ES449928A1 - Fungicidal and biocidal compositions - Google Patents
Fungicidal and biocidal compositionsInfo
- Publication number
- ES449928A1 ES449928A1 ES449928A ES449928A ES449928A1 ES 449928 A1 ES449928 A1 ES 449928A1 ES 449928 A ES449928 A ES 449928A ES 449928 A ES449928 A ES 449928A ES 449928 A1 ES449928 A1 ES 449928A1
- Authority
- ES
- Spain
- Prior art keywords
- general formula
- group
- atom
- compound
- hydrogen atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000003115 biocidal effect Effects 0.000 title 1
- 230000000855 fungicidal effect Effects 0.000 title 1
- 239000000203 mixture Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 5
- 125000004429 atom Chemical group 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 229910052751 metal Chemical group 0.000 abstract 3
- 239000002184 metal Chemical group 0.000 abstract 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 3
- SKZKKFZAGNVIMN-UHFFFAOYSA-N Salicilamide Chemical compound NC(=O)C1=CC=CC=C1O SKZKKFZAGNVIMN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- -1 alkoxycarbonyl chloride Chemical compound 0.000 abstract 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 2
- 125000004457 alkyl amino carbonyl group Chemical group 0.000 abstract 2
- 125000004448 alkyl carbonyl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- 229960000581 salicylamide Drugs 0.000 abstract 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001266 acyl halides Chemical class 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 150000001350 alkyl halides Chemical class 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 239000013067 intermediate product Substances 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- HFFLGKNGCAIQMO-UHFFFAOYSA-N trichloroacetaldehyde Chemical compound ClC(Cl)(Cl)C=O HFFLGKNGCAIQMO-UHFFFAOYSA-N 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Peptides Or Proteins (AREA)
Abstract
A process for preparing derivatives of N-β, β-dichloro vinyl) salicylamide, represented by the formula **(See formula)** where X represents a hydrogen atom, chlorine atom, bromine atom, methyl group or nitro group, Y represents hydrogen atom, methyl group, an alkylcarbonyl group where the alkyl group has from 1 to 12 carbon atoms, preferably from 1 to 3 carbon atoms and can be substituted by one or more halogen atoms, a group lower alkoxycarbonyl, a lower alkylaminocarbonyl group or a metal atom whose valence is 1 or 2, Z represents hydrogen atom or chlorine atom and n represents 1 or 2, but when X and Z represent hydrogen atom, Y does not represent hydrogen atom or the metal atom, characterized in that in a first phase, chloral and a salicylamide of the general formula (II) are reacted under the action of heat **(See formula)** to constitute the condensation intermediate product of the general formula (III) **(See formula)** and, in a second phase of the process, converting the compound of the general formula (III) to the compound of the general formula (I) by reducing said compound of the general formula (III) with zinc in a solvent medium, preferably selected from acetic acid, methanol or ethanol, at a temperature between room temperature and 120ºC, provided that: - when Y in the general formula (I) is a methyl group, an alkylcarbonyl group where the alkyl group has 1 to 12 carbon atoms and can be substituted by one or more halogen atoms, a lower alkoxycarbonyl group or a lower alkylaminocarbonyl group, the compound of the general formula (IV) is obtained in said reduction which is reacted with an alkyl halide, an acyl halide, an alkoxycarbonyl chloride or an alkyl isocyanate in the presence of a base preferably selected from trimethylamine or triethylamine, in an inert solvent at a temperature between 5º and 120ºC; O well - when Y in the general formula (I) is the metallic atom, except an alkali metal, the compound of the general formula (IV), previously obtained, is reacted with a halide, an acetate or a sulfate of said metallic atom O well - when the Y metal of the general formula (I) is an alkali metal, the compound of the general formula (IV), previously obtained, is reacted with an alkali metal hydroxide in water. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP50088088A JPS5215823A (en) | 1975-07-18 | 1975-07-18 | Germicide for agriculture and gardening |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES449928A1 true ES449928A1 (en) | 1977-12-01 |
Family
ID=13933099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES449928A Expired ES449928A1 (en) | 1975-07-18 | 1976-07-17 | Fungicidal and biocidal compositions |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5215823A (en) |
| CA (1) | CA1061250A (en) |
| DE (1) | DE2631709A1 (en) |
| ES (1) | ES449928A1 (en) |
| FR (1) | FR2317879A1 (en) |
| GB (1) | GB1518378A (en) |
| IT (1) | IT1066045B (en) |
| NL (1) | NL7607862A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6058905B2 (en) * | 1978-08-25 | 1985-12-23 | 日本化薬株式会社 | New 2-hydroxybenzamide derivative and soil fungicide |
| WO2007114273A1 (en) * | 2006-03-30 | 2007-10-11 | Nippon Steel Engineering Co., Ltd. | Bubble-dividing apparatus for slurry bed bubble column and slurry bed bubble column |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5112926A (en) * | 1974-07-19 | 1976-01-31 | Nippon Kayaku Kk | Kogyoyosatsukin bokabizai |
| US4055639A (en) * | 1975-07-14 | 1977-10-25 | Nippon Kayaku Kabushiki Kaisha | Derivatives of N-(2,2-dichlorovinyl) salicylamide and use thereof as bactericides, fungicides and algicides for industry |
-
1975
- 1975-07-18 JP JP50088088A patent/JPS5215823A/en active Granted
-
1976
- 1976-07-08 GB GB2847176A patent/GB1518378A/en not_active Expired
- 1976-07-14 DE DE19762631709 patent/DE2631709A1/en not_active Withdrawn
- 1976-07-15 NL NL7607862A patent/NL7607862A/en not_active Application Discontinuation
- 1976-07-16 CA CA257,135A patent/CA1061250A/en not_active Expired
- 1976-07-16 IT IT5046376A patent/IT1066045B/en active
- 1976-07-16 FR FR7621906A patent/FR2317879A1/en active Granted
- 1976-07-17 ES ES449928A patent/ES449928A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CA1061250A (en) | 1979-08-28 |
| NL7607862A (en) | 1977-01-20 |
| JPS5215823A (en) | 1977-02-05 |
| DE2631709A1 (en) | 1977-02-03 |
| FR2317879B1 (en) | 1980-09-05 |
| IT1066045B (en) | 1985-03-04 |
| FR2317879A1 (en) | 1977-02-11 |
| JPS5735807B2 (en) | 1982-07-31 |
| GB1518378A (en) | 1978-07-19 |
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