DE102005026482A1 - Active substance combination, useful e.g. for combating unwanted phytopathogenic fungus, comprises herbicides e.g. glyphosate and active substances e.g. strobilurin, triazoles, valinamide and carboxamide - Google Patents

Abstract

Active substance combination comprises herbicides such as glyphosate, glufosinate or glufosinate-ammonium and at least an active substance from e.g. strobilurin, triazoles, sulfenamide, valinamide, carboxamide, dithiocarbamate, acylalanine, anilinopyrimidine, benzimidazole, carbamate, dicarboximide, guandine, imidazole, morpholine, pyrrole, phosphonate, phenylethaneamide, fungicides, thio(urea) derivatives, amides, triazolopyrimidine or iodochromone. Active substance combination (I) comprises herbicides such as glyphosate, glufosinate or glufosinate-ammonium and at least an active substance from strobilurin e.g. azoxystrobin, fluoxastrobin, (2E)2-(2-{[6-(3-chloro-2-methylphenoxy)-5-fluoro-4-pyrimidinyl]oxy}phenyl)-2(methoxyimino)-N-methylethaneamide, trifloxystrobin, orysastrobin, dimoxystrobin, picoxystrobin, pyraclostrobin, metominostrobin and enestroburin; triazoles e.g. azaconazole, etaconazole, propiconazole, difenoconazole, bromuconazole, cyproconazole, hexaconazole, penconazole and myclobutanil; sulfenamide e.g. dichlofluanide and tolylfluanide; valinamide e.g. iprovalicarb, N 1>-[2-(4-{[3-(4-chlorophenyl)-2-propynyl]oxy}-3-methoxyphenyl)ethyl]-N 2>(methylsulfonyl)-D-valinamide or benthiavalicarb; carboxamide e.g. N-[2-(1,3-dimethylbutyl)phenyl]-1,3-dimethyl-1H-pyrazole-4-carboxamide, N-[2-(1,3-dimethylbutyl)phenyl]-5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, N-(4'-chloro-3'-fluoro-1,1'-biphenyl-2-yl)-2-methyl-4 (difluoromethyl)-1,3-thiazole-5-carboxamide, thaboxam, fenhexamide, carpropamide, 2-chloro-4-(2-fluoro-2-methylpropionylamino)- N,N-dimethyl-benzamide, fluopicolide, zoxamide, 3,4-dichloro-N-(2-cyanophenyl)-isothiazole-5-carboxamide, carboxin, tiadinil, silthiofam, N-[2-(1,3-dimethylbutyl)phenyl]-1-methyl-4-(trifluoromethyl)-1H-pyrrole-3-carboxamide and N-{2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]ethyl}-2-(trifluoromethyl)-benzamide; dithiocarbamate e.g. mancozeb, maneb, metiram, propineb, thiram, zineb and ziram; acylalanine e.g. benalaxyl, furalaxyl, metalaxyl, metalaxyl-M and benalaxyl-M; anilinopyrimidine e.g. cyprodinil, mepanipyrim and pyrimethanil; benzimidazole e.g. benomyl, carbendazim, chlorfenazole, fuberidazole and thiabendazole; carbamate e.g. diethofencarb, propamocarb, propamocarb hydrochlorides and propamocarb fosetyl; dicarboximide e.g. captafol, captan, folpet, iprodione, procymidone and vinclozolin; guanidine e.g. dodine, guazatine, iminoctadine triacetate and iminoctadine trichloroethylene tris(albesilate); imidazole e.g. cyazofamide, prochloraz, triazoxide and pefurazoate; morpholine e.g. aldimorph, tridemorph, dodemorph, fenpropimorph and dimethomorph; pyrrole e.g. fenpiclonil, fludioxonil and pyrrolnitrine; phosphonate e.g. fosetyl aluminum and phosphonic acid; phenylethaneamide e.g. 2-(2,3-dihydro-1H-inden-5-yl)-N-[2-(3,4-dimethoxyphenyl)- ethyl]-2-(methoxyimino)acetamide, 2-(4-chlorophenyl)-N-[2-(3,4-dimethoxyphenyl)-ethyl]-2 (methoxyimino)-acetamide, 2-(4-methylphenyl)-N-[2-(3,4-dimethoxyphenyl)-ethyl]-2-(methoxyimino)-acetamide and 2-(4-ethylphenyl)-N-[2-(3,4-dimethoxyphenyl)-ethyl]-2-(methoxyimino)-acetamide; fungicides e.g. acibenzolar-S-methyl, chlorothalonil, cymoxanil, edifenphos, famoxadone, fluazinam, copperoxychloride, oxadixyl, spiroxamine, dithianon, metrafenone, fenamidone, 2,3-dibutyl-6-chloro-thieno-[2,3-d]-pyrimidin-4 (3H)one and quinoxyfen; (thio)urea derivatives e.g. pencycuron, thiophanate methyl and thiophanate-ethyl; amides e.g. fenoxanil or diclocymet; triazolopyrimidine e.g. 5-chloro-N-[(1S)-2,2,2-trifluoro-1-methylethyl]-6-(2,4,6-trifluorophenyl)[1,2,4]triazolo[1,5-a]pyrimidine-7-amine and 5-chloro-6-(2,4,6-trifluorophenyl)-7-(4-methylpiperidin-1-yl)[1,2,4]triazolo[1,5-a]pyrimidine; or iodochromone e.g. 2-butoxy-6-iodo-3-propyl-benzopyran-4-one, 2-ethoxy-6-iodo-3-propyl-benzopyran-4-one, 6-iodo-2-propoxy-3-propyl-benzopyran-4-one, 2-but-2-inyloxy-6-iodo-3-propylbenzopyran-4-one and 6-iodo-2 (1-methyl-butoary)-3-propyl-benzopyran-4-one. Independent claims are included for: (1) a method for combating unwanted phytopathogenic fungus comprising, applying (I) to the unwanted phytopathogenic fungus and/or their habitat and/or seeds; (2) the preparation of a fungicidal agent comprising mixing (I) with a diluting agent and/or surface-active materials; (3) a pickling agent comprising (I); and (4) methods for pickling (transgenic) seeds, comprising applying (I) on the (transgenic) seeds. ACTIVITY : Fungicide. MECHANISM OF ACTION : None given.

Description

The The present invention relates to novel drug combinations which on the one hand a known herbicide selected from glyphosate, glufosinate or glufosinate-ammonium, and on the other hand at least one known contains fungicidal active substance and very good to combat of unwanted phytopathogenic fungi are suitable. Particularly preferred is the Use of these mixtures on transgenic plants which oppose the mentioned herbicides are resistant.

It is already known that glyphosate, glufosinate and glufosinate-ammonium herbicidal properties have (see DE-A 21 52 826, DE-A 27 17 440). Furthermore, it is known that numerous carboxamides, triazole derivatives, aniline derivatives, dicarboximides and other heterocycles can be used for combating fungi (compare WO 03/010149, DE-A 103 03 589, EP-A 0 040 345, US Pat. DE A 22 01 063 . DE A 23 24 010 , Pesticide Manual, 9th. Edition (1991), pages 249 and 827, EP-A 0 382 375 and EP-A 0 515 901). The effect of these substances is not always sufficient at low application rates. Furthermore, it is already known that 1- (3,5-dimethyl-isoxazole-4-sulfonyl) -2-chloro-6,6-difluoro [1,3] -dioxolo- [4,5f] -benzimidazole has fungicidal properties (see WO 97/06171). Finally, it is also known that substituted halopyrimidines have fungicidal properties (compare DE-A1-196 46 407, EP-B-712 396).

It were now new drug combinations with very good fungicidal Properties found containing

Group (1) a herbicide selected out

• (1-1) Glyphosate (known from DE-A 21 52 826) of the formula
  
• (1-2) Glufosinate (known from DE-A 27 17 440) of the formula
  
• (1-3) Glufosinate-ammonium (known from Pesticide Manual, 13th edition, British Crop Protection Council, 2003, pages 511-512) of the formula
  

Group (2) strobilurins selected out

• (2-1) Azoxystrobin (known from EP-A 0 382 375) of the formula
  
• (2-2) Fluoxastrobin (known from DE-A 196 02 095) of the formula
  
• (2-3) (2E-2- (2 - {[6- (3-Chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -N-methylethanamide ( known from DE-A 196 46 407, EP-B 0 712 396) of the formula
  
• (2-4) Trifloxystrobin (known from EP-A 0 460 575) of the formula
  
• (2-5) (2E) -2- (methoxyimino) -N-methyl-2- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide (known from EP-A 0 569 384) of the formula
  
• (2-6) (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) ({1- [3- (trifluoromethyl) phenyl] ethoaryl} imino) methyl] phenyl} ethanamide ( known from EP-A 0 596 254) of the formula
  
• (2-7) Orysastrobin (known from DE-A 195 39 324) of the formula
  
• (2-8) 5-Methoxy-2-methyl-4- (2 - {[({(1E-1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4- dihydro-3H-1,2,4-triazol-3-one (known from WO 98/23155) of the formula
  
• (2-9) Kresoxim-methyl (known from EP-A 0 253 213) of the formula
  
• (2-10) Dimoxystrobin (known from EP-A 0 398 692) of the formula
  
• (2-11) Picoxystrobin (known from EP-A 0 278 595) of the formula
  
• (2-12) Pyraclostrobin (known from DE-A 44 23 612) of the formula
  
• (2-13) Metominostrobin (known from EP-A 0 398 692) of the formula
  
• (2-14) (2E) -2- {2 - [({[(1E) -1- (3 - {[(E) -1-fluoro-2-phenylvinyl] oxy} phenyl) ethylidenes} amino} oxy ) methyl] phenyl} -2- (methoxyimino) -N-methylacetamide (known from WO 01/12585) of the formula
  
• (2-15) Enestroburin (known from EP-A 0 936 213) of the formula
  

Group (3) triazoles selected from

• (3-1) Azaconazole (known from DE-A 25 51 560) of the formula
  
• (3-2) Etaconazole (known from DE-A 25 51 560) of the formula
  
• (3-3) Propiconazole (known from DE-A 25 51 560) of the formula
  
• (3-4) Difenoconazole (known from EP-A 0 112 284) of the formula
  
• (3-5) Bromuconazoles (known from EP-A 0 258 161) of the formula
  
• (3-6) Cyproconazole (known from DE-A 34 06 993) of the formula
  
• (3-7) Hexaconazole (known from DE-A 30 42 303) of the formula
  
• (3-8) Penconazole (known from DE-A 27 35 872) of the formula
  
• (3-9) Myclobutanil (known from EP-A 0 145 294) of the formula
  
• (3-10) Tetraconazoles (known from EP-A 0 234 242) of the formula
  
• (3-11) Flutriafol (known from EP-A 0 015 756) of the formula
  
• (3-12) Epoxiconazoles (known from EP-A 0 196 038) of the formula
  
• (3-13) Flusilazoles (known from EP-A 0 068 813) of the formula
  
• (3-14) Simeconazole (known from EP-A 0 537 957) of the formula
  
• (3-15) Prothioconazole (known from WO 96/12048) of the formula
  
• (3-16) Fenbuconazole (known from DE-A 37 21 786) of the formula
  
• (3-17) Tebuconazole (known from EP-A 0 040 345) of the formula
  
• (3-18) Ipconazole (known from EP-A 0 329 397) of the formula
  
• (3-19) Metconazole (known from EP-A 0 329 397) of the formula
  
• (3-20) Triticonazole (known from EP-A 0 378 953) of the formula
  
• (3-21) Bitertanol (known from DE-A 23 24 010) of the formula
  
• (3-22) Triadimenol (known from DE-A 23 24 010) of the formula
  
• (3-23) Triadimefon (known from DE-A 22 01 063) of the formula
  
• (3-24) Fluquinconazole (known from EP-A 0 183 458) of the formula
  
• (3-25) Quinconazole (known from EP-A 0 183 458) of the formula
  

Group (4) sulfenamides selected out

• (4-1) Dichlofluanid (known from DE-A 11 93 498) of the formula
  
• (4-2) Tolylfluanid (known from DE-A 11 93 498) of the formula
  

Group (5) Valinamide selected out

• (5-1) Iprovalicarb (known from DE-A 40 26 966) of the formula
  
• (5-2) N ¹ - [2- (4 - {[3- (4-chlorophenyl) -2-propynyl] oxy} -3-methoxyphenyl) ethyl] -N ² (methylsulfonyl) -D-valinamide
• (5-3) Benthiavalicarb (known from WO 96/04252) of the formula
  

Group (6) carboxamides selected out

• (6-1) N- [2- (1,3-dimethylbutyl) phenyl] -1,3-dimethyl-1H-pyrazole-4-carboxamide (known from JP-A 10-251240) of the formula
  
• (6-2) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (known from WO 03/010149) of the formula
  
• (6-3) N- [2- (1,3-Dimethylbutyl) phenyl] -5-chloro-1,3-dimethyl-1H-pyrazole-4-carboxamide (known from JP-A 10-251240) of the formula
  
• (6-4) 3- (Difluoromethyl) -N- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-1H-pyrazole-4-carboxamide of the formula
  
• (6-5) 3- (Trifluoromethyl) -N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide (known from WO 2004/067515) of formula
  
• (6-6) 3- (Trifluoromethyl) -N- [2- (1,3-dimethylbutyl) phenyl] -5-chloro-1-methyl-1H-pyrazole-4-carboxamide (known from JP-A 10-251240 ) of the formula
  
• (6-7) 1,3-Dimethyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide of the formula
  
• (6-8) 5-Fluoro-1,3-dimethyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide (known from WO 03/010149) of the formula
  
• (6-9) 3- (Difluoromethyl) -1-methyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide of the formula
  
• (6-10) 3- (Trifluoromethyl) -1-methyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide of the formula
  
• (6-11) 3- (Trifluoromethyl) -5-fluoro-1-methyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide (known from WO 2004/067515 ) of the formula
  
• (6-12) 3- (Trifluoromethyl) -5-chloro-1-methyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide of the formula
  
• (6-13) N- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide (known from WO 2004/005242) of the formula
  
• (6-14) 2-iodo-N- [2- (1,3,3-trimethylbutyl) phenyl] benzamide (known from WO 2004/005242) of the formula
  
• (6-15) N- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide (known from WO 2004/005242) of the formula
  
• (6-16) 2- (trifluoromethyl) -N- [2- (1,3,3-trimethylbutyl) phenyl] benzamide (known from WO 2004/005242) of the formula
  
• (6-17) 2-Chloro-N- (1,1,3-trimethyl-indan-4-yl) nicotinamide (known from EP-A 0 256 503) of the formula
  
• (6-18) Boscalid (known from DE-A 195 31 813) of the formula
  
• (6-19) Furametpyr (known from EP-A 0 315 502) of the formula
  
• (6-20) 1-Methyl-3-h-trifluoromethyl-1H-pyrazole-4-carboxylic acid (3-p-tolyl-thiophen-2-yl) -amide (known from EP-A 0 737 682) of the formula
  
• (6-21) Penthiopyrad (known from EP-A 0 737 682) of the formula
  
• (6-22) N- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide (known from WO 02/38542) of the formula
  
• (6-23) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide ( known from WO 03/070705) of the formula
  
• (6-24) 3- (Difluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H pyrazole-4-carboxamide (known from WO 02/08197) of the formula
  
• (6-25) 3- (Trifluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H pyrazole-4-carboxamide (known from WO 02/08197) of the formula
  
• (6-26) N- (3 ', 4'-dichloro-1,1'-biphenyl-2-yl) -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (known from WO 00 / 14701) of the formula
  
• (6-27) N- (4'-Chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (trifluoromethyl) -1,3-thiazole-5-carboxamide ( known from WO 03/066609) of the formula
  
• (6-28) N- (4'-chloro-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide (known from WO 03 / 066610) of the formula
  
• (6-29) N- (4'-Bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide (known from WO 03 / 066610) of the formula
  
• (6-30) 4- (Difluoromethyl) -2-methyl-N- [4 '- (trifluoromethyl) -1,1'-biphenyl-2-yl] -1,3-thiazole-5-carboxamide (known from WO 03/066610) of the formula
  
• (6-31) N- (4'-iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide (known from WO 03 / 066610) of the formula
  
• (6-32) N- (4'-Chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide ( known from WO 03/066610) of the formula
  
• (6-33) Ethaboxam (known from EP-A 0 639 574) of the formula
  
• (6-34) Fenhexamide (known from EP-A 0 339 418) of the formula
  
• (6-35) carpropamide (known from EP-A 0 341 475) of the formula
  
• (6-36) 2-Chloro-4- (2-fluoro-2-methylpropionylamino) -N, N-dimethylbenzamide (known from EP-A 0 600 629) of the formula
  
• (6-37) Fluopicolides (known from WO 99/42447) of the formula
  
• (6-38) Zoxamide (known from EP-A 0 604 019) of the formula
  
• (6-39) 3,4-Dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide (known from WO 99/24413) of the formula
  
• (6-40) Carboxin (known from US 3,249,499 ) of the formula
  
• (6-41) Tiadinil (known from US 6,616,054 ) of the formula
  
• (6-42) Silthiofam (known from WO 96/18631) of the formula
  
• (6-43) N- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide (known from WO 02/38542) of the formula
  
• (6-44) N - {2- [3-Chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide of the formula
  

Group (7) dithiocarbamates selected out

• (7-1) Mancozeb (known from DE-A 12 34 704) with the IUPAC name Manganese ethylenebis (dithiocarbamate) (polymeric) complex with zinc salt
• (7-2) Maneb (known from US 2,504,404 ) of the formula
  
• (7-3) Metiram (known from DE-A 10 76 434) with the IUPAC name Zinc ammoniate ethylenebis (dithiocarbamate) - poly (ethylenethiuram disulfide)
• (7-4) Propineb (known from GB 935,981 ) of the formula
  
• (7-5) Thiram (known from US 1,972,961 ) of the formula
  
• (7-6) Zineb (known from DE-A 10 81446) of the formula
  
• (7-7) Ziram (known from US 2,588,428 ) of the formula
  

Group (8) acylalanines selected out

• (8-1) Benalaxyl (known from DE-A 29 03 612) of the formula
  
• (8-2) Furalaxyl (known from DE-A 25 13 732) of the formula
  
• (8-3) metalaxyl (known from DE-A 25 15 091) of the formula
  
• (8-4) metalaxyl-M (known from WO 96/01559) of the formula
  
• (8-5) Benalaxyl-M of the formula
  

Group (9): anilino-pyrimidines selected out

• (9-1) Cyprodinil (known from EP-A 0 310 550) of the formula
  
• (9-2) mepanipyrim (known from EP-A 0 270 111) of the formula
  
• (9-3) pyrimethanethanol (known from DD 151 404 ) of the formula
  

Group (10): benzimidazoles selected out

• (10-1) 6-Chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-f] benzimidazole ( known from WO 97/06171) of the formula
  
• (10-2) Benomyl (known from US 3,631,176 ) of the formula
  
• (10-3) Carbendazim (known from US 3,010,968 ) of the formula
  
• (10-4) Chlorfenazoles of the formula
  
• (10-5) Fuberidazole (known from DE-A 12 09 799) of the formula
  
• (10-6) Thiabendazole (known from US 3,206,468 ) of the formula
  

Group (11): carbamate selected out

• (11-1) Diethofencarb (known from EP-A 0 078 663) of the formula
  
• (11-2) Propamocarb (known from US 3,513,241 ) of the formula
  
• (11-3) Propamocarb hydrochloride (known from US 3,513,241 ) of the formula
  
• (11-4) Propamocarb-Fosetyl of the formula
  

Group (12): dicarboximides selected out

• (12-1) Captafol (known from US 3,178,447 ) of the formula
  
• (12-2) Captan (known from US 2,553,770 ) of the formula
  
• (12-3) Folpet (known from US 2,553,770 ) of the formula
  
• (12-4) Iprodione (known from DE-A 2149 923) of the formula
  
• (12-5) procymidones (known from DE-A 20 12 656) of the formula
  
• (12-6) Vinclozoline (known from DE-A 22 07 576) of the formula
  

Group (13): guanidines selected out

• (13-1) Dodine (known from GB 11 03 989 ) of the formula
  
• (13-2) Guazatine (known from GB 11 14 155 )
• (13-3) iminoctadine triacetate (known from EP-A 0 155 509) of the formula
  
• (13-4) iminoctadine tris (albesilate)

Group (14): imidazoles selected out

• (14-1) Cyazofamide (known from EP-A 0 298 196) of the formula
  
• (14-2) prochloraz (known from DE A 24 29 523 ) of the formula
  
• (14-3) triazoxides (known from DE-A 28 02 488) of the formula
  
• (14-4) Pefurazoate (known from EP-A 0 248 086) of the formula
  

Group (15): morpholine selected out

• (15-1) Aldimorph (known from DD 140 041 ) of the formula
  
• (15-2) Tridemorph (known from GB 988 630 ) of the formula
  
• (15-3) Dodemorph (known from DE-A 25 432 79) of the formula
  
• (15-4) Fenpropimorph (known from DE-A 26 56 747) of the formula
  
• (15-5) Dimethomorph (known from EP-A 0 219 756) of the formula
  

Group (16): Pyrroles selected from

• (16-1) Fenpiclonil (known from EP-A 0 236 272) of the formula
  
• (16-2) Fludioxonil (known from EP-A 0 206 999) of the formula
  
• (16-3) pyrroline nitrines (known from JP-A 65-25876) of the formula
  

Group (17): phosphonates selected out

• (17-1) Fosetyl-Al (known from DE-A 24 56 627) of the formula
  
• (17-2) Phosphonic acid of the formula
  

Group (18): phenylethanamides (known from WO 96/23793, E or Z isomer, preferably E isomer) selected out

• (18-1) 2- (2,3-Dihydro-1H-inden-5-yl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
  
• (18-2) N - [2- (3,4-Dimethoxyphenyl) ethyl] -2- (methoxyimino) -2- (5,6,7,8-tetrahydronaphthalen-2-yl) acetamide of the formula
  
• (18-3) 2- (4-Chlorophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
  
• (18-4) 2- (4-Bromophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
  
• (18-5) 2- (4-Methylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
  
• (18-6) 2- (4-ethylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
  

Group (19): Fungicides selected out

• (19-1) acibenzolar-S-methyl (known from EP-A 0 313 512) of the formula
  
• (19-2) chlorothalonil (known from US 3,290,353 ) of the formula
  
• (19-3) Cymoxanil (known from DE-A 23 12 956) of the formula
  
• (19-4) Edifenphos (known from DE-A 14 93 736) of the formula
  
• (19-5) Famoxadone (known from EP-A 0 393 911) of the formula
  
• (19-6) fluazinam (known from EP-A 0 031 257) of the formula
  
• (19-7) copper oxychloride
• (19-9) Oxadixyl (known from DE-A 30 30 026) of the formula
  
• (19-10) spiroxamine (known from DE-A 37 35 555) of the formula
  
• (19-11) Dithianone (known from JP-A 44-29464) of the formula
  
• (19-12) Metrafenone (known from EP-A 0 897 904) of the formula
  
• (19-13) Fenamidone (known from EP-A 0 629 616) of the formula
  
• (19-14) 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) on (known from WO 99/14202) of the formula
  
• (19-15) Probenazoles (known from US 3,629,428 ) of the formula
  
• (19-16) isoprothiolanes (known from US 3,856,814 ) of the formula
  
• (19-17) Kasugamycin (known from GB 1 094 567 ) of the formula
  
• (19-18) Phthalides (known from JP-A 57-55844) of the formula
  
• (19-19) Ferimzone (known from EP-A 0 019 450) of the formula
  
• (19-20) tricyclazoles (known from DE-A 22 50 077) of the formula
  
• (19-21) N - ({4 - [(Cyclopropylamino) carbonyl] phenyl} sulfonyl) -2-methoxybenzamide of the formula
  
• (19-22) 2- (4-chlorophenyl) -N- {2- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yne) 1-yloxy) acetamide (known from WO 01/87822) of the formula
  
• (19-23) proquinazide (known from WO 09426722) of the formula
  
• (19-24) Quinoxyfen (known from EP-A 0 326 330) of the formula
  

Group (20): (thio) urea derivatives selected out

• (20-1) Pencycuron (known from DE-A 27 32 257) of the formula
  
• (20-2) thiophanate-methyl (known from DE-A 18 06 123) of the formula
  
• (20-3) Thiophanate-ethyl (known from DE-A 18 06 123) of the formula
  

Group (21): Amides selected from

• (21-1) Fenoxanil (known from EP-A 0 262 393) of the formula
  
• (21-2) Diclocymet (known from JP-A 7-206608) of the formula
  

Group (22): triazolopyrimidines selected out

• (22-1) 5-Chloro-N - [(1S) -2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1 , 5-a] pyrimidin-7-amine (known from US 5,986,135 ) of the formula
  
• (22-2) 5-Chloro-N - [(1R) -1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidine 7-amine (known from WO 02/38565) of the formula
  
• (22-3) 5-Chloro-6- (2-chloro-6-fluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine (known out US 5,593,996 ) of the formula
  
• (22-4) 5-Chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine (known from DE-A 101 24 208) of the formula
  

Group (23): iodochromones selected out

• (23-1) 2-Butoxy-6-iodo-3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula
  
• (23-2) 2-Ethoxy-6-iodo-3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula
  
• (23-3) 6-iodo-2-propoary-3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula
  
• (23-4) 2-But-2-ynyloxy-6-iodo-3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula
  
• (23-5) 6-iodo-2- (1-methylbutoxy) 3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula
  
• (23-6) 2-But-3-enyloxy-6-iodobenzopyran-4-one (known from WO 03/014103) of the formula
  
• (23-7) 3-Butyl-6-iodo-2-isopropoxy-benzopyran-4-one (known from WO 03/014103) of the formula
  

Surprisingly is the fungicidal action of the active compound combinations according to the invention significantly higher as the sum of the effects of each agent. It is so an unpredictable, true synergistic effect before and not just an effect supplement.

(1R,3S)-2,2-Dichlor-N-[(1R)-1-(4-chlorphenyl)ethyl]-1-ethyl-3-methylcyclopropancarboxamid der Formel

The compound (6-35) carpropamid has three asymmetric substituted carbon atoms. The compound (6-35) can therefore be present as a mixture of different isomers or in the form of a single component. Particularly preferred are the compounds (1S, 3R) -2,2-dichloro-N - [(1R) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide of the formula

(1R, 3S) -2,2-dichloro-N - [(1R) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide of the formula

highlighted are active compound combinations according to the invention, in addition to (1-1) glyphosate one or more, preferably one, Mixing partners of groups (2) to (23) included.

highlighted are active compound combinations according to the invention, in addition to (1-2) glufosinates one or more, preferably one, Mixing partners of groups (2) to (23) included.

highlighted are active compound combinations according to the invention, which in addition to (1-3) glufosinate-ammonium one or more, preferred one, mixing partners of groups (2) to (23) included.

When Mixing partners of groups (2) to (23) are the following active ingredients prefers:

• (2-1) Azoxystrobin
• (2-2) Fluoxastrobin
• (2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -N-methylethanamide
• (2-4) Trifloxystrobin
• (2-5) (2E) -2- (methoxyimino) -N-methyl-2- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide
• (2-6) (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide
• (2-8) 5-Methoxy-2-methyl-4- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4 dihydro-3H-1,2,4-triazol-3-one
• (2-11) Picoxystrobin
• (2-9) Kresoxim-methyl
• (2-10) dimoxystrobin
• (2-12) Pyraclostrobin
• (2-13) Metominostrobin
• (3-3) propiconazole
• (3-4) difenoconazole
• (3-6) Cyproconazole
• (3-7) hexaconazole
• (3-8) Penconazole
• (3-9) myclobutanil
• (3-10) Tetraconazole
• (3-13) Flusilazole
• (3-15) prothioconazole
• (3-16) fenbuconazole
• (3-17) Tebuconazole
• (3-21) Bitertanol
• (3-22) Triadimenol
• (3-23) Triadphone
• (3-12) Epoxiconazoles
• (3-19) Metconazole
• (3-24) Fluquinconazole
• (4-1) Dichlofluanid
• (4-2) tolylfluanid
• (5-1) Iprovalicarb
• (5-3) Benthiavalicarb
• (6-2) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide
• (6-5) 3- (Trifluoromethyl) -N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide
• (6-8) 5-Fluoro-1,3-dimethyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide
• (6-13) N- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide
• (6-15) N- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide
• (6-18) Boscalid
• (6-19) Furametpyr
• (6-21) Penthiopyrad
• (6-22) N- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide
• (6-23) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide
• (6-24) 3- (Difluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H pyrazole-4-carboxamide
• (6-25) 3- (Trifluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H pyrazole-4-carboxamide
• (6-26) N- (3 ', 4'-dichloro-1,1'-biphenyl-2-yl) -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide
• (6-29) N- (4'-Bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide
• (6-31) N- (4'-iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide
• (6-32) N- (4'-Chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide
• (6-33) Ethaboxam
• (6-34) fenhexamide
• (6-35) carpropamide
• (6-36) 2-Chloro-4 - [(2-fluoro-2-methylpropanoyl) amino] -N, N-dimethylbenzamide
• (6-37) fluopicolides
• (6-38) Zoxamide
• (6-39) 3,4-Dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide
• (6-43) N- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide
• (6-44) N - {2- [3-Chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide
• (7-1) Mancozeb
• (7-2) Maneb
• (7-4) Propylene
• (7-5) Thiram
• (7-6) Zineb
• (8-1) Benalaxyl
• (8-2) Furalaxyl
• (8-3) metalaxyl
• (8-4) metalaxyl-M
• (8-5) Benalaxyl-M
• (9-1) Cyprodinil
• (9-2) mepanipyrim
• (9-3) pyrimethanil
• (10-1) 6-Chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-f] benzimidazole
• (10-3) carbendazim
• (11-1) Diethofencarb
• (11-2) Propamocarb
• (11-3) Propamocarb hydrochloride
• (11-4) Propamocarb-Fosetyl
• (12-2) Captan
• (12-3) Folpet
• (12-4) Iprodione
• (12-5) procymidones
• (13-1) Dodine
• (13-2) Guazatine
• (13-3) iminoctadine triacetate
• (14-1) Cyazofamide
• (14-2) prochloraz
• (14-3) triazoxide
• (15-5) dimethomorph
• (15-4) fenpropimorph
• (16-2) fludioxonil
• (17-1) fosetyl-Al
• (17-2) Phosphonic acid
• (19-1) acibenzolar S-methyl
• (19-2) chlorothalonil
• (19-3) cymoxanil
• (19-5) Famoxadone
• (19-6) fluazinam
• (19-9) oxadixyl
• (19-10) spiroxamine
• (19-7) copper oxychloride
• (19-13) fenamidone
• (19-22) 2- (4-chlorophenyl) -N- {2- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yne) 1-yloxy) acetamide
• (20-1) Pencycuron
• (20-2) thiophanate-methyl
• (22-1) 5-Chloro-N - [(1S) -2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1 , 5-a] pyrimidin-7-amine
• (22-2) 5-Chloro-N - [(1R) -1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidine -7-amine
• (22-4) 5-Chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine
• (23-1) 2-Butoxy-6-iodo-3-propyl-benzopyran-4-one
• (23-2) 2-ethoxy-6-iodo-3-propyl-benzopyran-4-one
• (23-3) 6-iodo-2-propoxy-3-propyl-benzopyran-4-one

When Mixing partners of groups (2) to (23) are the following active ingredients especially preferred:

• (2-2) Fluoxastrobin
• (2-4) Trifloxystrobin
• (2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -N-methylethanamide
• (3-15) prothioconazole
• (3-17) Tebuconazole
• (3-21) Bitertanol
• (3-22) Triadimenol
• (3-24) Fluquinconazole
• (4-1) Dichlofluanid
• (4-2) tolylfluanid
• (5-1) Iprovalicarb
• (6-2) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide
• (6-8) 5-Fluoro-1,3-dimethyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide
• (6-13) N- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide
• (6-15) N- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide
• (6-18) Boscalid
• (6-21) Penthiopyrad
• (6-22) N- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide
• (6-23) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide
• (6-29) N- (4'-Bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide
• (6-31) N- (4'-iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide
• (6-32) N- (4'-Chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide
• (6-34) fenhexamide
• (6-35) carpropamide
• (6-37) fluopicolides
• (6-44) N - {2- [3-Chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide
• (7-4) Propylene
• (8-4) metalaxyl-M
• (8-5) Benalaxyl-M
• (9-3) pyrimethanil
• (10-3) carbendazim
• (11-4) Propamocarb-Fosetyl
• (12-4) Iprodione
• (14-2) prochloraz
• (14-3) triazoxide
• (16-2) fludioxonil
• (19-10) spiroxamine
• (19-22) 2- (4-chlorophenyl) -N- {2- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yne) 1-yloxy) acetamide
• (22-4) 5-Chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine

in the In the following, preferred active substance combinations are described, which consist of two groups of active ingredients and in each case at least a herbicide of group (1) and at least one active ingredient of the indicated Group (2) to (23) included.

Tabelle 1:

Tabelle 1:

Tabelle 1:

Highlighted are the active ingredient combinations listed in Table 1 below: Table 1:

Table 1:

Table 1:

Table 1:

The active compound combinations according to the invention contain at least one active substance of group (1) Active ingredient of the compounds of groups (2) to (23). You can go beyond that Also contain other fungicidal Zumischkomponenten.

Thus, for example, each of the combinations of active ingredients listed in Table 1 may contain a third active substance selected from the following list:
(2-1) azoxystrobin, (2-2) fluoxastrobin, (2-3) (2E) 2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy } phenyl) -2- (methoxyimino) -N-methylethaneamide, (2-4) trifloxystrobin, (2-5) (2E) -2- (methoxyimino) -N-methyl-2- (2 - {[(( 1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide, (2-6) (2E) -2- (methoxyimino) -N-methyl-2- {2- [ (E) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide, (2-7) orysastrobin, (2-8) 5-methoxy-2-methyl-4- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro- 3H-1,2,4-triazol-3-one, (2-9) kresoxim-methyl, (2-10) dimoxystrobin, (2-11) picoxystrobin, (2-12) pyraclostrobin, (2-13) metominostrobin , (2-14) (2E) -2- {2 - [({[(1E) -1- (3 - {[(E) -1-fluoro-2-phenylvinyl] oxy} phenyl) ethylidenes] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylacetamide, (2-15) enestroburine, (3-1) azaconazole, (3-2) etaconazole, (3-3) propiconazole, (3-4) Difenoconazole, (3-5) bromuconazoles, (3-6) cyproconazoles, (3-7) hexaconazoles, (3-8) penconazoles, (3-9) myclobutanil, (3-10) tetraconazoles, (3-11) flutriafol , (3-12) epoxiconazoles, (3-13) flusilazoles, (3-14) simeconazoles, (3-15) prothioconazoles, (3-16) fenbuconazoles, (3-17) tebuconazoles, (3-18) ipconazole, (3-19) metconazole, (3-20) triticonazole, (3-21) bitertanol, (3-22) triadimenol, (3-23) triadimefon, (3-24) fluquinconazole, (3-25) quinconazole, ( 4-1) Dichlofluanid, (4-2) tolylfluanid, (5-1) Iprovalicarb, (5-2) N ¹ - [2- (4 - {[3- (4-chlorophenyl) -2-propynyl] oxy} 3-methoxyphenyl) ethyl] -N ² - (methylsulfonyl) -D-valinamide, (5-3) Be nthiavalicarb, (6-1) N- [2- (1,3-dimethylbutyl) phenyl] -1,3-dimethyl-1H-pyrazole-4-carboxamide, (6-2) N- [2- (1,3 -Dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, (6-3) N- [2- (1,3-dimethylbutyl) phenyl] -5-chloro-1, 3-dimethyl-1H-pyrazole-4-carboxamide, (6-4) 3- (difluoromethyl) -N- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-1H-pyrazole-4-carboxamide, (6-5) 3- (Trifluoromethyl) -N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (6-6) 3- ( Trifluoromethyl) -N- [2- (1,3-dimethylbutyl) phenyl] -5-chloro-1-methyl-1H-pyrazole-4-carboxamide, (6-7) 1,3-dimethyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide, (6-8) 5-fluoro-1,3-dimethyl-N- [2- (1,3,3-trimethylbutyl) phenyl] ] -1H-pyrazole-4-carboxamide, (6-9) 3- (difluoromethyl) -1-methyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide, (6-10) 3- (Trifluoromethyl) -1-methyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide, (6-11) 3 (trifluoromethyl) -5-fluoro-1-methyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide id, (6-12) 3- (trifluoromethyl) -5-chloro-1-methyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide, (6-13 ) N- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide, (6-14) 2-iodo-N- [2- (1,3,3-trimethylbutyl) phenyl] benzamide, (6 15) N- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide, (6-16) 2- (trifluoromethyl) -N- [2- (1,3,3-trimethylbutyl) phenyl ] benzamide, (6-17) 2-chloro-N- (1,1,3-trimethyl-indan-4-yl) nicotinamide, (6-18) boscalid, (6-19) furametpyr (6-20 ) 1-Methyl-3-trifluoromethyl-1H-pyrazole-4-carboxylic acid (3-p-tolyl-thiophen-2-yl) -amide, (6-21) penthiopyrad, (6-22) N- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide, (6-23) N- (3 ', 4'-dichloro-5-fluoro-1, 1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (6-24) 3- (difluoromethyl) -N- {3'-fluoro-4'- [(E) (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H-pyrazole-4-carboxamide, (6-25) 3- (trifluoromethyl) -N- {3 ' -fluoro-4 '- [(e) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H-pyrazole-4-carboxamide, (6-26) N- (3 ', 4'-dichloro-1,1'-biphenyl-2-yl) -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, (6-27 ) N- (4'-chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (trifluoromethyl) -1,3-thiazole-5-carboxamide, (6-28 ) N- (4'-chloro-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-29) N- (4 'Bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-30) 4- (difluoromethyl) -2-methyl -N- [4 '- (trifluoromethyl) -1,1'-biphenyl-2-yl] -1,3-thiazole-5-carboxamide, (6-31) N- (4'-iodo-1,1' -biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-32) N- (4'-chloro-3'-fluoro-1,1 ' -biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide, (6-33) ethaboxam, (6-34) hexhexamide, (6-35) carpropamide, ( 6-36) 2-chloro-4- (2-fluoro-2-methylpropionylamino) -N, N-dimethylbenzamide, (6-37) fluopicolides, (6-38) zoxamides, (6-39) 3 , 4-dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide, (6-40) carboxyne, (6-41) tiadinil, (6-42) silthiofam, (6-43) N- [2- (2-6) 1,3-dimethylbutyl) phenyl] -1-methyl -4- (trifluoromethyl) -1H-pyrrole-3-carboxamide, (6-44) N - {2- [3-chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoro-ethyl) -benzamide , (7-1) mancozeb, (7-2) maneb, (7-3) metiram, (7-4) propineb, (7-5) thiram, (7-6) zineb, (7-7) ziram, (8-1) Benalaxyl, (8-2) Furalaxyl, (8-3) Metalaxyl, (8-4) Metalaxyl-M, (8-5) Benalaxyl-M, (9-1) Cyprodinil, (9-2 ) Mepanipyrim, (9-3) pyrimethanil, (10-1) 6-chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-f] benzimidazole, (10-2) benomyl, (10-3) carbendazim, (10-4) chlorfenazoles, (10-5) fuberidazoles, (10-6) thiabendazoles, (11-1) diethofencarb , (11-2) propamocarb, (11-3) propamocarb-hydrochloride, (11-4) propamocarb-fosetyl, (12-1) captafol, (12-2) captan, (12-3) folpet, (12- 4) iprodione, (12-5) procymidone, (12-6) vinclozoline, (13-1) dodine, (13-2) guazatine, (13-3) iminoctadine triacetate, (13-4) iminoctadine tris (albesilate) , (14-1) cyazofamide, (14-2) prochloraz, (14-3) triazoxide, (14-4) pefurazoate, (15-1) aldimorph, (15-2) tride morph, (15-3) dodemorph, (15-4) fenpropimorph, (15-5) dimethomorph, (16-1) fenpiclonil, (16-2) fludioxonil, (16-3) pyrroline nitrine, (17-1) fosetyl -Al, (17-2) phosphonic acid, (18-1) 2- (2,3-dihydro-1H-inden-5-yl) - N - [2- (3,4-dimethoxyphenyl) ethyl] -2 - (methoxyimino) acetamide, (18-2) N - [2 (-3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) -2- (5,6,7,8-tetrahydronaphthalen-2-yl) acetamide , (18-3) 2- (4-Chlorophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, (18-4) 2- (4-bromophenyl) -N - [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, (18-5) 2- (4-methylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2 - (methoxyimino) acetamide, (18-6) 2- (4-ethylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, (19-1) acibenzolar-S -methyl, (19-2) chlorothalonil, (19-3) cymoxanil, (19-4) edifenphos, (19-5) famoxadone, (19-6) fluazinam, (19-7) copper oxychloride, (19-9) Oxadixyl, (19-10) spiroxamine, (19-11) dithianone, (19-12) metrafenone, (19-13) fenamidone, (19-14) 2,3-dibutyl-6-chlorothieno [2,3 -d] pyrimidin-4 (3H) one, (19-15) sample azoles, (19-16) isoprothiolanes, (19-17) kasugamycin, (19-18) phthalides, (19-19) ferric zone, (19-20) tricyclazoles, (19-21) N - ({4 - [(Cyclopropylamino) carbonyl] phenyl} sulfonyl) -2-methoxybenzamide, (19-22) 2- (4-chlorophe nyl) - N - {2- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yn-1-yloxy) acetamide, (19-23 ) Proquinazide, (19-24) quinoxyfen, (20-1) pencycuron, (20-2) thiophanate-methyl, (20-3) thiophanate-ethyl, (21-1) fenoxanil, (21-2) diclocymet, ( 22-1) 5-chloro-N - [(1S) -2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1, 5-a] pyrimidin-7-amine, (22-2) 5-chloro-N - [(1R) -1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2, 4] triazolo [1,5-a] pyrimidin-7-amine, (22-3) 5-chloro-6- (2-chloro-6-fluorophenyl) -7- (4-methylpiperidin-1-yl) [1 , 2,4] triazolo [1,5-a] pyrimidine, (22-4) 5-chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1, 2,4] triazolo [1,5-a] pyrimidine, (23-1) 2-butoxy-6-iodo-3-propyl-benzopyran-4-one, (23-2) 2-ethoxy-6-iodo 3-propylbenzopyran-4-one, (23-3) 6-iodo-2-propoxy-3-propyl-benzopyran-4-one, (23-4) 2-but-2-ynyloxy-6-iodo-3 propyl-benzopyran-4-one, (23-5) 6-iodo-2- (1-methylbutoxy) -3-propyl-benzopyran-4-one, (23-6) 2-but-3-enyloxy- 6-iodo-benzopyran-4-one, (23-7) 3-butyl-6-iodo-2-isopropoxy-b enzopyran-4-one.

If the active ingredients in the active compound combinations according to the invention in certain weight ratios are present, the synergistic effect is particularly evident. However, you can the weight ratios the active ingredients in the drug combinations in a relatively large area be varied. In general, the combinations according to the invention contain Active compounds of the formula (I) and a mixed partner from one of the groups (2) to (23) in the following Table 2 by way of example specified mixing ratios.

Tabelle 2: Mischungsverhältnisse

Tabelle 2: Mischungsverhältnisse

The mixing ratios are based on weight ratios. The ratio is to be understood as active substance of the group (1): Mischpartner. Table 2: Mixing ratios

Table 2: Mixing ratios

Table 2: Mixing ratios

The mixing ratio is to be chosen in each case so that a synergistic mixture is obtained. The mixing ratios between the compound of formula (I) and a compound of one of the groups (2) to (23) can also be between the individual Compounds of a group vary.

The active compound combinations according to the invention have very good fungicidal properties and can be combated by phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc. use.

By way of example but not limitation, some pathogens of fungal and bacterial diseases, which fall under the above-enumerated generic terms, are named:
Diseases caused by powdery mildew pathogens such as Blumeria species such as Blumeria graminis; Podosphaera species, such as Podosphaera leucotricha; Sphaerotheca species, such as Sphaerotheca fuliginea; Uncinula species, such as Uncinula necator;
Diseases caused by pathogens of rust diseases such as Gymnosporangium species, such as Gymnosporangium sabinae Hemileia species, such as Hemileia vastatrix; Phakopsora species such as Phakopsora pachyrhizi and Phakopsora meibomiae; Puccinia species, such as Puccinia recondita; Uromyces species, such as Uromyces appendiculatus;
Diseases caused by agents of the group of Oomycetes such as Bremia species, such as Bremia lactucae; Peronospora species such as Peronospora pisi or P. brassicae; Phytophthora species, such as Phytophthora infestans; Plasmopara species, such as Plasmopara viticola; Pseudoperonospora species, such as, for example, Pseudoperonospora humuli or Pseudoperonospora cubensis; Pythium species such as Pythium ultimum;
Leaf spot diseases and leaf wilt caused by, for example, Alternaria species such as Alternaria solani; Cercospora species, such as Cercospora beticola; Cladiosporum species, such as Cladiosporium cucumerinum; Cochliobolus species, such as Cochliobolus sativus (conidia form: Drechslera, Syn: Helminthosporium); Colletotrichum species, such as Colletotrichum lindemuthanium; Cycloconium species such as cycloconium oleaginum; Diaporthe species, such as Diaporthe citri; Elsinoe species, such as Elsinoe fawcettii; Gloeosporium species, such as, for example, Gloeosporium laeticolor; Glomerella species, such as Glomerella cingulata; Guignardia species, such as Guignardia bidwelli; Leptosphaeria species, such as Leptosphaeria maculans; Magnaporthe species, such as Magnaporthe grisea; Mycosphaerella species, such as Mycosphaerelle graminicola; Phaeosphaeria species, such as Phaeosphaeria nodorum; Pyrenophora species, such as, for example, Pyrenophora teres; Ramularia species, such as Ramularia collo-cygni; Rhynchosporium species, such as Rhynchosporium secalis; Septoria species, such as Septoria apii; Typhula species, such as Typhula incarnata; Venturia species, such as Venturia inaequalis;
Root and stem diseases caused by, for example, corticium species such as Corticium graminearum; Fusarium species such as Fusarium oxysporum; Gaeumannomyces species such as Gaeumannomyces graminis; Rhizoctonia species, such as Rhizoctonia solani; Tapesia species, such as Tapesia acuformis; Thielaviopsis species, such as Thielaviopsis basicola;
Ear and panicle diseases (including corncob) caused by eg Alternaria species, such as Alternaria spp .; Aspergillus species, such as Aspergillus flavus; Cladosporium species such as Cladosporium spp .; Claviceps species, such as Claviceps purpurea; Fusarium species such as Fusarium culmorum; Gibberella species, such as Gibberella zeae; Monographella species, such as Monographella nivalis;
Diseases caused by fire fungi such as Sphacelotheca species, such as Sphacelotheca reiliana; Tilletia species, such as Tilletia caries; Urocystis species, such as Urocystis occulta; Ustilago species such as Ustilago nuda;
Fruit rot caused, for example, by Aspergillus species, such as Aspergillus flavus; Botrytis species, such as Botrytis cinerea; Penicillium species such as Penicillium expansum; Sclerotinia species, such as Sclerotinia sclerotiorum; Verticilium species such as, for example, Verticilium alboat rum;
Seed and soil rots and wilts, and seedling diseases caused by, for example, Fusarium species such as Fusarium culmorum; Phytophthora species, such as Phytophthora cactorum; Pythium species such as Pythium ultimum; Rhizoctonia species, such as Rhizoctonia solani; Sclerotium species, such as Sclerotium rolfsii;
Cancers, bile and witch brooms caused by eg Nectria species such as Nectria galligena;
Wilting diseases caused by, for example, Monilinia species, such as Monilinia laxa;
Deformations of leaves, flowers and fruits caused by, for example, Taphrina species such as Taphrina deformans;
Degenerative diseases of woody plants, caused by eg Esca species, such as Phaemoniella clamydospora;
Floral and seed diseases caused by, for example, Botrytis species such as Botrytis cinerea;
Diseases of plant tubers caused by eg Rhizoctonia species, such as Rhizoctonia solani;
Diseases caused by bacterial pathogens such as Xanthomonas species, such as Xanthomonas campestris pv. Oryzae; Pseudomonas species, such as Pseudomonas syringae pv. Lachrymans; Erwinia species, such as Erwinia amylovora;
Preferably, the following diseases of soybean beans can be controlled:
Fungus diseases on leaves, stems, pods and seeds caused by, for example, Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. Truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Dandelion leaf leaf (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye leaf spot (Cercospora sojina), Leptosphaerulina leaf spot (Leptosphaerulina trifolii) , Phyllostica Leaf Spot (Phyllosticta sojaecola), Powdery Mildew (Microsphaera diffusa), Pyrenochaeta Leaf Spot (Pyrenochaeta glycines), Rhizoctonia Aerial, Foliage, and Web Blight (Rhizoctonia solani), Rust (Phakopsora pachyrhizi), Scab (Sphaceloma glycines), Stemphylium Leaf Blight (Stemphylium botryosum), Target Spot (Corynespora cassiicola)
Fungal diseases of roots and stem base caused by eg Black Root Red (Calonectria crotalariae), Charcoal Red (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Red, and Pod and Collar Red (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti) , Mycoleptodiscus Root Red (Mycoleptodiscus terrestris), Neocosmospora (Neocosmopspora vasinfecta), Pod and Stem Blight (Diaporthe phaseolorum), Stem Canker (Diaporthe phaseolorum var. Caulivora), Phytophthora red (Phytophthora megasperma), Brown Stem Red (Phialophora gregata), Pythium Red (Pythium aphanidermatum, Pythium irregulare, Pythium debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Red, Stem Decay, and Damping Off (Rhizoctonia solani), Sclerotinia Stem Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsii), Thielaviopsis Root Red (Thielaviopsis basicola).

The good plant tolerance the drug combinations in the fight against plant diseases necessary concentrations allows treatment of whole plants (above-ground parts of plants and roots), of planting and seed, and the soil. The active compound combinations according to the invention can used for foliar application or as a mordant.

One greater Part of damage to crops caused by phytopathogenic fungi is already caused by the infestation of the seed during storage and after the introduction of the seed into the soil as well as during and immediately after the germination of the plants. This phase is particularly critical as the Particularly sensitive to the roots and shoots of the growing plant are and already a small damage to the death of the whole plant to lead can. There is therefore a particular interest in the seed and the germinating plant by the use of suitable means protect.

The fight of phytopathogenic fungi that damage plants after emergence occurs primarily by the treatment of the soil and the above ground Plant parts with pesticides. Due to concerns about of a possible Influence of plant protection products on the environment and health of people and animals there are efforts, the amount of applied To reduce active ingredients.

The control of phytopathogenic fungi by the treatment of the seed of plants has long been known and is the subject of constant improvement. Nevertheless, there are a number of problems in the treatment of seeds that can not always be satisfactorily resolved. Thus, it is desirable to develop methods of protection of the seed and the germinating plant that the make additional application of pesticides after sowing or after emergence of the plants superfluous or at least significantly reduce. It is also desirable to optimize the amount of the active ingredient used in such a way that the seed and the germinating plant is best protected against attack by phytopathogenic fungi, but without damaging the plant itself by the active ingredient used. In particular, methods for treating seed should also include the intrinsic fungicidal properties of transgenic plants in order to achieve optimum protection of the seed and the germinating plant with a minimum of pesticide use.

The The present invention therefore more particularly relates to Method for protecting seed and germinating plants from the Infestation of phytopathogenic fungi by adding the seed with an agent according to the invention is treated.

The The invention also relates to the use of the agents according to the invention for the treatment of seed for the protection of seed and germinating Plant in front of phytopathogenic fungi.

Farther The invention relates to seed, which protects against phytopathogenic Mushrooms with an agent according to the invention was treated.

one the advantages of the present invention is that due to the particular systemic properties of the agents according to the invention the treatment of the seed with these means not only the seed itself, but also the resulting plants after the Protrusion against phytopathogenic fungi protects. In this way, the immediate treatment of the culture at the time of sowing or shortly then omitted.

As well it is to be regarded as advantageous that the mixtures according to the invention especially in transgenic seeds can be used.

The agents according to the invention are suitable for the protection of seed of any plant variety that in agriculture, in the greenhouse, used in forestry or horticulture. In particular, acts these are seeds of cereals (such as wheat, barley, rye, Millet and oats), corn, cotton, soy, rice, potatoes, sunflower, Bean, coffee, turnip (for example, sugar beet and fodder beet), Peanut, vegetables (like tomato, cucumber, onions and lettuce), turf and ornamental plants. Of particular importance is the treatment of the seed of cereals (like wheat, barley, rye and oats), corn and rice too.

in the Within the scope of the present invention is the agent according to the invention applied alone or in a suitable formulation on the seed. Preferably, the seed is treated in a state in which so stable is that no damage occur during treatment. In general, the treatment can of the seed at any time between harvesting and sowing respectively. Usually seed separated from the plant and used by flasks, Shells, stalks, shell Wool or pulp was freed. For example, seeds used, harvested, cleaned and up to a moisture content was dried below 15 wt .-%. Alternatively, seed can also be used used after drying, e.g. treated with water and then dried again.

in the In general, care must be taken when treating the seed be that the amount of applied to the seed agent of the invention and / or other additives is chosen so that germination of the seed or the resulting plant is not damaged. This is especially important in the case of active ingredients, which are certain Application rates can show phytotoxic effects.

The agents according to the invention can be applied directly, ie without containing further components and without being diluted. In general, it is preferable to apply the agents to the seed in the form of a suitable formulation. Suitable formulations and methods for seed treatment are known to the person skilled in the art and are described, for example, in the following documents: US 4,272,417 A . US 4,245,432 A . US 4,808,430 A . US 5,876,739 A , US 2003/0176428 A1, WO 2002/080675 A1, WO 2002/028186 A2.

The active compound combinations according to the invention are also suitable for increasing crop yield. They are also less toxic and have good plant tolerance.

According to the invention, all plants and parts of plants can be treated. Being under plants understood here all plants and plant populations, such as desirable and undesirable wild plants or crops (including naturally occurring crops). Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights. Plant parts are to be understood as meaning all aboveground and subterranean parts and organs of the plants, such as shoot, leaf, flower and root, examples of which include leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes. The plant parts also include crops and vegetative and generative propagation material, such as cuttings, tubers, rhizomes, offshoots and seeds.

The Treatment according to the invention the plants and plant parts with the active ingredients are made directly or by affecting their environment, habitat or storage space the usual Treatment methods, e.g. by dipping, spraying, evaporating, misting, Sprinkle, spread and propagate material, in particular in seeds, further by single or multi-layer wrapping.

As already mentioned above, can According to the invention, all plants and their parts are treated. In a preferred embodiment are wild or by conventional biological breeding methods, such as crossing or protoplast fusion obtained plant species and Treated plant varieties and their parts. In a further preferred embodiment are transgenic plants and plant varieties produced by genetic engineering Methods if necessary in combination with conventional methods were obtained (Genetically Modified Organisms) and their parts treated. The term "parts" or "parts of plants "or" plant parts "has been explained above.

Especially plants according to the invention are preferred the respective commercial or plant varieties in use.

ever according to plant species or plant varieties, their location and growth conditions (Floors, Climate, vegetation period, nutrition) can by the treatment according to the invention also superadditives ("Synergistic") effects occur. For example, reduced application rates and / or expansions of the Spectrum of action and / or an increase in the effect of the invention can be used Substances and agents, better plant growth, increased tolerance across from high or low temperatures, increased tolerance to dryness or against water or Soil salt content, increased flowering performance, facilitated harvest, acceleration of maturity, higher crop yields, higher quality and / or higher Nutritional value of Harvested products, higher Shelf life and / or workability of the harvested products possible, beyond the actually expected Go beyond effects.

The preferred plants or plant cultivars to be treated according to the invention include all plants which have obtained genetic material by the genetic engineering modification which gives these plants particularly advantageous valuable properties ("traits".) Examples of such properties are better plant growth. increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms, increased flowering efficiency, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, such as insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances. Examples of transgenic plants include the important crops such as cereals (wheat, rice), corn, soy, potato, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soy, potato, cotton and rapeseed should be highlighted. Traits that are particularly emphasized are the increased defense of the plants against insects by toxins formed in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (for example by the genes CryIA (a), CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CryIF and their combinations) are produced in the plants (hereinafter "Bt plants"). Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene). Each having the desired properties ( "traits") conferring genes can occur together in the transgenic plants in combination. Examples of "Bt plants" are maize varieties, cotton varieties, soya bean varieties and potato varieties may be mentioned that corn under the trade names YIELD GARD ^® (eg , Cotton, soy), KnockOut ^® (eg corn), StarLink ^® (for example maize), Bollgard ^® (cotton), NuCOTN ^® (cotton) and NewLeaf ^® (potato). Examples of herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties may be mentioned that against under the trade names Roundup Ready ^® (tolerance to glyphosate, for example maize, cotton, soya bean), Liberty Link ^® (tolerance to phosphinotricin, for example oilseed rape), IMI ^® (tolerance Imidazolinone) and STS ^® (tolerance to sulfonylureas such as corn) are sold. Herbicide-resistant (conventionally grown on herbicide tolerance) plants are also the varieties marketed under the name Clearfield ^® (eg corn) mentioned. Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.

The active compound combinations according to the invention can dependent on from their respective physical and / or chemical properties in the usual Formulations are transferred, like solutions, emulsions, Suspensions, powders, dusts, mousses, Pastes, soluble Powders, granules, aerosols, suspension emulsion concentrates, Active ingredient impregnated Natural and synthetic substances as well as ultrafine encapsulations in polymers Fabrics and in enveloping materials for seeds, as well as ULV cold and wet mist formulations.

These Formulations are prepared in a known manner, e.g. by Mixing the active substances or the active substance combinations with extenders, So liquid solvents liquefied under pressure Gases and / or solid carriers, optionally using surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.

in the Traps of using water as diluent may be e.g. also organic solvents as auxiliary solvent be used. As liquid solvent are essentially in question: aromatics, such as xylene, toluene or Alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic Hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, Alcohols, such as butanol or glycol, and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, as well as water.

With liquefied gaseous Extenders or carriers are such liquids meaning which are gaseous at normal temperature and under normal pressure, e.g. Aerosol propellants, such as butane, propane, nitrogen and carbon dioxide.

When solid carriers come into question: e.g. Ammonium salts and ground natural minerals, such as kaolins, Clay, talc, chalk, quartz, attapulgite, montmorillonite or Diatomaceous earth and ground synthetic minerals, such as fumed silica, alumina and silicates. As solid carriers come for granules in question: e.g. broken and fractionated natural rocks such as calcite, Marble, pumice, sepiolite, dolomite and synthetic granules inorganic and organic flours and granules of organic Material such as sawdust, Coconut shells, corn cobs and tobacco stems. As emulsifying and / or foam-producing Means are eligible: e.g. nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, Polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkylsulfonates, alkylsulfates, arylsulfonates as well as protein hydrolysates. Suitable dispersants are: e.g. Lignin liquors and methylcellulose.

It can in the formulations adhesives such as carboxymethylcellulose, natural and synthetic powdery, granular or latex-shaped Polymers such as gum arabic, polyvinyl alcohol, Polyvinyl acetate, as well as natural Phospholipids, such as cephalins and lecithins, and synthetic phospholipids. Further Additives can mineral and vegetable oils be.

It can Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, Ferrocyan blue and organic dyes such as alizarin, azo and Metal phthalocyanine dyes and trace nutrients, such as salts of iron, Manganese, boron, copper, cobalt, molybdenum and zinc are used.

Of the Active substance content prepared from the commercial formulations Application forms can vary widely. The drug concentration the forms of application for fighting animal pests such as insects and acarids can range from 0.0000001 up to 95% by weight of active ingredient, preferably between 0.0001 and 1 wt .-%. The application happens in a custom forms adapted to the application forms Wise.

The Formulations to combat undesirable Phytopathogenic fungi generally contain between 0.1 and 95% by weight of active ingredients, preferably between 0.5 and 90%.

The active compound combinations according to the invention can as such, in the form of their formulations or the ones prepared from them Use forms, such as ready-to-use solutions, emulsifiable concentrates, emulsions, Suspensions, wettable powder, soluble Powder, dusts and granules. The application happens in usual Way, e.g. by pouring (drenchen), drip irrigation, Spraying, spraying, Scattering, dusting, foaming, Brushing, spreading, dry pickling, wet pickling, wet pickling, slurry treatment, Encrusting etc.

The active compound combinations according to the invention can in commercial Formulations and in those prepared from these formulations Forms of use mixed with other active substances, such as insecticides, Attractants, sterilants, bactericides, acaricides, nematicides, Fungicides, growth regulators or herbicides.

At the Use of the active compound combinations according to the invention can the application rates within a larger range, depending on the type of application be varied. In the treatment of plant parts are the Application rates of active ingredient combination generally between 0.1 and 10 000 g / ha, preferably between 10 and 1000 g / ha. In the Seed treatment are the application rates of drug combination generally between 0.001 and 50 g per kilogram of seed, preferably between 0.01 and 10 g per kilogram of seed. In the treatment the soil are the application rates of drug combination in general between 0.1 and 10,000 g / ha, preferably between 1 and 5,000 g / ha.

The Drug combinations can as such, in the form of concentrates or general Formulations such as powders, granules, solutions, suspensions, emulsions or pastes are applied.

The mentioned formulations in a manner known per se, e.g. by mixing the active ingredients with at least one solvent or diluent, Emulsifier, dispersing and / or binding or fixing agent, water repellent, optionally siccative and UV stabilizers and optionally Dyes and pigments and other processing aids.

The good fungicidal action of the active compound combinations according to the invention is apparent from the examples below. While the individual active ingredients in the fungicidal action weaknesses show the combinations have an effect over a simple effect summation goes beyond.

One synergistic effect is always present in fungicides, though the fungicidal action of the active ingredient combinations is greater as the sum of the effects of the individually applied active ingredients.

The expected fungicidal activity for a given combination of two drugs can be calculated according to SR Colby (Calculating Synergistic and Antagonistic Responses of Herbicide Combinations, Weeds 1967, 15, 20-22) as follows:
If
X means the efficiency when using the active ingredient A at a rate of mg / ha,
Y means the efficiency when using the active ingredient B in an application rate of ng / ha, and
E means the efficiency when using the active compounds A and B in application rates of m and ng / ha,
then

there the efficiency is determined in%. It means 0% efficiency, which corresponds to that of the controller, while an efficiency of 100% means that no infestation is observed.

is the actual fungicidal action greater than calculated, the combination is over-additive in its effect, i.e. there is a synergistic effect. In this case, must the actual observed efficiency to be greater as the one from the above Formula calculated value for the expected efficiency (E).

The invention is illustrated by the following examples. However, the invention is not limited to the examples. Application Examples Example A: Phytophthora test (tomato) / protective Solvent: 24.5 parts by weight of acetone 24.5 parts by weight of dimethylacetamide emulsifier: 1 part by weight of alkyl-aryl-polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on The plants are treated with an aqueous spore suspension inoculated by Phytophthora infestans. The plants will be then in an incubation cabin at approx. 20 ° C and 100% relative humidity established.

3 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example B: Plasmopara test (vine) / protective Solvent: 24.5 parts by weight of acetone 24.5 parts by weight of dimethylacetamide emulsifier: 1 part by weight of alkyl-aryl-polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on The plants are treated with an aqueous spore suspension of Plasmopara viticola and then remain in for 1 day an incubation cabin at about 20 ° C and 100% relative humidity. Subsequently the plants are kept in the greenhouse for 4 days at approx. 21 ° C and approx. 90% humidity installed. The plants are then moistened and put in an incubation cabin for 1 day.

6 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example C: Podosphaera test (apple) / protective Solvent: 24.5 parts by weight of acetone 24.5 parts by weight of dimethylacetamide emulsifier: 1 part by weight of alkyl-aryl-polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on The plants are treated with an aqueous spore suspension of the apple mildew pathogen Podosphaera leucotricha. The Plants are then grown in the greenhouse at about 23 ° C and a relative humidity of about 70%.

10 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example D: Sphaerotheca test (cucumber) / protective Solvent: 24.5 parts by weight of acetone 24.5 parts by weight of dimethylacetamide emulsifier: 1 part by weight of alkyl-aryl-polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on The plants are treated with an aqueous spore suspension inoculated by Sphaerotheca fuliginea. The plants will be then at about 23 ° C and a relative humidity of about 70% in the greenhouse established.

7 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example E: Uncinula test (vine) / protective Solvent: 24.5 parts by weight of acetone 24.5 parts by weight of dimethylacetamide emulsifier: 1 part by weight of alkyl-aryl-polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on The plants are treated with an aqueous spore suspension inoculated by Uncinula necator. The plants are then in the greenhouse at about 23 ° C and a relative humidity of about 70%.

14 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example F: Phakopsora test (soy) / protective Solvent: 24.5 parts by weight of acetone 24.5 parts by weight of dimethylacetamide emulsifier: 1 part by weight of alkyl-aryl-polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on The plants are treated with an aqueous spore suspension of the roster pathogen Phakopsora pachyrhizi. The plants then be in the greenhouse at about 23 ° C and a relative humidity of about 90%.

10 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example G: Venturia test (apple) / protective Solvent: 24.5 parts by weight of acetone 24.5 parts by weight of dimethylacetamide emulsifier: 1 part by weight of alkyl-aryl-polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on The plants are treated with an aqueous conidia suspension of the apple scab pathogen Venturia inaequalis and remain inoculated then 1 day at about 20 ° C and 100% relative humidity in an incubation cabin.

The Plants are then grown in the greenhouse at about 21 ° C and a relative humidity of about 90%.

10 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example H: Alternaria test (tomato) / protective Solvent: 2 24.5 parts by weight of acetone 24.5 parts by weight of dimethylacetamide emulsifier: 1 part by weight of alkyl-aryl-polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on The plants are treated with an aqueous spore suspension inoculated by Alternaria solani. The plants are then in one Incubation cabin at approx. 20 ° C and 100% relative humidity.

3 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example I: Botrytis test (bean) / protective Solvent: 24.5 parts by weight of acetone 24.5 parts by weight of dimethylacetamide emulsifier: 1 part by weight of alkyl-aryl-polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on on each leaf are 2 small overgrown with Botrytis cinerea agar pieces hung up. The inoculated plants are darkened in a Chamber at about 20 ° C and 100% relative humidity.

2 days after the inoculation, the size of the infestation spots on the leaves is evaluated. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example J: Erysiphe test (barley) / protective Solvent: 50 parts by weight of N, N-dimethylacetamide emulsifier: 1.0 part by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam sprayed on protective activity you young plants with the preparation of active compound in the specified Application rate.

To The plants with spores of Erysiphe graminis f.sp. hordei pollinated.

The Plants are in a greenhouse at a temperature of about 20 ° C and a relative humidity of about 80% set up to to favor the development of mildew pustules.

7 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example K: Erysiphe test (wheat) / protective Solvent: 50 parts by weight of N, N-dimethylacetamide emulsifier: 1.0 part by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam sprayed on protective activity you young plants with the preparation of active compound in the specified Application rate.

To The plants with spores of Erysiphe graminis f.sp. tritici pollinated.

The Plants are in a greenhouse at a temperature of about 20 ° C and a relative humidity of about 80% set up to to favor the development of mildew pustules.

7 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example L: Fusarium culmorum test (wheat) / protective Solvent: 50 parts by weight of N, N-dimethylacetamide emulsifier: 1.0 part by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam sprayed on protective activity you young plants with the preparation of active compound in the specified Application rate.

To The spray coating is dried on the plants with a conidia suspension sprayed by Fusarium culmorum.

The Plants are in a greenhouse under translucent Incubation hoods at a temperature of about 20 ° C and a Relative humidity of about 100% set up.

4 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example M: Fusarium nivale (var. Majus) test (wheat) / protective Solvent: 50 parts by weight of N, N-dimethylacetamide emulsifier: 1.0 part by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on are the plants with a conidia suspension of Fusarium nivale (var. majus) sprayed.

The Plants are in a greenhouse under translucent Incubation hoods at a temperature of about 15 ° C and a Relative humidity of about 100% set up.

4 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example N: Fusarium graminearum test (barley) / protective Solvent: 50 parts by weight of N, N-dimethylacetamide emulsifier: 1.0 part by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on are the plants with a conidia suspension of Fusarium graminearum sprayed.

The Plants are in a greenhouse under translucent Incubation hoods at a temperature of about 15 ° C and a Relative humidity of 100%.

4 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example O: Lentosphaeria nodorum test (wheat) / protective Solvent: 50 parts by weight of N, N-dimethylacetamide emulsifier: 1.0 part by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on are the plants with a spore suspension of Leptosphaeria nodorum sprinkles. The plants remain for 48 hours at 20 ° C and 100% relative humidity in an incubation cabin.

The Plants are in a greenhouse at a temperature of about 15 ° C and a relative humidity of 80%.

10 Days after the inoculation the evaluation takes place. This means 0% an efficiency equal to that of the control while a Efficiency of 100% means that no infestation is observed.

Example P: Pseudocercosporella herpotrichoides test; R strain (wheat) / protective Solvent: 50 parts by weight of N, N-dimethylacetamide emulsifier: 1.0 part by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on The plants are grown on the stem base with spores of the R strain of Pseudocercosporella herpotrichoides inoculated.

The Plants are in a greenhouse at a temperature of about 10 ° C and a relative humidity of 80%.

21 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example Q: Pseudocercosporella herpotrichoides test; W strain (wheat) / protective Solvent: 50 parts by weight of N, N-dimethylacetamide emulsifier: 1.0 part by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on The plants are planted on the stem base with spores of the W strain of Pseudocercosporella herpotrichoides inoculated.

The Plants are in a greenhouse at a temperature of about 10 ° C and a relative humidity of 80%.

21 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example R: Puccinia test (wheat) / protective Solvent: 50 parts by weight of N, N-dimethylacetamide emulsifier: 1.0 part by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on are the plants with a conidia suspension of Puccinia recondita sprayed. The plants remain at 2000 and 100% relative humidity for 48 hours in an incubation cabin.

The Plants are then grown in a greenhouse at a temperature from about 20 ° C and a relative humidity of 80% set up to the Development of rust pustules to favor.

10 days after the inoculation the evaluation takes place. In this case, 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed. Example S: Pyrenophora teres test (barley) / protective Solvent: 50 parts by weight of N, N-dimethylacetamide emulsifier: 1.0 part by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with water to the desired concentration.

to exam Protective effectiveness of young plants with the preparation of active ingredient sprayed in the specified rate. After the spray coating has dried on are the plants with a conidia suspension of Pyrenophora teres sprayed. The plants remain for 48 hours at 20 ° C and 100% relative humidity in an incubation cabin.

The Plants are then grown in a greenhouse at a temperature from about 20 ° C and relative humidity of about 80%.

7 Days after the inoculation the evaluation takes place. This means 0% an efficiency equal to that of the control while a Efficiency of 100% means that no infestation is observed.

Claims (14)

Active substance combinations containing group (1) a herbicide selected from (1-1) glyphosate (1-2) glufosinate (1-3) glufosinate-ammonium and at least one active substance selected from the following groups (2) to (23) : Group (2) strobilurins selected from (2-1) azoxystrobin, (2-2) fluoxastrobin, (2-3) (2E) 2- (2 - {[6- (3-chloro-2-methylphenoxy) -5 -fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -N-methylethanamide, (2-4) trifloxystrobin, (2-5) (2E) 2- (methoxyimino) -N-methyl-2- ( 2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide, (2-6) (2E) 2- (methoxyimino) -N-methyl- 2- {2 - [(E) - ({1- [3- (trifluoromethyl) -hexyl] -ethoxy} -imino) -methyl] -phenyl} -ethanamide, (2-7) orysastrobin, (2-8) 5-methoxy-2- methyl-4- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro-3H-1,2,4- triazol-3-one, (2-9) kresoxim-methyl, (2-10) dimoxystrobin, (2-11) picoxystrobin, (2-12) pyraclostrobin, (2-13) metominostrobin, (2-14) (2E ) -2- {2 - [({[(1E) -1- (3 - {[(e) -1-fluoro -2-phenylvinyl] oxy} phenyl) ethylidenes] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylacetamide, (2-15) enestroburin, group (3) triazoles selected from (3-1) azaconazoles , (3-2) etaconazole, (3-3) propiconazole, (3-4) difenoconazole, (3-5) bromuconazole, (3-6) cyproconazole, (3-7) hexaconazole, (3-8) penconazole, (3-9) myclobutanil, (3-10) tetraconazoles, (3-11) flutriafol, (3-12) epoxiconazoles, (3-13) flusilazoles, (3-14) simeconazoles, (3-15) prothioconazole, ( 3-16) fenbuconazole, (3-17) tebuconazole, (3-18) ipconazole, (3-19) metconazole, (3-20) triticonazole, (3-21) bitertanol, (3-22) triadimenol, (3 -23) triadimefon, (3-24) fluquinconazole, (3-25) quinconazole, group (4) sulfenamides selected from (4-1) dichlofluanid, (4-2) tolylfluanid, group (5) valinamides selected from (5- 1) iprovalicarb, (5-2) N ¹ - [2- (4 - {[3- (4-chlorophenyl) -2-propynyl] oxy} -3-methoxyphenyl) ethyl] -N ² - (methylsulfonyl) -D -valinamide, (5-3) Benthiavalicarb, group (6) Carboxamides selected from (6-1) N- [2- (1,3 -Dimethylbutyl) phenyl] -1,3-dimethyl-1H-pyrazole-4-carboxamide, (6-2) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl 1H-pyrazole-4-carboxamide, (6-3) N- [2- (1,3-dimethyl-butyl) -phenyl] -5-chloro-1,3-dimethyl-1H-pyrazole-4-carboxamide, (6-4 ) 3- (Difluoromethyl) -N- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-1H-pyrazole-4-carboxamide, (6-5) 3- (trifluoromethyl) -N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (6-6) 3- (trifluoromethyl) -N- [2- (1,3-dimethylbutyl) phenyl ] -5-chloro-1-methyl-1H-pyrazole-4-carboxamide, (6-7) 1,3-dimethyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole 4-carboxamide, (6-8) 5-fluoro-1,3-dimethyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide, (6-9) 3 - (Difluoromethyl) -1-methyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide, (6-10) 3- (trifluoromethyl) -1-methyl-N - [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide, (6-11) 3- (trifluoromethyl) -5-fluoro-1-me ethyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide, (6-12) 3- (trifluoromethyl) -5-chloro-1-methyl-N- [2 - (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide, (6-13) N- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide, (6-14) 2-iodo-N- [2- (1,3,3-trimethylbutyl) phenyl] benzamide, (6-15) N- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide, ( 6-16) 2- (trifluoromethyl) -N- [2- (1,3,3-trimethylbutyl) phenyl] benzamide, (6-17) 2-chloro-N- (1,1,3-trimethyl-indane 4-yl) -nicotinamide, (6-18) boscalid, (6-19) furametpyr, (6-20) 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxylic acid (3-p-tolylthiophene -2-yl) -amide, (6-21) penthiopyrad, (6-22) N- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3 -carboxamide, (6-23) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4 carboxamide, (6-24) 3- (difluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1- Methyl-1H-pyrazole-4-carboxamide, (6-25) 3- (trifluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H-pyrazole-4-carboxamide, (6-26) N- (3 ', 4'-dichloro-1,1'-biphenyl- 2-yl) -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, (6-27) N- (4'-chloro-3'-fluoro-1,1'-biphenyl-2-yl) yl) -2-methyl-4- (trifluoromethyl) -1,3-thiazole-5-carboxamide, (6-28) N- (4'-chloro-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-29) N- (4'-bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2 -methyl-1,3-thiazole-5-carboxamide, (6-30) 4- (difluoromethyl) -2-methyl-N- [4 '- (trifluoromethyl) -1,1'-biphenyl-2-yl] - 1,3-thiazole-5-carboxamide, (6-31) N- (4'-iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole -5-carboxamide, (6-32) N- (4'-chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole -5-carboxamide, (6-33) ethaboxam, (6-34) fenhexamide, (6-35) carpropamide, (6-36) 2-chloro-4- (2-fluoro-2-methylpropionylamino) -N, N -dimethylbenzamide, (6-37) fluopicolides, (6-38) zoxamides, (6-39) 3,4-dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide, (6-40) carboxin, (6-41) Tiadinil, (6-42) Silthiofam, (6-43) N- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide, (6-44) N- {2- [3-Chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide, group (7): dithiocarbamates selected from (7-1) mancozeb, (7-2) maneb, (7 -3) metiram, (7-4) propineb, (7-5) thiram, (7-6) zineb, (7-7) ziram, group (8): acylalanines selected from (8-1) benalaxyl, (8 -2) furalaxyl, (8-3) metalaxyl, (8-4) metalaxyl-M, (8-5) benalaxyl-M, group (9): anilino-pyrimidines selected from (9-1) cyprodinil, (9- 2) mepanipyrim, (9-3) pyrimethanil, group (10): benzimidazoles selected from (10-1) 6-chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro -5H- [1,3] dioxolo [4,5-f] benzimidazole, (10-2) benomyl, (10-3) carbendazim, (10-4) chlorfenazoles, (10-5) fuberidazoles, (10-6 ) Thiabendazoles, group (11): carbamates selected from (11-1) diethofencarb, (11-2) propamocarb, (11-3) propamocarb-hydrochlorides, (11-4) propamocarb-fosetyl, group (12): dicarboximides selected out (12-1) captafol, (12-2) captan, (12-3) folpet, (12-4) iprodione, (12-5) procymidone, (12-6) vinclozolin, group (13): guanidines selected from (13-1) dodine, (13-2) guazatine, (13-3) iminoctadine triacetate, (13-4) iminoctadine tris (albesilate), group (14): imidazoles selected from (14-1) cyazofamide, (14 -2) prochloraz, (14-3) triazoxides, (14-4) pefurazoates, group (15): morpholines selected from (15-1) aldimorph, (15-2) tridemorph, (15-3) dodemorph, (15 -4) fenpropimorph, (15-5) dimethomorph, group (16): pyrroles selected from (16-1) fenpiclonil, (16-2) fludioxonil, (16-3) pyrrolonitrines, group (17): phosphonates selected from ( 17-1) Fosetyl-Al, (17-2) phosphonic acid, group (18): phenylethanamides (18-1) 2- (2,3-dihydro-1H-inden-5-yl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, (18-2) N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) -2- (5,6, 7,8-tetrahydronaphthalen-2-yl) acetamide, (18-3) 2- (4-chlorophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, (18-4) 2- (4-Bromophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, (18-5) 2- (4-methylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, (18-6) 2- (4-ethylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, group (19): Fungicides selected from (19-1) acibenzolar-S-methyl, (19-2) chlorothalonil, (19-3) cymoxanil, (19-4) edifenphos, (19-5) Famoxadone, (19-6) fluazinam, (19-7) copper oxychloride, (19-9) oxadixyl, (19-10) spiroxamine, (19-11) dithianone, (19-12) metrafenone, (19-13) fenamidone , (19-14) 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) one, (19-15) sample azoles, (19-16) isoprothiolanes, (19-17 ) Kaugamycin, (19-18) phthalides, (19-19) ferric zone, (19-20) tricyclazoles, (19-21) N - ({4 - [(cyclopropylamino) carbonyl] phenyl} sulfonyl) -2-methoxybenzamide, (19-22) 2- (4-chlorophenyl) -N- {2- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yne) 1-yloxy) acetamide, (19-23) proquinazide, (19-24) quinoxyfen, group (20): (thio) urea derivatives stops (20-1) pencycuron, (20-2) thiophanate-methyl, (20-3) thiophanate-ethyl, group (21): amides selected from (21-1) fenoxanil, (21-2) diclocymet, group (22 ): Triazolopyrimidines selected from (22-1) 5-chloro-N - [(1S) -2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2, 4] triazolo [1,5-a] pyrimidin-7-amine, (22-2) 5-chloro-N - [(1R) -1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine, (22-3) 5-chloro-6- (2-chloro-6-fluorophenyl) -7- (4-methylpiperidine-1 -yl) [1,2,4] triazolo [1,5-a] pyrimidine, (22-4) 5-chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidine-1) yl) [1,2,4] triazolo [1,5-a] pyrimidine, group (23): iodochromones selected from (23-1) 2-butoxy-6-iodo-3-propyl-benzopyran-4-one, (23-2) 2-Ethoxy-6-iodo-3-propyl-benzopyran-4-one, (23-3) 6-iodo-2-propoxy-3-propyl-benzopyran-4-one, (23-4 ) 2-But-2-ynyloxy-6-iodo-3-propylbenzopyran-4-one, (23-5) 6-iodo-2- (1-methyl-butoary) -3-propyl-benzopyran-4-one, (23-6) 2-But-3-enyloxy-6-iodobenzopyran-4-one, (23-7) 3-butyl-6-iodo-2-isopropoxy-benz opyran-4-one. Active substance combinations according to Claim 1, containing (1-1) Glyphosate and at least one fungicidal active ingredient of the groups (2) to (23). Active substance combinations according to Claim 1, containing (1-2) Glufosinate and at least one fungicidal active substance of the groups (2) to (23). Active substance combinations according to Claim 1, containing (1-3) Glufosinate-ammonium and at least one fungicidal active substance of Groups (2) to (23). Use of active compound combinations according to claim 1 to combat of unwanted phytopathogenic fungi. Use of active compound combinations according to claim 1 for the treatment of transgenic plants. Use according to claim 6, characterized in that the treated transgenic plants against Glyphosate, glufosinate or glufosinate-ammonium are resistant. Method for fighting of unwanted phytopathogenic fungi, characterized in that one drug combinations according to claim 1 on the unwanted phytopathogenic fungi and / or their habitat and / or seed comprises applying. Process for producing fungicidal agents, characterized in that one drug combinations according to claim 1 mixed with extenders and / or surfactants. Mordant containing an active ingredient combination according to claim 1. Use of active compound combinations according to claim 1 for the treatment of seeds. Use of active compound combinations according to claim 1 for the treatment of seeds of transgenic plants. Method for pickling seeds, characterized that an active ingredient combination according to claim 1 to the seed applies. Method of pickling transgenic seeds, thereby characterized in that a combination of active ingredients according to claim 1 on the transgenic seed.