyadditionsprodukten und die so erhaltenen formkoerper
US5251849A (en) * 1989-12-26 1993-10-12 Florida International University For Board Of Regents Strain reduced airplane skin
DE4001249A1 (de) * 1990-01-18 1991-07-25 Bayer Ag Verfahren zur herstellung von offenzelligen, kaltverformbaren polyurethan-hartschaumstoffen und deren verwendung zur herstellung von autohimmeln
US5057544A (en) * 1990-11-16 1991-10-15 Basf Corporation Integral skin rigid urethane foam
CA2071030A1 (en) * 1991-06-17 1992-12-18 Kenneth P. Klapper Thermoformable polyisocyanurate foam laminates for interior finishing applications
US5260344A (en) * 1992-03-13 1993-11-09 Asahi Glass Company, Ltd. Open cell rigid isocyanurate foams and method for producing the same and vacuum heat insulating layer by use of the same
FR2737433B1 (fr) * 1995-08-02 1997-10-31 Maillet Orthopedie Sarl Procede de fabrication par moulage d'un siege notamment d'un siege orthopedique et siege obtenu
US6723761B1 (en) * 1996-02-15 2004-04-20 Bose Corporation Microcellular foaming
US6722611B1 (en) * 1999-09-20 2004-04-20 Kuang-Hsi Wu Reinforced aircraft skin and method
JP2002155125A (ja) * 2000-11-20 2002-05-28 Sumika Bayer Urethane Kk ポリウレタン変性ポリイソシアヌレートフォームの製造方法
EP1358240A1 (en) 2000-12-27 2003-11-05 World Properties, Inc. Polyurethane foams and method of manafacture thereof
US6990754B2 (en) * 2002-08-05 2006-01-31 R. G. Barry Corporation Slipper insole, slipper, and method for manufacturing a slipper
US6931763B2 (en) * 2002-08-05 2005-08-23 R.G. Barry Corporation Slipper insole, slipper, and method for manufacturing a slipper
EP1631606B1 (en) 2003-06-12 2011-08-24 Huntsman International Llc Process for preparing a polyisocyanurate polyurethane material
US7238730B2 (en) * 2003-06-26 2007-07-03 Basf Corporation Viscoelastic polyurethane foam
US7208531B2 (en) * 2003-06-26 2007-04-24 Basf Corporation Viscoelastic polyurethane foam
US20040266900A1 (en) * 2003-06-26 2004-12-30 Raymond Neff Viscoelastic polyurethane foam
US20070033835A1 (en) * 2005-08-02 2007-02-15 Bray Walter T Jr Insole arrangement; footwear with insole arrangement; and, method of preparation
BRPI0616666B1 (pt) * 2005-10-13 2017-06-06 Huntsman Int Llc processo para a preparação de um material de poliisocianurato poliuretano elastomérico, e, material
BRPI0616662B1 (pt) * 2005-10-13 2017-06-13 Huntsman International Llc Process for the preparation of a solid material of polyesocyanurate polyurethane, and, material
AU2007217657B2 (en) * 2006-02-21 2011-08-04 Huntsman International Llc Process for making a polyisocyanurate composite
CA2653656C (en) * 2006-06-14 2013-11-19 Huntsman International Llc Composite panel
EP2015014A1 (de) * 2007-07-11 2009-01-14 Bayer MaterialScience AG Verfahren zur Trocknung von Schäumen aus wässrigen PUR-Dispersionen
JP5986838B2 (ja) * 2011-07-28 2016-09-06 株式会社東洋クオリティワン 吸音衝撃吸収材及びその製造方法
CN102875770B (zh) * 2012-09-20 2014-03-26 吴江市天源塑胶有限公司 一种耐高温的改性聚异氰脲酸酯泡沫塑料的制备方法
CN109053993A (zh) * 2018-08-08 2018-12-21 浙江清优材料科技有限公司 一种动力电池电芯用防护材料
DE102018217545A1 (de) * 2018-10-12 2020-04-16 BSH Hausgeräte GmbH Verfahren und Haushaltsgerät
WO2024133871A1 (en) 2022-12-23 2024-06-27 Recticel Pir chemical recycling by alkaline cleavage

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3745133A (en) * 1968-02-05 1973-07-10 Upjohn Co Cellular isocyanurate containing polymers
US3644232A (en) * 1968-05-24 1972-02-22 Mobay Chemical Corp Flame-resistant, nonbursting polyisocyanurate foams
US3676380A (en) * 1969-05-19 1972-07-11 Upjohn Co Low friability polyisocyanurate foams
FR2086977A5 (es) * 1970-04-15 1971-12-31 Naphtachimie Sa
US3857800A (en) * 1970-06-19 1974-12-31 Dunlop Holdings Ltd Flexible polyurethane foams prepared from a mixture of polyether polyols
BE792706A (nl) * 1972-01-13 1973-06-14 Shell Int Research Compositie geschikt voor toepassing in stijve isocyanuraten en werkwijze ter bereiding van dergelijke stijve isocyanuraten
JPS48101497A (es) * 1972-04-04 1973-12-20
US3836424A (en) * 1972-07-18 1974-09-17 R Grieve Polyisocyanurate foam articles
US4009130A (en) * 1975-06-11 1977-02-22 Texaco Development Corporation Preparation of isocyanurate foams using alkali metal tertiaryamino dithiocarbamate salt catalysts

Also Published As

Publication number Publication date
DE2607380A1 (de) 1977-08-25
JPS546280B2 (es) 1979-03-27
IT1083472B (it) 1985-05-21
DE2607380C3 (de) 1981-07-23
JPS52103495A (en) 1977-08-30
SE434161B (sv) 1984-07-09
US4129697A (en) 1978-12-12
BE851698A (fr) 1977-08-22
GB1517673A (en) 1978-07-12
BR7700994A (pt) 1977-10-18
SE7702008L (sv) 1977-08-25
DE2607380B2 (de) 1980-09-18
NL7701943A (nl) 1977-08-26

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