ES396223A1 - Herbicidal phosphonomethylglycine compounds and compositions containing them - Google Patents
Herbicidal phosphonomethylglycine compounds and compositions containing themInfo
- Publication number
- ES396223A1 ES396223A1 ES396223A ES396223A ES396223A1 ES 396223 A1 ES396223 A1 ES 396223A1 ES 396223 A ES396223 A ES 396223A ES 396223 A ES396223 A ES 396223A ES 396223 A1 ES396223 A1 ES 396223A1
- Authority
- ES
- Spain
- Prior art keywords
- group
- carbon atoms
- halogen
- salt
- monovalent hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 2
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical class OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title 1
- 230000002363 herbicidal effect Effects 0.000 title 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- -1 ammonium cations Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000000962 organic group Chemical group 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A compound of the formula **(See formula)** wherein R, R1 and R2 are independently selected from the group consisting of: halogen; -OH; -SH; -NR4R5 where R4 and R5 are independently selected from the group consisting of hydrogen, alkyl and hydroxyalkyl having 1 to 4 carbon atoms, alkenyl having 2 to 4 carbon atoms, and R4 and R5 together with the atom of Nitrogen can form a heterocyclic ring; -OR3 and -SR3, wherein is selected from the group consisting of monovalent hydrocarbon groups, monovalent hydrocarbononoxyhydrocarbon groups each containing from 1 to 18 carbon atoms, halogenated monovalent hydrocarbon groups, halogenated monovalent hydrocarbon groups, each containing 1 to 18 carbon atoms and 1 to 3 halogen groups (see formula) where n is from 1 to 4 and R4 and R5 are as defined above, provided that not more than two of R, R1 or R2 can be -NR4R5, -OR3 or -SR3; and -OR6 where R is a salt-forming cation, selected from the group consisting of alkali metal, alkaline earth metal, copper, zinc, manganese, nickel, ammonium, organic ammonium cations, provided that when the organic group is aryl, the ammonium salt is a primary amine salt, and mixtures of such salts, provided that when any of R, R1, or R2 is halogen, the others of R, R1, or R2 cannot be -OR6, and provided that in addition, not more than two of R, R1 or R2 are -OR6 when R6 is ammonia or organic ammonia, and provided that when said compound is different from a strong acid salt, not more than two of R. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12305771A | 1971-03-10 | 1971-03-10 | |
| US00170385A US3799758A (en) | 1971-08-09 | 1971-08-09 | N-phosphonomethyl-glycine phytotoxicant compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES396223A1 true ES396223A1 (en) | 1975-03-16 |
Family
ID=26821180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES396223A Expired ES396223A1 (en) | 1971-03-10 | 1971-10-21 | Herbicidal phosphonomethylglycine compounds and compositions containing them |
Country Status (31)
| Country | Link |
|---|---|
| JP (1) | JPS566401B1 (en) |
| BE (1) | BE774349A (en) |
| BG (1) | BG18585A3 (en) |
| BR (1) | BR7107076D0 (en) |
| CA (1) | CA936865A (en) |
| CH (1) | CH571306A5 (en) |
| CY (1) | CY837A (en) |
| DD (1) | DD100868A6 (en) |
| DE (3) | DE2167051C2 (en) |
| DK (1) | DK140433B (en) |
| ES (1) | ES396223A1 (en) |
| FI (1) | FI57955C (en) |
| FR (1) | FR2129327A5 (en) |
| GB (1) | GB1366379A (en) |
| HU (1) | HU174479B (en) |
| IE (1) | IE35501B1 (en) |
| IL (3) | IL47972A (en) |
| IT (1) | IT946007B (en) |
| KE (1) | KE2599A (en) |
| MY (1) | MY7600110A (en) |
| NL (1) | NL146171B (en) |
| NO (1) | NO141090C (en) |
| OA (1) | OA03838A (en) |
| PH (2) | PH16509A (en) |
| PT (1) | PT56642A1 (en) |
| RO (2) | RO72460A (en) |
| SE (3) | SE400695B (en) |
| SU (3) | SU638238A3 (en) |
| TR (1) | TR18244A (en) |
| YU (1) | YU36532B (en) |
| ZM (1) | ZM15071A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10555527B2 (en) | 2009-05-18 | 2020-02-11 | Monsanto Technology Llc | Use of glyphosate for disease suppression and yield enhancement in soybean |
| US10575526B2 (en) | 2004-03-30 | 2020-03-03 | Monsanto Technology Llc | Methods for controlling plant pathogens using N-phosphonomethylglycine |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1436843A (en) * | 1972-07-21 | 1976-05-26 | Ici Ltd | Preparation of n-phosphonomethyl-glycine |
| DE2717440C2 (en) * | 1976-05-17 | 1984-04-05 | Hoechst Ag, 6230 Frankfurt | Weed control with [(3-amino-3-carboxy) propyl-1] methylphosphinic acid derivatives |
| EG12897A (en) * | 1976-12-13 | 1980-07-31 | Monsanto Co | N,n,methylebebis-co,o-diaryl-n-phosphonomethylglycinonitrilles |
| US4140513A (en) * | 1978-01-03 | 1979-02-20 | Monsanto Company | Sodium sesquiglyphosate |
| DE2962495D1 (en) * | 1978-04-06 | 1982-05-27 | Monsanto Co | Derivatives of n-trifluoroacetyl n-phosphonomethylglycine dichloride, their preparation and their use as herbicides |
| US4218235A (en) * | 1978-07-10 | 1980-08-19 | Monsanto Company | Ester derivatives of n-trifluoroacetyl-n-phosphonomethylglycine and the herbicidal use thereof |
| US4175946A (en) * | 1978-07-10 | 1979-11-27 | Monsanto Company | Thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine |
| US4359332A (en) * | 1978-07-10 | 1982-11-16 | Monsanto Company | Amide and hydrazide derivatives of N-trifluoroacetyl-N-phosphonomethylglycine as herbicides |
| US4180394A (en) * | 1978-07-10 | 1979-12-25 | Monsanto Company | Derivatives of N-trifluoroacetyl-N-phosphonomethylglycinates and the herbicidal use thereof |
| US4414158A (en) | 1980-04-29 | 1983-11-08 | Ciba-Geigy Corporation | Phosphonomethylglycylhydroxamic acid and novel herbicidally active salts thereof |
| ES8603901A1 (en) * | 1983-07-27 | 1986-01-01 | Rhone Poulenc Agrochimie | Herbicides of the sulfon imide-type with an aminomethylphosphonic group. |
| DE3614788A1 (en) * | 1986-05-02 | 1987-11-05 | Hoechst Ag | HERBICIDE EMULSIONS |
| FR2644036B1 (en) * | 1989-03-07 | 1992-01-17 | Rhone Poulenc Agrochimie | HERBICIDE COMBINATION OF A WATER-SOLUBLE POLYMERIC PACKAGE AND AN N-PHOSPHONOMETHYLGLYCIN-CONTAINING HERBICIDE |
| DE19528054A1 (en) * | 1995-07-31 | 1997-02-06 | Bayer Ag | Process for the preparation of N-phosphonomethylglycine esters |
| DE19528060A1 (en) * | 1995-07-31 | 1997-02-06 | Bayer Ag | Process for the preparation of N-phosphonomethyl-glycine esters |
| IL116695A0 (en) * | 1996-01-07 | 1996-05-14 | Yeda Res & Dev | Seed dressing compositions |
| AU1790697A (en) * | 1996-02-28 | 1997-09-16 | Bayer Aktiengesellschaft | Use of n-phosphonomethylglycine esters in aqueous solution as herbicides, and new n-phosphonomethylglycine esters |
| MX2007015376A (en) | 2005-06-09 | 2008-02-14 | Bayer Cropscience Ag | Active substance combinations. |
| DE102005026482A1 (en) | 2005-06-09 | 2006-12-14 | Bayer Cropscience Ag | Active substance combination, useful e.g. for combating unwanted phytopathogenic fungus, comprises herbicides e.g. glyphosate and active substances e.g. strobilurin, triazoles, valinamide and carboxamide |
| UA108623C2 (en) | 2009-09-30 | 2015-05-25 | LOWER-CELL AMIN ANTI-PESTICIDE SALTS | |
| EP2460404A1 (en) | 2010-12-01 | 2012-06-06 | Basf Se | Compositions containing identical polyamine salts of mixed anionic pesticides |
| US11109591B2 (en) | 2017-04-24 | 2021-09-07 | Taminco Bvba | Single phase liquids of alkanolamine salts of dicamba |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3160632A (en) * | 1961-01-30 | 1964-12-08 | Stauffer Chemical Co | Aminomethylenephosphinic acids, salts thereof, and process for their production |
-
1971
- 1971-10-11 PH PH12914A patent/PH16509A/en unknown
- 1971-10-15 SU SU711714528A patent/SU638238A3/en active
- 1971-10-21 NL NL717114487A patent/NL146171B/en not_active IP Right Cessation
- 1971-10-21 HU HU71MO810A patent/HU174479B/en unknown
- 1971-10-21 ES ES396223A patent/ES396223A1/en not_active Expired
- 1971-10-22 CA CA125905A patent/CA936865A/en not_active Expired
- 1971-10-22 BE BE774349A patent/BE774349A/en not_active IP Right Cessation
- 1971-10-22 NO NO3926/71A patent/NO141090C/en unknown
- 1971-10-22 DE DE2167051A patent/DE2167051C2/en not_active Expired
- 1971-10-22 CY CY837A patent/CY837A/en unknown
- 1971-10-22 IE IE1340/71A patent/IE35501B1/en unknown
- 1971-10-22 BR BR7076/71A patent/BR7107076D0/en unknown
- 1971-10-22 SE SE7113473A patent/SE400695B/en unknown
- 1971-10-22 BG BG018842A patent/BG18585A3/en unknown
- 1971-10-22 GB GB4926371A patent/GB1366379A/en not_active Expired
- 1971-10-22 PT PT56642A patent/PT56642A1/en unknown
- 1971-10-22 IT IT30219/71A patent/IT946007B/en active
- 1971-10-22 JP JP8384671A patent/JPS566401B1/ja active Pending
- 1971-10-22 RO RO7168548A patent/RO72460A/en unknown
- 1971-10-22 DE DE2166573A patent/DE2166573C3/en not_active Expired
- 1971-10-22 DD DD160070A patent/DD100868A6/xx unknown
- 1971-10-22 ZM ZM150/71A patent/ZM15071A1/en unknown
- 1971-10-22 OA OA54402A patent/OA03838A/en unknown
- 1971-10-22 TR TR18244A patent/TR18244A/en unknown
- 1971-10-22 RO RO7199872A patent/RO77018A/en unknown
- 1971-10-22 IL IL47972A patent/IL47972A/en unknown
- 1971-10-22 DE DE2152826A patent/DE2152826C3/en not_active Expired
- 1971-10-22 IL IL37993A patent/IL37993A/en unknown
- 1971-10-22 FR FR7138086A patent/FR2129327A5/fr not_active Expired
- 1971-10-22 FI FI3000/71A patent/FI57955C/en active
- 1971-10-22 DK DK514071AA patent/DK140433B/en not_active IP Right Cessation
- 1971-10-22 CH CH1539171A patent/CH571306A5/xx not_active IP Right Cessation
- 1971-10-22 YU YU02686/71A patent/YU36532B/en unknown
-
1972
- 1972-10-09 SU SU721834717A patent/SU665775A3/en active
- 1972-10-09 SU SU721834717D patent/SU963446A3/en active
-
1974
- 1974-02-28 SE SE7402719A patent/SE400158B/en not_active IP Right Cessation
- 1974-02-28 SE SE7402718A patent/SE399267B/en not_active IP Right Cessation
-
1975
- 1975-08-21 IL IL47972A patent/IL47972A0/en unknown
-
1976
- 1976-02-11 KE KE2599*UA patent/KE2599A/en unknown
- 1976-12-30 MY MY110/76A patent/MY7600110A/en unknown
-
1979
- 1979-10-16 PH PH23177A patent/PH13752A/en unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10575526B2 (en) | 2004-03-30 | 2020-03-03 | Monsanto Technology Llc | Methods for controlling plant pathogens using N-phosphonomethylglycine |
| US10555527B2 (en) | 2009-05-18 | 2020-02-11 | Monsanto Technology Llc | Use of glyphosate for disease suppression and yield enhancement in soybean |
| US11479787B2 (en) | 2009-05-18 | 2022-10-25 | Monsanto Technology, Llc | Use of glyphosate for disease suppression and yield enhancement in soybean |
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