ES380609A1 - NEW 4-SUBSTITUTED AMINO-5,7-DINITRO-2-(alpha,alpha-DIFLUOROALKYL)-BENZIMIDAZOLE COMPOUNDS HAVING INSECTICIDAL ACTIVITY, AND PROCESS FOR PREPARING SAME - Google Patents

NEW 4-SUBSTITUTED AMINO-5,7-DINITRO-2-(alpha,alpha-DIFLUOROALKYL)-BENZIMIDAZOLE COMPOUNDS HAVING INSECTICIDAL ACTIVITY, AND PROCESS FOR PREPARING SAME

Info

Publication number
ES380609A1
ES380609A1 ES380609A ES380609A ES380609A1 ES 380609 A1 ES380609 A1 ES 380609A1 ES 380609 A ES380609 A ES 380609A ES 380609 A ES380609 A ES 380609A ES 380609 A1 ES380609 A1 ES 380609A1
Authority
ES
Spain
Prior art keywords
alpha
dinitro
chloro
reaction
benzimidazole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES380609A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eli Lilly and Co
Original Assignee
Eli Lilly and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eli Lilly and Co filed Critical Eli Lilly and Co
Publication of ES380609A1 publication Critical patent/ES380609A1/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D235/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C07D235/04Benzimidazoles; Hydrogenated benzimidazoles
    • C07D235/06Benzimidazoles; Hydrogenated benzimidazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2
    • C07D235/10Radicals substituted by halogen atoms or nitro radicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Compounds of formula and their 4,6-dinitro-8-substituted-amino tautomers, wherein y is hydrogen, chlorine, fluorine, -CF 3 or -CF 2 CF 3 and the group -NR0R1 is. one of many specified secondary or tertiary, optionally cyclic, amino groups, and alkali metal and alkaline earth metal salts thereof, are prepared by reaction of the corresponding chlorobenzimidazole with an amine, followed, if desired, by reaction with an alkali metal alkoxide or alkaline earth metal oxide. 4 - Chloro - 5,7 - dinitro - 2 - trifluoromethyl benzimidazole is prepared by reaction of 3-chloro o-phenylene diamine with trifluoroacetic acid to give 4 - chloro 2 - trifluoromethyl - benzimidazole, followed by nitration. The products of the invention have insecticidal, arachnicidal and nematocidal activity and may be used in pesticidal compositions or incorporated into inks, adhesives, soaps, polymers, cutting oils, oil or latex paints, textiles, cellulosic materials, grain, wood, lumber or seeds.
ES380609A 1969-06-16 1970-06-10 NEW 4-SUBSTITUTED AMINO-5,7-DINITRO-2-(alpha,alpha-DIFLUOROALKYL)-BENZIMIDAZOLE COMPOUNDS HAVING INSECTICIDAL ACTIVITY, AND PROCESS FOR PREPARING SAME Expired ES380609A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US83368569A 1969-06-16 1969-06-16

Publications (1)

Publication Number Publication Date
ES380609A1 true ES380609A1 (en) 1973-04-01

Family

ID=25265017

Family Applications (1)

Application Number Title Priority Date Filing Date
ES380609A Expired ES380609A1 (en) 1969-06-16 1970-06-10 NEW 4-SUBSTITUTED AMINO-5,7-DINITRO-2-(alpha,alpha-DIFLUOROALKYL)-BENZIMIDAZOLE COMPOUNDS HAVING INSECTICIDAL ACTIVITY, AND PROCESS FOR PREPARING SAME

Country Status (6)

Country Link
JP (1) JPS4916938B1 (en)
CH (1) CH554345A (en)
DE (1) DE2029753A1 (en)
ES (1) ES380609A1 (en)
FR (1) FR2052666A5 (en)
GB (1) GB1272208A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8273764B2 (en) 2009-04-28 2012-09-25 Sumitomo Chemical Company, Limited Fused heterocyclic compounds and use thereof
EP2878198B1 (en) 2013-11-29 2016-09-14 Flügel GmbH Method for attraction of cambiophagous, xylophagous and/or myzetophagous insects

Also Published As

Publication number Publication date
DE2029753A1 (en) 1970-12-17
FR2052666A5 (en) 1971-04-09
JPS4916938B1 (en) 1974-04-25
GB1272208A (en) 1972-04-26
CH554345A (en) 1974-09-30

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